CN102153949A - As-cast finish concrete simulated coating - Google Patents

As-cast finish concrete simulated coating Download PDF

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Publication number
CN102153949A
CN102153949A CN 201110032299 CN201110032299A CN102153949A CN 102153949 A CN102153949 A CN 102153949A CN 201110032299 CN201110032299 CN 201110032299 CN 201110032299 A CN201110032299 A CN 201110032299A CN 102153949 A CN102153949 A CN 102153949A
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coating
polymer
water
pigment
coated
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CN102153949B (en
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郑柏存
傅乐峰
李漠
冯中军
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SHANGHAI SANRUI HIGH-POLYMER MATERIAL CO., LTD.
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SHANGHAI SANRUI CHEMISTRY CO Ltd
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Abstract

The invention discloses an as-cast finish concrete simulated coating. The coating consists of a bottom coating, a middle coating and a surface coating, wherein the bottom coating is an organic silicon polymer; the middle coating is a composition consisting of self-crosslinked polymer, filler, pigment, other auxiliary agents and water; the surface coating is a fluorine silicon resin polymer; the bottom coating is a closing layer and can play a role in closing pores of a base material; the middle coating is a coloring layer and can play a role in approaching the effect of the required as-cast finish concrete; and the surface coating is a cover surface layer and plays a role in resisting weather and contamination. The coating breaks through the technical bottleneck of as-cast finish concrete at home, and radically reduces the construction cost of the as-cast finish concrete.

