CN102199453B - Improved Lurgi gasification furnace waste heat recovering method and device - Google Patents

Improved Lurgi gasification furnace waste heat recovering method and device Download PDF

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CN102199453B
CN102199453B CN2011100926482A CN201110092648A CN102199453B CN 102199453 B CN102199453 B CN 102199453B CN 2011100926482 A CN2011100926482 A CN 2011100926482A CN 201110092648 A CN201110092648 A CN 201110092648A CN 102199453 B CN102199453 B CN 102199453B
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waste heat
heat boiler
raw gas
steam
pipeline
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CN102199453A (en
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盖恒军
王祥远
吴文颖
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Qingdao University of Science and Technology
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Qingdao University of Science and Technology
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

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Abstract

The invention belongs to the technical field of energy recovery and relates to a method for secondary recovery of waste heat of a Lurgi gasification furnace and a device for realizing the method. The waste heat recovery is realized by adopting two stages of waste heat boilers. The method comprises the following steps: raw gas discharged from the gasification process of coal is firstly subjected to spray cooling by utilizing diluted phenol water from a diluted phenol water tank in a primary spray cooler, the cooled raw gas enters to a primary waste heat boiler, and in the primary waste heat boiler, steam is generated by boiler feedwater in the heating shell pass of the raw gas; raw gas discharged from the primary waste heat boiler is subjected to spray cooling by utilizing diluted phenol water in a secondary spray cooler, the cooled raw gas enters into a secondary waste heat boiler, and in the secondary waste heat boiler, steam is generated by boiler feedwater in the heating shell pass of the raw gas. The device disclosed by the invention has the advantages of novel structure, simpleness in equipment manufacturing, low cost, optimized energy layout, energy resource saving, remarkable economic benefits and capabilities of generating partial 0.8-1.5MPa steam as a byproduct by utilizing the waste heat of the gasification furnace, meeting the requirement on a factory for the steam in the pressure range and effectively reducing the consumption of the steam with high pressure level.

