CN102100233B - A kind of containing the fungicidal composition of benziothiazolinone and own azoles alcohol - Google Patents
A kind of containing the fungicidal composition of benziothiazolinone and own azoles alcohol Download PDFInfo
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- CN102100233B CN102100233B CN201110048414.8A CN201110048414A CN102100233B CN 102100233 B CN102100233 B CN 102100233B CN 201110048414 A CN201110048414 A CN 201110048414A CN 102100233 B CN102100233 B CN 102100233B
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Abstract
The present invention relates to a kind of Bactericide composition with synergistic function, its effective active composition contains benziothiazolinone and own azoles alcohol, the wherein weight ratio 1: 40��80: 5 of benziothiazolinone and own azoles alcohol, effective active composition adds auxiliary agent and promoting agent makes wettable powder, water dispersible granules, suspension agent, is mainly used in preventing and treating the Powdery Mildew of vegetables and fruit tree, black spot, gray mold.
Description
Technical field
The invention belongs to technical field of pesticide, it relates to a kind of containing the fungicidal composition of benziothiazolinone and own azoles alcohol.
Technical background
Benziothiazolinone (Benziothiazolinone) is the heterocyclic nitrogen-group fungicide of Shaanxi Xi great HuaTe Science Industrial Co., Ltd. exploitation. Molecular formula: C7H5NOS, chemical name: 1,2 benzisothiazole-3-ketones.
Benziothiazolinone is a kind of efficient, wide-spectrum bactericide, has and destroys germ nuclear structures, and interference germ cell metabolism so that it is physiologic derangement causes germ dead.
Own azoles alcohol (Hexaconazole) is the triazole bactericidal agent of Syngenta Co., Ltd's exploitation. Molecular formula: C14H17Cl2X3O, chemical name: (RS)-2-(2,4 dichloro benzene base)-1-(1H-1,2,4-triazol-1-yl)-own-2-alcohol.
Own azoles alcohol belongs to sterol demethylation inhibitors, destroys and stops the biosynthesizing of the cytolemma important composition composition ergosterol of germ, cause cytolemma not formed, and makes germ dead. Suction, protective material therapeutic activity in tool.
No matter be benziothiazolinone, own azoles alcohol or other efficient germicides, be used alone for a long time, it is easy to disease is developed immunity to drugs, cause dosage to strengthen, anti-effect reduces, the problem of lasting period shortening, is unfavorable for environment sustainable development. The effective constituent of the different mechanism of action carries out mixture, is delay disease to develop immunity to drugs conventional method, and judges that this mixture is synergism or antagonistic action according to the effect in production application. Mixture effect is significantly filled a prescription, it is possible to significantly improve anti-effect, greatly reduces the dosage of agricultural chemicals, also can expand fungicidal spectrum, it is to increase germ-killing efficiency. Benziothiazolinone destroys germ nuclear structures, and own azoles alcohol acts on the cytolemma of germ, and the mechanism of action is different, and mutual mixture has good synergism within the specific limits.
Summary of the invention
It is an object of the invention to propose a kind of have synergistic function, use cost effect low, anti-good containing the fungicidal composition of benziothiazolinone and own azoles alcohol.
The present invention is achieved through the following technical solutions:
Containing a fungicidal composition for benziothiazolinone and own azoles alcohol, wherein benziothiazolinone and own azoles alcohol weight ratio are 1-40: 80-5.
The described fungicidal composition containing benziothiazolinone and own azoles alcohol, wherein benziothiazolinone and own azoles alcohol weight ratio are 1-30: 70-10.
The described fungicidal composition containing benziothiazolinone and own azoles alcohol, wherein benziothiazolinone and own azoles alcohol weight ratio are 1-20: 60-20.
The described fungicidal composition containing benziothiazolinone and own azoles alcohol, wherein effective active component content accounts for the 10-80% of gross weight.
Can being mixed with, during the described fungicidal composition practical application containing benziothiazolinone and own azoles alcohol, any formulation agriculturally allowed, preparation formulation makes the green pesticide forms such as wettable powder, water dispersible granules or suspension agent.
Comprise when constituent makes wettable powder and form content as follows: benziothiazolinone 1-40%, own azoles alcohol 5-80%, dispersion agent 5-10%, wetting agent 2-10%, filler 8-90%.
