CN102242022B - Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof - Google Patents
Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof Download PDFInfo
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- CN102242022B CN102242022B CN 201110160696 CN201110160696A CN102242022B CN 102242022 B CN102242022 B CN 102242022B CN 201110160696 CN201110160696 CN 201110160696 CN 201110160696 A CN201110160696 A CN 201110160696A CN 102242022 B CN102242022 B CN 102242022B
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- 102000004190 Enzymes Human genes 0.000 title claims abstract description 44
- 108090000790 Enzymes Proteins 0.000 title claims abstract description 44
- 239000007788 liquid Substances 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000003599 detergent Substances 0.000 title abstract description 5
- 238000005406 washing Methods 0.000 claims abstract description 31
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000011734 sodium Substances 0.000 claims abstract description 13
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 11
- 239000002253 acid Substances 0.000 claims abstract description 11
- 230000003165 hydrotropic effect Effects 0.000 claims abstract description 11
- 239000001509 sodium citrate Substances 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 239000003381 stabilizer Substances 0.000 claims abstract description 11
- -1 polyoxyethylene Polymers 0.000 claims abstract description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 8
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229940088598 enzyme Drugs 0.000 claims description 39
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 26
- 238000003756 stirring Methods 0.000 claims description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 claims description 10
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 10
- 150000002632 lipids Chemical class 0.000 claims description 9
- 108091005804 Peptidases Proteins 0.000 claims description 7
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical group OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 229960003500 triclosan Drugs 0.000 claims description 7
- 239000003643 water by type Substances 0.000 claims description 7
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 6
- BWRPYSJNBVBIRP-FLFBIERCSA-N Ineketone Chemical compound O[C@H]1C[C@@](C)(C=C)C=C2C(=O)C[C@]3(O)C(C)(C)CCC[C@H]3[C@@]21C BWRPYSJNBVBIRP-FLFBIERCSA-N 0.000 claims description 6
- BWRPYSJNBVBIRP-UHFFFAOYSA-N Ineketone Natural products OC1CC(C)(C=C)C=C2C(=O)CC3(O)C(C)(C)CCCC3C21C BWRPYSJNBVBIRP-UHFFFAOYSA-N 0.000 claims description 6
- 229910021538 borax Inorganic materials 0.000 claims description 6
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 239000011344 liquid material Substances 0.000 claims description 6
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 6
- 238000005070 sampling Methods 0.000 claims description 6
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 6
- 239000004328 sodium tetraborate Substances 0.000 claims description 6
- 229940038773 trisodium citrate Drugs 0.000 claims description 6
- 229960004418 trolamine Drugs 0.000 claims description 6
- NSFKBZXCXCJZDQ-UHFFFAOYSA-N cumene;sodium Chemical compound [Na].CC(C)C1=CC=CC=C1 NSFKBZXCXCJZDQ-UHFFFAOYSA-N 0.000 claims description 5
- 229940048842 sodium xylenesulfonate Drugs 0.000 claims description 5
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 claims description 4
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 4
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims description 4
- 238000001514 detection method Methods 0.000 claims description 4
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 108010059892 Cellulase Proteins 0.000 claims description 3
- 102000035195 Peptidases Human genes 0.000 claims description 3
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 claims description 3
- 230000032683 aging Effects 0.000 claims description 3
- 229940106157 cellulase Drugs 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 125000001931 aliphatic group Chemical group 0.000 abstract description 3
- 239000004744 fabric Substances 0.000 abstract description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract 2
- 150000002191 fatty alcohols Chemical class 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 230000002421 anti-septic effect Effects 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 238000005282 brightening Methods 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 abstract 1
- 239000000047 product Substances 0.000 description 15
- 235000019263 trisodium citrate Nutrition 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 5
- 239000004365 Protease Substances 0.000 description 4
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 4
- 239000013543 active substance Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000002894 chemical waste Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000008237 rinsing water Substances 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention relates to a detergent for daily use, and specifically relates to an environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and a preparation method thereof. The prepared product in the invention is mobile liquid with low viscosity, contains no phosphates, fluorescent brightening agents or alkylphenol polyoxyethylene, and has no pollution to environment. The production process for the product is simple; preparation and mass production of the product are easy; the product can be widely used for washing of various fabrics and clothing and is both applicable to hand wash and machine wash. The environment-friendly type hyperconcentration biological enzyme liquid laundry detergent comprises, by weight, 0.5 to 50 parts of fatty alcohol polyoxyethylene ether sodium sulfate-70, 0.5 to 50 parts of fatty alcohol polyoxyethylene ether-9, 0.5 to 30 parts of sodium alkylbenzene sulfonate-60, 0.2 to 15 parts of triethanolamine, 0.1 to 10 parts of sodium citrate, 0 to 5 parts of citric acid, 0 to 5 parts of aliphatic acid, 0.02 to 8 parts of biological enzyme, 0.1 to 20 parts of an enzyme stabilizer, 0.5 to 30 parts of a solvent, 0 to 15 parts of a hydrotropic agent, 0 to 5 parts of a bactericide, 0.001 to 5 parts of an antiseptic, 0 to 3 parts of essence and 1.0 to 40 parts of softened water.
