CN102197830A - Composite sanitizer tablet containing trichloroiminocyanuric acid (TCCA) and preparation method thereof - Google Patents
Composite sanitizer tablet containing trichloroiminocyanuric acid (TCCA) and preparation method thereof Download PDFInfo
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Abstract
The invention belongs to the technical field of sanitizers and discloses a preparation method of a composite sanitizer tablet containing trichloroiminocyanuric acid (TCCA). The preparation method of the composite sanitizer tablet comprises the following steps: selecting 90% TCCA, copper sulfate pentahydrate, aluminum sulfate tetrakaidecahydrate, zinc sulfate, boric acid, sodium tetraborate and the like, placing all the selected components into a mixing machine, uniformly mixing to prepare a combinational material, delivering the combinational material into a granulator for granulation, then sieving out granules of 8-30 meshes, tabletting the granules of 8-30 meshes into tablets by using a tabletting machine, detecting in groups, packaging, warehousing, and delivering out of a factory. In the composite sanitizer tablet containing TCCA, prepared by the method, the zinc sulfate is added to be used as a synergistic bactericide and an algicide, so that the coordination function of the bactericide and a flocculant is enhanced; and the composite sanitizer tablet has the characteristics of stable performance, low toxicity, no stimulation, broad-spectrum bactericidal performance, enhanced bactericidal effect and the like, and can accelerate the settlement of suspended matters in water, increase water transparency and greatly improve water quality condition, thereby being a new-generation composite preparation integrating multiple functions of sterilizing, disinfecting, alga removing and the like.
Description
Technical field
The invention belongs to the disinfectant field, relate to a kind of sym-closene composite bactericidal disinfectant tablet and preparation method thereof.
Background technology
Sym-closene is a kind of broad-spectrum high efficacy bactericide, is widely used in the disinfection of health care, epidemic prevention, fields such as the sterilization processing of industrial cycle water treatment, swimming pool, waste water treatment.At present, the sym-closene bactericide on the market is the bactericide of simple function.For example, number of patent application is 94107663.6, publication number is the application for a patent for invention disclosed " sym-closene bactericide " of CN1099222A, although have the few advantage of the rapid residue of dissolving, but bactericidal effect is single, also to add into other water treatment agents such as algicide, flocculants when adding disinfectant, can reach the requirement of processing.Therefore independent sym-closene tablet can not satisfy water treatment requirement more and more widely.
A kind of trichloro-isocyanide uric acid disinfection product compound formulation has appearred on the market, this compound formulation is the double-deck antibiotic tablet of forming with sym-closene, sodium sulphite and auxiliary material, this composite sheet has the characteristics of composite efficacy, but constitute this composite sheet and comprised many and numerous and diverse auxiliary material such as sodium sulphite, polyvinylpyrrolidone, sodium bicarbonate, tartaric acid, sodium sulphate, dodecyl sodium sulfate and lauryl magnesium sulfate, sodium carboxymethylcellulose, its complicated process of preparation, operation easier is very big, is difficult to suitability for industrialized production.
Summary of the invention
Purpose of the present invention just provides a kind of preparation method with sym-closene composite bactericidal disinfectant tablet that effect is rapid, sterilizing power is strong and applied widely.
The technical scheme that realizes the object of the invention is:
A kind of sym-closene composite bactericidal disinfectant tablet is characterized in that containing:
14 water aluminum sulfate of the cupric sulfate pentahydrate of the TCCA of 50-98 weight portion 90%, 1-10 weight portion, 1-10 weight portion, the zinc sulphate of 1-10 weight portion, the boric acid of 1-3 weight portion.
Constitute in the sym-closene composite bactericidal disinfectant tablet and contain the sodium tetraborate of 1-5 weight portion, the PBTCA of 1-5 weight portion, the sodium sulphate of 5-30 weight portion and the essence of 1-5 weight portion.
