CN106431366A - Desert-like glazed porcelain prepared by utilizing quartz tailings and manufacturing process - Google Patents
Desert-like glazed porcelain prepared by utilizing quartz tailings and manufacturing process Download PDFInfo
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- CN106431366A CN106431366A CN201610786279.XA CN201610786279A CN106431366A CN 106431366 A CN106431366 A CN 106431366A CN 201610786279 A CN201610786279 A CN 201610786279A CN 106431366 A CN106431366 A CN 106431366A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention belongs to the field of ceramic manufacturing, and specifically relates to a desert-like glazed porcelain prepared by utilizing quartz tailings and a manufacturing process. The desert-like glazed porcelain prepared by utilizing the quartz tailings provided by the invention has the following characteristics: the glazed surface has base colors of yellowish brown and tawny; granulated quartz crystalline particles are uniformly distributed on the glazed surface; the handfeel to the glazed surface is harsh and forms rough and retro artistic effects with the base colors of the glazed surface; and a feeling similar to a desert and a beach is given to people. The desert-like glazed porcelain uses cheap raw materials; the level of a product is improved through unique artistic effects; and the competitiveness of the product is enhanced. With the process for preparation of the desert-like glazed porcelain by using the quartz tailings provided by the invention, calcined quartz tailings are introduced as a raw material; the particle size and the number of the quartz crystalline particles can be adjusted through the formula and the thickness of a glazing material; the sintering temperature of the quartz crystalline particles is low, so energy consumption is reduced; and a great amount of the quartz tailings are introduced as the raw material of a green body and the glazing material, so significant social and environment-protection significances are achieved, and the development mode of urban recycling economy is met.
Description
Technical field
The invention belongs to ceramic manufacture field is and in particular to a kind of prepare desert glaze porcelain using Quartz Tails and make work
Skill.
Background technology
Effect in our ceramic industries for the quartz is extremely important, inside ceramic common element, SiO2Comparatively it is
Using purity highest and the generally the least expensive one kind of price, no matter being therefore in base substrate or glaze, producing substantially acceptable
In the case of, often substantial amounts of be used quartz as raw material.
Developing rapidly with ceramics, quartz is a large amount of to be exploited and utilizes, the annual discarded Quartz Tails producing nearly hundred tons,
The situation that the mine tailing of mining glass is arbitrarily stacked is serious, there is production safety and environmental protection accident potential, had a strong impact on agricultural and
The safety of people's lives and properties, greatly wastes mineral resources, destroys ecological environment again.
In existing ceramic production technology, the addition of quartz must strictly control, and traditional ceramic effect is thought, glaze paint
Surface needs smooth, smooth glazing effect, and substantial amounts of using quartzy or siliceous high raw material, base substrate and glaze can be led to
The substantial amounts of residual quartz crystalline phase of middle appearance, covers the color of chinaware body itself, the effect of impact glaze paint.Therefore, if can profit
Use quartzy tail, and suitably increase consumption in pottery for the Quartz Tails, the porcelain producing effect unique is to improve ceramic product
Added value, there is positive economic and social benefit.
Content of the invention
In order to solve the above problems, the invention provides a kind of prepare desert glaze porcelain using Quartz Tails and make work
Skill.
Using Quartz Tails preparation desert glaze porcelain, blank stock is as follows in parts by weight:Quartz Tails 40-50 part,
Flyash 20-30 part, white clouds soil 10-15, bentonite 10-15 part, clay 5-10 part, binding agent 1-5 part;Glaze raw material is according to weight
Amount part meter is as follows:Quartz Tails 30-40 part, clear frit 10-15 part, yellow colorant 10-15 part, potassium feldspar 5-10, brium carbonate
5-10 part, dry powder 5-10 part, lime stone 5-10 part, zinc oxide 5-10 part, copper 1-3 part, manganese 1-3 part, iron 1-3 part.
Optimize, blank stock is as follows in parts by weight:46 parts of Quartz Tails, 21 parts of flyash, white clouds soil 13, swelling
12 parts of soil, 6 parts of clay, 2 parts of binding agent.
Optimize, glaze raw material is as follows in parts by weight:36 parts of Quartz Tails, 13 parts of clear frit, yellow colorant 12
Part, potassium feldspar 6,6 parts of brium carbonate, 5 parts of dry powder, 7 parts of lime stone, 6 parts of zinc oxide, 2 parts of copper, 3 parts of manganese, 3 parts of iron.
Optimize, blank stock is as follows in parts by weight:48 parts of Quartz Tails, 23 parts of flyash, white clouds soil 10, swelling
11 parts of soil, 5 parts of clay, 3 parts of binding agent.