Description

A kind of imitative Clear Concrete Paint
Technical field
The present invention relates to the building decoration technology field, particularly a kind of imitative Clear Concrete Paint.
Background technology
Clear-water concrete claims decorative concrete again, gains the name because of it has decorative effect.It belongs to one-time cast-forming; do not do any outer decoration; directly adopt the natural surface effect of onsite concrete as facing; therefore be different from normal concrete, surfacing is smooth, and color and luster is even; corner angle are clearly demarcated; N/D and pollution just are coated with one deck or two-layer transparent protective material on the surface, seem very natural, serious.
" yet clear-water concrete " enters Chinese technology later on and bigger variation has taken place technology.Because domestic concrete casting injection formation technology level and external gap are bigger, one-time formed concrete natural look scarcely possesses ornamental, common cold joint seam, the accumulation of salt in the surface soil, rust staining, pitted skin, honeycomb or the like defective is difficult to reach the high standard requirement of clear-water concrete moulding on technology.Must carry out later stage repairing and application handles.
Summary of the invention
The purpose of this invention is to provide a kind of imitative Clear Concrete Paint, described coating contains the primary coat sealer coat, in be coated with pigmented layer and face is coated with finish coat, multiple functions such as the waterproof of coating excellence, weather-proof, anti-contamination and decoration have been given, thereby broken through clear-water concrete technical bottleneck at home, and fundamentally reduced the building cost of clear-water concrete.
The object of the present invention is achieved like this:
A kind of imitative Clear Concrete Paint, this coating by primary coat, in be coated with and face is coated with and forms, wherein:
Primary coat is an organosilicon polymer;
In be coated with the following substances in percentage by weight of serving as reasons and form: self-crosslinking polymer 20~70%, filler 10~50%, pigment 10~30%, the water of other auxiliary agent 1~20% and surplus, gross weight is in 100%;
Face is painted with the fluorine silicon resin polymkeric substance;
Described organosilicon polymer is aqueous silane/siloxane polymer;
Described self-crosslinking polymer is a kind of or its mixture in pure third polymer emulsion, siloxane-acrylate copolymer emulsion or the cinepazid polymer emulsion, and its second-order transition temperature is 15~70 ℃;
Described filler is a kind of or its mixture in cement, silica powder, water-ground limestone, kaolin, barium sulfate, mica powder or the talcum powder;
Described pigment is a kind of or its mixture in Rutile type Titanium Dioxide, iron oxide pigment, phthalocyanine pigment or the composite pigment;
Described other auxiliary agent is to be made up of a kind of or wherein several mixing in dispersion agent, frostproofer, wetting agent, film coalescence aid, sterilant, coupling agent or the defoamer.
Described fluorine silicon resin polymkeric substance is a kind of or its mixture in the polymer-modified and water-based fluororesin polymkeric substance of water-based silicon third.
Primary coat of the present invention is a sealer coat, can play the effect of sealing base material pore; In be painted with pigmented layer, can play the effect near required clear-water concrete effect; Face is painted with finish coat, plays the effect of weather-proof and anti-contamination, and the present invention has broken through clear-water concrete technical bottleneck at home, and has fundamentally reduced the building cost of clear-water concrete.
Embodiment
Following examples further specify application of the present invention, but scope of the present invention are not produced any restriction.
In following examples, the main raw material(s) of using is described as follows:
Wacker E22, organic silican polymer emulsion, Wa Ke company produces, performance index such as following table;
Table 1 organic silican polymer emulsion performance index
Figure 632289DEST_PATH_IMAGE001
Vivid-410, the self-crosslinking acrylic polymer emulsion, Shanghai Sanrui Chemistry Co., Ltd produces, performance index such as following table:
Table 2 self-crosslinking acrylic polymer emulsion performance index
FSJ, fluorocarbon surfactant, E.I.Du Pont Company produces;
R-706, the rutile titanium white powder, E.I.Du Pont Company produces;
2-3168, the silicone resin defoamer is provided by Dow Corning Corporation;
Protectosil SC 60, the silicon-fluorine polymer thing is provided by Evonik Degussa Corp..
Embodiment 1
A kind of imitative Clear Concrete Paint, its prescription is (weight percent):
The imitative Clear Concrete Paint A prescription of table 3
Figure 250800DEST_PATH_IMAGE003
Add entry in reactor, add Wacker E22 or Protectosil SC 60 under stirring action, after being uniformly dispersed, keep stirring 20 ~ 50 minutes, the primary coat or the face that obtain among the composition A are coated with.
In reactor, add deionized water, under stirring action, add Sodium hexametaphosphate 99,2-3168, Texanol successively, after a component disperses or dissolves evenly, can add next component, after all components is uniformly dispersed, stir 5 minutes with the rotating speed maintenance of 600 ~ 700rpm.Under stirring action, add cement, R706 successively after finishing, after a component is uniformly dispersed, can add next component, after all components is uniformly dispersed, stirred 20 ~ 30 minutes with the rotating speed maintenance of 1000 ~ 1500rpm.The back rotating speed that finishes transfers to 500 ~ 600rpm, slowly adds Vivid-410, keep to stir 20 ~ 50 minutes, obtain among the composition A in be coated with.
Embodiment 2
A kind of imitative Clear Concrete Paint, its prescription is (weight percent):
The imitative Clear Concrete Paint B prescription of table 4
Figure 932579DEST_PATH_IMAGE004
Add entry in reactor, add Wacker E22 or Protectosil SC 60 under stirring action, after being uniformly dispersed, keep stirring 20 ~ 50 minutes, the primary coat or the face that obtain among the composition B are coated with.
In reactor, add deionized water, under stirring action, add Sodium hexametaphosphate 99, propylene glycol, 2-3168, Texanol successively, after a component disperses or dissolves evenly, can add next component, after all components is uniformly dispersed, stir 5 minutes with the rotating speed maintenance of 600 ~ 700rpm.Under stirring action, add water-ground limestone, barium sulfate, R706 successively after finishing, after a component is uniformly dispersed, can add next component, after all components is uniformly dispersed, stirred 20 ~ 30 minutes with the rotating speed maintenance of 1000 ~ 1500rpm.The back rotating speed that finishes transfers to 500 ~ 600rpm, slowly adds Vivid-410, keep to stir 20 ~ 50 minutes, obtain among the composition B in be coated with.
Embodiment 3
A kind of imitative Clear Concrete Paint, its prescription is (weight percent):
The imitative Clear Concrete Paint C prescription of table 5
Figure 811542DEST_PATH_IMAGE005
Add entry in reactor, add Wacker E22 or Protectosil SC 60 under stirring action, after being uniformly dispersed, keep stirring 20 ~ 50 minutes, the primary coat or the face that obtain among the composition C are coated with.
In reactor, add deionized water, under stirring action, add sodium polyphosphate, 2-3168, Texanol, FSJ, AMP-95 successively, after dispersing or dissolving evenly, a component can add next component, after all components is uniformly dispersed, stirred 5 minutes with the rotating speed maintenance of 600 ~ 700rpm.Under stirring action, add silica powder, kaolin, R706 successively after finishing, after a component is uniformly dispersed, can add next component, after all components is uniformly dispersed, stirred 20 ~ 30 minutes with the rotating speed maintenance of 1000 ~ 1500rpm.The back rotating speed that finishes transfers to 500 ~ 600rpm, slowly adds Vivid-410, keep to stir 20 ~ 50 minutes, obtain among the composition C in be coated with.
The performance test results sees Table 6:
Table 6 imitative Clear Concrete Paint The performance test results of the present invention
Explanation to above-mentioned term of using and testing method:
1 water tolerance
Measure according to GB/T 1733-1993 " water-resistance property of coating assay method ".
2 alkali resistances
Measure according to GB 9265-1988 " the alkali-proof mensuration of building coating coating ".
3 washability
Measure according to GB/T 9266-2009 " mensuration of building coating coating abrasion resistance ".
4 artificial weathering ageing resistances
Measure according to GB/T 14522-2008 " mechanical industry product plastics, coating, elastomeric material artificial weathering test method fluorescent ultraviolet lamp ", test conditions is as shown in table 7:
Table 7 artificial weathering ageing resistance test conditions
Figure 715616DEST_PATH_IMAGE007

