CN102318639A - Preparation and application with compound Alevaire of sterilization and insecticidal function - Google Patents

Preparation and application with compound Alevaire of sterilization and insecticidal function Download PDF

Info

Publication number
CN102318639A
CN102318639A CN201110124064A CN201110124064A CN102318639A CN 102318639 A CN102318639 A CN 102318639A CN 201110124064 A CN201110124064 A CN 201110124064A CN 201110124064 A CN201110124064 A CN 201110124064A CN 102318639 A CN102318639 A CN 102318639A
Authority
CN
China
Prior art keywords
alevaire
mixture
mixed
compound
mass percent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201110124064A
Other languages
Chinese (zh)
Inventor
李新建
李新旺
Original Assignee
覃终
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 覃终 filed Critical 覃终
Priority to CN201110124064A priority Critical patent/CN102318639A/en
Publication of CN102318639A publication Critical patent/CN102318639A/en
Pending legal-status Critical Current

Links

Abstract

The present invention is preparation and the application with compound Alevaire of sterilization and insecticidal function, and its mass percent component is: sanitizing composition: 0.01 ~ 10%; Pesticidal combination: 0.1 ~ 10%; Surfactant: 10 ~ 30%; Alevaire: 0 ~ 30%; Water: surplus.The object of the invention comprises provides above-mentioned preparation with compound Alevaire of sterilization and insecticidal function: Pesticidal combination and surfactant were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring; Said mixture matter A is mixed stirring be mixed with compounding substances B in 1 hour with the water of above-mentioned mass percent 50%; Sanitizing composition and Alevaire mixed with the water of above-mentioned mass percent remaining 50% to stir by above-mentioned mass percent be mixed with compounding substances C in 1 hour; Said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.The present invention has people, animal harmless, can not produce harmful substance, do not pollute the environment, and safety and environmental protection, non-stimulated to skin and mucosa; Article and fabric are not had corrosivity, have no irritating odor, colourless, do not receive the influence of environment, organic matter, acid, alkali and other physics, chemical factor, characteristics such as persistence is long, and cost is low.

