CN102094330A - Polypropylene tow spinning oil for cigarettes and production method thereof - Google Patents
Polypropylene tow spinning oil for cigarettes and production method thereof Download PDFInfo
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- CN102094330A CN102094330A CN 201010251170 CN201010251170A CN102094330A CN 102094330 A CN102094330 A CN 102094330A CN 201010251170 CN201010251170 CN 201010251170 CN 201010251170 A CN201010251170 A CN 201010251170A CN 102094330 A CN102094330 A CN 102094330A
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Abstract
The invention relates to polypropylene tow spinning oil for cigarettes and a production method thereof. The polypropylene tow spinning oil contains a component A and a component B in proportion by weight, wherein the component A comprises an internal lubricant composed of one or both of tributyl citrate and acetyl tributyl citrate, an emulsifying agent formed by mixing tween-80 and a palm wax emulsifying agent GR202 produced by Shanghai Greening Chemical Science & Technology Co., Ltd, and pure water which is added to form an emulsion; and the component B is a polyoxyethylene solution formed by dissolving polyoxyethylene in pure water. The invention has the following advantages that due to the internal lubricant, the anti-yellowing ability is greatly improved; the consumption of the emulsifying agent is reduced and efficient emulsifying is realized; and due to the external lubricant polyoxyethylene, the broken filament phenomenon in the spinning process is reduced and also the cohesion of tows is enhanced.
Description
[technical field] the present invention relates to the cigarette raw and auxiliary material, promptly a kind of cigarette polypropylene fiber tow spinning oil and production method thereof.
[background technology] cigarette polypropylene fiber tow spinning oil, be all the time with surfactant such as tween, sapn etc. composite after, white oil, palm oil or salad wet goods are carried out emulsification, add materials such as preservative sodium benzoate, humectant glycerol and a small amount of antistatic additive, defoamer again, become the emulsion of oil-in-water type, spin the position in the front and back of spinning and oil by diluting the back, with the lubricating requirement that satisfies spinning process and the obvolvent requirement of tow.This kind spinning oil has following deficiency: 1. the white oil of Jia Ruing, palm oil, the lubricated composition of salad wet goods are easy to generate xanthochromia and rotten in tow drying and shaping process; 2. Sodium Benzoate is a kind of preservative agent of limited amount control, and itself is harmful; 3. tow is under high-temperature baking typing condition, and glycerol generates aldehyde material easily, can produce harm to human body; 4. antistatic additive, defoamer itself also are harmful materials.Thereby become in the cigarette polypropylene fiber tow spinning production process difficult problem that does not overcome for a long time.
[summary of the invention] the objective of the invention is to the above-mentioned defective at existing spinning oil, and a kind of finish and production method thereof safe, that can satisfy the poly-interior alkene tow spinning production requirement of cigarette usefulness are provided.
This cigarette polypropylene fiber tow spinning oil is characterized in that, the A component and the B component that contain constitute by following part by weight:
The A component comprises, 1. a kind of in ATBC and the tributyl 2-acetylcitrate or two kinds are formed in-lubricant parts, weight portion 10-20; 2. two kinds of composite emulsifying agents of material of palm wax emulsifying agent GR202 of producing of the intercalation peaceful Chemical Industry Science Co., Ltd of Tween-80 and Shanghai lattice, weight portion 13-50; 3. add pure water 30-77 part, the emulsion of making;
The B component comprises that the polyoxyethylene powder body material is dissolved in pure water, makes the polyoxyethylene solution of 0.5%-3.0%.
In-lubricant in the described A component is 10-20 part ATBC.
In-lubricant in the described A component is 10-20 part tributyl 2-acetylcitrate.
In-lubricant in the described A component is 10-20 part ATBC and tributyl 2-acetylcitrate.