Optimize, glaze raw material is as follows in parts by weight:Glaze raw material is as follows in parts by weight:Quartz Tails 33
Part, 12 parts of clear frit, 14 parts of yellow colorant, 8 parts of potassium feldspar, 7 parts of brium carbonate, dry powder 8,6 parts of lime stone, 7 parts of zinc oxide,
2 parts of copper, 1 part of manganese, 2 parts of iron.
Optimize, blank stock is as follows in parts by weight:42 parts of Quartz Tails, 26 parts of flyash, white clouds soil 12, swelling
12 parts of soil, 7 parts of clay, 1 part of binding agent.
Optimize, glaze raw material is as follows in parts by weight:39 parts of Quartz Tails, 15 parts of clear frit, yellow colorant 10
Part, potassium feldspar 5,8 parts of brium carbonate, 6 parts of dry powder, 5 parts of lime stone, 5 parts of zinc oxide, 3 parts of copper, 3 parts of manganese, 1 part of iron.
Prepare the manufacture craft of desert glaze porcelain using Quartz Tails it is characterised in that comprising the following steps:
Step 1, Quartz Tails are dried, pulverize, sieve, and obtain Quartz Tails powder;
Step 2, the Quartz Tails powder that step 1 is obtained is calcined, and obtains calcining quartz mine tailing powder;
Step 3, according to composition of raw materials weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, prepared blank slurry, incite somebody to action
Ceramic body made by blank slurry, puts to drying;
Step 4, according to glaze formula weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, sieve, prepared glaze slip;
Step 5, step 4 is obtained glaze slip and uniformly imposes on ceramic body surface;
Step 6, after ceramic blank drying, kiln-firing, firing temperature is 1200-1250 DEG C, obtains desert glaze porcelain.
Further, in step one, Quartz Tails powder calcining heat is 575-600 DEG C.
Further, during wet ball mill, material:Ball:Water=1:0.8:1.2, the time is 5-10min, crosses 100 mesh sieves.
Seen from the above description, the utilization Quartz Tails preparation desert glaze porcelain that the present invention provides, its glaze paint have the colour of loess,
Filemot background color, is uniformly distributed with granular quartz crystal particle in glaze paint, and glaze paint feel is coarse and glaze paint background color
Form rough, pseudo-classic artistic effect, give similar to the impression as desert, sandy beach, this kind of desert glaze porcelain is using at a low price
Raw material, improve the class of product by unique artistic effect, improving product competitiveness;
This kind utilizes Quartz Tails preparation desert glaze porcelain, introduces the Quartz Tails after calcining as raw material, quartz crystal
Particle diameter and quantity can be adjusted by the formula of glaze and thickness, its firing temperature is low, reduce energy consumption, introduce substantial amounts of
Quartz Tails, as the raw material of base substrate, glaze, have great society, environment protection significance, meet Development Models of Circular Economy in Urban.
Specific embodiment
In order to be better understood from technical scheme, below the embodiment that provides of the peering present invention.
The invention provides a kind of, using Quartz Tails preparation desert glaze porcelain, blank stock is as follows in parts by weight:
Quartz Tails 40-50 part, flyash 20-30 part, white clouds soil 10-15, bentonite 10-15 part, clay 5-10 part, binding agent 1-5
Part;
Glaze raw material is as follows in parts by weight:Quartz Tails 30-40 part, clear frit 10-15 part, yellow colorant 10-
15 parts, potassium feldspar 5-10, brium carbonate 5-10 part, dry powder 5-10 part, lime stone 5-10 part, zinc oxide 5-10 part, copper 1-3 part,
Manganese 1-3 part, iron 1-3 part.
Specific embodiment one:
A kind of, using Quartz Tails preparation desert glaze porcelain, blank stock is as follows in parts by weight:Quartz Tails 46
Part, 21 parts of flyash, white clouds soil 13,12 parts of bentonite, 6 parts of clay, 2 parts of binding agent;
Glaze raw material is as follows in parts by weight:36 parts of Quartz Tails, 13 parts of clear frit, 12 parts of yellow colorant, potassium are long
Stone 6,6 parts of brium carbonate, 5 parts of dry powder, 7 parts of lime stone, 6 parts of zinc oxide, 2 parts of copper, 3 parts of manganese, 3 parts of iron.
Specific embodiment two:
A kind of, using Quartz Tails preparation desert glaze porcelain, blank stock is as follows in parts by weight:Quartz Tails 48
Part, 23 parts of flyash, white clouds soil 10,11 parts of bentonite, 5 parts of clay, 3 parts of binding agent.
Glaze raw material is as follows in parts by weight:Glaze raw material is as follows in parts by weight:33 parts of Quartz Tails, transparent molten
12 parts of block, 14 parts of yellow colorant, 8 parts of potassium feldspar, 7 parts of brium carbonate, dry powder 8,6 parts of lime stone, 7 parts of zinc oxide, 2 parts of copper, manganese 1
Part, 2 parts of iron.
