CN102203151B - 具有双峰b嵌段的aba-三嵌段共聚物的制备方法 - Google Patents
具有双峰b嵌段的aba-三嵌段共聚物的制备方法 Download PDFInfo
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- CN102203151B CN102203151B CN200980143668.9A CN200980143668A CN102203151B CN 102203151 B CN102203151 B CN 102203151B CN 200980143668 A CN200980143668 A CN 200980143668A CN 102203151 B CN102203151 B CN 102203151B
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- segmented copolymer
- block
- methyl
- monomer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Graft Or Block Polymers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
Abstract
Description
实施例 | 1 | 2 | 3 | 4 | 5 |
单体1 | 1a)n-BA | 1b)n-BA | 1c)n-BA | 1d)n-BA | 1e)n-BA |
用量 | 120.4g | 120.5g | 200.6g | 121.6g | 121.4g |
氧化铜(I) | 0.8g | 0.8g | 1.3g | 2.4g | 2.4g |
PMDETA | 2.0g | 2.0g | 3.3g | 6.0g | 6.0g |
引发剂1 | 1.01g | 1.01g | 0.85g | 3.06g | 2.36g |
引发剂2 | 1.01g | 1.01g | 2.52g | 3.06g | 4.13g |
单体2 | 2a)n-BA | 2b)MMA | 2c)n-BA | 2d)n-BA | 2e)n-BA |
用量 | 30.1g | 30.2g | 50.2g | 30.3g | 30.3g |
单体3 | 3a)MEMO | 3b)MEMO | 3c)MEMO | 3d)AMA | 3e)HEMA |
用量 | 6.2g | 6.2g | 10.4g | 10.5g | 9.9g |
Mn(第1阶段) | 26 500 | 28 600 | 26 500 | 11 500 | 7500 |
D | 2.15 | 1.98 | 2.15 | 1.95 | 3.14 |
Mn(终产物) | 31 800 | 34 800 | 31 900 | 14 600 | 11 500 |
D | 2.07 | 2.02 | 2.07 | 1.81 | 2.02 |
对比实施例 | 1 | 2 | 3 |
单体1 | 1f)MMA | 1g)n-BA | 1h)n-BA |
用量 | 81.0g | 79.6g | 79.6g |
单体2 | 2f)MMA | 2g)MMA | 2h)n-BA |
用量 | 19.9g | 19.9g | 20.0g |
单体3 | 3f)MEMO | 3g)MEMO | 3h)MEMO |
用量 | 4.8g | 4.8g | 4.8g |
引发剂用量 | 1.25g | 1.25g | 1.25g |
Mn(第1阶段) | 21 600 | 17 800 | 18 100 |
D | 1.21 | 1.22 | 1.28 |
Mn(终产物) | 26 800 | 20 300 | 22 500 |
D | 1.31 | 1.36 | 1.38 |
Claims (18)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008043668.2 | 2008-11-12 | ||
DE102008043668A DE102008043668A1 (de) | 2008-11-12 | 2008-11-12 | Verfahren zur Herstellung von ABA-Triblockcopolymeren mit einem bimodalen B-Block |
PCT/EP2009/062933 WO2010054898A1 (de) | 2008-11-12 | 2009-10-06 | Verfahren zur herstellung von aba-triblockcopolymeren mit einem bimodalen b-block |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102203151A CN102203151A (zh) | 2011-09-28 |
CN102203151B true CN102203151B (zh) | 2014-09-17 |
Family
ID=41278767
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200980143668.9A Expired - Fee Related CN102203151B (zh) | 2008-11-12 | 2009-10-06 | 具有双峰b嵌段的aba-三嵌段共聚物的制备方法 |
Country Status (8)
Country | Link |
---|---|
US (1) | US8895669B2 (zh) |
EP (1) | EP2344559B1 (zh) |
JP (1) | JP5992172B2 (zh) |
CN (1) | CN102203151B (zh) |
AU (1) | AU2009315877A1 (zh) |
BR (1) | BRPI0921202A2 (zh) |
DE (1) | DE102008043668A1 (zh) |
WO (1) | WO2010054898A1 (zh) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2268758B1 (en) | 2008-03-20 | 2013-12-18 | Avery Dennison Corporation | Acrylic polymers having controlled placement of functional groups |