Description

Preparation and application with compound Alevaire of sterilization and insecticidal function
Technical field
The invention belongs to sterilization and desinsection product scope; Relate to compound Alevaire, especially contain of preparation and the application of the composition of sanitizing composition, Pesticidal combination, surfactant, Alevaire as compound Alevaire with sterilization and insecticidal function with sterilization and insecticidal function.
Background technology
In the present common infectious disease of WHO report; There is 1/3rd infectious disease to cause, like the plague, cholera, dengue fever, bird flu, Hemorrhagic fever, Japanese Type-B encephalitis, kala-azar, malaria, schistosomiasis, influenza etc. by pests such as insects which are carriers of diseases.For a long time, in practical application, but be divided into disinfectant and insecticide to PCO, the former belongs to the Ministry of Public Health and examines management, and the latter belongs to the Ministry of Agriculture and examines management, has been divided into two big types from what system and management were thought.But sterilization is inseparable with desinsection when the health and epidemic prevention of disease prevention and cure and Public Health Emergencies; So put into different categories and can cause the back desinsection of in actual application, sterilizing earlier; Not only the wasting manpower and material resources has increased use cost, also can exist sterilization and insecticidal effect undesirable.
For a long time, extensively adopt chlorine-containing disinfectant, brominated disinfectant etc. in the sterile products field always.Employed insecticide is contact insecticide and fumigant in control health and pest field.
The disinfection principle of chlorine-containing disinfectant is based on its hypochlorous sterilizing mechanisms through generating behind the hydrolysis in water.But in long-term use, find following shortcoming:
1, the pH value narrow range of its effective killing microorganisms, its minimum dissociation reaction occurs in the pH7.0 place, and when the pH value continued to raise, hypochlorous acid was dissociated into the hypochlorite ion of the power extreme difference of killing livestock easily in a large number.Because hypochlorite ion has negative electrical charge, when its during near microorganism, receive the anion exclusion of load on the microorganism wall, be difficult to permeate through cell membranes, therefore just lost the vigor of killing microorganisms;
2, can generate the carcinogenic substance chloroform with the organic matter in the water;
3, the smelly pungent taste of unpleasant chlorine is arranged, skin is had excitant;
4, metal is corrosive, fabric is had damage etc.
The disinfection principle of bromine-containing disinfectant is based on its sterilizing mechanisms through the hypobromous acid that generates behind the hydrolysis in water.But in use, find following shortcoming:
1, its solvability in water is little, and dissolution velocity is slow, has influenced it greatly as the application of disinfectant in the sterilization field;
2, unpleasant bromine pungent taste is arranged, skin is had excitant;
3, metal is corrosive etc.
Mostly contact insecticide is the pyrethroid medicament, like Permanone, tetramethrin, decis, flucythrinate, cypermethrin etc.
Permanone has stronger tagging and stomach poison function, has that the power of knocking down is strong, the fireballing characteristics of desinsection.More stable to light, also slower to the pest resistance development under equal service condition, efficient to lepidopterous larvae.Can be used for various pests such as crop control cabbage caterpillar, aphid, cotton bollworm, pink bollworm, cotten aphid, green plant bug, striped flea-beetle, peach fruit borer, phyllocnistis citrella stainton, potato ladybug, tea geometrid, tea caterpillar, the thin moth of tea such as vegetables, tealeaves, fruit tree, cotton, sanitary insect pests such as mosquito, fly, flea, cockroach, louse are also had good effect.
Tetramethrin is a kind of powerful synthetic pesticide, belongs to pyrethroid.Sanitary insect pests such as mosquito, fly are had quick down effect, but the poor performance that causes death has anabiosis, use therefore will be mixed with the medicament of other good disinsection effect.This medicine has certain effect of driveing to blattaria, perch is run out under the effect of blattaria at tetramethrin at dark place and receives the poisoning of other insecticides and causes death.This medicine is that world health organisation recommendations is used for one of sanitarian main insecticide, but result of use is not obvious separately.
Decis has another name called " decis ", is the highest a kind of of virulence in the present chrysanthemum ester insecticide; Insecticidal spectrum is wide; Effective to various pests such as Lepidoptera, orthoptera, thrips, Semiptera, diptera, coleopteras, but very low or invalid basically to preventive effects such as mite class, scale insect, mirid pentatomids, also can stimulate the breeding of mite class; When the worm mite is concurrent, use with specialized acaricide.Decis belongs to the poison class of poisoning.The skin contact can cause irritation, red papule occurs.During acute poisoning, the lighter has headache, dizziness, feels sick, vomiting, poor appetite, weak, and weight person muscle bundle also can occur and tremble and twitch, and the WHO hazard rating is the II level, medium harmfulness.
Flucythrinate is claimed flucythrinate again, belongs to pyrethrin pesticide, is the moderate toxicity insecticide, the mode of action with tag, stomach toxicity is main, do not have stifling and systemic action, insecticidal spectrum is wide, drug effect is rapid.Can use with general insecticide, bactericide, its biologically active is lower than by Influence of Temperature and kills chrysanthemum ester and chlorobenzene chrysanthemum ester, and the WHO hazard rating is the II level, medium harmfulness.
Cypermethrin is claimed struggle again, belongs to the chrysanthemum esters medicine, is the moderate toxicity insecticide, and insecticidal spectrum is wide, and drug effect is rapid, and the WHO hazard rating is the II level, medium harmfulness.
The long-term use of above-mentioned pyrethroid medicament makes sanitary insect pest such as insects such as cockroach, mosquitos and flies improve greatly the pesticide resistance of this medicament, has occurred the generally reduction of control efficiency in recent years.
Mostly fumigant is Celfume and vikane.
Celfume is a kind of liquid of colorless and odorless; It has strong fumigation action, can be efficient, kill various pests wide spectrum, soil is had very strong penetration capacity; Can be penetrated in the organism that rots to decompose, thereby reach the purpose of deinsectization, diseases prevention, weeding.Along with closing on of World Earth Day, this methyl bromide fumigation agent that is widely used has caused global concern.Since the forties in 20th century, just be widely used by various countries always.Because it has plurality of advantages, thereby very popular; Caused many environment and soil issues because of it again, thus controversial.Rise the nineties in 20th century; Countries in the world government all is tending towards stopping using this fumigant from security consideration; Also halted by United Nations Environment Programme for the previous period, it is a kind of material of ozone layer depletion, according to " Montreal Protocol Copenhagen amendment "; Developed country eliminated in 2005, and developing country also will eliminate in 2015.
Vikane is no color or smell gas at normal temperatures and pressures; Have that diffusion permeability is strong, broad spectrum disinfestation, dosage are economized, residual quantity is low, desinsection speed fast, the gas time of loosing is short, low temperature is easy to use, to germination rate characteristics such as influence and toxicity is not lower, be applied to the survive the winter control of insect, the tree moth dryness insect that lives of warehouse, freighter, container and building, reservoir dam, termite control and gardens more and more widely.China has just begun to manufacture experimently vikane the beginning of the eighties.But U.S.'s scientist's current research shows, can become a kind of strong effect greenhouse gases after being dispersed into air, and it endangers greater than the previous judgement of scientist, and its acute toxic action mainly damages central nervous system, causes convulsions.Environment there is harm, can pollutes water body.It is reported that it is 4800 times of one kilogram of carbonic acid gas that one kilogram of vikane is discharged in the atmosphere effect to global warming, but it is increasing with annual 5% speed.