Description
One, technical field:
The present invention relates to a kind of environment-friendly type ultra concentrated enzyme laundry liquid and preparation method thereof.
Two, background technology:
In daily life, washing composition is the requisite that is used for fabric, clothing cleaning.Product such as washing powder, washing liquid etc. commonly used at present.
Continuous development along with modern industry; Resource, the energy and environmental problem that various countries, the whole world face become increasingly conspicuous; Common washing liquid, washing powder be owing to use tensio-active agent and a large amount of alkaline matter that is difficult to degrade, and like TX10 (APE), water glass, yellow soda ash etc., phosphaticly uses and discharge in a large number; Be prone to cause the eutrophication problem of rivers and lakes, cause serious variation of water quality and water environment pollution; Active matter content is low in addition, and detersive power is not good, a large amount of chemical wastes and discharging; The production energy consumption of common washing liquid and washing powder is high, and problems such as resource consumption height make the production of common washing liquid and washing powder, use cause many environmental problems.
Three, summary of the invention:
The object of the present invention is to provide a kind of environment-friendly type ultra concentrated enzyme laundry liquid, its not phosphorous hydrochlorate, white dyes, TX10, environmentally safe.Production technique is simple and direct, is easy to preparation.
For realizing above-mentioned purpose; The technical scheme that the present invention adopts is: a kind of environment-friendly type ultra concentrated enzyme laundry liquid; It is characterized in that described washing liquid comprises that following feed composition is: 0.5～50 part on polyoxyethylenated alcohol sodium sulfate-70 type, AEO-9 0.5～50 part, SAS-60 type 0.5～30,0.2～15 part of trolamine, 0.1～10 part of Trisodium Citrate, 0～5 part of Hydrocerol A, 0～5 part in lipid acid, 0.02～8 part of enzyme, 0.1～20 part of enzyme stabilizers, 0.5～30 part of solvent, 0～15 part of hydrotropic agent, 0～5 part in sterilant, 0.001～5 part of sanitas, 0～3 part in essence, 1.0～40 parts of softening waters.
Described lipid acid is that carbon chain lengths is a kind of or its mixture in 12～18.
Described enzyme is one or more in proteolytic enzyme, lypase, cellulase and the glycase of liquid.
Described enzyme stabilizers is one or more of Ucar 35, glycerine, borax, formate, propionic salt or adipate.
Described solvent is a kind or 2 kinds in ethanol, terepthaloyl moietie, Ucar 35 butyl ether, dipropylene glycol butyl ether, dipropylene glycol propyl ether, Diethylene Glycol butyl ether, butyl glycol ether, dipropylene glycol ether or the dipropylene glycol phenylate.
Described hydrotropic agent is one or both of cumene sodium sulfonate or sodium xylene sulfonate.
Described sterilant is a Triclosan.
Described sanitas is 1,2-benzisothiazole-3-ketone or methylisothiazolinone/chlormethylisothiazo,ine ketone.
