CN102250279B - 一种自交联型氟硅丙烯酸树脂及其制备方法 - Google Patents
一种自交联型氟硅丙烯酸树脂及其制备方法 Download PDFInfo
- Publication number
- CN102250279B CN102250279B CN 201110131621 CN201110131621A CN102250279B CN 102250279 B CN102250279 B CN 102250279B CN 201110131621 CN201110131621 CN 201110131621 CN 201110131621 A CN201110131621 A CN 201110131621A CN 102250279 B CN102250279 B CN 102250279B
- Authority
- CN
- China
- Prior art keywords
- acrylic resin
- self
- coupling agent
- preparation
- silane coupling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004925 Acrylic resin Substances 0.000 title claims abstract description 29
- 229920000178 Acrylic resin Polymers 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 229940104869 fluorosilicate Drugs 0.000 title abstract description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 21
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 20
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 16
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 238000007599 discharging Methods 0.000 claims abstract description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 28
- 238000004132 cross linking Methods 0.000 claims description 22
- 229920001296 polysiloxane Polymers 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 19
- 150000002148 esters Chemical class 0.000 claims description 19
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 14
- -1 alkyl ethyl acrylate Chemical compound 0.000 claims description 12
- CRTKHIYQIPONDX-UHFFFAOYSA-N FC(C(C(F)(F)F)(F)F)(C(C(C(C(F)(F)F)(F)F)=C(C(F)(F)F)F)(F)F)F Chemical group FC(C(C(F)(F)F)(F)F)(C(C(C(C(F)(F)F)(F)F)=C(C(F)(F)F)F)(F)F)F CRTKHIYQIPONDX-UHFFFAOYSA-N 0.000 claims description 8
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 8
- 238000009413 insulation Methods 0.000 claims description 8
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pent-2-ene Chemical group CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 claims description 6
- BINACNSGGVXHDR-UHFFFAOYSA-N 1,1,1,2,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro-3-(1,1,2,2,2-pentafluoroethyl)non-2-ene Chemical group C(=C(C(F)(F)F)F)(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)C(C(F)(F)F)(F)F BINACNSGGVXHDR-UHFFFAOYSA-N 0.000 claims description 4
- 239000011347 resin Substances 0.000 abstract description 20
- 229920005989 resin Polymers 0.000 abstract description 20
- 239000000126 substance Substances 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 3
- 125000000524 functional group Chemical group 0.000 abstract description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 239000002966 varnish Substances 0.000 description 6
- 229910018557 Si O Inorganic materials 0.000 description 4
- 239000007822 coupling agent Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical compound C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 description 3