The production method of finish comprises the steps that following each raw material is a weight ratio:
1. in the in-lubricant of a kind of or two kinds of compositions in 10-20 part ATBC and tributyl 2-acetylcitrate, add the emulsifying agent that 13-50 part is made up of two kinds of materials of palm wax emulsifying agent GR202 of Tween-80 and the production of the intercalation peaceful Chemical Industry Science Co., Ltd of Shanghai lattice, heat to 105 ℃ ± 5 ℃, insulation is melted into liquid until mixture;
2. in whipping process, progressively add 30-77 part pure water, keeping temperature to be not less than under 80 ℃ of situations, until forming uniform emulsion, a kind of A component of cigarette polypropylene spinning oil;
3. with the polyoxyethylene powder body material, in pure water, stir, dissolving, make the polyoxyethylene aqueous solution of 0.5%-3.0%, a kind of B component of cigarette polypropylene spinning oil;
4. take by weighing A component 3-10 part, B component 2-8 part, mix, add pure water and be diluted to 100 parts, stir, 200 mesh filter screens filter, produce and go up the spinning oil that uses.
In-lubricant in the described A component is 10-20 part ATBC.
In-lubricant in the described A component is 10-20 part tributyl 2-acetylcitrate.
In-lubricant in the described A component is 10-20 part ATBC and tributyl 2-acetylcitrate.
Through applying unit checking, advantage of the present invention is as follows: 1. use the in-lubricant that meets food standard fully such as ATBC, tributyl 2-acetylcitrate, not only meet food security, and anti-xanthochromia ability improves greatly; 2. use the palm oil emulsifying agent GR202 of the intercalation peaceful Chemical Industry Science Co., Ltd of efficient food emulsifying agent such as Tween-80 and Shanghai lattice production, reduced the consumption of emulsifying agent, reached the purpose of efficient emulsification; 3. the polyoxyethylated use of the external lubricant of food-grade had both reduced the lousiness phenomenon in the spinning process, had strengthened the coherent of tow again; 4. this finish does not contain antistatic additive and humectant glycerol, can overcome after antistatic additive and the glycerol hydroformylation harm to human body; 5. because this spinning oil is difficult for going mouldy, preservative agent need not be added, the harm of preservative agent can be avoided human body; 6. the two components of this finish employing A, B, and A component are emulsion oil-in-waters, and its anti-mildew change characteristics increase substantially, and the shelf-life was brought up to 12 months by 3 months.
[specific embodiment] further set forth the present invention below in conjunction with embodiment:
Embodiment one:
1, in 2 liters enamelled vessel or rustless steel container, add 167 gram tributyl 2-acetylcitrates, 133 gram palm wax emulsifying agent GR202 and 367 gram Tween-80s, to heat to 105 ℃ ± 5 ℃, insulation is melted into liquid until mixture;
2, in whipping process, progressively add 333 gram pure water, and keep temperature to be not less than under 80 ℃ of situations, until forming uniform emulsion, a kind of A component of cigarette polypropylene spinning oil;
3, with polyoxyethylene powder body material 0.5 gram, in 99.5 gram pure water, stir, dissolving, make 0.5% the polyoxyethylene aqueous solution, a kind of B component of cigarette polypropylene spinning oil;
4, take by weighing 0.3 kilogram of A component, 0.8 kilogram of B component mixes, and adds pure water and is diluted to 10 kilograms, stirs, and 200 mesh filter screens filter, the cigarette polypropylene fiber tow spinning oil.
Embodiment two:
1, in 2 liters enamelled vessel or rustless steel container, add 100 gram tributyl 2-acetylcitrates, 67 gram ATBCs, 233 gram palm wax emulsifying agent GR202 and 267 gram Tween-80s, heat to 105 ℃ ± 5 ℃, insulation is melted into liquid until mixture;
2, in whipping process, progressively add 333 gram pure water, and keep temperature to be not less than under 80 ℃ of situations, until forming uniform emulsion, a kind of A component of cigarette polypropylene spinning oil;
3, with polyoxyethylene powder body material 3 gram, in 97 gram pure water, stir, dissolving, make 3% the polyoxyethylene aqueous solution, a kind of B component of cigarette polypropylene spinning oil;
4, take by weighing 1 kilogram of A component, 0.2 kilogram of B component mixes, and adds pure water and is diluted to 10 kilograms, stirs, and 200 mesh filter screens filter, the cigarette polypropylene fiber tow spinning oil.