The preparation method of described a kind of environment-friendly type ultra concentrated enzyme laundry liquid is characterized in that: comprise that described preparing method's step is:
(1) gets the raw materials ready by above-mentioned each constituent mass proportioning;
(2) start preparing tank and stir, add the AEO-9 and trolamine heat temperature raising that preheat fusing;
(3) temperature rises to 55 ℃～75 ℃, adds lipid acid then, is stirred to whole fusings and homogeneous transparent;
(4) add solvent, stir 3～5 minutes to even; Stop heating, order adds polyoxyethylenated alcohol sodium sulfate-70 type and SAS-60 type, stirs 10 minutes;
(5) add softening water, and the cooling of beginning liquid material, make liquid material temperature remain on 20 ℃～40 ℃, after stirring made homogeneous transparent, order added Trisodium Citrate, hydrotropic agent and enzyme stabilizers again, is stirred to dissolving;
(6) order adds sterilant and enzyme, stirs to add essence, sanitas again after 10 minutes;
(7) work in-process samplings detect qualified after, filter, ageing is handled;
(8) sampling Detection, can, finished product packing.
Compared with prior art, the present invention has the following advantages and effect:
Employing is easy to biodegradable tensio-active agent (biological degradation rate is more than 90%), not phosphorous hydrochlorate, environmentally safe.Active matter content can reach 35%～70%, reaches 4 times of ultra concentrated, only needs very small amount can reach same washing effect.Adopt the novel low bubble technology that is prone to float, reduced the washing rinsing water.Add the multi-biological enzyme, improve removal effect multiple stain.Use multiple enzyme stabilization technique, ensure that product was increased to more than 2 years in the storage quality guaranteed period.Adopt New-type adjuvant, eliminate liquid crystal and gel problem in the common liq washing composition enrichment process, this product also has fast under 10 ℃ of low temperature, dispersing and dissolving property completely even make, and is more suitable for the cold washing that Chinese family generally adopts and is accustomed to.Adopt the cold technology of joining of low temperature in the production, reduce energy consumption.
Product of the present invention is the LV pourable liquid, and technical requirements meets HJ 458-2009 " environmental labelling product technical requirements washing composition ", not phosphorous hydrochlorate, white dyes, TX10, environmentally safe.Production technique is simple and direct, is easy to prepare and produce in batches the washing that can be widely used in various fabrics and clothing, and hand washing and machine washing are all suitable.
Four, description of drawings:
Fig. 1 is the detersive power contrast of environment-friendly type ultra concentrated enzyme laundry liquid and common washing liquid.
Five, embodiment:
The present invention is through AS and the polynary compatibility of nonionogenic tenside; Add zymin and enzyme stabilizers; Cooperate solvent and hydrotropic agent to regulate and control product viscosity, cold-resistant thermotolerance, accomplish the production of environment-friendly type ultra concentrated enzyme laundry liquid through scientific and reasonable blending process.
A kind of environment-friendly type ultra concentrated enzyme laundry liquid; Described washing liquid comprises that following feed composition is: 0.5～50 part on polyoxyethylenated alcohol sodium sulfate-70 type, AEO-9 0.5～50 part, SAS-60 type 0.5～30,0.2～15 part of trolamine, 0.1～10 part of Trisodium Citrate, 0～5 part of Hydrocerol A, 0～5 part in lipid acid, 0.02～8 part of enzyme, 0.1～20 part of enzyme stabilizers (Ucar 35, glycerine, borax or formate), 0.5～30 part of solvent (ethanol, terepthaloyl moietie or alcohol ether), 0～15 part of hydrotropic agent (cumene sodium sulfonate or sodium xylene sulfonate), 0～5 part in sterilant (Triclosan), 0.001～5 part of sanitas (1,2-benzisothiazole-3-ketone or methylisothiazolinone/chlormethylisothiazo,ine ketone), 0～3 part in essence, 1.0～40 parts of softening waters.
Described lipid acid is that carbon chain lengths is a kind of or its mixture in 12～18.
Described enzyme is one or more in proteolytic enzyme, lypase, cellulase and the glycase of liquid.
Described enzyme stabilizers is one or more of Ucar 35, glycerine, borax, formate, propionic salt or adipate.
Described solvent is a kind or 2 kinds in ethanol, terepthaloyl moietie, Ucar 35 butyl ether, dipropylene glycol butyl ether, dipropylene glycol propyl ether, Diethylene Glycol butyl ether, butyl glycol ether, dipropylene glycol ether or the dipropylene glycol phenylate.
Described hydrotropic agent is one or both of cumene sodium sulfonate or sodium xylene sulfonate.
Described sterilant is a Triclosan.
Described sanitas is 1,2-benzisothiazole-3-ketone or methylisothiazolinone/chlormethylisothiazo,ine ketone.