By benziothiazolinone, own azoles alcohol, dispersion agent, wetting agent, filler mixing, mixing in mixed cylinder, after micronizer mill is pulverized, remix is even, namely can be made into benziothiazolinone own azoles alcohol wettable powder product.
Following component concentration is comprised: benziothiazolinone 1-40%, own azoles alcohol 5-80%, dispersion agent 3-12%, wetting agent 1-8%, disintegrating agent 1-10%, filler 10-90% when composition makes water dispersible granules.
Benziothiazolinone, own azoles alcohol, dispersion agent, wetting agent, disintegrating agent, filler etc. are obtained through comminution by gas stream together the particle diameter needed, obtains granulation materials. Item is quantitatively sent in fluidized bed granulation drying machine through granulating and after drying, obtain benziothiazolinone diniconazole water dispersible granule product.
Following component concentration is comprised: benziothiazolinone 1-40%, own azoles alcohol 5-80%, dispersion agent 2-10%, wetting agent 2-10%, defoamer 0.1-1%, thickening material 0.1-2%, antifreezing agent 0.1-8%, deionized water add to 100% when constituent makes suspension agent.
By dispersion agent in above-mentioned formulation material, wetting agent, defoamer, thickening material, antifreezing agent through telling that shear-mixed is even, add benziothiazolinone, own azoles alcohol, ball milling machine ball milling 2-3 hour, make diameter of particle all at 5 ��m once, obtained benziothiazolinone hexaconazole suspending agent product.
Described dispersion agent be selected from polycarboxylate, sulfonated lignin, alkylphenol-polyethenoxy phonetic formaldehyde condensation products vitriol, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acidformaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, ester polyoxyethylene phonetic in one or more.
Described wetting agent is selected from: one or more in sodium lauryl sulphate, Sodium dodecylbenzene sulfonate, Nekal BX, moistening permeate agent F, spaonin powder, silkworm excrement, Seed of Chinese Soapberry powder.
Described antifreezing agent is selected from: one or more in ethylene glycol, propylene glycol, glycerol, polyoxyethylene glycol.
Described defoamer is selected from: one or more in silicone oil, silicone compound, C10-20 saturated fatty acid compounds, C8-10 aliphatic alcohols compound.
Described thickening material is selected from: one or more in xanthan gum, polyvinyl alcohol, polyoxyethylene glycol.
Described disintegrating agent is selected from: one or more in wilkinite, urea, ammonium sulfate, aluminum chloride.
Described filler is selected from: one or more in kaolin, diatomite, wilkinite, attapulgite, white carbon black, starch, light calcium carbonate.
The composition of the present invention is mainly used in control vegetables and fruit tree Powdery Mildew, gray mold, black spot.
The useful effect of the present invention: (1) present composition effective active composition benziothiazolinone belongs to the sterilant of two kinds of different mechanisms of action from own azoles alcohol, both mutual mixtures can not produce to conflict;(2) present composition has good synergism within the specific limits, and anti-effect is higher than single dose, and dosage is little; (3) the present invention does not use organic solvent, not easily produces poisoning, is convenient to transport and storage; (4) Powdery Mildew of vegetables and fruit tree, gray mold, black spot are had special efficacy by the present composition.
Embodiment
Below in conjunction with embodiment to further instruction of the present invention, the per-cent in embodiment is all weight percentage, but the present invention is not limited thereto.
The embodiment of the present invention is the method adopting Toxicity Determination and field test to combine.
Implementation of an application example one
Benziothiazolinone and own azoles alcohol mixture are to powdery mildew of cucumber Toxicity Determination.
Test medicine all has Shaanxi Xi great HuaTe Science Industrial Co., Ltd. to provide.
