CN108611852A - A kind of ES fibers are without the multiple hydrophilic finish of silicon - Google Patents
A kind of ES fibers are without the multiple hydrophilic finish of silicon Download PDFInfo
- Publication number
- CN108611852A CN108611852A CN201810431208.7A CN201810431208A CN108611852A CN 108611852 A CN108611852 A CN 108611852A CN 201810431208 A CN201810431208 A CN 201810431208A CN 108611852 A CN108611852 A CN 108611852A
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- Prior art keywords
- silicon
- fibers
- fatty alcohol
- hydrophilic finish
- multiple hydrophilic
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
- D06M13/17—Polyoxyalkyleneglycol ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
- D06M13/295—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof containing polyglycol moieties; containing neopentyl moieties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention discloses a kind of ES fibers without the multiple hydrophilic finish of silicon.Repeatedly hydrophilic finish is made of the no silicon emulsifier, wetting agent, antistatic agent, azochlorosulfonate propyl lycine, distilled water.The ES fibers and its non-woven fabrics prepared using the finish has the function of multiple hydrophilic, rapid osmotic, and environmentally safe, is mainly used as the surface material of baby paper diaper.
Description
Technical field
The present invention relates to a kind of no silicon, repeatedly hydrophilic finish, the ES fibers and its non-woven fabrics prepared using the finish are mainly used
Make the surface material of paper diaper.
Background technology
ES fibers are a kind of composite fibres being prepared by polyethylene and polypropylene.Repeatedly hydrophilic finish is to answer to ES fibers
For the auxiliary agent in ES fiber production process, it makes ES fibers have the performances such as excellent convergence, antistatic property, to make ES
Fiber can smoothly be processed into ES non-woven fabrics, and the non-woven fabrics formed has multiple hydrophilicity.
In recent years, the requirement with people to paper diaper comfort is continuously improved, and paper diaper technology is also constantly updated with suitable
Answer the demand in market.ES non-woven fabrics is chosen as the surface material of paper diaper with the excellent properties such as soft comfortable, gas permeability be good, but
Traditional ES non-woven fabrics does not have multiple hydrophilicity mostly, and urine is difficult to multiple quick penetration ES non-woven fabrics, this easily causes urine
It leaks out or urine is contacted with infant skin for a long time, comfort difference is caused even to cause diaper rash.Multiple parent currently on the market
Water finish is mostly siliceous hydrophilic finish, and permeability, the adsorptivity of silicon are especially strong, easily block skin pore, and it is strong to be unfavorable for skin
Health, and the surface tension of silicon is especially low, finish, which is discharged into environment, to pollute water environment.
Invention content
In order to overcome drawbacks described above, the purpose of the present invention is to provide a kind of ES fibers of environmental protection without the multiple hydrophilic oil of silicon
Agent.
The present invention the technical solution adopted is that:A kind of ES fibers are without the multiple hydrophilic finish of silicon, by following weight hundred
The component of point content mixes:7% emulsifier, 5% wetting agent 1,5% wetting agent 2,10.45-15.95% antistatic agents, 7-
13% azochlorosulfonate propyl lycine, remaining is distilled water.The azochlorosulfonate propyl lycine is 3- sulfopropyl dodecyl dimethyl beets
Alkali, structure are as follows:
Wherein, n=10.
Further, the emulsifier is polysorbate60.
Further, the wetting agent 1 is isomery fatty alcohol polyoxyethylene ether, the isomery fatty alcohol polyoxyethylene ether
Fatty alcohol alkyl chain carbon atomicity is 13, and polyoxyethylene (EO) adduct number is 8.
Further, the wetting agent 2 is straight-chain fatty alcohol polyoxyethylene ether, the straight-chain fatty alcohol polyoxyethylene ether
Fatty alcohol alkyl chain carbon atomicity is 12, and polyoxyethylene (EO) addition is 5.
Further, the antistatic agent is aliphatic alcohol polyoxyvinethene phosphate sylvite.The aliphatic alcohol polyethenoxy
The fatty alcohol alkyl chain carbon atomicity of ether phosphate sylvite is 12, and polyoxyethylene (EO) adduct number is 5.
Azochlorosulfonate propyl lycine of the present invention, azochlorosulfonate acid anion and quaternary ammonium root cation on main chain have had both the moon
The insertion of the property of cation, cationic head advantageously reduces the repulsion in micella between anion and increases the size of micella,
Micella becomes large-sized the Van der Waals force increased between finish and ES fibers, can firmly be adsorbed on ES fiber surfaces and be formed
Hydrophilic film, to realize resistance to washability.Wherein, the number of hydrophobic side alkyl number is inversely proportional with its infiltration rate.The present invention
By many experiments, screening determines the hydrophobic side alkyl number of the azochlorosulfonate propyl lycine, has finally reached its hydrophily and answer
Use standard.In addition, it has excellent wetability, bactericidal properties and biological degradability etc., it is applied to multiple hydrophilic finish, it can
The ES fibers and its non-woven fabrics for making preparation have excellent comfort.
