Summary of the invention
The purpose of this invention is to provide a kind of imitative Clear Concrete Paint, described coating contains the primary coat sealer coat, in be coated with pigmented layer and face is coated with finish coat, multiple functions such as the waterproof of coating excellence, weather-proof, anti-contamination and decoration have been given, thereby broken through clear-water concrete technical bottleneck at home, and fundamentally reduced the building cost of clear-water concrete.
The object of the present invention is achieved like this:
A kind of imitative Clear Concrete Paint, this coating by primary coat, in be coated with and face is coated with and forms, wherein:
Primary coat is an organosilicon polymer;
In be coated with the following substances in percentage by weight of serving as reasons and form: self-crosslinking polymer 20~70%, filler 10~50%, pigment 10~30%, the water of other auxiliary agent 1~20% and surplus, gross weight is in 100%;
Face is painted with the fluorine silicon resin polymkeric substance;
Described organosilicon polymer is aqueous silane/siloxane polymer;
Described self-crosslinking polymer is a kind of or its mixture in pure third polymer emulsion, siloxane-acrylate copolymer emulsion or the cinepazid polymer emulsion, and its second-order transition temperature is 15~70 ℃;
Described filler is a kind of or its mixture in cement, silica powder, water-ground limestone, kaolin, barium sulfate, mica powder or the talcum powder;
Described pigment is a kind of or its mixture in Rutile type Titanium Dioxide, iron oxide pigment, phthalocyanine pigment or the composite pigment;
Described other auxiliary agent is to be made up of a kind of or wherein several mixing in dispersion agent, frostproofer, wetting agent, film coalescence aid, sterilant, coupling agent or the defoamer.
Described fluorine silicon resin polymkeric substance is a kind of or its mixture in the polymer-modified and water-based fluororesin polymkeric substance of water-based silicon third.
Primary coat of the present invention is a sealer coat, can play the effect of sealing base material pore; In be painted with pigmented layer, can play the effect near required clear-water concrete effect; Face is painted with finish coat, plays the effect of weather-proof and anti-contamination, and the present invention has broken through clear-water concrete technical bottleneck at home, and has fundamentally reduced the building cost of clear-water concrete.
Embodiment
Following examples further specify application of the present invention, but scope of the present invention are not produced any restriction.
In following examples, the main raw material(s) of using is described as follows:
Wacker E22, organic silican polymer emulsion, Wa Ke company produces, performance index such as following table;
Table 1 organic silican polymer emulsion performance index
Vivid-410, the self-crosslinking acrylic polymer emulsion, Shanghai Sanrui Chemistry Co., Ltd produces, performance index such as following table:
Table 2 self-crosslinking acrylic polymer emulsion performance index
FSJ, fluorocarbon surfactant, E.I.Du Pont Company produces;
R-706, the rutile titanium white powder, E.I.Du Pont Company produces;
2-3168, the silicone resin defoamer is provided by Dow Corning Corporation;
Protectosil SC 60, the silicon-fluorine polymer thing is provided by Evonik Degussa Corp..
Embodiment 1
A kind of imitative Clear Concrete Paint, its prescription is (weight percent):
The imitative Clear Concrete Paint A prescription of table 3
Add entry in reactor, add Wacker E22 or Protectosil SC 60 under stirring action, after being uniformly dispersed, keep stirring 20 ~ 50 minutes, the primary coat or the face that obtain among the composition A are coated with.
In reactor, add deionized water, under stirring action, add Sodium hexametaphosphate 99,2-3168, Texanol successively, after a component disperses or dissolves evenly, can add next component, after all components is uniformly dispersed, stir 5 minutes with the rotating speed maintenance of 600 ~ 700rpm.Under stirring action, add cement, R706 successively after finishing, after a component is uniformly dispersed, can add next component, after all components is uniformly dispersed, stirred 20 ~ 30 minutes with the rotating speed maintenance of 1000 ~ 1500rpm.The back rotating speed that finishes transfers to 500 ~ 600rpm, slowly adds Vivid-410, keep to stir 20 ~ 50 minutes, obtain among the composition A in be coated with.
Embodiment 2
A kind of imitative Clear Concrete Paint, its prescription is (weight percent):
The imitative Clear Concrete Paint B prescription of table 4
Add entry in reactor, add Wacker E22 or Protectosil SC 60 under stirring action, after being uniformly dispersed, keep stirring 20 ~ 50 minutes, the primary coat or the face that obtain among the composition B are coated with.
In reactor, add deionized water, under stirring action, add Sodium hexametaphosphate 99, propylene glycol, 2-3168, Texanol successively, after a component disperses or dissolves evenly, can add next component, after all components is uniformly dispersed, stir 5 minutes with the rotating speed maintenance of 600 ~ 700rpm.Under stirring action, add water-ground limestone, barium sulfate, R706 successively after finishing, after a component is uniformly dispersed, can add next component, after all components is uniformly dispersed, stirred 20 ~ 30 minutes with the rotating speed maintenance of 1000 ~ 1500rpm.The back rotating speed that finishes transfers to 500 ~ 600rpm, slowly adds Vivid-410, keep to stir 20 ~ 50 minutes, obtain among the composition B in be coated with.
Embodiment 3
A kind of imitative Clear Concrete Paint, its prescription is (weight percent):
The imitative Clear Concrete Paint C prescription of table 5
Add entry in reactor, add Wacker E22 or Protectosil SC 60 under stirring action, after being uniformly dispersed, keep stirring 20 ~ 50 minutes, the primary coat or the face that obtain among the composition C are coated with.
In reactor, add deionized water, under stirring action, add sodium polyphosphate, 2-3168, Texanol, FSJ, AMP-95 successively, after dispersing or dissolving evenly, a component can add next component, after all components is uniformly dispersed, stirred 5 minutes with the rotating speed maintenance of 600 ~ 700rpm.Under stirring action, add silica powder, kaolin, R706 successively after finishing, after a component is uniformly dispersed, can add next component, after all components is uniformly dispersed, stirred 20 ~ 30 minutes with the rotating speed maintenance of 1000 ~ 1500rpm.The back rotating speed that finishes transfers to 500 ~ 600rpm, slowly adds Vivid-410, keep to stir 20 ~ 50 minutes, obtain among the composition C in be coated with.
The performance test results sees Table 6:
Table 6 imitative Clear Concrete Paint The performance test results of the present invention
Explanation to above-mentioned term of using and testing method:
1 water tolerance
Measure according to GB/T 1733-1993 " water-resistance property of coating assay method ".
2 alkali resistances
Measure according to GB 9265-1988 " the alkali-proof mensuration of building coating coating ".
3 washability
Measure according to GB/T 9266-2009 " mensuration of building coating coating abrasion resistance ".
4 artificial weathering ageing resistances
Measure according to GB/T 14522-2008 " mechanical industry product plastics, coating, elastomeric material artificial weathering test method fluorescent ultraviolet lamp ", test conditions is as shown in table 7:
Table 7 artificial weathering ageing resistance test conditions