Description

A kind of improved Lurgi gasification furnace waste heat recovering method and device thereof
Technical field:
The invention belongs to technical field of energy recovery, relate to the method for Lurgi gasifier waste heat secondary recovery and realize the device of this method, the waste heat that causes in can the stove burning to various coal gas reclaims effectively, realizes the effect of energy-saving and emission-reduction.
Background technology:
Along with the Continued of oil price, coal more and more comes into one's own in the application of the energy and chemical field, and gasification is cleaning, efficiently utilizes the effective means of coal, is widely used in the industry such as gas maked coal, synthetic ammonia, coal power generation; When raw gas leaves vapourizing furnace, temperature is generally all more than 400 ℃, in order to reclaim this part heat, present way is that raw gas is suitably cooling through spraying water, send in waste heat boiler, being used for the gasification boiler feedwater and producing pressure is the low-pressure steam of 0.5-0.7MPa, therefore the waste-heat recovery device of current Lurgi gasifier can only reclaim the low-pressure steam of 0.5-0.7MPa, thereby in general gasification plant, 0.5-0.7MPa steam more than needed in a large number, unnecessary low-pressure steam can only be as the power steam of low value, and the value of steam per ton only is equivalent to 20-30 unit; On the other hand, enforcement along with techniques such as new phenol recovery, low-temperature rectisols, the steam supply wretched insufficiency of the 0.8-1.5MPa that the device such as phenol recovery, low-temperature rectisol is required, being forced to the above steam of driven force district's extraction pressure 2.0MPa replaces, waste one's talent on a petty job, reduced the value of this part high pressure steam; Therefore, seek a kind of steam by vapourizing furnace waste heat by-product part 0.8-1.5MPa, satisfy plant area to the demand of this pressure range steam, reduce the consumption of high pressure grade steam, thereby optimize current energy layout, the technological method of increasing economic efficiency is the development research target of energy dissipation during current solution coal gasification is utilized.
Summary of the invention:
The object of the invention is to overcome the defective of prior art, seek to design the device that provides a kind of improvement type coal to utilize the method for vapourizing furnace waste heat recovery in process and realize the method.
To achieve these goals, the present invention adopts the two-stage waste heat boiler to realize waste heat recovery, first the raw gas of coming out of the stove in the coal gasification process is used rare phenol water spraying cooling from rare phenol tank in the one-level spray cooler after 200-270 ℃, enter first step waste heat boiler, again in first step waste heat boiler, the oiler feed of raw gas heating shell side, the steam of generation pressure 0.8-1.5MPa; The raw gas that goes out first step waste heat boiler in the secondary spray cooler with rare phenol water spraying cooling after 160-210 ℃, enter second stage waste heat boiler, in the waste heat boiler of the second stage, the oiler feed of raw gas heating shell side, producing pressure is the steam of 0.3-0.8MPa; Enter the one-level spray cooler from coal gasification stove raw gas out through the raw gas pipeline, the spray water washing that is come from tank is cooling, and the condensed water in the one-level spray cooler is processed from bottom discharge system; Cooled raw gas enters the one-level waste heat boiler, the feedwater heating and gasifying that will enter by the feedwater pipeline, the raw gas of output one-level waste heat boiler enters the secondary spray cooler through the raw gas pipeline, the spray water washing that is come from tank is cooling, the cooled raw gas of secondary enters the secondary waste heat boiler, the feedwater heating and gasifying that will enter by the feedwater pipeline; The raw gas of output secondary waste heat boiler enters subsequent handling processing through the raw gas pipeline; The steam that in the steam that in the one-level waste heat boiler, gasification produces and secondary waste heat boiler, gasification produces enters respectively the steam pipe system of corresponding pressure through steam-pipe; Condensed water in secondary spray cooler and I and II waste heat boiler is drained in tank by lower part outlet duct type separately and recycles.
The agent structure of the inventive method device for carrying out said comprises one-level waste heat boiler, secondary waste heat boiler, one-level spray cooler, secondary spray cooler, tank, raw gas intake ducting, feedwater pipeline, steam-pipe, replenishes the spray water pipeline, effluxes spray water pipeline and water circulating pump; The raw gas intake ducting connects one-level spray cooler opening for feed, the centre exit place duct type of one-level spray cooler and the corresponding connection of tube side opening for feed of one-level waste heat boiler, and the bottom of one-level spray cooler is shaped with and exports and efflux the spray water pipeline and be communicated with; Tube side outlet and the secondary spray cooler pipeline communication of one-level waste heat boiler; The top inlet of one-level spray cooler and secondary spray cooler is connected with tank by the water circulating pump duct type; Secondary spray cooler, I and II waste heat boiler lower part outlet be the duct type connection water channel respectively; The tube side opening for feed place duct type of the centre exit place of secondary spray cooler and secondary waste heat boiler is communicated with; The shell side ingress of I and II waste heat boiler is connected with the feedwater pipeline respectively by pipeline, and the shell side outlet is connected with steam-pipe with pressure respectively by pipeline; The water inlet of tank is shaped with and replenishes the spray water pipeline.