Summary of the invention
The objective of the invention is to provides the compound Alevaire with sterilization and insecticidal function to the various drawbacks of existing disinfectant and insecticide with for solving the technical problem that exists in the known technology; Especially with preparation and the application as the compound Alevaire with sterilization and insecticidal function of the composition of sanitizing composition, Pesticidal combination, surfactant, Alevaire, it has characteristics such as safety, efficient, wide spectrum, convenient, low toxicity, environmental protection.
One of the object of the invention provides has the sterilization and the compound Alevaire of insecticidal function, especially sterilizes and the preparation of the compound Alevaire of insecticidal function as having with the composition of sanitizing composition, Pesticidal combination, surfactant, Alevaire.
Compound Alevaire with sterilization and insecticidal function of the present invention contains following component by mass percent:
Component Mass percent %
Sanitizing composition 0.01 ~ 10
Pesticidal combination 0.1 ~ 10
Surfactant 10 ~ 30
Alevaire 0 ~ 30
Water Surplus
Sanitizing composition described in the component is selected from: the mixture of one or more of quaternary ammonium compound, guanidine compound; Quaternary ammonium compound comprises one or more mixture of benzalkonium bromide, benzalkonium chloride, n-zephiran, n-alkyl dimethyl ethylbenzylammonium chloride and two n-alkyl-dimethyl ammonium chlorides; Guanidine compound comprises polyhexamethylene guanide, hexamethylene, gather and encircle guanidine, gather one or more the mixture in [2-(2-ethyoxyl)-ethyoxyl second fat] guanidine, or one or more mixture of above-mentioned each guanidine compound pharmaceutically acceptable salt.
Wherein the n in the n-zephiran is 8 ~ 18, like cetalkonium chloride, and molecular formula: C 25H 46NCl is white or light yellow solid.Soluble in water, ethanol are insoluble to benzene, ether.The fusing point of pure article is 68 ℃, has cleaning, bactericidal action.Character with typical cationic surfactants can produce significant foam during its aqueous solution brute force vibration.Good dispersion is arranged, peel off the foundry loam effect.Stable in properties, fast light, heat-resisting, non-volatility, but long term storage.
N in wherein two n-alkyl-dimethyl ammonium chlorides is 8 ~ 14.Two n-alkyl-dimethyl ammonium chlorides are two long chain quaternaries.Product type has multiple combining forms such as two octyl groups, two certain herbaceous plants with big flowers base, two dodecyls, octyl group certain herbaceous plants with big flowers base, and its bactericidal effect obviously strengthens.As: two certain herbaceous plants with big flowers base dimethyl ammonium bromides, two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride, 2-(2-phenoxy group ethyoxyl) ethyl-trimethyl salmiac etc.
Wherein the n in the n-alkyl dimethyl ethylbenzylammonium chloride is 12 ~ 18, molecular formula: N-C 23H 42Cl, molecular weight: 368.0393, can be used as hospital, the nursing home; Disinfectant in public place and the industry, and the Biocidal algae-killing agent in swimming pool and the Treatment of Industrial Water, wood preservation, and the sterilization of medicine equipment; Can be used as deodorant simultaneously, product is: alkyl (50%C12,30%C14,17%C16; 3%C18) dimethyl ethyl benzyl ammonium chloride, alkyl (60%C14,30%C16; 5%C12,5%C18) dimethyl ethyl benzyl ammonium chloride, as: dodecyl dimethyl ethylbenzylammonium chloride, myristyl dimethyl ethyl benzyl ammonium chloride etc.
Wherein benzalkonium bromide is claimed dodecyl dimethyl benzyl ammonium bromide again, molecular formula: C 21H 38BrN is white waxy solid or yellow colloid, and the aqueous solution shows neutrality or faintly alkaline reaction; Soluble in water, be slightly soluble in ethanol, be one of surfactant of using always; Have cleaning, sterilizing and algae removal effect; Being widely used in aspects such as sterilization, sterilization, anticorrosion, emulsification, de-sludging, solubilising, is industrial cycle water treatment non-oxidizable Biocidal algae-killing agent commonly used, glutinous mud remover and cleaning agent, also can be used for the control of microorganisms and the cleaning of circulation.
Wherein benzalkonium chloride is claimed the dimethyl benzyl alkyl ammomium chloride again, molecular formula: C 17H 30ClN; Belong to cationic surfactant; Belong to non-oxidizable bactericide, have wide spectrum, sterilization algae removal ability efficiently, can control bacterium algae propagation and foundry loam growth in the water effectively; And have the effect of peeling off of good foundry loam and certain dispersion, osmosis, have simultaneously certain deoil, deodorizing capability and corrosion inhibition.
Wherein the hydrochloride in the polyhexamethylene guanide is a kind of white amorphous powder, and no special odor is soluble in water, and the aqueous solution is colourless to faint yellow, tasteless, does not fire not quick-friedly, and metal material is not had corrosion basically, and decomposition temperature is greater than 400 ℃, and molecular formula is (C 7H 16N 3Cl) n, to the handle no discoloration in surface, undergoing no deterioration in 2 years, the aqueous solution of 0.1 % concentration has the taste of little hardship.Very extensive in the every field application, can be used as the candida albicans disinfectant of various body surfaces, and can make daily mould inhibitor; Can be widely used in beverage and food-processing industry; Drinking water and swimming pool; Lake water, pool, cooling tower, fountain, remove algae, oil exploitation, construction material mildewproof additive; Plant's sterilization, and be used for textile industry, paper-making industry, wood-processing industry, rubber industry, agricultural etc., also can be used as the flocculant of waste water treatment.
Hexamethylene wherein; Its colorless and odorless, water-soluble fully, stable in properties; Its bactericidal mechanism is different with chlorine-containing disinfectant, and strong oxidation reaction does not take place in the sterilization process, produces precipitation in the cell; The quantity of endocellular phosphorus rises simultaneously, thereby block cell wall and nucleic acid is synthetic; Reduce the cell permeability of the membrane, stop phosphorus to cell exocrine, and the ability bind protein, this disinfectant is widely used in pharmaceuticals industry, has when reporting it as mouthwash, and is very strong to the Gram-negative bacteria property killed.
Pesticidal combination described in the component is selected from: the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.
Es-EXTHIN wherein, chemical name: dextrorotation-trans-2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid-(R, S)-2-methyl-3-pi-allyl-4-oxo-ring penta-2-alkenyl esters, molecular formula: C 19H 26O 3, molecular weight: 302.41, be the former medicine of a kind of wide spectrum pyrethroid, for upsetting the contact killing type never poison of aixs cylinder conduction; Act on insect and cause the violent paralysis effect of ordering, reclining falls, until death; Very strong tagging and repellent action arranged, and the power of knocking down is stronger, and it is strong 2 times that its insecticidal toxicity is executed allethrin than the right side; And knock down the active tetramethrin that surpasses, mainly be used for preventing and treating flying pests such as mosquito, fly, mosquito, fly, wasp, cockroach, flea, ant are had special effect.
S-bioallethrin wherein, chemical name: (1R)-trans-chrysanthemate-(S)-and 2-methyl-3-pi-allyl-4-oxo-ring penta-2-alkenyl esters, molecular formula: C 19H 26O 3, molecular weight: 302.41, be a kind of wide spectrum pyrethroid insecticides, very strong tagging and repellent action arranged, the power of knocking down is stronger, and insecticidal toxicity is 4.9 times of allethrin.