The preparation method of above-mentioned a kind of sym-closene composite bactericidal disinfectant tablet is; composition proportion batching by the aforesaid right requirement; evenly stir and formed the combination material in 25-40 minute; described combination material is sent into comminutor forms particle, after therefrom divide and sift out 8-30 purpose particle, be used for the compression moulding tablet with the 8-30 order particle that described branch sifts out again; after grouping detects; pack, warehouse-in dispatches from the factory.
Sym-closene composite bactericidal disinfectant tablet provided by the present invention and preparation method thereof compared with prior art has following advantage:
1, owing in sym-closene composite bactericidal disinfectant tablet, increased zinc sulphate as Synergistic biocidal agent and algicide, strengthened the coordinative role of bactericide and flocculant, except that having characteristics such as stable performance, low toxicity, non-stimulated, broad-spectrum sterilization, when bactericidal effect is improved, can quicken the sedimentation of suspension in the water, increase the transparency of water, improve the water quality situation greatly, be sterilization of new generation, sterilization, remove the compound formulation of multi-functional unifications such as algae;
2, sym-closene composite bactericidal disinfectant tablet is in potent disinfectant sym-closene, added auxiliary additives such as 14 water aluminum sulfate, cupric sulfate pentahydrate, zinc sulphate, rolling then forming.Cupric sulfate pentahydrate suppresses the breeding of algae in the water as the water algicide in this product, and an amount of copper ion can make water present beautiful sky blue simultaneously; It is heavy that 14 water aluminum sulfate promote that as the flocculant in the water suspension in the swimming-pool water adds prompt drop, thereby play the effect that purifies water, and makes water after the processing when disinfection is satisfied, more as clear as crystal; Zinc sulphate has strengthened the coordinative role of bactericide and flocculant as Synergistic biocidal agent and algicide; The introducing of control sodium ion in each link of production process, the water quality of effectively having avoided being caused by sodium ion is turned to be yellow, and seems muddy problem; Auxiliary additive 14 water aluminum sulfate in this tablet, cupric sulfate pentahydrate, zinc sulphate are all soluble in water, drop into back dissolving rapidly in the water, have increased the sym-closene not soluble in water and the contact area of water, quicken its dissolving.
3, in the technology of preparation sym-closene composite bactericidal disinfectant tablet; adopt batch mixing step after the first granulation: because each component ratio differs greatly in the prescription; when the particle batch mixing; in order to guarantee that material as far as possible evenly; adopt the cupric sulfate pentahydrate, 14 water aluminum sulfate, the zinc sulphate batch mixing that add 10% sym-closene particle and formula ratio earlier; the sym-closene particle that adds surplus behind the mixing again makes the uniformity of product can reach requirement.
Embodiment
Preparation method to sym-closene composite bactericidal disinfectant tablet provided by the present invention is described in further detail below in conjunction with technological process.
Embodiment 1
Select the TCCA of 50 weight portions 90%, the cupric sulfate pentahydrate of 7 weight portions, 14 water aluminum sulfate of 5 weight portions, the zinc sulphate of 3 weight portions, the boric acid of 1 weight portion; insert evenly to stir in the batch mixer and formed the combination material in 35 minutes; the combinations thereof material is sent into comminutor cause particle; therefrom divide then and sift out 8-30 purpose particle; again with tablet press machine with divide the 8-30 order particle that sifts out be pressed into tablet, after grouping detects, pack; warehouse-in dispatches from the factory.
Embodiment 2
Select the TCCA of 98 weight portions 90%, the cupric sulfate pentahydrate of 1.0 weight portions, 14 water aluminum sulfate of 8.0 weight portions, the zinc sulphate of 7.0 weight portions, the boric acid of 1.0 weight portions; insert evenly to stir in the batch mixer and formed the combination material in 40 minutes; the combinations thereof material is sent into comminutor cause particle; therefrom divide then and sift out 8-30 purpose particle; again with tablet press machine with divide the 8-30 order particle that sifts out be pressed into tablet, after grouping detects, pack; warehouse-in dispatches from the factory.