Embodiment three:
1, in 2 liters enamelled vessel or rustless steel container, add 80 gram tributyl 2-acetylcitrates, 20 gram ATBCs, 100 gram palm wax emulsifying agent GR202 and 30 gram Tween-80s, heat to 105 ℃ ± 5 ℃, insulation is melted into liquid until mixture;
2, in whipping process, progressively add 770 gram pure water, and keep temperature to be not less than under 80 ℃ of situations, until forming uniform emulsion, a kind of A component of cigarette polypropylene spinning oil;
3, with polyoxyethylene powder body material 2 gram, in 98 gram pure water, stir, dissolving, make 2% the polyoxyethylene aqueous solution, a kind of B component of cigarette polypropylene spinning oil;
4, take by weighing 1 kilogram of A component, 0.2 kilogram of B component mixes, and adds pure water and is diluted to 10 kilograms, stirs, and 200 mesh filter screens filter, the cigarette polypropylene fiber tow spinning oil.
Embodiment four:
1, in 2 liters enamelled vessel or rustless steel container, add 100 gram tributyl 2-acetylcitrates, 100 gram ATBCs, 233 gram palm wax emulsifying agent GR202 and 267 gram Tween-80s, heat to 105 ℃ ± 5 ℃, insulation is melted into liquid until mixture;
2, in whipping process, progressively add 300 gram pure water, and keep temperature to be not less than under 80 ℃ of situations, until forming uniform emulsion, a kind of A component of cigarette polypropylene spinning oil;
3, with polyoxyethylene powder body material 0.5 gram, in 99.5 gram pure water, stir, dissolving, make 0.5% the polyoxyethylene aqueous solution, a kind of B component of cigarette polypropylene spinning oil;
4, take by weighing 0.8 kilogram of A component, 0.2 kilogram of B component mixes, and adds pure water and is diluted to 10 kilograms, stirs, and 200 mesh filter screens filter, the cigarette polypropylene fiber tow spinning oil.
Embodiment five:
1, in 2 liters enamelled vessel or rustless steel container, add 67 gram tributyl 2-acetylcitrates, 100 gram ATBCs, 233 gram palm wax emulsifying agent GR202 and 167 gram Tween-80s, heat to 105 ℃ ± 5 ℃, insulation is melted into liquid until mixture;
2, in whipping process, progressively add 433 gram pure water, and keep temperature to be not less than under 80 ℃ of situations, until forming uniform emulsion, a kind of A component of cigarette polypropylene spinning oil;
3, with polyoxyethylene powder body material 1.5 gram, in 98.5 gram pure water, stir, dissolving, make 1.5% the polyoxyethylene aqueous solution, a kind of B component of cigarette polypropylene spinning oil;
4, take by weighing 0.7 kilogram of A component, 0.4 kilogram of B component mixes, and adds pure water and is diluted to 10 kilograms, stirs, and 200 mesh filter screens filter, the cigarette polypropylene fiber tow spinning oil.
Through authoritative testing agency to the test of tow, the tow that uses finish of the present invention to produce, aldehyde-containing type material not, and the tow of the production of the finish before using contain the aldehyde material of PPM level; When finish before using and use finish of the present invention were produced tow, tow quality test-data and production equipment data comparing result were as shown in the table:
Claims (8)
1. a cigarette polypropylene fiber tow spinning oil is characterized in that, the A component and the B component that contain constitute by following part by weight:
The A component comprises, 1. a kind of in ATBC and the tributyl 2-acetylcitrate or two kinds are formed in-lubricant parts, weight portion 10-20; 2. two kinds of composite emulsifying agents of material of palm wax emulsifying agent GR202 of producing of the intercalation peaceful Chemical Industry Science Co., Ltd of Tween-80 and Shanghai lattice, weight portion 13-50; 3. add pure water 30-77 part, the emulsion of making;
The B component comprises that the polyoxyethylene powder body material is dissolved in pure water, makes the polyoxyethylene solution of 0.5%-3.0%.
2. a kind of cigarette polypropylene fiber tow spinning oil according to claim 1 is characterized in that, the in-lubricant in the described A component is 10-20 part ATBC.
3. a kind of cigarette polypropylene fiber tow spinning oil according to claim 1 is characterized in that, the in-lubricant in the described A component is 10-20 part tributyl 2-acetylcitrate.