The trans phenothrin of wherein rich dextrorotation, claim d-phenothrin again, chemical name: (1R)-and trans-2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic)-cyclopropane-carboxylic acid-3-phenoxy benzyl ester, molecular formula: C 23H 26O 3, molecular weight: 350.45, these article are unique nontoxic products in the pyrethroid, are that the unique allowance of the U.S. is used for the insecticide that civil aviaton uses, and are one of insecticides of world health organisation recommendations.These article have for insect tags and stomach poison function, and insecticidal spectrum is wide, high 8.5 ~ 20 times than the Dalmatian chrysanthemum class to the deadly power of insect, can be widely used in the control of household, warehousing, public health, industrial area insect.
Tetrafluoro methothrin wherein, chemical name: 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid 2,3,5,6-tetrafluoro-4-(methoxy) benzyl ester, molecular formula: C 19H 22F 4O 3, molecular weight: the 374.37th, suck and the contact killing type insecticide agent, knock down and kill activity to what sanitary insect pests such as mosquito, fly had a brilliance.In the experimental concentration scope; The acute toxicity and chronic toxicity of tetrafluoro methothrin is extremely low, and teratogenesis, carcinogenic do not observe, to Aedes aegypti, housefly, Groton bug, that a curtain casemaking clothes moth is knocked down speed is fast; Consumption is little; Be suitable for the hygienic biocide goods, belong to broad spectrum pesticide, ability effectively preventing sanitary insect pest and storage insect; Dipteral insect such as mosquito class there are quick knockdown effect, and cockroach, bedbug are had good residual effect.
Transfluthrin wherein, chemical name: 2,3,5, the 6-ptfe benzyl (1R, 3S)-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, molecular formula: C 15H 12Cl 2F 4O 2, molecular weight: 371.16, this article desinsection wide spectrum, ability effectively preventing sanitary insect pest and storage insect; Dipteral insect such as mosquito class there are quick knockdown effect, and cockroach, bedbug are had good residual effect.
Seven fluorobenzene chrysanthemum esters wherein, chemical name: 2,3,5,6-tetrafluoro-4-methyl-benzyl (Z)-(1RS, 3RS)-3-(2-chloro-2,3,3-trifluoropropyl-1-thiazolinyl)-2,2-dimethyl cyclopropane carboxylic acid ester, molecular formula: C 17H 14ClF 7O 2, molecular weight: 418.73, these article belong to pyrethroid insecticides, are soil insecticides, can prevent and treat coleoptera and the Lepidoptera and some Diptera pest that perch in soil well, than transfluthrin stronger killing action are arranged.
Surfactant described in the component is selected from: (TX/NP)-and one or more mixture in n, OP-10, AE0-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc.
(TX/NP)-n wherein, chemical name: NPE, have been widely used at washing agent, printing and dyeing, chemical industry, good penetration, emulsification, dispersion, antiacid, alkali resistant, anti-hard water, anti-reduction, oxidation resistance are arranged; Wherein n is 3,4,6 among (TX/NP)-n; 7,10,15.
OP-10 wherein; Chemical name: APES; Main with the emulsifier on the used as pesticides, also be the good finishing agent of textile industry, antifoaming agent, washing agent, dispersant, emulsifier, softening agent, dyeing assistant, fibre finishing, crude oil demulsifier etc.
AE0-n wherein; Chemical name: AEO; Chemical composition: natural fatty alcohol and ethylene oxide adduct, wherein the n among the AE0-n is 3 or 9, AEO-3 can make water-in-oil emulsifier; AEO-9 is mainly used in Wool detergent, woolen industry degreasing agent, fabric detergent with the liquid detergent active component, and general industry is as emulsifier.
Isomery alcohol APEO wherein, chemical composition: isomery alcohol and polymers of ethylene oxide belong to nonionic surface active agent; Structural formula: RO-(C2H4O) n H: (general R is C8, C11, C13); Performance: these article are colourless or weak yellow liquid, and emulsifying capacity is strong, and surface-active is high; Anti-hard water, the washing performance is strong, and chemical stability and Environmental compatibility are good in the pH value scope of broad.Can be used as dispersant, wetting agent, bleeding agent, washing agent, be widely used in family expenses and industrial washing field, leather is had tangible degreasing; Be specially adapted to do emulsifier, better performances.
Wherein isomery alcohol polyoxyethylene poly-oxygen propylene aether is to react in proportion with oxirane, expoxy propane with isomery alcohol to form, and is one and has 100% biodegradable novel, low bubble, efficient, environment-friendly type non-ionic surface active agent.Good, acidproof, alkaline-resisting, anti-oxidant with various surfactants, auxiliary agent, additive, solvent compatibility.Characteristics: have excellent emulsification, dispersibility; Have excellent permeation property and alkali tolerance; Have excellent washing, dirt-removing power; Extremely low foam belongs to ultralow bubble interfacial agent, does not use antifoaming agent, does not therefore have silicon spot problem; Nontoxic, non-stimulated, free from extraneous odour, nonflammable explosive, safe in utilization.
Alevaire described in the component is selected from: ethylene glycol APEO, 1, the mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.
Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.It has passed through the U.S. FDA authentication, meets American Pharmacopeia (USP), NF (NF), and Food Chemistry code (FCC) standard is widely used in the production of industries such as food, pharmacy, feed, personal care articles, chemistry.It is the water white transparency thick liquid, and it is sweet to distinguish the flavor of, and has hygroscopicity, and is miscible with water, lower aliphatic alcohols, glycerine, acetic acid, acetone, can be used as solvent, dispersant, lubricant, emulsifier etc. and is used for cosmetics, agricultural chemicals, food, medicine and other fields.
Wherein 1; The 2-dihydroxypropane is the stable water imbibition liquid of colourless thickness, and almost tasteless odorless is with water, ethanol and multiple immiscible organic solvent; As gas-chromatography fixer, solvent, antifreeze, plasticizer, dehydrating agent, carrier solvent, wetting agent, NMF, anticaking agent, antioxidant, surface-active, stabilizing agent, thickener, emulsifier, processing aid; It classifies food processing aid as among the GB 2760-96, and its aqueous solution is effective antifreeze, can be used as NMF in the cosmetics; Softening agent, solvent etc.
Wherein trihydroxy propane outward appearance is the water white transparency thick liquid; Odorless, tasteless, have hygroscopicity, humectation property, a property of softening; It is neutral that the aqueous solution is; Can mix arbitrarily with water, ethanol, methyl alcohol; Have good freeze-proof, be widely used in industries such as weaving, printing and dyeing, papermaking, printing, washing agent, daily use chemicals, system wine, food, cigarette, glassine paper, enamel, oil, electronics, rubber, plastics, process hides, chemistry, chemical fibre, mainly as NMF, humectant, hygroscopic agent, lubricant, softening agent, softening agent, thickener, plasticizer, thinner, antifreezing agent etc.
Wherein the triethylene-glycol outward appearance is that no color or smell has the hygroscopicity thick liquid, can be miscible with water, ethanol, benzene, toluene, be insoluble in ethers, and be insoluble to benzinum, have hygroscopicity, have the character of pure and mild ether.As solvent, extractant, desiccant, air disinfection agent etc.The toxicity data are little poison, LD 50(rat oral) 16.8ml/kg. is to eyes and skin nonirritant.
Water described in the component is: deionized water.
Each component is role in the present invention:
Sanitizing composition described in the component is the environmental protection and safety type disinfectant, has the quick sterilization effect, to mucocutaneous nonirritant, to metal and fabric non-corrosiveness, does not receive organic substance influence, good stability;
Pesticidal combination described in the component for sucking and the contact killing type insecticide agent, has and knocks down fast and quick-acting killing actions, to mucocutaneous nonirritant, to metal and fabric non-corrosiveness, receives organic substance influence slight, good stability;
