CN102134415B - 溶剂型涂料用含氟类丙烯酸酯流平剂 - Google Patents
溶剂型涂料用含氟类丙烯酸酯流平剂 Download PDFInfo
- Publication number
- CN102134415B CN102134415B CN2011100593535A CN201110059353A CN102134415B CN 102134415 B CN102134415 B CN 102134415B CN 2011100593535 A CN2011100593535 A CN 2011100593535A CN 201110059353 A CN201110059353 A CN 201110059353A CN 102134415 B CN102134415 B CN 102134415B
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- CN
- China
- Prior art keywords
- leveling agent
- butyl acetate
- acrylate
- fluorine
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 32
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 title claims abstract description 19
- 239000002904 solvent Substances 0.000 title claims abstract description 16
- 238000000576 coating method Methods 0.000 title claims abstract description 14
- 239000011248 coating agent Substances 0.000 title claims abstract description 13
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 229910052731 fluorine Inorganic materials 0.000 title claims abstract description 9
- 239000011737 fluorine Substances 0.000 title claims abstract description 9
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical group CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 9
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 7
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical group CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 7
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- 238000010992 reflux Methods 0.000 claims description 6
- YJKHMSPWWGBKTN-UHFFFAOYSA-N 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl 2-methylprop-2-enoate Chemical group CC(=C)C(=O)OCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)F YJKHMSPWWGBKTN-UHFFFAOYSA-N 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 3
- 239000003999 initiator Substances 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 239000002966 varnish Substances 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical group COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- QTKPMCIBUROOGY-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)F QTKPMCIBUROOGY-UHFFFAOYSA-N 0.000 description 2
- FEUFEGJTJIHPOF-UHFFFAOYSA-N 2-butyl acrylic acid Chemical compound CCCCC(=C)C(O)=O FEUFEGJTJIHPOF-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- -1 Hexafluorobutyl Chemical group 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 2
- 241000675108 Citrus tangerina Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000006115 industrial coating Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
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- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2011100593535A CN102134415B (zh) | 2011-03-11 | 2011-03-11 | 溶剂型涂料用含氟类丙烯酸酯流平剂 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2011100593535A CN102134415B (zh) | 2011-03-11 | 2011-03-11 | 溶剂型涂料用含氟类丙烯酸酯流平剂 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102134415A CN102134415A (zh) | 2011-07-27 |
CN102134415B true CN102134415B (zh) | 2013-06-12 |
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CN2011100593535A Active CN102134415B (zh) | 2011-03-11 | 2011-03-11 | 溶剂型涂料用含氟类丙烯酸酯流平剂 |
Country Status (1)
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CN (1) | CN102134415B (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105524208B (zh) * | 2015-09-17 | 2017-11-21 | 韶关欧文化学工业有限公司 | 一种含氟丙烯酸酯共聚物流平剂的制备方法 |
CN107652746A (zh) * | 2016-07-23 | 2018-02-02 | 天津市新丽华色材有限责任公司 | 一种丙烯酸酯类流平剂 |
CN108707213B (zh) * | 2018-05-18 | 2020-05-29 | 杭州师范大学 | 一种超支化嵌段高分子共聚物的制备方法与应用 |
CN111154025B (zh) * | 2018-11-07 | 2022-04-22 | 上海飞凯材料科技股份有限公司 | 含氟树脂、涂料及制备方法 |
CN110128659B (zh) * | 2019-05-15 | 2021-11-09 | 珠海东诚新材料股份有限公司 | 一种可改善涂料复涂性能的有机硅流平剂及其应用 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101225262B (zh) * | 2008-01-30 | 2011-05-25 | 陈永康 | 涂料油墨用氟碳化合物改性聚丙烯酸酯流平剂及生产方法 |
CN101284960B (zh) * | 2008-05-20 | 2011-06-22 | 陈永康 | 涂料油墨用浮色发花分散剂及其生产方法 |
CN101591486A (zh) * | 2009-06-12 | 2009-12-02 | 陈永康 | 防涂鸦和易清洗氟硅改性丙烯酸酯流平剂及生产方法 |
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- 2011-03-11 CN CN2011100593535A patent/CN102134415B/zh active Active
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CN102134415A (zh) | 2011-07-27 |
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Owner name: ANHUI XOANONS CHEMICAL CO., LTD. Free format text: FORMER OWNER: CHEN YONGKANG Effective date: 20130402 |
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C41 | Transfer of patent application or patent right or utility model | ||
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Free format text: CORRECT: ADDRESS; FROM: 226152 NANTONG, JIANGSU PROVINCE TO: 247200 CHIZHOU, ANHUI PROVINCE |
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TA01 | Transfer of patent application right |
Effective date of registration: 20130402 Address after: 247200 Anhui city of Chizhou province Dongzhi County Xiang Yu Chemical Industrial Park Tonghe Road Applicant after: ANHUI JIAZHI XINNUO CHEMICAL CO.,LTD. Address before: 226152 Jiangsu province Nantong Jiazhi Haimen Yu Dong Industrial Zone Xinyu CIGNA (Nantong) Chemical Co. Ltd. Applicant before: Chen Yongkang |
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C14 | Grant of patent or utility model | ||
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C56 | Change in the name or address of the patentee | ||
CP01 | Change in the name or title of a patent holder |
Address after: 247200 Anhui city of Chizhou province Dongzhi County Xiang Yu Chemical Industrial Park Tonghe Road Patentee after: ANHUI XOANONS CHEMICAL Co.,Ltd. Address before: 247200 Anhui city of Chizhou province Dongzhi County Xiang Yu Chemical Industrial Park Tonghe Road Patentee before: ANHUI JIAZHI XINNUO CHEMICAL CO.,LTD. |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Fluorine containing acrylic leveling agents for solvent based coatings Effective date of registration: 20231129 Granted publication date: 20130612 Pledgee: Agricultural Bank of China Limited Dongzhi County Branch Pledgor: ANHUI XOANONS CHEMICAL Co.,Ltd. Registration number: Y2023980068311 |