- 229940094989 trimethylsilane Drugs 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 241000024287 Areas Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 125000002769 thiazolinyl group Chemical group 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Macromonomer-Based Addition Polymer (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
原料名称 | 质量百分含量(g) |
二甲苯 | 45 |
丙烯酸 | 0.6 |
甲基丙烯酸甲酯 | 32.0 |
丙烯酸乙酯 | 16.0 |
丙烯酸羟乙酯 | 3.4 |
乙烯基三甲氧基硅烷偶联剂 | 1.5 |
全氟辛基乙基丙烯酸酯 | 0.5 |
叔丁基过氧化氢 | 1.0 |
原料名称 | 质量百分含量(g) |
二甲苯 | 50 |
丙烯酸 | 0.4 |
甲基丙烯酸甲酯 | 27.4 |
丙烯酸乙酯 | 13.7 |
丙烯酸羟乙酯 | 2.1 |
乙烯基三甲氧基硅烷偶联剂 | 3.2 |
全氟辛基乙基丙烯酸酯 | 2.5 |
叔丁基过氧化氢 | 0.7 |
原料名称 | 质量百分含量(g) |
二甲苯 | 55 |
丙烯酸 | 0.3 |
甲基丙烯酸甲酯 | 22.5 |
丙烯酸乙酯 | 11.3 |
丙烯酸羟乙酯 | 0.9 |
乙烯基三甲氧基硅烷偶联剂 | 5.0 |
全氟辛基乙基丙烯酸酯 | 4.5 |
叔丁基过氧化氢 | 0.5 |
原料名称 | 质量百分含量(g) |
二甲苯 | 55 |
丙烯酸 | 0.4 |
甲基丙烯酸甲酯 | 23.9 |
丙烯酸乙酯 | 11.9 |
丙烯酸羟乙酯 | 0.9 |
乙烯基三乙基硅烷偶联剂 | 4.9 |
全氟己基乙基丙烯酸酯 | 2.5 |
叔丁基过氧化氢 | 0.5 |
原料名称 | 质量百分含量(g) |
二甲苯 | 50 |
丙烯酸 | 0.5 |
甲基丙烯酸甲酯 | 28.0 |
丙烯酸乙酯 | 14.0 |
丙烯酸-2-羟乙酯 | 3.1 |
-甲基丙烯酰氧基丙基三甲基硅烷偶联剂 | 3.2 |
全氟丁乙基丙烯酸酯 | 0.5 |
叔丁基过氧化氢 | 0.7 |
原料名称 | 质量百分含量(g) |
二甲苯 | 45 |
丙烯酸 | 0.4 |
甲基丙烯酸甲酯 | 30 |
丙烯酸乙酯 | 14.8 |
丙烯酸羟乙酯 | 1.1 |
-甲基丙烯酰氧基丙基三乙基硅烷偶联剂 | 3.2 |
全氟己基乙基丙烯酸酯 | 4.5 |
叔丁基过氧化氢 | 1.0 |
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110131621 CN102250279B (zh) | 2011-05-20 | 2011-05-20 | 一种自交联型氟硅丙烯酸树脂及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110131621 CN102250279B (zh) | 2011-05-20 | 2011-05-20 | 一种自交联型氟硅丙烯酸树脂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102250279A CN102250279A (zh) | 2011-11-23 |
CN102250279B true CN102250279B (zh) | 2013-05-08 |
Family
ID=44977875
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 201110131621 Active CN102250279B (zh) | 2011-05-20 | 2011-05-20 | 一种自交联型氟硅丙烯酸树脂及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102250279B (zh) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103012665B (zh) * | 2012-12-26 | 2015-07-15 | 河北智生环保科技有限公司 | 一种紫外光交联的有机硅改性丙烯酸酯共聚物乳液 |
CN104231122B (zh) * | 2014-02-21 | 2017-02-08 | 江苏中瀛涂料有限公司 | 一种有机硅改性的氟碳树脂及其制备方法 |
CN105778684A (zh) * | 2016-03-21 | 2016-07-20 | 苏州天键衡电子信息科技有限公司 | 一种船舶用耐高温涂料 |
CN106928802B (zh) * | 2017-03-15 | 2018-05-01 | 广东中星科技股份有限公司 | 一种基于氟硅改性丙烯酸树脂的防腐涂料及其制备 |
CN108878618B (zh) * | 2017-05-11 | 2020-03-24 | Tcl集团股份有限公司 | 一种qled器件及其制备方法 |
CN107722185B (zh) * | 2017-09-15 | 2020-12-18 | 浙江大学 | 一种低表面能氟硅防污树脂及其制备方法 |
CN107739586A (zh) * | 2017-10-25 | 2018-02-27 | 浙江星丰科技有限公司 | 一种防水胶粘剂及其制备方法 |
CN108192254A (zh) * | 2017-12-28 | 2018-06-22 | 珠海市盛西源机电设备有限公司 | 高抗污亚克力实体面材及其制备方法 |
CN108504280A (zh) * | 2018-03-24 | 2018-09-07 | 江西省科学院应用化学研究所 | 一种水性氟硅树脂防腐涂料的制备方法 |
CN108441056B (zh) * | 2018-04-12 | 2020-07-03 | 太仓中化环保化工有限公司 | 一种环保型氟素电路板三防漆组合物及其制备方法和应用 |
CN109135485A (zh) * | 2018-08-14 | 2019-01-04 | 南通中国科学院海洋研究所海洋科学与技术研究发展中心 | 一种氟硅共聚改性两亲性丙烯酸酯聚合物防腐蚀涂料及其制备方法 |