The present invention compared with prior art, its structure design is novel, equipment preparation technology is simple, cost is low, can by the steam of vapourizing furnace waste heat by-product part 0.8-1.5MPa, satisfy plant area to the demand of this pressure range steam, effectively reduce the consumption of high pressure grade steam, the optimization energy layout is saved the energy, remarkable in economical benefits.
Description of drawings:
Fig. 1 is the structural principle schematic diagram of waste-heat recovery device of the present invention.
Embodiment
The invention will be further described below in conjunction with accompanying drawing and by embodiment.
Embodiment:
The present embodiment adopts the two-stage waste heat boiler to realize waste heat recovery, first the raw gas of coming out of the stove in the coal gasification process is used rare phenol water spraying cooling from rare phenol tank in the one-level spray cooler after 200-270 ℃, enter first step waste heat boiler, again in first step waste heat boiler, the oiler feed of raw gas heating shell side, the steam of generation pressure 0.8-1.5MPa; The raw gas that goes out first step waste heat boiler in the secondary spray cooler with rare phenol water spraying cooling after 160-210 ℃, enter second stage waste heat boiler, in the waste heat boiler of the second stage, the oiler feed of raw gas heating shell side, producing pressure is the steam of 0.3-0.8MPa.
The agent structure that the present embodiment is implemented comprises one-level waste heat boiler 3, secondary waste heat boiler 5, one-level spray cooler 1, secondary spray cooler 4, tank 2, raw gas intake ducting 6,7 and 8, feedwater pipeline 9, steam-pipe 10 and 11, replenishes spray water pipeline 12, effluxes spray water pipeline 13 and water circulating pump 14; Raw gas intake ducting 6 connects one-level spray cooler 1 opening for feed, the centre exit place duct type of one-level spray cooler 1 and the corresponding connection of tube side opening for feed of one-level waste heat boiler 3, the bottom of one-level spray cooler 1 are shaped with outlet and efflux spray water pipeline 13 and be communicated with; Tube side outlet and secondary spray cooler 4 pipeline communications of one-level waste heat boiler 3; The top inlet of one-level spray cooler 1 and secondary spray cooler 4 is connected with tank 2 by recycle pump 14 duct types; Secondary spray cooler 4, I and II waste heat boiler 3,5 lower part outlets are duct type connection water channel 2 respectively; The tube side opening for feed place duct type of the centre exit place of secondary spray cooler 4 and secondary waste heat boiler 5 is communicated with; I and II waste heat boiler 3 and 5 shell side ingress are connected with feedwater pipeline 9 respectively by pipeline, and the shell side outlet is connected with steam-pipe 10 with pressure respectively by pipeline; The water inlet of tank 2 is shaped with and replenishes spray water pipeline 12.
In the present embodiment implementation process, enter one-level spray cooler 1 from coal gasification stove raw gas out through raw gas pipeline 6, cooling by the spray water washing from tank 2, the condensed water in one-level spray cooler 1 is processed from bottom discharge system; Cooled raw gas enters one-level waste heat boiler 3, the feedwater heating and gasifying that will enter by feedwater pipeline 8, the raw gas of output one-level waste heat boiler 3 enters secondary spray cooler 4 through raw gas pipeline 7, cooling by the spray water washing from tank 2, the cooled raw gas of secondary enters secondary waste heat boiler 5, the feedwater heating and gasifying that will enter by feedwater pipeline 9; The raw gas of output secondary waste heat boiler 5 enters subsequent handling processing through raw gas pipeline 8; The steam that in the steam that in one-level waste heat boiler 3, gasification produces and secondary waste heat boiler 5, gasification produces enters respectively the steam pipe system of corresponding pressure through steam-pipe 10 and 11; Condensed water in secondary spray cooler 4 and I and II waste heat boiler 3 and 5 is drained in tank 2 by lower part outlet duct type separately and recycles.
A practical application example of the present embodiment: production capacity be 35000 marks vertical/hour Lurgi gasifier, residual neat recovering system originally can by-product goes out 22 tons/hour of the steam of 0.5MPa; After its residual neat recovering system being pressed the workflow reengineering of accompanying drawing 1, tapping temperature be the raw gas of 570 ℃ after the one-level spray cooler is cooled to 250 ℃, enter the one-level waste heat boiler, by-product goes out 8 tons/hour of the steam of 1.5MPa; The raw gas that goes out the one-level waste heat boiler enters the secondary spray cooler, after being cooled to 190 ℃, enters the secondary waste heat boiler, and by-product goes out 12.5 tons/hour of the steam of 0.5MPa; The steam of the 1.5MPa that after transformation, residual neat recovering system reclaims is used for the phenol retrieving arrangement, and each hour can be saved 7.8 tons of 4.0MPa steam.