Surfactant described in the component plays emulsification, the dissolving insecticide component;
Alevaire described in the component plays good dispersion, atomizing, synergy and antifreeze effect, to mucocutaneous non-stimulated, good stability is harmless to article, to metal and fabric non-corrosiveness.
The present invention has the most preferably proportioning of mass percent as follows of sterilization and the compound Alevaire of insecticidal function:
Component Mass percent %
Sanitizing composition 1 ~ 5
Pesticidal combination 1 ~ 8
Surfactant 15 ~ 25
Alevaire 5 ~ 25
Water Surplus
Sanitizing composition described in the component is selected from: the mixture of one or more of quaternary ammonium compound, guanidine compound; Quaternary ammonium compound comprises one or more mixture of benzalkonium bromide, benzalkonium chloride, n-zephiran, n-alkyl dimethyl ethylbenzylammonium chloride and two n-alkyl-dimethyl ammonium chlorides; Wherein the n in the n-zephiran is 8 ~ 18, the n in the n-alkyl dimethyl ethylbenzylammonium chloride is 12 ~ 18, the n in two n-alkyl-dimethyl ammonium chloride is 8 ~ 14; Guanidine compound comprises polyhexamethylene guanide, hexamethylene, gather and encircle guanidine, gather one or more the mixture in [2-(2-ethyoxyl)-ethyoxyl second fat] guanidine, or one or more mixture of above-mentioned each guanidine compound pharmaceutically acceptable salt.
Pesticidal combination described in the component is selected from: the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.
Surfactant described in the component is selected from: (TX/NP)-one or more mixture in n, OP-10, AE0-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc., wherein n is 3,4 among (TX/NP)-n; 6; 7,10,15; N among the AEO-n is 3 or 9.
Alevaire described in the component is selected from: ethylene glycol APEO, 1, the mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.; Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.
Water described in the component is: deionized water.
Another object of the present invention is, the compound method of the compound Alevaire with sterilization and insecticidal function is provided, it mainly be employing sanitizing composition, Pesticidal combination, surfactant, Alevaire and water through mix, reaction, stir, leave standstill formulated:
The above-mentioned compound method with sterilization and compound Alevaire of insecticidal function that contains the mass percent component is following:
1, Pesticidal combination and surfactant were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, sanitizing composition and Alevaire are mixed with the water of above-mentioned mass percent remaining 50% to stir by above-mentioned mass percent be mixed with compounding substances C in 1 hour;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
The object of the invention also comprises provides above-mentioned application with compound Alevaire of sterilization and insecticidal function:
1, through the multi-functional atomizer (patent No.: 201020662097.X) with the Portable atomizer (patent No.: 201020682031.7) be applied to the environment of public health field, food processing field and medicine and hygiene fields and the sterilization and the desinsection of air, can effectively prevent and harmful insects such as pathogenic microbe killing and mosquitos and flies, cockroach;
2, through the multi-functional atomizer (patent No.: 201020662097.X) with the Portable atomizer (patent No.: 201020682031.7) be applied to the internal container of inspection and quarantine system; The air of railway carriage, cabin, automotive interior and the sterilization of environment and desinsection can effectively prevent and harmful insects such as pathogenic microbe killing and mosquitos and flies, cockroach;
3, through the multi-functional atomizer (patent No.: 201020662097.X) with the Portable atomizer (patent No.: 201020682031.7) be applied to the environment in livestock and poultry cultivation field, the sterilization and the desinsection of indoor and air, can effectively prevent and harmful insects such as pathogenic microbe killing and mosquitos and flies, cockroach.
Combination matching between each component with sterilization and compound Alevaire of desinsection of the present invention has the effect of Synergistic, and has following advantage and good effect:
1, harmless to people, animal, can not produce harmful substance, do not pollute the environment safety and environmental protection;
2, non-stimulated to skin and mucosa, article and fabric there are not corrosivity;
3, have no irritating odor, colourless, do not receive the influence of environment, organic matter, acid, alkali and other physics, chemical factor.
Have an experimental study that sterilization and the compound Alevaire product of desinsection carry out to according to the invention:
The disinfectant of experimental example 1 said component and the sterilization experiment of one-component thimerosal contrast (cooperative synergism effect experiment):
1, the prescription of one-component thimerosal and component sanitizing composition is formed:
Component Prescription
A Be dodecyl benzyl dimethyl ammonium chloride
B Be polyhexamethylene guanide
A+B The combination of consumption (or content) separately separately for A and B
2, experimental result:
Component Content 1min kills logarithm value to Escherichia coli
A (quaternary ammonium compound) 100ppm >1.2
B (guanidine compound) 100ppm >1.0
A+B >3.0
Investigate by above-mentioned experimental technique; When quaternary ammonium compound wherein is selected from: (wherein the n in the n-zephiran is 8-18 to the mixture of one or more in benzalkonium bromide, benzalkonium chloride, n-zephiran, n-alkyl dimethyl ethylbenzylammonium chloride and the two n-alkyl-dimethyl ammonium chloride; N in two n-alkyl-dimethyl ammonium chlorides is 8-14, and the n in the n-alkyl dimethyl ethylbenzylammonium chloride is 12 ~ 18); Guanidine compound is selected from: polyhexamethylene guanide, hexamethylene, gather and encircle guanidine, gather one or more the mixture in [2-(2-ethyoxyl)-ethyoxyl second fat] guanidine; Or when being selected from the mixture of above-mentioned guanidine compound and polyhexamethylene guanide; Also obtained effect like the same Synergistic of experimental example 1 (cooperative synergism effect experiment); Promptly ideal with the sterilization effect of A+B; Simultaneously, the combining form of the A+B of described product investigating the killing in the process of bacterial propagule, mycobacterium, virus, fungi etc., has equally also been shown the Disinfection Effect of the good Synergistic of A+B combination; Be that special feature of the present invention is; After sanitizing composition in the component was made up by quarternary ammonium salt compound and guanidine compound, it is active that it has outstanding disinfection, and this activity is to be predicted out by the bactericidal action of known single component.
The Pesticidal combination of experimental example 2 said components and the lethality rate of one-component insecticide contrast (cooperative synergism effect experiment):
1, one-component insecticide described in the component and component insecticide formulation are formed:
Component Prescription
A Be the Es-EXTHIN
B Be the trans phenothrin of rich dextrorotation
A+B The combination of consumption (or content) separately separately for A and B
3, result of the test:
Component To American cockroach 24H lethality rate
A >70%
B >70%
A+B >95%
Investigate by above-mentioned experimental technique; When Pesticidal combination that will be wherein is selected from: during the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.; Also obtained effect like the same Synergistic of experimental example 1 (cooperative synergism effect experiment); Promptly ideal with the desinsection of A+B; Simultaneously; The combining form of the A+B of described product is being investigated killing in the process American cockroach, mosquitos and flies etc.; The killing effect that has equally also shown the good Synergistic of A+B combination, special feature promptly of the present invention be, the Pesticidal combination in the component by one or more the mixture combination in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc. after; It has the outstanding activity of killing, and this activity is to be predicted out by the killing action of known single component.