Embodiment 3
Select the TCCA of 70 weight portions 90%, the cupric sulfate pentahydrate of 8 weight portions, 14 water aluminum sulfate of 7 weight portions, the zinc sulphate of 8 weight portions, the boric acid of 1.0 weight portions; insert evenly to stir in the batch mixer and formed the combination material in 25 minutes; the combinations thereof material is sent into comminutor cause particle; therefrom divide then and sift out 8-30 purpose particle; again with tablet press machine with divide the 8-30 order particle that sifts out be pressed into tablet, after grouping detects, pack; warehouse-in dispatches from the factory.
Embodiment 4:
Select the TCCA of 60 weight portions 90%, the cupric sulfate pentahydrate of 7 weight portions, 14 water aluminum sulfate of 6 weight portions, the zinc sulphate of 5 weight portions, the boric acid of 1.2 weight portions and the sodium tetraborate of 5.0 weight portions; insert evenly to stir in the batch mixer and formed the combination material in 30 minutes; the combinations thereof material is sent into comminutor cause particle; therefrom divide then and sift out 8-30 purpose particle; again with tablet press machine with divide the 8-30 order particle that sifts out be pressed into tablet, after grouping detects, pack; warehouse-in dispatches from the factory.
Embodiment 5
Select the TCCA of 80 weight portions 90%, the cupric sulfate pentahydrate of 6 weight portions, 14 water aluminum sulfate of 5 weight portions, the zinc sulphate of 6 weight portions, the boric acid of 1.0 weight portions and the sodium tetraborate of 1.0 weight portions; insert evenly to stir in the batch mixer and formed the combination material in 35 minutes; the combinations thereof material is sent into comminutor cause particle; therefrom divide then and sift out 8-30 purpose particle; again with tablet press machine with divide the 8-30 order particle that sifts out be pressed into tablet, after grouping detects, pack; warehouse-in dispatches from the factory.
Embodiment 6
Select the TCCA of 75 weight portions 90%, the cupric sulfate pentahydrate of 5 weight portions, 14 water aluminum sulfate of 4 weight portions, the zinc sulphate of 3 weight portions, the boric acid of 1.5 weight portions and the sodium tetraborate of 3.0 weight portions; insert evenly to stir in the batch mixer and formed the combination material in 25 minutes; the combinations thereof material is sent into comminutor cause particle; therefrom divide then and sift out 8-30 purpose particle; again with tablet press machine with divide the 8-30 order particle that sifts out be pressed into tablet, after grouping detects, pack; warehouse-in dispatches from the factory.
Embodiment 7
Select the TCCA of 65 weight portions 90%, the cupric sulfate pentahydrate of 4 weight portions, 14 water aluminum sulfate of 3 weight portions, the zinc sulphate of 4 weight portions, the boric acid of 1.0 weight portions and the sodium tetraborate of 2.0 weight portions; insert evenly to stir in the batch mixer and formed the combination material in 30 minutes; the combinations thereof material is sent into comminutor cause particle; therefrom divide then and sift out 8-30 purpose particle; again with tablet press machine with divide the 8-30 order particle that sifts out be pressed into tablet, after grouping detects, pack; warehouse-in dispatches from the factory.
The purpose of adding a certain amount of sodium tetraborate in the foregoing description is in order further to improve the virus killing effect of prepared sym-closene composite bactericidal disinfectant tablet.
Embodiment 8
Select the TCCA of 85 weight portions 90%, the cupric sulfate pentahydrate of 3 weight portions, 14 water aluminum sulfate of 5 weight portions, the zinc sulphate of 7 weight portions, the boric acid of 1.5 weight portions, the sodium tetraborate of 1.5 weight portions and the PBTCA of 5.0 weight portions; insert evenly to stir in the batch mixer and formed the combination material in 35 minutes; the combinations thereof material is sent into comminutor cause particle; therefrom divide then and sift out 8-30 purpose particle; again with tablet press machine with divide the 8-30 order particle that sifts out be pressed into tablet; after grouping detects; pack; warehouse-in dispatches from the factory.