Determining after the effective inhibition concentration scope of each medicament through prerun, each medicament establishes 5 dosage process respectively by active constituent content, if clear water comparison. Carry out with reference to " farm-chemical indoor determination test rule sterilant ", adopt mycelial growth rate method to measure medicament to the virulence of powdery mildew of cucumber. Measure colony diameter with cross interior extrapolation after 72h, calculate each process net growth, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (�� g/mL) converts logarithmic value (x) to, try to achieve virulence regression equation (y=a+bx) with method of least squares, and thus calculate the EC50 value of often kind of medicament. Colleague calculates two medicaments different ratio synergy ratio (SR) according to Wadley method, and SR < 0.5 is antagonistic action, and 0.5��SR��1.5 are summation action, and SR > 1.5 is synergism. Calculation formula is as follows:
Wherein: a, b are respectively own azoles alcohol and benziothiazolinone ratio shared in combination
A is own azoles alcohol
B is benziothiazolinone
Test-results is as shown in table 1:
The own azoles alcohol of table 1, benziothiazolinone and mixture thereof are to the toxicity test analysis of results table of powdery mildew of cucumber
As shown in Table 1, the EC50 of powdery mildew of cucumber is respectively 0.18mg/L and 32.38mg/L by own azoles alcohol, benziothiazolinone. The virulence of own azoles alcohol is higher than the virulence of benziothiazolinone. The synergy ratio of own azoles alcohol and benziothiazolinone proportioning 1: 1,1: 5,1: 10,1: 20,1: 30 is respectively 1.66,1.89,2.06,1.86,1.54, illustrate that own azoles alcohol and benziothiazolinone mixture in 1: 1-1: 20 scopes all shows obvious synergism, wherein when own azoles alcohol and benziothiazolinone weight ratio are 1: 10, synergy ratio SR is maximum, and synergism is the most obvious.
Implementation of an application example two
The implementation of Formulation Example
Embodiment 1
The 80% own azoles alcohol wettable powder of benziothiazolinone
Benziothiazolinone 30%, own azoles alcohol 50%, polycarboxylate 5%, Sodium dodecylbenzene sulfonate 3%, Seed of Chinese Soapberry powder 2%, white carbon black 10%, mixture carries out comminution by gas stream, the obtained 80% own azoles alcohol wettable powder of benziothiazolinone.
Embodiment 2
The 70% own azoles alcohol wettable powder of benziothiazolinone
Benziothiazolinone 20%, own azoles alcohol 50%, sulfonated lignin 5%, spaonin powder 3%, white carbon black 7%, diatomite 15%, mixture carry out comminution by gas stream, the obtained 70% own azoles alcohol wettable powder of benziothiazolinone.
Embodiment 3
The 60% own azoles alcohol wettable powder of benziothiazolinone
Benziothiazolinone 15%, own azoles alcohol 45%, alkylphenol-polyethenoxy are phonetic 5%, Sodium dodecylbenzene sulfonate 3%, white carbon black 12%, wilkinite 20%, mixture carry out gas pulverizing, the obtained 60% own azoles alcohol wettable powder of benziothiazolinone.
Embodiment 4
The 50% own azoles alcohol wettable powder of benziothiazolinone
Benziothiazolinone 8%, own azoles alcohol 42%, sulfonated lignin 5%, wetting and penetrating agent F3%, white carbon black 12%, wilkinite 30%, mixture carry out comminution by gas stream, the obtained 50% own azoles alcohol wettable powder of benziothiazolinone.
Embodiment 5
80% benziothiazolinone diniconazole water dispersible granule
Benziothiazolinone 10%, own azoles alcohol 70%, alkylphenol-polyethenoxy are phonetic 3%, sulfonated lignin 3%, sodium lauryl sulphate 4%, starch 10%, the obtained 80% benziothiazolinone diniconazole water dispersible granule of mixing.
Embodiment 6
65% benziothiazolinone diniconazole water dispersible granule
Benziothiazolinone 5%, own azoles alcohol 60%, polycarboxylate 3%, polyoxyethylene carboxylate 3%, sodium lauryl sulphate 4%, sodium bicarbonate 3%, starch 22%, the obtained 65% benziothiazolinone diniconazole water dispersible granule of mixing.
Embodiment 7
50% benziothiazolinone diniconazole water dispersible granule
Benziothiazolinone 4%, own azoles alcohol 46%, alkylphenol-polyethenoxy are phonetic 5%, dodecylbenzene sulfonate 3%, starch 20%, wilkinite 22%, the obtained 50% benziothiazolinone diniconazole water dispersible granule of mixing.
Embodiment 8
15% benziothiazolinone diniconazole water dispersible granule
Benziothiazolinone 5%, own azoles alcohol 10%, alkylphenol-polyethenoxy are phonetic 4%, Witco 1298 Soft Acid 4%, ammonium sulfate 5%, starch 20%, diatomite 52%, the obtained 15% benziothiazolinone diniconazole water dispersible granule of mixing.