Experimental example 3 the present invention have the effect experiment of the compound Alevaire of sterilization and desinsection:
The killing effect of 1 pair of American cockroach of example, culex, housefly:
The killing effect of example 2 pairs of staphylococcus aureuses (ATCC 6538), Escherichia coli (8099), Candida albicans (ATCC10231):
The killing effect of 3 pairs of verdigris vacations of example unicellular (ATCC15542):
Experimental example 4 the present invention have the field experiment of the compound Alevaire of sterilization and desinsection:
Example 1 certain port container (volume: 33.2m3) to the on-the-spot killing effect of American cockroach, culex, housefly:
The air that example 2 is done in certain hospital and the field experiment of body surface:
Embodiment
Embodiment 1
Component Mass percent %
Dodecyl benzyl dimethyl ammonium chloride 0 ~ 3
Two dodecyl dimethyl ammonium chlorides 0 ~ 3
The dodecyl dimethyl ethylbenzylammonium chloride 0 ~ 3
Two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chlorides 0 ~ 3
The Es-EXTHIN 1 ~ 5
The trans phenothrin of rich dextrorotation 1 ~ 5
OP-10 15 ~ 25
1, the 2-dihydroxypropane 5 ~ 25
Trihydroxy propane 5 ~ 25
Water Surplus
1, Es-EXTHIN, the trans phenothrin of rich dextrorotation and OP-10 are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with dodecyl benzyl dimethyl ammonium chloride, two dodecyl dimethyl ammonium chloride, dodecyl dimethyl ethylbenzylammonium chloride, two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride and 1,2-dihydroxypropane, trihydroxy propane mix stirring by above-mentioned mass percent and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 2
Component Mass percent %
Dodecyl benzyl dimethyl ammonium chloride 0 ~ 3
The dodecyl dimethyl ethylbenzylammonium chloride 0 ~ 3
Two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chlorides 0 ~ 3
Two octyldimethyl ammonium chlorides 0 ~ 3
Octyl group certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride 0 ~ 3
The Es-EXTHIN 1 ~ 5
The trans phenothrin of rich dextrorotation 1 ~ 5
TX-10 15 ~ 25
1, the 2-dihydroxypropane 5 ~ 25
Trihydroxy propane 5 ~ 25
Water Surplus
1, Es-EXTHIN, the trans phenothrin of rich dextrorotation and TX-10 are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with dodecyl benzyl dimethyl ammonium chloride, dodecyl dimethyl ethylbenzylammonium chloride, two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride, two octyldimethyl ammonium chloride, octyl group certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride and 1,2-dihydroxypropane, trihydroxy propane mix stirring by above-mentioned mass percent and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 3
Component Mass percent %
Dodecyl benzyl dimethyl ammonium chloride 0 ~ 3
The dodecyl dimethyl ethylbenzylammonium chloride 0 ~ 3
Polyhexamethylene guanide 0 ~ 3
The tetrafluoro methothrin 1 ~ 5
Seven fluorobenzene chrysanthemum esters 1 ~ 5
NP-15 15 ~ 25
Ethylene glycol APEO 200 5 ~ 25
Trihydroxy propane 5 ~ 25
Water Surplus
1, tetrafluoro methothrin, seven fluorobenzene chrysanthemum esters and NP-15 are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, dodecyl benzyl dimethyl ammonium chloride, dodecyl dimethyl ethylbenzylammonium chloride, polyhexamethylene guanide and ethylene glycol APEO 200, trihydroxy propane are mixed stirring by above-mentioned mass percent with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances C in 1 hour;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 4
Component Mass percent %
Benzalkonium bromide 0 ~ 3
Benzalkonium chloride 0 ~ 3
Hexamethylene 0 ~ 3
The Es-EXTHIN 1 ~ 5
Seven fluorobenzene chrysanthemum esters 1 ~ 5
AEO-9 15 ~ 25
Ethylene glycol APEO 200 5 ~ 25
Triethylene-glycol 5 ~ 25
Water Surplus
1, Es-EXTHIN, seven fluorobenzene chrysanthemum esters and AEO-9 are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, benzalkonium bromide, benzalkonium chloride, hexamethylene and ethylene glycol APEO 200, triethylene-glycol are mixed stirring by above-mentioned mass percent with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances C in 1 hour;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 5
Component Mass percent %
Dodecyl benzyl dimethyl ammonium chloride 1 ~ 5
Hexamethylene 0 ~ 3
Seven fluorobenzene chrysanthemum esters 2 ~ 5
TX-7 15 ~ 25
1, the 2-dihydroxypropane 5 ~ 25
Trihydroxy propane 5 ~ 25
Water Surplus
1, seven fluorobenzene chrysanthemum esters and TX-7 were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with dodecyl benzyl dimethyl ammonium chloride, hexamethylene and 1,2-dihydroxypropane, trihydroxy propane mix stirring by above-mentioned mass percent and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 6
Component Mass percent %
The dodecyl dimethyl ethylbenzylammonium chloride 1 ~ 5
Polyhexamethylene guanide 0 ~ 3
The S-bioallethrin 2 ~ 5
Isomery alcohol APEO 15 ~ 25
1, the 2-dihydroxypropane 5 ~ 25
Water Surplus
1, S-bioallethrin and isomery alcohol APEO were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with dodecyl dimethyl ethylbenzylammonium chloride, polyhexamethylene guanide and 1, the 2-dihydroxypropane mixes stirring by above-mentioned mass percent and was mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 7
Component Mass percent %
Benzalkonium bromide 1 ~ 5
Polyhexamethylene guanide 0 ~ 3
The S-bioallethrin 1 ~ 5
Transfluthrin 1 ~ 5
Seven fluorobenzene chrysanthemum esters 1 ~ 5
Isomery alcohol polyoxyethylene poly-oxygen propylene aether 15 ~ 25
1, the 2-dihydroxypropane 5 ~ 25
Water Surplus
1, S-bioallethrin, transfluthrin, seven fluorobenzene chrysanthemum esters and isomery alcohol polyoxyethylene poly-oxygen propylene aether are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with benzalkonium bromide, polyhexamethylene guanide and 1, the 2-dihydroxypropane mixes stirring by above-mentioned mass percent and was mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 8
Component Mass percent %
Benzalkonium bromide 0 ~ 3
Benzalkonium chloride 0 ~ 3
Polyhexamethylene guanide 0 ~ 3
Hexamethylene 0 ~ 3
Transfluthrin 1 ~ 5
Seven fluorobenzene chrysanthemum esters 1 ~ 5
OP-10 5 ~ 25
NP-7 10 ~ 25
1, the 2-dihydroxypropane 5 ~ 25
Water Surplus
1, transfluthrin, seven fluorobenzene chrysanthemum esters and OP-10, NP-7 are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with benzalkonium bromide, benzalkonium chloride, polyhexamethylene guanide, hexamethylene and 1, the 2-dihydroxypropane mixes stirring by above-mentioned mass percent and was mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 9
Component Mass percent %
Benzalkonium bromide 0 ~ 3
Benzalkonium chloride 0 ~ 3
Polyhexamethylene guanide 0 ~ 3
Hexamethylene 0 ~ 3
Transfluthrin 1 ~ 5
Seven fluorobenzene chrysanthemum esters 1 ~ 5
Isomery alcohol polyoxyethylene poly-oxygen propylene aether 5 ~ 25
Isomery alcohol APEO 10 ~ 25
1, the 2-dihydroxypropane 5 ~ 25
Water Surplus
1, transfluthrin, seven fluorobenzene chrysanthemum esters and isomery alcohol polyoxyethylene poly-oxygen propylene aether, isomery alcohol APEO are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with benzalkonium bromide, benzalkonium chloride, polyhexamethylene guanide, hexamethylene and 1, the 2-dihydroxypropane mixes stirring by above-mentioned mass percent and was mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 10
Component Mass percent %
Polyhexamethylene guanide 0 ~ 4
Hexamethylene 0 ~ 4
Transfluthrin 1 ~ 5
Seven fluorobenzene chrysanthemum esters 1 ~ 5
Isomery alcohol APEO 10 ~ 25
1, the 2-dihydroxypropane 5 ~ 25
Water Surplus
1, transfluthrin, seven fluorobenzene chrysanthemum esters and isomery alcohol polyoxyethylene poly-oxygen propylene aether are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with polyhexamethylene guanide, hexamethylene and 1, the 2-dihydroxypropane mixes stirring by above-mentioned mass percent and was mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
The present invention does further elaboration through above embodiment, but does not limit the scope of the invention.
The present invention is with the various variations of described scope of soverlay technique scheme and claim scope; Under the prerequisite that does not depart from technical scheme of the present invention, any improvement that those skilled in the art that the present invention did are realized easily all belongs to the present invention's scope required for protection.