Specific embodiment three:
A kind of, using Quartz Tails preparation desert glaze porcelain, blank stock is as follows in parts by weight:Quartz Tails 42
Part, 26 parts of flyash, white clouds soil 12,12 parts of bentonite, 7 parts of clay, 1 part of binding agent;
Glaze raw material is as follows in parts by weight:39 parts of Quartz Tails, 15 parts of clear frit, 10 parts of yellow colorant, potassium are long
Stone 5,8 parts of brium carbonate, 6 parts of dry powder, 5 parts of lime stone, 5 parts of zinc oxide, 3 parts of copper, 3 parts of manganese, 1 part of iron.
Prepare the manufacture craft of desert glaze porcelain using Quartz Tails, make the desert glaze described in specific embodiment one to three
Porcelain, comprises the following steps:
Step 1, Quartz Tails are dried, pulverize, sieve, and obtain Quartz Tails powder;
Step 2, the Quartz Tails powder that step 1 is obtained is calcined, and obtains calcining quartz mine tailing powder, Quartz Tails powder
Calcining heat is 575-600 DEG C;
Step 3, according to composition of raw materials weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, and prepared blank slurry is wet
During ball milling, material:Ball:Water=1:1.5:0.8, the time be 30min, cross 250 mesh sieves, blank slurry is made ceramic body, put to
It is dried;
Step 4, according to glaze formula weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, sieve, prepared glaze slip,
During wet ball mill, material:Ball:Water=1:0.8:1.2, the time is 5-10min, crosses 100 mesh sieves;
Step 5, step 4 is obtained glaze slip and uniformly imposes on ceramic body surface;
Step 6, after ceramic blank drying, kiln-firing, firing temperature is 1200-1250 DEG C, obtains desert glaze porcelain.
Above-mentioned utilization Quartz Tails preparation desert glaze porcelain, its glaze paint has the colour of loess, filemot background color, in glaze paint all
Even is distributed with granular quartz crystal particle, and glaze paint feel is coarse and glaze paint background color forms rough, pseudo-classic art effect
Really, give similar to the impression as desert, sandy beach, this kind of desert glaze porcelain uses the raw material of low price, by unique art
Effect improves the class of product, improving product competitiveness;
This kind utilizes Quartz Tails preparation desert glaze porcelain, introduces the Quartz Tails after calcining as raw material, quartz crystal
Particle diameter and quantity can be adjusted by the formula of glaze and thickness, its firing temperature is low, reduce energy consumption, introduce substantial amounts of
Quartz Tails, as the raw material of base substrate, glaze, have great society, environment protection significance, meet Development Models of Circular Economy in Urban.
The above, only present pre-ferred embodiments, therefore can not with this limit the present invention enforcement scope, that is, according to
Equivalence changes and modification that scope of the present invention patent and description are made, all should still belong to the model that patent of the present invention covers
In enclosing.
Claims (10)
1. utilize Quartz Tails preparation desert glaze porcelain it is characterised in that
Blank stock is as follows in parts by weight:Quartz Tails 40-50 part, flyash 20-30 part, white clouds soil 10-15, bentonite
10-15 part, clay 5-10 part, binding agent 1-5 part;
Glaze raw material is as follows in parts by weight:Quartz Tails 30-40 part, clear frit 10-15 part, yellow colorant 10-15 part,
Potassium feldspar 5-10, brium carbonate 5-10 part, dry powder 5-10 part, lime stone 5-10 part, zinc oxide 5-10 part, copper 1-3 part, manganese 1-3
Part, iron 1-3 part.
2. utilization Quartz Tails preparation desert glaze porcelain according to claim 1 is it is characterised in that described blank stock is pressed
As follows according to weight portion meter:46 parts of Quartz Tails, 21 parts of flyash, white clouds soil 13,12 parts of bentonite, 6 parts of clay, 2 parts of binding agent.
3. utilization Quartz Tails preparation desert glaze porcelain according to claim 1 and 2 is it is characterised in that described glaze is former
Material is as follows in parts by weight:36 parts of Quartz Tails, 13 parts of clear frit, 12 parts of yellow colorant, potassium feldspar 6,6 parts of brium carbonate,
5 parts of dry powder, 7 parts of lime stone, 6 parts of zinc oxide, 2 parts of copper, 3 parts of manganese, 3 parts of iron.
4. utilization Quartz Tails preparation desert glaze porcelain according to claim 1 is it is characterised in that described blank stock is pressed
As follows according to weight portion meter:48 parts of Quartz Tails, 23 parts of flyash, white clouds soil 10,11 parts of bentonite, 5 parts of clay, 3 parts of binding agent.