According to above-described environment-friendly type ultra concentrated enzyme laundry liquid, it is characterized in that comprising following technology of preparing step:
(1) gets the raw materials ready by above-mentioned each constituent mass proportioning;
(2) start preparing tank and stir, add the AEO-9, the trolamine that preheat fusing, heat temperature raising;
(3) temperature rises to 55 ℃～75 ℃, adds lipid acid then, is stirred to whole fusings and homogeneous transparent;
(4) add solvent (ethanol, terepthaloyl moietie or alcohol ether), stir 3～5 minutes to even; Stop heating, order adds polyoxyethylenated alcohol sodium sulfate-70 type, and SAS-60 type stirred 10 minutes;
(5) add softening water, and the cooling of beginning liquid material, make liquid material temperature remain on 20 ℃～40 ℃.After stirring made homogeneous transparent, order added Trisodium Citrate, hydrotropic agent (cumene sodium sulfonate or sodium xylene sulfonate), enzyme stabilizers (Ucar 35, glycerine, borax) again, is stirred to dissolving;
(6) order adds sterilant (Triclosan), enzyme, stirs to add essence, sanitas (1,2-benzisothiazole-3-ketone or methylisothiazolinone/chlormethylisothiazo,ine ketone) after 10 minutes again;
(7) work in-process samplings detect qualified after, filter, ageing is handled;
(8) sampling Detection, can, finished product packing.
Embodiment 1:
20 kilograms on polyoxyethylenated alcohol sodium sulfate-70 type, AEO-9 26 kilogram, 15 kilograms on SAS-60 type, 8 kilograms of trolamines; 3 kilograms of Trisodium Citrates, 0.2 kilogram of Hydrocerol A, 1 kilogram of tetradecanoic acid, 1 kilogram of liquid protease; 0.5 kilogram of liquid aliphatic enzyme, 0.5 kilogram of borax, 5 kilograms of Ucar 35; 12 kilograms of dipropylene glycol butyl ether, 0.3 kilogram of Triclosan, 1; 0.05 kilogram of 2-benzisothiazole-3-ketone, 0.2 kilogram in essence, 7.25 kilograms of softening waters.Raw material is mixed with the washing liquid finished product by above-mentioned preparation method.
Embodiment 2:
30 kilograms on polyoxyethylenated alcohol sodium sulfate-70 type, AEO-9 20 kilogram, 6 kilograms on SAS-60 type, 5 kilograms of trolamines; 2 kilograms of Trisodium Citrates, 0.6 kilogram of palmitinic acid, 0.5 kilogram of liquid protease, 0.2 kilogram of liquid aliphatic enzyme; 6 kilograms of Ucar 35,2 kilograms of ethanol, 12 kilograms of dipropylene glycol propyl ether; 0.002 kilogram of methylisothiazolinone/chlormethylisothiazo,ine ketone, 0.2 kilogram in essence, 15.498 kilograms of softening waters.Raw material is mixed with the washing liquid finished product by above-mentioned preparation method.
Embodiment 3:
15 kilograms on polyoxyethylenated alcohol sodium sulfate-70 type, AEO-9 28 kilogram, 15 kilograms on SAS-60 type, 8 kilograms of trolamines; 2 kilograms of Trisodium Citrates, 1.6 kilograms of palmitinic acids, 1 kilogram of liquid protease, 3 kilograms of Ucar 35; 8 kilograms of Diethylene Glycol butyl ether, 3 kilograms of sodium xylene sulfonates, 0.3 kilogram of Triclosan, 1; 0.05 kilogram of 2-benzisothiazole-3-ketone, 0.2 kilogram in essence, 14.85 kilograms of softening waters.Raw material is mixed with the washing liquid finished product by above-mentioned preparation method.
Embodiment 4:
28 kilograms on polyoxyethylenated alcohol sodium sulfate-70 type, AEO-9 22 kilogram, 8 kilograms on SAS-60 type, 8 kilograms of trolamines; 4 kilograms of ethanol, 8 kilograms of terepthaloyl moietie, 2 kilograms of Trisodium Citrates, 0.5 kilogram of Hydrocerol A; 0.8 kilogram of Triple Pressed Stearic Acid, 1 kilogram of liquid protease, 8 kilograms of glycerine, 1 kilogram of sodium formiate; 1,0.05 kilogram of 2-benzisothiazole-3-ketone, 0.2 kilogram in essence, 8.45 kilograms of softening waters.Raw material is mixed with the washing liquid finished product by above-mentioned preparation method.