Claims (1)

1. imitative Clear Concrete Paint, it is characterized in that this coating by primary coat, in be coated with and face is coated with and forms, wherein:
Primary coat is an organosilicon polymer;
In be coated with the following substances in percentage by weight of serving as reasons and form: self-crosslinking polymer 20~70%, filler 10~50%, pigment 10~30%, the water of other auxiliary agent 1~20% and surplus, gross weight is in 100%;
Face is painted with the fluorine silicon resin polymkeric substance;
Described organosilicon polymer is aqueous silane/siloxane polymer;
Described self-crosslinking polymer is a kind of or its mixture in pure third polymer emulsion, siloxane-acrylate copolymer emulsion or the cinepazid polymer emulsion, and its second-order transition temperature is 15~70 ℃;
Described filler is a kind of or its mixture in cement, silica powder, water-ground limestone, kaolin, barium sulfate, mica powder or the talcum powder;
Described pigment is a kind of or its mixture in Rutile type Titanium Dioxide, iron oxide pigment, phthalocyanine pigment or the composite pigment;
Described other auxiliary agent is to be made up of a kind of or wherein several mixing in dispersion agent, frostproofer, wetting agent, film coalescence aid, sterilant, coupling agent or the defoamer;
Described fluorine silicon resin polymkeric substance is a kind of or its mixture in the polymer-modified and water-based fluororesin polymkeric substance of water-based silicon third.
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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102417746A (en) * 2012-01-04 2012-04-18 许从玉 Powdered emulsion paint and production method thereof
CN102531498A (en) * 2012-01-04 2012-07-04 许从玉 Powdery anti-cracking elastic coating and production method thereof
CN102976788A (en) * 2012-09-29 2013-03-20 北京东方雨虹防水技术股份有限公司 Preparation method and use method of as-cast finish concrete surface protection coating material
CN103146302A (en) * 2013-02-25 2013-06-12 广州市诚美涂饰工程有限公司 Coating for protecting fair-faced concrete and construction technology thereof
CN103881496A (en) * 2014-03-18 2014-06-25 中国兵器工业集团第五三研究所 Transparent protective coat for concrete
CN103922800A (en) * 2014-03-14 2014-07-16 上海市建筑科学研究院(集团)有限公司 Protective agent for clear water concrete
CN104109471A (en) * 2014-07-15 2014-10-22 武汉武大巨成结构股份有限公司 High-air-permeability high-weather-resistance green architectural protective paint
CN104891876A (en) * 2015-05-08 2015-09-09 上海贝塔建筑科技有限公司 As-cast concrete and preparation method thereof
CN105130315A (en) * 2015-07-03 2015-12-09 上海贝塔建筑科技有限公司 Organic elastic pseudo-fair-faced concrete paint
CN105368239A (en) * 2014-08-12 2016-03-02 关西涂料株式会社 Pollution resistant matting aqueous paint composition and forming method thereof
CN105623502A (en) * 2016-03-29 2016-06-01 上海科焱建筑装饰工程有限公司 Coating for surface protection of bare concrete
CN106590264A (en) * 2016-12-30 2017-04-26 上海奇想青晨新材料科技股份有限公司 Carbon-titanium modified acrylic resin anticorrosion intermediate paint and preparation method thereof
CN108165167A (en) * 2018-01-23 2018-06-15 中国铁道科学研究院铁道建筑研究所 A kind of concrete surface aberration modified coating material
CN109021799A (en) * 2018-06-29 2018-12-18 深圳市艾贝比品牌管理咨询有限公司 A kind of automobile-used paint for decoration
CN110903056A (en) * 2018-09-18 2020-03-24 武汉源锦商品混凝土有限公司 High-strength self-compacting fair-faced concrete and preparation method thereof
CN111040540A (en) * 2019-12-20 2020-04-21 上海衡峰厚千水性氟碳涂料有限公司 Fluorocarbon primer coat for concrete
CN111777430A (en) * 2020-09-04 2020-10-16 湖南固特邦土木技术发展有限公司 Water-based high-weather-resistance fair-faced concrete protective coating system and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1919945A (en) * 2006-09-20 2007-02-28 江苏晨光涂料有限公司 Elastic thin layer thermal insulation coat
CN101585992A (en) * 2009-06-25 2009-11-25 袁泉利 Heat insulating reflecting anticorrosive paint