Claims (9)

1. one kind has the sterilization and the compound Alevaire of insecticidal function, it is characterized in that this has to sterilize and compound Alevaire of insecticidal function comprises following component by mass percent:
Component Mass percent % Sanitizing composition 0.01~10 Pesticidal combination 0.1~10 Surfactant 10~30 Alevaire 0~30 Water Surplus
2. the compound Alevaire with sterilization and insecticidal function as claimed in claim 1 is characterized in that comprising following most preferably component by mass percent:
Component Mass percent % Sanitizing composition 1~5 Pesticidal combination 1~8 Surfactant 15~25 Alevaire 5~25 Water Surplus
3. the compound Alevaire with sterilization and insecticidal function as claimed in claim 1; It is characterized in that described sanitizing composition is selected from: the mixture of one or more of quaternary ammonium compound, guanidine compound; Quaternary ammonium compound comprises one or more mixture of benzalkonium bromide, benzalkonium chloride, n-zephiran, n-alkyl dimethyl ethylbenzylammonium chloride and two n-alkyl-dimethyl ammonium chlorides; Wherein the n in the n-zephiran is 8 ~ 18, the n in the n-alkyl dimethyl ethylbenzylammonium chloride is 12 ~ 18, the n in two n-alkyl-dimethyl ammonium chloride is 8 ~ 14; Guanidine compound comprises polyhexamethylene guanide, hexamethylene, gather and encircle guanidine, gather one or more the mixture in [2-(2-ethyoxyl)-ethyoxyl second fat] guanidine, or one or more mixture of above-mentioned each guanidine compound pharmaceutically acceptable salt.
4. the compound Alevaire with sterilization and insecticidal function as claimed in claim 1 is characterized in that described Pesticidal combination is selected from: the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.
5. the compound Alevaire with sterilization and insecticidal function as claimed in claim 1; It is characterized in that described surfactant is selected from: the surfactant described in the component is selected from: (TX/NP)-one or more mixture in n, OP-10, AE0-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc., wherein n is 3,4 among (TX/NP)-n; 6; 7,10,15; N among the AEO-n is 3 or 9.
6. the compound Alevaire with sterilization and insecticidal function as claimed in claim 1; It is characterized in that described Alevaire is selected from: ethylene glycol APEO, 1; The mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.; Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.
7. the compound Alevaire with sterilization and insecticidal function as claimed in claim 1 is characterized in that described water is: deionized water.
8. like the described arbitrary preparation of claim 1-7, it is characterized in that: Pesticidal combination and surfactant were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring with compound Alevaire of sterilization and insecticidal function; Said mixture matter A is mixed stirring be mixed with compounding substances B in 1 hour with the water of above-mentioned mass percent 50%; Sanitizing composition and Alevaire mixed with the water of above-mentioned mass percent remaining 50% to stir by above-mentioned mass percent be mixed with compounding substances C in 1 hour; Said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
9. like the described arbitrary application of claim 1-7 with compound Alevaire of sterilization and insecticidal function; It is characterized in that: through the multi-functional atomizer (patent No.: 201020662097.X) with the Portable atomizer (patent No.: 201020682031.7) be applied to the environment of public health field, food processing field and medicine and hygiene fields and the sterilization and the desinsection of air, can effectively prevent and harmful insects such as pathogenic microbe killing and mosquitos and flies, cockroach; Through the multi-functional atomizer (patent No.: 201020662097.X) with the Portable atomizer (patent No.: 201020682031.7) be applied to the internal container of inspection and quarantine system; The air of railway carriage, cabin, automotive interior and the sterilization of environment and desinsection can effectively prevent and harmful insects such as pathogenic microbe killing and mosquitos and flies, cockroach; Through the multi-functional atomizer (patent No.: 201020662097.X) with the Portable atomizer (patent No.: 201020682031.7) be applied to the environment in livestock and poultry cultivation field, the sterilization and the desinsection of indoor and air, can effectively prevent and harmful insects such as pathogenic microbe killing and mosquitos and flies, cockroach.
CN201110124064A 2011-05-15 2011-05-15 Preparation and application with compound Alevaire of sterilization and insecticidal function Pending CN102318639A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201110124064A CN102318639A (en) 2011-05-15 2011-05-15 Preparation and application with compound Alevaire of sterilization and insecticidal function

