CN102351988B - 一种自交联聚合物表面施胶剂及其制备方法 - Google Patents
一种自交联聚合物表面施胶剂及其制备方法 Download PDFInfo
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- CN102351988B CN102351988B CN 201110215607 CN201110215607A CN102351988B CN 102351988 B CN102351988 B CN 102351988B CN 201110215607 CN201110215607 CN 201110215607 CN 201110215607 A CN201110215607 A CN 201110215607A CN 102351988 B CN102351988 B CN 102351988B
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- stearyl alcohol
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- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims abstract description 88
- -1 ester octadecanol ester Chemical class 0.000 claims abstract description 52
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 49
- 239000003999 initiator Substances 0.000 claims abstract description 45
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000011976 maleic acid Substances 0.000 claims abstract description 34
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 34
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 19
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims abstract description 19
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims abstract description 17
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims abstract description 17
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims abstract description 17
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000000178 monomer Substances 0.000 claims description 72
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 claims description 54
- 238000006243 chemical reaction Methods 0.000 claims description 43
- 229950007687 macrogol ester Drugs 0.000 claims description 32
- 238000009413 insulation Methods 0.000 claims description 28
- 239000003643 water by type Substances 0.000 claims description 24
- 239000008367 deionised water Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
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- 235000019394 potassium persulphate Nutrition 0.000 claims description 16
- 238000007599 discharging Methods 0.000 claims description 14
- 238000010792 warming Methods 0.000 claims description 14
- 235000019270 ammonium chloride Nutrition 0.000 claims description 12
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004159 Potassium persulphate Substances 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
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- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- FSAJWMJJORKPKS-UHFFFAOYSA-N octadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C=C FSAJWMJJORKPKS-UHFFFAOYSA-N 0.000 abstract 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 abstract 1
- 229940117958 vinyl acetate Drugs 0.000 abstract 1
- 239000000123 paper Substances 0.000 description 69
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- 241000209094 Oryza Species 0.000 description 21
- 235000007164 Oryza sativa Nutrition 0.000 description 21
- 235000009566 rice Nutrition 0.000 description 21
- 239000003995 emulsifying agent Substances 0.000 description 17
- 239000000839 emulsion Substances 0.000 description 14
- 238000004519 manufacturing process Methods 0.000 description 14
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000010791 domestic waste Substances 0.000 description 8
- 229920002472 Starch Polymers 0.000 description 7
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- 239000008107 starch Substances 0.000 description 7
- 235000019698 starch Nutrition 0.000 description 7
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- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
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- 230000002085 persistent effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
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- Macromonomer-Based Addition Polymer (AREA)
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Abstract
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Claims (7)
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Application Number | Priority Date | Filing Date | Title |
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CN 201110215607 CN102351988B (zh) | 2011-07-29 | 2011-07-29 | 一种自交联聚合物表面施胶剂及其制备方法 |
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CN 201110215607 CN102351988B (zh) | 2011-07-29 | 2011-07-29 | 一种自交联聚合物表面施胶剂及其制备方法 |
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CN102351988A CN102351988A (zh) | 2012-02-15 |
CN102351988B true CN102351988B (zh) | 2013-06-19 |
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CN 201110215607 Expired - Fee Related CN102351988B (zh) | 2011-07-29 | 2011-07-29 | 一种自交联聚合物表面施胶剂及其制备方法 |
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CN101871183B (zh) * | 2010-05-11 | 2011-09-14 | 陕西科技大学 | 一种反应型乳化剂两性苯丙表面施胶剂及其制备方法 |
CN101831839B (zh) * | 2010-05-11 | 2011-12-28 | 陕西科技大学 | 一种反应型乳化剂苯丙表面施胶剂及其制备方法 |
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Effective date of registration: 20201202 Address after: No.6 Xinqiao West Road, Jingjiang City, Taizhou City, Jiangsu Province Patentee after: JINGJIANG SHENJU VESSEL MANUFACTURING Co.,Ltd. Address before: 808, floor 8, building B, business center, gangzhilong science and Technology Park, No. 6, Qinglong Road, Qinghua community, Longhua street, Longhua District, Shenzhen City, Guangdong Province Patentee before: Shenzhen Pengbo Information Technology Co.,Ltd. Effective date of registration: 20201202 Address after: 808, floor 8, building B, business center, gangzhilong science and Technology Park, No. 6, Qinglong Road, Qinghua community, Longhua street, Longhua District, Shenzhen City, Guangdong Province Patentee after: Shenzhen Pengbo Information Technology Co.,Ltd. Address before: 710021 Shaanxi province Xi'an Weiyang university campus of Shaanxi University of Science and Technology Patentee before: SHAANXI University OF SCIENCE & TECHNOLOGY |
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Granted publication date: 20130619 |