Embodiment 9
Select the TCCA of 65 weight portions 90%, the cupric sulfate pentahydrate of 5 weight portions, 14 water aluminum sulfate of 6 weight portions, the zinc sulphate of 6 weight portions, the boric acid of 1.5 weight portions, the sodium tetraborate of 2.5 weight portions and the PBTCA of 1.2 weight portions; insert evenly to stir in the batch mixer and formed the combination material in 40 minutes; the combinations thereof material is sent into comminutor cause particle; therefrom divide then and sift out 8-30 purpose particle; again with tablet press machine with divide the 8-30 order particle that sifts out be pressed into tablet; after grouping detects; pack; warehouse-in dispatches from the factory.
Embodiment 10
Select the TCCA of 95 weight portions 90%, the cupric sulfate pentahydrate of 6 weight portions, 14 water aluminum sulfate of 7 weight portions, the zinc sulphate of 5 weight portions, the boric acid of 1.0 weight portions, the sodium tetraborate of 3.5 weight portions and the PBTCA of 3.0 weight portions; insert evenly to stir in the batch mixer and formed the combination material in 35 minutes; the combinations thereof material is sent into comminutor cause particle; therefrom divide then and sift out 8-30 purpose particle; again with tablet press machine with divide the 8-30 order particle that sifts out be pressed into tablet; after grouping detects; pack; warehouse-in dispatches from the factory.
Embodiment 11
Select the TCCA of 75 weight portions 90%, the cupric sulfate pentahydrate of 7 weight portions, 14 water aluminum sulfate of 8 weight portions, the zinc sulphate of 7 weight portions, the boric acid of 1.0 weight portions, the sodium tetraborate of 4.5 weight portions and the PBTCA of 2.0 weight portions; insert evenly to stir in the batch mixer and formed the combination material in 30 minutes; the combinations thereof material is sent into comminutor cause particle; therefrom divide then and sift out 8-30 purpose particle; again with tablet press machine with divide the 8-30 order particle that sifts out be pressed into tablet; after grouping detects; pack; warehouse-in dispatches from the factory.
Embodiment 12
Select the TCCA of 80 weight portions 90%, the cupric sulfate pentahydrate of 8 weight portions, 14 water aluminum sulfate of 6 weight portions, the zinc sulphate of 8 weight portions, the boric acid of 1.5 weight portions, the sodium tetraborate of 4.0 weight portions, the PBTCA of 1.5 weight portions and the essence of 1.5 weight portions; insert evenly to stir in the batch mixer and formed the combination material in 25 minutes; the combinations thereof material is sent into comminutor cause particle; therefrom divide then and sift out 8-30 purpose particle; again with tablet press machine with divide the 8-30 order particle that sifts out be pressed into tablet; after grouping detects; pack; warehouse-in dispatches from the factory.
Embodiment 13
Select the TCCA of 90 weight portions 90%, the cupric sulfate pentahydrate of 6 weight portions, 14 water aluminum sulfate of 5 weight portions, the zinc sulphate of 4 weight portions, the boric acid of 1.0 weight portions, the sodium tetraborate of 3.0 weight portions, the PBTCA of 2.5 weight portions and the essence of 2.0 weight portions; insert evenly to stir in the batch mixer and formed the combination material in 45 minutes; the combinations thereof material is sent into comminutor cause particle; therefrom divide then and sift out 8-30 purpose particle; again with tablet press machine with divide the 8-30 order particle that sifts out be pressed into tablet; after grouping detects; pack; warehouse-in dispatches from the factory.