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201110124064A CN102318639A (en) 2011-05-15 2011-05-15 Preparation and application with compound Alevaire of sterilization and insecticidal function

Publications (1)

Publication Number Publication Date
CN102318639A true CN102318639A (en) 2012-01-18

Family

ID=45446585

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201110124064A Pending CN102318639A (en) 2011-05-15 2011-05-15 Preparation and application with compound Alevaire of sterilization and insecticidal function

Country Status (1)

Country Link
CN (1) CN102318639A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103210950A (en) * 2013-04-26 2013-07-24 王福建 Disinfection and pest-killing mixture
CN103285415A (en) * 2012-02-23 2013-09-11 朱启亮 Method for clearing peculiar smell and pollutants in car
CN105746572A (en) * 2016-03-31 2016-07-13 太仓市璜泾新明农机作业专业合作社 Deinsectization and sterilization composition
CN110583686A (en) * 2019-08-27 2019-12-20 中国人民解放军东部战区疾病预防控制中心 Ultralow temperature resistant storage disinfection and disinsection compound preparation
CN116034997A (en) * 2022-09-29 2023-05-02 瑞普(天津)生物药业有限公司 Atomization aid and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101897342A (en) * 2010-06-04 2010-12-01 贵阳柏丝特化工有限公司 Preparation of insecticide solution and application thereof
CN101933521A (en) * 2009-07-01 2011-01-05 李新建 Preparation and application thereof of sterilization composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101933521A (en) * 2009-07-01 2011-01-05 李新建 Preparation and application thereof of sterilization composition
CN101897342A (en) * 2010-06-04 2010-12-01 贵阳柏丝特化工有限公司 Preparation of insecticide solution and application thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103285415A (en) * 2012-02-23 2013-09-11 朱启亮 Method for clearing peculiar smell and pollutants in car
CN103210950A (en) * 2013-04-26 2013-07-24 王福建 Disinfection and pest-killing mixture
CN103210950B (en) * 2013-04-26 2014-03-26 王福建 Disinfection and pest-killing mixture
CN105746572A (en) * 2016-03-31 2016-07-13 太仓市璜泾新明农机作业专业合作社 Deinsectization and sterilization composition
CN110583686A (en) * 2019-08-27 2019-12-20 中国人民解放军东部战区疾病预防控制中心 Ultralow temperature resistant storage disinfection and disinsection compound preparation
CN116034997A (en) * 2022-09-29 2023-05-02 瑞普(天津)生物药业有限公司 Atomization aid and preparation method and application thereof

Similar Documents

Publication Publication Date Title
US20230157279A1 (en) Mixed fatty acid soap/fatty acid based insecticidal, cleaning, and antimicrobial compositions
CN102283254A (en) Plant source environmentally-friendly pesticide preparation
BRPI0911317B1 (en) AQUOSA DISINFECTANT SOLUTION FORMULATION, ITS PREPARATION METHOD AND METHOD OF DISINFECTING A SURFACE
CN102450282A (en) Green long-acting zoonosis vector prevention and control medicament
CN102334501A (en) Preparation and application of multifunctional atomization agent for controlling pests
CN102090413A (en) Preparation and application of compound disinfectant
CN102318639A (en) Preparation and application with compound Alevaire of sterilization and insecticidal function
US20180249711A1 (en) Compositions and methods of use pertaining to insecticide
CN102334502A (en) Preparation and application of multifunctional atomization agent for controlling pests in sealed container
CN102210300A (en) Preparation and application of multifunctional atomizing agent for preventing and controlling pests of inspection and quarantine system
US20040253287A1 (en) Environmentally safe insecticides
CN1096631A (en) " hydro-peening (spilling) goes out "---space spraying and the good long-acting sterilized solution of washing performance
US9451763B2 (en) Disinfectant formulation
CN102302033A (en) Preparation and application of compounded disinfection atomization agent
CN102308844A (en) Preparation and applications of pesticidal atomizing agent
US9609864B2 (en) Disinfectant formulation
US20130122120A1 (en) Insecticidal compositions and methods
JP6509547B2 (en) Pest control agent and pest control method using the same
CN102308845A (en) Preparation and applications of atomizing agent with pesticide and deratization functions
CN102318634A (en) Preparation method of compound leather bactericidal and mildew-proof agent
RU2816103C1 (en) Disinfectant with repellent properties "dez garant anti fly" and method for production thereof
CN107438365A (en) Contain aldehyde compositions for insect control
JPH0912410A (en) Antimicrobial repellent composition for harmful organism
CN104255776A (en) Disposable hygienic quarantine treatment preparation
CN107232227A (en) A kind of AVM hereinafter triazophos compound pesticide and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20120118