Embodiment 9
50% benziothiazolinone hexaconazole suspending agent
Benziothiazolinone 10%, own azoles alcohol 40%, alkyl benzene sulfonate calcium salt 5%, sodium polyacrylate 2%, Witco 1298 Soft Acid 4%, silicone oil 0.1%, xanthan gum 0.3%, deionized water adds to 100%, is mixed and made into 50% benziothiazolinone hexaconazole suspending agent.
Embodiment 10
30% benziothiazolinone hexaconazole suspending agent
Benziothiazolinone 4%, own azoles alcohol 26%, polycarboxylate 4%, Seed of Chinese Soapberry powder 5%, silicone compound 0.1%, Natvosol 0.1%, ethylene glycol 2%, deionized water add to 100%, the obtained 30% benziothiazolinone hexaconazole suspending agent of mixing.
Embodiment 11
21% benziothiazolinone hexaconazole suspending agent
Benziothiazolinone 1%, own azoles alcohol 20%, polycarboxylate 2%, Sodium dodecylbenzene sulfonate 2%, silicone compound 0.1%, polyoxyethylene glycol 0.5%, glycerol 4%, deionized water add to 100%, the obtained 21% benziothiazolinone hexaconazole suspending agent of mixing.
Embodiment 12
10% benziothiazolinone hexaconazole suspending agent
Benziothiazolinone 5%, own azoles alcohol 5%, polycarboxylate 2%, Nekal BX 2%, C10-20 saturated fatty acid compounds 0.1%, polyoxyethylene glycol 0.5%, ethylene glycol 4%, deionized water add to 100%, the obtained 10% benziothiazolinone hexaconazole suspending agent of mixing.
Implementation of an application example three
Benziothiazolinone, own azoles alcohol and mixture thereof prevent and treat the pear scab test of pesticide effectiveness
This experimental establishment is in Bin County suburb, Shaanxi Province, and test medicine is by the research and development of Shaanxi Xi great HuaTe Science Industrial Co., Ltd., offer and comparison medicament 40% benziothiazolinone wettable powder, 10% hexaconazole suspending agent (commercial).
The medicine " Invest, Then Investigate " pear scab state of an illness, in the first time dispenser of state of an illness initial stage, every 7 dispensers once, are total to dispenser 3 times. Within after third time dispenser 7 days, 14 days, 30 days, investigate the pear scab state of an illness respectively and calculate anti-effect. Experimental result is as follows:
Table 2 benziothiazolinone, own azoles alcohol and mixture thereof prevent and treat the pear scab test of pesticide effectiveness
As can be seen from Table 2, effectively preventing pear scab after benziothiazolinone and own azoles alcohol mixture, prevention effect is all better than comparison medicament, and the lasting period is long. In test scope of medication, mark target crop is had no adverse effects.
Implementation of an application example four
Benziothiazolinone, own azoles alcohol and the mixture control grape grey mould test of pesticide effectiveness thereof
This experimental establishment is in suburb, Turfan city, Xinjiang, and test medicine is provided by the research and development of Shaanxi Xi great HuaTe Science Industrial Co., Ltd. and comparison medicament 40% benziothiazolinone wettable powder, 10% hexaconazole suspending agent (commercial).
The medicine " Invest, Then Investigate " grape grey mould state of an illness, in the first time dispenser of state of an illness initial stage, dispenser in every 7 days once, is total to dispenser 2 times. Within after second time dispenser 7 days, 14 days, 30 days, investigate grape grey mould disease index respectively and calculate anti-effect. Experimental result is as follows:
Table 3 benziothiazolinone, own azoles alcohol and the mixture control grape grey mould test of pesticide effectiveness thereof
As can be seen from Table 3, effectively preventing and treating downy mildew of garpe after benziothiazolinone and own azoles alcohol mixture, prevention effect is all better than comparison medicament, and dosage is little, and the lasting period is long. To mark target crop without harm in test scope of medication.
Implementation of an application example five
Benziothiazolinone, own azoles alcohol and the mixture control powdery mildew of strawberry test of pesticide effectiveness thereof
This experimental establishment is in Hu County, Shaanxi Province, and test medicine is by the research and development of Shaanxi Xi great HuaTe Science Industrial Co., Ltd., offer and comparison medicament 40% benziothiazolinone wettable powder, 10% hexaconazole suspending agent (commercial).