CN110590987B (zh) * | 2019-09-25 | 2020-12-22 | 华南理工大学 | 一种氟硅共聚丙烯酸树脂及其制备方法与应用 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101215805B1 (ko) * | 2004-12-03 | 2012-12-26 | 미쓰비시 가가꾸 가부시키가이샤 | 조성물, 경화물 및 물품 |
CN101092468A (zh) * | 2006-06-22 | 2007-12-26 | 广东鸿昌化工有限公司 | 一种氟硅改性自交联聚丙烯酸(酯)微乳液的制备方法 |
CN101570587A (zh) * | 2009-05-08 | 2009-11-04 | 厦门大学 | 氟-硅改性丙烯酸共聚物树脂及其制备方法 |
CN101560278B (zh) * | 2009-05-25 | 2011-01-12 | 河北工业大学 | 一种含氟丙烯酸酯-甲基丙烯酸甲酯-苯乙烯共聚物及其制备方法 |
JP5607337B2 (ja) * | 2009-10-27 | 2014-10-15 | リンテック株式会社 | 水分散型アクリル系粘着剤組成物、粘着シート及びその製造方法 |
CN102060952B (zh) * | 2010-10-29 | 2013-02-13 | 华南理工大学 | 具有疏水亲油氟硅改性核壳结构苯丙乳液及其制备方法 |
-
2011
- 2011-05-20 CN CN 201110131621 patent/CN102250279B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
CN102250279A (zh) | 2011-11-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102250279B (zh) | 一种自交联型氟硅丙烯酸树脂及其制备方法 | |
CN103214628B (zh) | 一种用于耐候性涂料的改性丙烯酸树脂及其制备方法 | |
CN109868026B (zh) | 一种有机硅改性丙烯酸酯树脂及其制备方法和疏水耐候缓释改性丙烯酸树脂涂料 | |
CN107298733B (zh) | 一种增透减反镀膜液用模板剂及其制备方法和应用 | |
CN101982512B (zh) | 一种硅丙涂料树脂及其制备方法 | |
CN103396687B (zh) | 含硅氧烷有机氟改性(甲基)丙烯酸酯聚合物乳液的涂料 | |
CN103102446B (zh) | 一种汽车修补漆用羟基丙烯酸树脂及其制备方法 | |
CN103360540B (zh) | 一种长侧链的有机硅改性含氟(甲基)丙烯酸树脂 | |
CN103012714B (zh) | 高柔韧性水性丙烯酸聚氨酯弹性树脂及其涂料 | |
CN101081962A (zh) | 一种环氧树脂改性有机硅耐高温防腐涂料 | |
CN101735379B (zh) | 自干型低脂肪链硅氧烷改性的水性丙烯酸树脂的制备方法 | |
CN110627950A (zh) | 一种水性氟改性丙烯酸乳液及其制备方法、应用 | |
CN101619116B (zh) | 一种热塑性含氟丙烯酸树脂及其制备方法 | |
CN102464784A (zh) | 一种有机硅改性丙烯酸酯共聚物的合成方法 | |
CN101775144B (zh) | 氟硅树脂及其制备方法和防污涂料 | |
CN110885630A (zh) | 有机硅水性耐高温特种涂料及制备方法 | |
CN102492102A (zh) | 含硅丙烯酸改性环氧酯树脂及其涂料 | |
CN106519941B (zh) | 一种疏水耐蚀杂化防护涂料及其制备方法 | |
CN107033296A (zh) | 超耐候聚硅氧烷改性丙烯酸树脂及面漆制备方法 | |
CN101747464B (zh) | 一种具有含氟侧基或含氟支链的氟烯烃共聚氟树脂 | |
CN114891166A (zh) | 一种有机硅油复合丙烯酸乳胶及其制备方法 | |
CN101125993A (zh) | 含有含氟丙烯酸酯嵌段共聚物的复合涂料及其生产方法 | |
CN102492100A (zh) | 水分散型含氟羟基丙烯酸-环氧酯杂化体树脂及其涂料 | |
CN102604580A (zh) | 太阳能电池背板pet与pe膜复合专用聚酯胶水及其制备方法 | |
CN108424488B (zh) | 一种抗污、耐水硅丙乳液及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Self-crosslinked fluorosilicate acrylic resin and preparation method thereof Effective date of registration: 20170925 Granted publication date: 20130508 Pledgee: Industrial Commercial Bank of China Ltd Jinzhou branch Pledgor: Jinzhou Huifa Tianhe Chemical Co., Ltd. Registration number: 2017210000019 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PP01 | Preservation of patent right | ||
PP01 | Preservation of patent right |
Effective date of registration: 20180417 Granted publication date: 20130508 |
|
PD01 | Discharge of preservation of patent | ||
PD01 | Discharge of preservation of patent |
Date of cancellation: 20210417 Granted publication date: 20130508 |
|
PP01 | Preservation of patent right | ||
PP01 | Preservation of patent right |
Effective date of registration: 20210417 Granted publication date: 20130508 |