Environment-friendly type ultra concentrated enzyme laundry liquid of the present invention adopts new green environment protection tensio-active agent and auxiliary agent; Utilization high-tech liquid bio zymotechnic, the collaborative compatibility technology of tensio-active agent and ultra concentratedization technology develop that environmental protection is without phosphorus, the Superconcentrated washing liquid product innovation of low-carbon emission, reduction resource consumption and energy consumption.
Use multiple natural biological leavened prod efficient liquid enzyme, greatly improved the detersive power of liquid washing agent, multiple stain is had powerful removal effect.It is the interpolation of alternative a large amount of chemical that minute quantity is added, and has reduced the discharging of chemical in the washing process.Use multiple enzyme stabilization technique simultaneously, ensure the enzyme activity stability of product in storage process, the shelf life of products of common liq washing composition was increased to more than 2 years from half a year.
Through experimental test; Environment-friendly type ultra concentrated enzyme laundry liquid phase of the present invention is than common washing liquid; Carry out the decontamination test with the GB soiled cotton: under the wash concentration of 2g/L; To common dirt---carbon black greasy dirt dirt, albumen dirt, sebum dirt, detersive power improves nearly 50%, 200%, 30% (as shown in Figure 1) respectively.
This product meets national industry development direction, and overall performance is in international and leading domestic level, is representing the developing direction of the field environmental protection of current cleaning detergent, energy-saving and cost-reducing, low-carbon economy, has good demonstration induced effect.
Claims (2)
1. environment-friendly type ultra concentrated enzyme laundry liquid; It is characterized in that described washing liquid comprises that following feed composition is: 0.5～50 part on polyoxyethylenated alcohol sodium sulfate-70 type, AEO-9 0.5～50 part, SAS-60 type 0.5～30,0.2～15 part of trolamine, 0.1～10 part of Trisodium Citrate, 0～5 part of Hydrocerol A, 0～5 part in lipid acid, 0.02～8 part of enzyme, 0.1～20 part of enzyme stabilizers, 0.5～30 part of solvent, 0～15 part of hydrotropic agent, 0～5 part in sterilant, 0.001～5 part of sanitas, 0～3 part in essence, 1.0～40 parts of softening waters;
Described lipid acid is that carbon chain lengths is a kind of or its mixture in 12～18;
Described enzyme is one or more in proteolytic enzyme, lypase, cellulase and the glycase of liquid;
Described enzyme stabilizers is one or more of Ucar 35, glycerine, borax, formate, propionic salt or adipate;
Described solvent is a kind or 2 kinds in ethanol, terepthaloyl moietie, Ucar 35 butyl ether, dipropylene glycol butyl ether, dipropylene glycol propyl ether, Diethylene Glycol butyl ether, butyl glycol ether, dipropylene glycol ether or the dipropylene glycol phenylate;
Described hydrotropic agent is one or both of cumene sodium sulfonate or sodium xylene sulfonate;
Described sterilant is a Triclosan;
Described sanitas is 1,2-benzisothiazole-3-ketone, methylisothiazolinone or chlormethylisothiazo,ine ketone.
2. the preparation method of a kind of environment-friendly type ultra concentrated enzyme laundry liquid according to claim 1 is characterized in that: comprise that described preparing method's step is:
Get the raw materials ready by above-mentioned each constituent mass proportioning;
Start preparing tank and stir, add the AEO-9 and trolamine heat temperature raising that preheat fusing;
Temperature rises to 55 ℃～75 ℃, adds lipid acid then, is stirred to whole fusings and homogeneous transparent;
Add solvent, stir 3～5 minutes to even; Stop heating, order adds polyoxyethylenated alcohol sodium sulfate-70 type and SAS-60 type, stirs 10 minutes;
Add softening water, and the cooling of beginning liquid material, make liquid material temperature remain on 20 ℃～40 ℃, after stirring made homogeneous transparent, order added Trisodium Citrate, hydrotropic agent and enzyme stabilizers again, is stirred to dissolving;
Order adds sterilant and enzyme, stirs to add essence, sanitas again after 10 minutes;
After work in-process sampling detection is qualified, filter, ageing is handled;
Sampling Detection, can, finished product packing.
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