Embodiment 14
Select the TCCA of 65 weight portions 90%, the cupric sulfate pentahydrate of 5 weight portions, 14 water aluminum sulfate of 4 weight portions, the zinc sulphate of 1 weight portion, the boric acid of 1.5 weight portions, the sodium tetraborate of 2.0 weight portions, the PBTCA of 3.5 weight portions and the essence of 3.0 weight portions; insert evenly to stir in the batch mixer and formed the combination material in 25 minutes; the combinations thereof material is sent into comminutor cause particle; therefrom divide then and sift out 8-30 purpose particle; again with tablet press machine with divide the 8-30 order particle that sifts out be pressed into tablet; after grouping detects; pack; warehouse-in dispatches from the factory.
Embodiment 15
Select the TCCA of 60 weight portions 90%, the cupric sulfate pentahydrate of 4 weight portions, 14 water aluminum sulfate of 1 weight portion, the zinc sulphate of 5 weight portions, the boric acid of 1.0 weight portions, the sodium tetraborate of 1.0 weight portions, the PBTCA of 4.5 weight portions and the essence of 4.5 weight portions; insert evenly to stir in the batch mixer and formed the combination material in 30 minutes; the combinations thereof material is sent into comminutor cause particle; therefrom divide then and sift out 8-30 purpose particle; again with tablet press machine with divide the 8-30 order particle that sifts out be pressed into tablet; after grouping detects; pack; warehouse-in dispatches from the factory.
The sym-closene composite bactericidal disinfectant tablet that utilizes method provided by the present invention to make can slowly dissolve in water, can effectively kill various pathogeny bacterium, sterilizing rate reaches 99.9%, said preparation proves through quantitative disinfecting test, said preparation acts on 1 minute when concentration 1000mg/L be 99.8% to the natural bacteria killing rate on the desktop, this disinfectant effective chlorine density 100mg/L effect was 99.95 to the staphylococcus aureus killing rate in 3 minutes, and 15 minutes killing rates of 50mg/L effect are 99.995%.
Above-mentioned prepared sym-closene composite bactericidal disinfectant tablet also has following characteristics: the potion multiple-effect, reduce the dispensing number of times, and easy to use.This product has increased zinc sulphate as Synergistic biocidal agent and algicide, Synergistic biocidal agent and flocculant coordinative role have been strengthened, through optimization of C, the sym-closene composite sheet of preparation is except that having characteristics such as stable performance, low toxicity, non-stimulated, broad-spectrum sterilization, make product have the action and efficacy of algicide, flocculant in efficient sterilizing, promptly the potion multiple-effect has reduced the swimming pool maintenance cost that the different efficacies product is offerd medicine respectively and caused, reduce labour intensity, be highly commended by customers deeply.
In addition, add cosolvent, quicken the dissolving of sheet, enable to satisfy multiple use.Behind an amount of adding 14 water aluminum sulfate, zinc sulphate, the cupric sulfate pentahydrate, not only on the use effect, be significantly improved, and because they all are sulphate soluble in water, drop into back dissolving rapidly in the water, increased the contact area that is difficult for molten sym-closene and water, promote its dissolving, play the effect of cosolvent.
3. avoid the introducing of sodium ion, strict control Na ion concentration strengthens the sense organ effect after swimming-pool water is handled below 250 ч g/g.This product passes through each raw-material control, and at granulation, batch mixing, roll the influence that each operational sequence such as sheet is noted factors such as environment, equipment, avoid the introducing of sodium ion, the an amount of simultaneously cupric sulfate pentahydrate that adds, use the back swimming pool to seem to present beautiful sky blue, make swimming-pool water reach the optimization process effect.