Investigation powdery mildew of strawberry state of an illness radix, total number of sheets, the sick number of sheets and sick leaf progression before medicine, in their early stage dispenser, once, dispenser 2 times altogether, investigates disease index and calculates anti-effect for after second time dispenser 7 days, 14 days respectively in dispenser in every 7 days. Experimental result is as follows:
Table 4 benziothiazolinone, own azoles alcohol and the mixture control powdery mildew of strawberry test of pesticide effectiveness thereof
As can be seen from Table 4, effectively preventing and treating powdery mildew of strawberry generation after benziothiazolinone and own azoles alcohol mixture, prevention effect is all better than comparison medicament, is had no adverse effects by mark target crop in this test scope of medication.
Implementation of an application example six
Benziothiazolinone, own azoles alcohol and mixture thereof prevent and treat the powdery mildew of cucumber test of pesticide effectiveness
This experimental establishment is in Jingyang County, Shaanxi Province, and test medicine is by the research and development of Shaanxi Xi great HuaTe Science Industrial Co., Ltd., offer and comparison medicament 40% benziothiazolinone wettable powder, 10% hexaconazole suspending agent (commercial).
Investigation powdery mildew of cucumber state of an illness radix, total number of sheets, the sick number of sheets and sick leaf progression before medicine, in their early stage dispenser, once, dispenser 2 times altogether, investigates disease index and calculates anti-effect for after second time dispenser 7 days, 15 days respectively in dispenser in every 7 days. Experimental result is as follows:
Table 5 benziothiazolinone, own azoles alcohol and mixture thereof prevent and treat the powdery mildew of cucumber test of pesticide effectiveness
As can be seen from Table 5, effectively preventing and treating powdery mildew of cucumber generation after benziothiazolinone and own azoles alcohol mixture, prevention effect is all better than comparison medicament, marks target crop and have no adverse effects in this test scope of medication.
Claims (4)
1. active principle be benziothiazolinone and own azoles alcohol fungicidal composition control vegetables and fruit tree Powdery Mildew in application, it is characterised in that the weight ratio of Bactericide composition effective active composition benziothiazolinone and own azoles alcohol is 1: (1��2).
2. application according to claim 1, it is characterised in that, wherein effective active component content accounts for the 10-80% of composition weight.
3. application according to claim 1, it is characterised in that, described composition can be mixed with any formulation agriculturally allowed.
4. application according to claim 3, it is characterised in that, the formulation of described composition is wettable powder, water dispersible granules or suspension agent green pesticide form.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102763657B (en) * | 2012-08-13 | 2014-09-17 | 江苏辉丰农化股份有限公司 | Germicide composite with synergistic effect |
| CN104041508B (en) * | 2013-06-09 | 2016-06-01 | 江苏辉丰农化股份有限公司 | Fungicidal composition containing benziothiazolinone |
| CN104542630B (en) * | 2014-12-27 | 2019-08-02 | 江西中迅农化有限公司 | A kind of bactericidal composition containing zinc thiazole and benziothiazolinone |
| CN106212479B (en) * | 2016-05-30 | 2018-08-28 | 江苏辉丰农化股份有限公司 | A kind of microbicide compositions |
| CN106259366B (en) * | 2016-06-26 | 2019-06-21 | 江苏辉丰农化股份有限公司 | A kind of microbicide compositions |
| CN106172437B (en) * | 2016-07-07 | 2018-06-19 | 江苏辉丰农化股份有限公司 | A kind of microbicide compositions |
| CN107646857A (en) * | 2017-09-28 | 2018-02-02 | 陕西西大华特科技实业有限公司 | A kind of bactericidal composition containing cyflufenamid and benziothiazolinone and its application |
| CN111466392B (en) * | 2019-01-24 | 2021-08-27 | 陕西西大华特科技实业有限公司 | Bactericidal composition containing benziothiazolinone and tetraconazole and application thereof |
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| JP3317962B2 (en) * | 1999-12-27 | 2002-08-26 | 武田薬品工業株式会社 | Antifungal and / or antialgal composition |
| JP2003213285A (en) * | 2002-01-25 | 2003-07-30 | Shinto Fine Co Ltd | Antimicrobial composition for water-soluble metal working lubricant |
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| CN101669486A (en) * | 2009-10-16 | 2010-03-17 | 深圳诺普信农化股份有限公司 | Benzolkresoxim-methyl containing bactericide composition |
| CN101695297A (en) * | 2009-11-04 | 2010-04-21 | 陕西西大华特科技实业有限公司 | Benziothiazolinone water suspension and preparation method thereof |
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