DE102008043669A1 (de) * | 2008-11-12 | 2010-05-20 | Evonik Röhm Gmbh | Verfahren zur Herstellung von ABA-Triblockcopolymeren mit einem breit verteilten B-Block |
CN103003321B (zh) | 2010-05-19 | 2018-11-27 | 艾利丹尼森公司 | 丙烯酸类聚合物中的有序构造 |
BR112014009065B1 (pt) * | 2011-10-14 | 2021-01-05 | Avery Dennison Corporation | polímero acrílico, composição reticulável e método de preparo de uma composição reticulável |
JP5932142B2 (ja) * | 2013-04-25 | 2016-06-08 | 株式会社カネカ | ビニル系重合体の製造方法 |
US9587062B2 (en) | 2014-12-15 | 2017-03-07 | Henkel IP & Holding GmbH and Henkel AG & Co. KGaA | Photocrosslinkable block copolymers for hot-melt adhesives |
WO2019208386A1 (ja) * | 2018-04-27 | 2019-10-31 | 東亞合成株式会社 | 硬化性樹脂組成物、並びに、ブロック共重合体及びその製造方法 |
CN109251284A (zh) * | 2018-08-02 | 2019-01-22 | 常州大学 | 一种可常温交联聚丙烯酸酯弹性体及其制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1637550A2 (en) * | 1999-03-23 | 2006-03-22 | Carnegie-Mellon University | Catalytic processes for the controlled polymerization of free radically (co) polymerizable monomers and functional polymeric systems prepared thereby |
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US6258911B1 (en) * | 1994-08-18 | 2001-07-10 | Xerox Corporation | Bifunctional macromolecules and toner compositions therefrom |
US5807937A (en) | 1995-11-15 | 1998-09-15 | Carnegie Mellon University | Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties |
EP0906342B2 (en) | 1996-06-12 | 2015-02-11 | Warwick Effect Polymers Limited | Polymerisation catalyst and process |
TW593347B (en) | 1997-03-11 | 2004-06-21 | Univ Carnegie Mellon | Improvements in atom or group transfer radical polymerization |
DE69829063T2 (de) | 1997-09-22 | 2006-03-23 | Kaneka Corp. | Polymer, verfahren zu dessen herstellung und härtbare zusammensetzung, die dieses polymer enthält |
US6143848A (en) * | 1997-10-23 | 2000-11-07 | The B.F.Goodrich Company | End-functionalized polymers by controlled free-radical polymerization process and polymers made therefrom |
US6649701B1 (en) | 1998-03-27 | 2003-11-18 | Kaneka Corporation | Polymer and process for producing polymer |
EP1764377B1 (en) | 1998-09-02 | 2008-11-19 | Kaneka Corporation | Polymer, process for producing polymer and composition |
AU3919500A (en) * | 1999-03-23 | 2000-10-09 | Carnegie Wave Energy Limited | Catalytic processes for the controlled polymerization of free radically (co)polymerizable monomers and functional polymeric systems prepared thereby |
JP2003064139A (ja) * | 2001-08-24 | 2003-03-05 | Dainippon Toryo Co Ltd | 顔料分散用樹脂及び該樹脂を含有する着色塗料組成物 |
TWI314934B (en) | 2002-02-13 | 2009-09-21 | Kaneka Corporatio | Polymer composition |
AU2003235436A1 (en) | 2002-05-31 | 2003-12-19 | Asahi Denka Co., Ltd. | Acrylic sol composition |
DE10350786A1 (de) * | 2003-10-29 | 2005-06-02 | Röhm GmbH & Co. KG | Mischungen zur Herstellung von Reaktivschmelzklebstoffen sowie daraus erhältliche Reaktivschmelzklebstoffe |