4. select boric acid to make releasing agent, efficiently solve the problem that a large amount of suspensions are arranged in the solution of product dissolving back.The normal dolomol of selecting is made releasing agent in domestic traditional pressed-disc technique, produces a large amount of floating foams in the solution when dolomol makes the product dissolving easily, influences clarity of solution and sense organ.If be used in the swimming pool, the time has been grown also and can form one deck mucous membrane on swimming pool wall, makes very stick-slip of pool wall, hidden danger such as cause that the swimmer slips easily; Sticking foam attached to doser, and the swimming-pool water cycle facilities on, cause very big trouble for the cleaning of medicine machine and recycle unit.Use boric acid place of magnesium stearate magnesium in this technology, by regulating each correlative factor such as pressure, frequency, releasing agent addition in the compressing tablet process, boric acid flowability and the relatively poor relatively problem of lubricity have been solved, make the tablet appearance that suppresses smooth, defectives such as no sliver, bad sheet and hole point, reach customer requirement, and avoided dolomol to make all drawbacks of releasing agent.
Claims (3)
1. sym-closene composite bactericidal disinfectant tablet is characterized in that containing:
14 water aluminum sulfate of the cupric sulfate pentahydrate of the TCCA of 50-98 weight portion 90%, 1-10 weight portion, 1-10 weight portion, the zinc sulphate of 1-10 weight portion, the boric acid of 1-3 weight portion.
2. sym-closene composite bactericidal disinfectant tablet according to claim 1 is characterized in that: constitute in the sym-closene composite bactericidal disinfectant tablet and contain the sodium tetraborate of 1-5 weight portion, the PBTCA of 1-5 weight portion, the sodium sulphate of 5-30 weight portion and the essence of 1-5 weight portion.
3. aforesaid right requires the preparation method of described sym-closene composite bactericidal disinfectant tablet to be; composition proportion batching by the aforesaid right requirement; evenly stir and formed the combination material in 25-40 minute; described combination material is sent into comminutor forms particle, after therefrom divide and sift out 8-30 purpose particle, be used for the compression moulding tablet with the 8-30 order particle that described branch sifts out again; after grouping detects; pack, warehouse-in dispatches from the factory.
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| CN 201110088196 CN102197830B (en) | 2011-04-09 | 2011-04-09 | Composite sanitizer tablet containing trichloroiminocyanuric acid (TCCA) and preparation method thereof |
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| CN 201110088196 CN102197830B (en) | 2011-04-09 | 2011-04-09 | Composite sanitizer tablet containing trichloroiminocyanuric acid (TCCA) and preparation method thereof |
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| CN102726447A (en) * | 2011-11-03 | 2012-10-17 | 上海蓝宇水处理有限公司 | Compound type disinfection tablet |
| CN102870809A (en) * | 2012-10-15 | 2013-01-16 | 鄄城康泰化工有限公司 | Trichloroisocyanuric acid sustained release tablets and preparation method thereof |
| CN106417365A (en) * | 2016-09-26 | 2017-02-22 | 四川环能德美科技股份有限公司 | Chemical algaecide for eutrophic water body algae and using method thereof |
| CN112369422A (en) * | 2020-11-16 | 2021-02-19 | 兰州理工大学 | Graphene oxide-trichloroisocyanuric acid compound, preparation method and application |
| CN113966748A (en) * | 2021-11-12 | 2022-01-25 | 嘉兴爱邦日用品有限公司 | Preparation method of stable and durable sterilizing aromatic tablet |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102726447A (en) * | 2011-11-03 | 2012-10-17 | 上海蓝宇水处理有限公司 | Compound type disinfection tablet |
| CN102870809A (en) * | 2012-10-15 | 2013-01-16 | 鄄城康泰化工有限公司 | Trichloroisocyanuric acid sustained release tablets and preparation method thereof |
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| CN112369422A (en) * | 2020-11-16 | 2021-02-19 | 兰州理工大学 | Graphene oxide-trichloroisocyanuric acid compound, preparation method and application |
| CN112369422B (en) * | 2020-11-16 | 2021-07-06 | 兰州理工大学 | Graphene oxide-trichloroisocyanuric acid compound, preparation method and application |
| CN113966748A (en) * | 2021-11-12 | 2022-01-25 | 嘉兴爱邦日用品有限公司 | Preparation method of stable and durable sterilizing aromatic tablet |
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