4. a kind of cigarette polypropylene fiber tow spinning oil according to claim 1 is characterized in that the in-lubricant in the described A component is 10-20 part ATBC and tributyl 2-acetylcitrate.
5. the production method of a cigarette polypropylene fiber tow spinning oil is characterized in that comprising the steps, following each raw material is a weight ratio:
1. in the in-lubricant of a kind of or two kinds of compositions in 10-20 part ATBC, tributyl 2-acetylcitrate, add the emulsifying agent that 13-50 part is made up of two kinds of materials of palm wax emulsifying agent GR202 of Tween-80 and the production of the intercalation peaceful Chemical Industry Science Co., Ltd of Shanghai lattice, heat to 105 ℃ ± 5 ℃, insulation is melted into liquid until mixture;
2. in whipping process, progressively add 30-77 part pure water, keeping temperature to be not less than under 80 ℃ of situations, until forming uniform emulsion, a kind of A component of cigarette polypropylene spinning oil;
3. with the polyoxyethylene powder body material, in pure water, stir, dissolving, make the polyoxyethylene aqueous solution of 0.5%-3.0%, a kind of B component of cigarette polypropylene spinning oil;
4. take by weighing A component 3-10 part, B component 2-8 part, mix, add pure water and be diluted to 100 parts, stir, 200 mesh filter screens filter, produce and go up the spinning oil that uses.
6. the production method of a kind of cigarette polypropylene fiber tow spinning oil according to claim 5 is characterized in that, the in-lubricant in the described A component is 10-20 part ATBC.
7. the production method of a kind of cigarette polypropylene fiber tow spinning oil according to claim 5 is characterized in that, the in-lubricant in the described A component is 10-20 part tributyl 2-acetylcitrate.
8. the production method of a kind of cigarette polypropylene fiber tow spinning oil according to claim 5 is characterized in that, the in-lubricant in the described A component is 10-20 part ATBC and tributyl 2-acetylcitrate.
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CN2010102511709A CN102094330B (en) | 2010-08-09 | 2010-08-09 | Polypropylene tow spinning oil for cigarettes and production method thereof |
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CN2010102511709A CN102094330B (en) | 2010-08-09 | 2010-08-09 | Polypropylene tow spinning oil for cigarettes and production method thereof |
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CN102094330A true CN102094330A (en) | 2011-06-15 |
CN102094330B CN102094330B (en) | 2012-05-23 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103484955A (en) * | 2013-08-28 | 2014-01-01 | 湖北金叶玉阳化纤有限公司 | Preparation method of quick drying polypropylene fiber tow |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4129507A (en) * | 1978-01-18 | 1978-12-12 | Allied Chemical Corporation | Spin finish for polyamide yarn |
CN1369593A (en) * | 2001-02-16 | 2002-09-18 | 中国石油天然气股份有限公司 | Finishing oil for fine-denier polypropylene staple fibres |
KR20060125163A (en) * | 2005-06-02 | 2006-12-06 | 주식회사 코오롱 | Spin-finish oil for thermoplastic synthetic filament |
CN101768858A (en) * | 2009-01-07 | 2010-07-07 | 马国胜 | Oil for polypropylene fibers |
-
2010
- 2010-08-09 CN CN2010102511709A patent/CN102094330B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4129507A (en) * | 1978-01-18 | 1978-12-12 | Allied Chemical Corporation | Spin finish for polyamide yarn |
CN1369593A (en) * | 2001-02-16 | 2002-09-18 | 中国石油天然气股份有限公司 | Finishing oil for fine-denier polypropylene staple fibres |
KR20060125163A (en) * | 2005-06-02 | 2006-12-06 | 주식회사 코오롱 | Spin-finish oil for thermoplastic synthetic filament |
CN101768858A (en) * | 2009-01-07 | 2010-07-07 | 马国胜 | Oil for polypropylene fibers |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103484955A (en) * | 2013-08-28 | 2014-01-01 | 湖北金叶玉阳化纤有限公司 | Preparation method of quick drying polypropylene fiber tow |
CN103484955B (en) * | 2013-08-28 | 2015-06-10 | 湖北金叶玉阳化纤有限公司 | Preparation method of quick drying polypropylene fiber tow |
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CN102094330B (en) | 2012-05-23 |
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