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1919945A (en) * 2006-09-20 2007-02-28 江苏晨光涂料有限公司 Elastic thin layer thermal insulation coat
CN101585992A (en) * 2009-06-25 2009-11-25 袁泉利 Heat insulating reflecting anticorrosive paint

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102531498A (en) * 2012-01-04 2012-07-04 许从玉 Powdery anti-cracking elastic coating and production method thereof
CN102417746A (en) * 2012-01-04 2012-04-18 许从玉 Powdered emulsion paint and production method thereof
CN102976788A (en) * 2012-09-29 2013-03-20 北京东方雨虹防水技术股份有限公司 Preparation method and use method of as-cast finish concrete surface protection coating material
CN102976788B (en) * 2012-09-29 2014-09-10 北京东方雨虹防水技术股份有限公司 Preparation method and use method of as-cast finish concrete surface protection coating material
CN103146302A (en) * 2013-02-25 2013-06-12 广州市诚美涂饰工程有限公司 Coating for protecting fair-faced concrete and construction technology thereof
CN103922800A (en) * 2014-03-14 2014-07-16 上海市建筑科学研究院(集团)有限公司 Protective agent for clear water concrete
CN103881496A (en) * 2014-03-18 2014-06-25 中国兵器工业集团第五三研究所 Transparent protective coat for concrete
CN103881496B (en) * 2014-03-18 2016-05-04 中国兵器工业集团第五三研究所 A kind of concrete transparent protecting coating
CN104109471A (en) * 2014-07-15 2014-10-22 武汉武大巨成结构股份有限公司 High-air-permeability high-weather-resistance green architectural protective paint
CN105368239A (en) * 2014-08-12 2016-03-02 关西涂料株式会社 Pollution resistant matting aqueous paint composition and forming method thereof
CN104891876A (en) * 2015-05-08 2015-09-09 上海贝塔建筑科技有限公司 As-cast concrete and preparation method thereof
CN105130315A (en) * 2015-07-03 2015-12-09 上海贝塔建筑科技有限公司 Organic elastic pseudo-fair-faced concrete paint
CN105623502A (en) * 2016-03-29 2016-06-01 上海科焱建筑装饰工程有限公司 Coating for surface protection of bare concrete
CN106590264A (en) * 2016-12-30 2017-04-26 上海奇想青晨新材料科技股份有限公司 Carbon-titanium modified acrylic resin anticorrosion intermediate paint and preparation method thereof
CN108165167A (en) * 2018-01-23 2018-06-15 中国铁道科学研究院铁道建筑研究所 A kind of concrete surface aberration modified coating material
CN109021799A (en) * 2018-06-29 2018-12-18 深圳市艾贝比品牌管理咨询有限公司 A kind of automobile-used paint for decoration
CN110903056A (en) * 2018-09-18 2020-03-24 武汉源锦商品混凝土有限公司 High-strength self-compacting fair-faced concrete and preparation method thereof
CN111040540A (en) * 2019-12-20 2020-04-21 上海衡峰厚千水性氟碳涂料有限公司 Fluorocarbon primer coat for concrete
CN111777430A (en) * 2020-09-04 2020-10-16 湖南固特邦土木技术发展有限公司 Water-based high-weather-resistance fair-faced concrete protective coating system and preparation method thereof

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