Claims (2)

1. improved Lurgi gasification furnace waste heat recovering method, it is characterized in that adopting the two-stage waste heat boiler to realize waste heat recovery, first the raw gas of coming out of the stove in the coal gasification process is used rare phenol water spraying cooling from rare phenol tank in the one-level spray cooler after 200-270 ℃, enter first step waste heat boiler, the oiler feed of raw gas heating shell side in first step waste heat boiler again, the steam of generation pressure 0.8-1.5MPa; The raw gas that goes out first step waste heat boiler in the secondary spray cooler with rare phenol water spraying cooling after 160-210 ℃, enter second stage waste heat boiler, the oiler feed of raw gas heating shell side in the waste heat boiler of the second stage, producing pressure is the steam of 0.3-0.8MPa; Enter the one-level spray cooler from coal gasification stove raw gas out through the raw gas pipeline, the spray water washing that is come from tank is cooling, and the condensed water in the one-level spray cooler is processed from bottom discharge system; Cooled raw gas enters the one-level waste heat boiler, the feedwater heating and gasifying that will enter by the feedwater pipeline, the raw gas of output one-level waste heat boiler enters the secondary spray cooler through the raw gas pipeline, the spray water washing that is come from tank is cooling, the cooled raw gas of secondary enters the secondary waste heat boiler, the feedwater heating and gasifying that will enter by the feedwater pipeline; The raw gas of output secondary waste heat boiler enters subsequent handling processing through the raw gas pipeline; The steam that in the steam that in the one-level waste heat boiler, gasification produces and secondary waste heat boiler, gasification produces enters respectively the steam pipe system of corresponding pressure through steam-pipe; Condensed water in secondary spray cooler and I and II waste heat boiler is recycled to tank by lower part outlet row of conduits separately.
2. the device that relates to of improved Lurgi gasification furnace waste heat recovering method as claimed in claim 1, is characterized in that the agent structure of device comprises one-level waste heat boiler, secondary waste heat boiler, one-level spray cooler, secondary spray cooler, tank, raw gas intake ducting, feedwater pipeline, steam-pipe, replenishes the spray water pipeline, effluxes spray water pipeline and water circulating pump; The raw gas intake ducting connects one-level spray cooler opening for feed, the centre exit place pipeline of one-level spray cooler and the corresponding connection of tube side opening for feed of one-level waste heat boiler, and the bottom of one-level spray cooler is shaped with and exports and efflux the spray water pipeline and be communicated with; Tube side outlet and the secondary spray cooler pipeline communication of one-level waste heat boiler; The top inlet of one-level spray cooler and secondary spray cooler is connected with tank by the water circulating pump pipeline; Secondary spray cooler, I and II waste heat boiler lower part outlet be the duct type connection water channel respectively; The tube side opening for feed place duct type of the centre exit place of secondary spray cooler and secondary waste heat boiler is communicated with; The shell side ingress of I and II waste heat boiler is connected with the feedwater pipeline respectively by pipeline, and the shell side outlet is connected with steam-pipe with pressure respectively by pipeline; The water inlet of tank is shaped with and replenishes the spray water pipeline.
CN2011100926482A 2011-04-01 2011-04-01 Improved Lurgi gasification furnace waste heat recovering method and device Active CN102199453B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102604685B (en) * 2011-12-29 2014-11-26 武汉凯迪工程技术研究总院有限公司 Biomass synthesis gas positive pressure purification process and system configuration for oil production
CN102585916B (en) * 2011-12-29 2014-11-26 武汉凯迪工程技术研究总院有限公司 Biomass synthesized gas negative pressure purifying process method and system configuration for producing oil
CN103265979B (en) * 2013-06-03 2015-04-08 武汉凯迪工程技术研究总院有限公司 Technology and device for cooling and purifying high-temperature and high-pressure biomass synthesis gas
CN104893762B (en) * 2015-06-15 2017-07-14 林兆晟 Raw gas ash disposal system
CN106753589A (en) * 2016-12-07 2017-05-31 广西北海浩邦新能源科技有限公司 Charing fuel gas handling process
CN113865365A (en) * 2021-10-26 2021-12-31 四川恩特普环保科技有限公司 Waste heat recovery system of titanium factory

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Publication number Priority date Publication date Assignee Title
CN201242165Y (en) * 2008-06-11 2009-05-20 周士友 Two-stage vertical gas making blowing heat recovery device
CN101614498A (en) * 2008-06-26 2009-12-30 上海梅山钢铁股份有限公司 Raw coke over gas riser residual heat recovery device
CN101768474A (en) * 2010-02-05 2010-07-07 刘金成 Waste heat recovery process for high-temperature rough gas of entrained flow bed

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201242165Y (en) * 2008-06-11 2009-05-20 周士友 Two-stage vertical gas making blowing heat recovery device
CN101614498A (en) * 2008-06-26 2009-12-30 上海梅山钢铁股份有限公司 Raw coke over gas riser residual heat recovery device
CN101768474A (en) * 2010-02-05 2010-07-07 刘金成 Waste heat recovery process for high-temperature rough gas of entrained flow bed

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