DE102005045458A1 (de) | 2005-09-22 | 2007-03-29 | Röhm Gmbh | Verfahren zur Herstellung von ABA-Triblockcopolymeren auf (Meth)acrylatbasis |
DE102006015846A1 (de) * | 2006-04-03 | 2007-10-04 | Röhm Gmbh | Kupferentfernung aus ATRP-Produkten mittels Zugabe von Schwefelverbindungen |
DE102006035726A1 (de) * | 2006-07-28 | 2008-01-31 | Evonik Röhm Gmbh | Verfahren zur Herstellung von ABA-Triblockcopolymeren auf (Meth)acrylatbasis |
DE102006037351A1 (de) * | 2006-08-09 | 2008-02-14 | Evonik Röhm Gmbh | Verfahren zur Herstellung von hydroxytelecheler ATRP-Produkten |
DE102006037352A1 (de) * | 2006-08-09 | 2008-02-14 | Evonik Röhm Gmbh | Verfahren zur Herstellung von säureterminierten ATRP-Produkten |
DE102006037350A1 (de) * | 2006-08-09 | 2008-02-14 | Evonik Röhm Gmbh | Verfahren zur Herstellung von halogenfreien ATRP-Produkten |
DE102006048154A1 (de) * | 2006-10-10 | 2008-04-17 | Evonik Röhm Gmbh | Verfahren zur Herstellung von silyltelechelen Polymeren |
DE102008002016A1 (de) | 2008-05-28 | 2009-12-03 | Evonik Röhm Gmbh | Verfahren zur Herstellung von silyl-funktionalisierten ABA-Triblockcopolymeren auf (Meth)acrylatbasis |
-
2008
- 2008-11-12 DE DE102008043668A patent/DE102008043668A1/de not_active Withdrawn
-
2009
- 2009-10-06 EP EP09783763.7A patent/EP2344559B1/de not_active Not-in-force
- 2009-10-06 US US13/127,159 patent/US8895669B2/en not_active Expired - Fee Related
- 2009-10-06 JP JP2011535947A patent/JP5992172B2/ja not_active Expired - Fee Related
- 2009-10-06 WO PCT/EP2009/062933 patent/WO2010054898A1/de active Application Filing
- 2009-10-06 CN CN200980143668.9A patent/CN102203151B/zh not_active Expired - Fee Related
- 2009-10-06 AU AU2009315877A patent/AU2009315877A1/en not_active Abandoned
- 2009-10-06 BR BRPI0921202A patent/BRPI0921202A2/pt not_active Application Discontinuation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1637550A2 (en) * | 1999-03-23 | 2006-03-22 | Carnegie-Mellon University | Catalytic processes for the controlled polymerization of free radically (co) polymerizable monomers and functional polymeric systems prepared thereby |
Also Published As
Publication number | Publication date |
---|---|
EP2344559A1 (de) | 2011-07-20 |
DE102008043668A1 (de) | 2010-05-20 |
JP2012508313A (ja) | 2012-04-05 |
CN102203151A (zh) | 2011-09-28 |
BRPI0921202A2 (pt) | 2016-02-23 |
WO2010054898A1 (de) | 2010-05-20 |
US20110207876A1 (en) | 2011-08-25 |
US8895669B2 (en) | 2014-11-25 |
JP5992172B2 (ja) | 2016-09-14 |
EP2344559B1 (de) | 2014-01-01 |
AU2009315877A1 (en) | 2010-05-20 |
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Owner name: HENKEL KGAA Free format text: FORMER OWNER: EVONIK ROEHM GMBH Effective date: 20121026 Free format text: FORMER OWNER: HENKEL KGAA Effective date: 20121026 |
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