5. the utilization Quartz Tails preparation desert glaze porcelain according to claim 1 or 4 is it is characterised in that described glaze is former
Material is as follows in parts by weight:Glaze raw material is as follows in parts by weight:33 parts of Quartz Tails, 12 parts of clear frit, yellow color
14 parts of material, 8 parts of potassium feldspar, 7 parts of brium carbonate, dry powder 8,6 parts of lime stone, 7 parts of zinc oxide, 2 parts of copper, 1 part of manganese, 2 parts of iron.
6. utilization Quartz Tails preparation desert glaze porcelain according to claim 1 is it is characterised in that described blank stock is pressed
As follows according to weight portion meter:42 parts of Quartz Tails, 26 parts of flyash, white clouds soil 12,12 parts of bentonite, 7 parts of clay, 1 part of binding agent.
7. the utilization Quartz Tails preparation desert glaze porcelain according to claim 1 or 6 is it is characterised in that described glaze is former
Material is as follows in parts by weight:39 parts of Quartz Tails, 15 parts of clear frit, 10 parts of yellow colorant, potassium feldspar 5,8 parts of brium carbonate,
6 parts of dry powder, 5 parts of lime stone, 5 parts of zinc oxide, 3 parts of copper, 3 parts of manganese, 1 part of iron.
8. prepare the manufacture craft of desert glaze porcelain it is characterised in that comprising the following steps using Quartz Tails:
Step 1, Quartz Tails are dried, pulverize, sieve, and obtain Quartz Tails powder;
Step 2, the Quartz Tails powder that step 1 is obtained is calcined, and obtains calcining quartz mine tailing powder;
Step 3, according to composition of raw materials weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, prepared blank slurry, by blank
Ceramic body made by slurry, puts to drying;
Step 4, according to glaze formula weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, sieve, prepared glaze slip;
Step 5, step 4 is obtained glaze slip and uniformly imposes on ceramic body surface;
Step 6, after ceramic blank drying, kiln-firing, firing temperature is 1200-1250 DEG C, obtains desert glaze porcelain.
9. utilization Quartz Tails according to claim 8 prepare desert glaze porcelain manufacture craft it is characterised in that:Described
In step one, Quartz Tails powder calcining heat is 575-600 DEG C.
10. utilize according to claim 8 Quartz Tails prepare desert glaze porcelain manufacture craft it is characterised in that:Described
During wet ball mill, material:Ball:Water=1:0.8:1.2, the time is 5-10min, crosses 100 mesh sieves.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109020485A (en) * | 2018-09-14 | 2018-12-18 | 福建省德化明源陶瓷有限公司 | A kind of release iron hoop protects desert white pottery porcelain and its preparation process |
CN110452020A (en) * | 2019-08-22 | 2019-11-15 | 福建省太古陶瓷有限责任公司 | It is a kind of to introduce black matrix flash glaze ceramics and its manufacture craft prepared by quartz mine tailings |
CN116174102A (en) * | 2022-12-08 | 2023-05-30 | 龙泉市光武青瓷文化有限公司 | Desert glazed porcelain production process and processing equipment thereof |
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CN104150965A (en) * | 2014-08-07 | 2014-11-19 | 福建省太古陶瓷有限责任公司 | Copper red glaze formula and manufacturing process of copper red glaze porcelain |
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CN102417343A (en) * | 2011-08-24 | 2012-04-18 | 重庆歌德陶瓷玛赛克制造有限公司 | Sandstone-like porcelain exterior wall tile and production method thereof |
CN104150965A (en) * | 2014-08-07 | 2014-11-19 | 福建省太古陶瓷有限责任公司 | Copper red glaze formula and manufacturing process of copper red glaze porcelain |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109020485A (en) * | 2018-09-14 | 2018-12-18 | 福建省德化明源陶瓷有限公司 | A kind of release iron hoop protects desert white pottery porcelain and its preparation process |
CN109020485B (en) * | 2018-09-14 | 2021-04-20 | 福建省德化明源陶瓷有限公司 | Iron-free environment-friendly desert white ceramic and preparation process thereof |
CN110452020A (en) * | 2019-08-22 | 2019-11-15 | 福建省太古陶瓷有限责任公司 | It is a kind of to introduce black matrix flash glaze ceramics and its manufacture craft prepared by quartz mine tailings |
CN110452020B (en) * | 2019-08-22 | 2023-09-01 | 福建省太古陶瓷有限责任公司 | Black matrix flash glaze ceramic prepared by introducing quartz ore tailings and manufacturing process thereof |
CN116174102A (en) * | 2022-12-08 | 2023-05-30 | 龙泉市光武青瓷文化有限公司 | Desert glazed porcelain production process and processing equipment thereof |
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Application publication date: 20170222 |