Through a large number of experiments, the present invention selects polysorbate60 as emulsifier, can cooperate with antistatic agent and wetting agent, common to tie up
Hold the stability of multiple hydrophilic finish mixed system.
The present invention selects E13C-8EO as one of wetting agent, surface tension 27.2mN/m, and its hydrophobic side has
Branched structure can increase with the active force of ES fibers.
The present invention selects 12C-5EO as another wetting agent, and surface tension 22.9mN/m has been embodied ultralow
Surface tension, so the surface tension of multiple hydrophilic finish mixed system can be reduced with it.
Preparation method of the ES fibers provided by the invention without the multiple hydrophilic finish of silicon is as follows:By the weight percent, according to
It is secondary that emulsifier, wetting agent, antistatic agent, azochlorosulfonate propyl lycine, distilled water are added in reaction kettle, it is heated to 80 DEG C;Startup is stirred
It mixes, speed of agitator is 200 revs/min, is stirred 30 minutes, and each component is made to be uniformly mixed;It is cooled to room temperature, discharging.
Without silicon, repeatedly hydrophilic finish is water white transparency viscous fluid, no suspended substance to ES fibers provided by the invention;In room temperature item
3 months are placed under part without lamination;Solid content is 40 ± 1wt%.
Application process of the ES fibers provided by the invention without the multiple hydrophilic finish of silicon:It is normal with reference to ES fibers well known in the art
It advises oiling process to execute, no particular/special requirement repeats no more.
Specific implementation mode:
Further detailed explanation is done to the present invention below in conjunction with specific embodiment, but the present invention is not limited to following embodiments.
Embodiment 1
Without silicon, repeatedly hydrophilic finish, total amount 100g are mixed the ES fibers of the present embodiment by following component:Tween
60,7g;E13C-8EO, 5g;12C-5EO, 5g;The 12C-5EO-PK, 19g that solid content is 55%;The 3- sulphurs that solid content is 50%
Propyl dodecyldimethylammonium hydroxide inner salt, 24g;Remaining is distilled water.
Preparation method:By the weight percent, successively by emulsifier, wetting agent, antistatic agent, azochlorosulfonate propyl lycine,
Distilled water is added in reaction kettle, is heated to 80 DEG C;Start stirring, speed of agitator is 200 revs/min, stirs 30 minutes, makes each group
Divide and is uniformly mixed;It is cooled to room temperature, discharging.
Embodiment 2
Without silicon, repeatedly hydrophilic finish, total amount 100g are mixed the ES fibers of the present embodiment by following component:Tween
60,7g;E13C-8EO, 5g;12C-5EO, 5g;The 12C-5EO-PK, 25g that solid content is 55%;The 3- sulphurs that solid content is 50%
Propyl dodecyldimethylammonium hydroxide inner salt, 17g;Remaining is distilled water.
Preparation method:With reference to embodiment 1.
Embodiment 3
Without silicon, repeatedly hydrophilic finish, total amount 100g are mixed the ES fibers of the present embodiment by following component:Tween
60,7g;E13C-8EO, 5g;12C-5EO, 5g;The 12C-5EO-PK, 20g that solid content is 55%;The 3- sulphurs that solid content is 50%
Propyl dodecyldimethylammonium hydroxide inner salt, 26g;Remaining is distilled water.
Preparation method:With reference to embodiment 1.
Embodiment 4
Without silicon, repeatedly hydrophilic finish, total amount 100g are mixed the ES fibers of the present embodiment by following component:Tween
60,7g;E13C-8EO, 5g;12C-5EO, 5g;The 12C-5EO-PK, 29g that solid content is 55%;The 3- sulphurs that solid content is 50%
Propyl dodecyldimethylammonium hydroxide inner salt, 14g;Remaining is distilled water.
Preparation method:With reference to embodiment 1.
Embodiment 5
Without silicon, repeatedly hydrophilic finish, total amount 100g are mixed the ES fibers of the present embodiment by following component:Tween
60,7g;E13C-8EO, 5g;12C-5EO, 5g;The 12C-5EO-PK, 23g that solid content is 55%;The 3- sulphurs that solid content is 50%
Propyl dodecyldimethylammonium hydroxide inner salt, 21g;Remaining is distilled water.
Preparation method:With reference to embodiment 1.
As with reference to comparing, following table list produce fiber using above-mentioned five kinds of finishes and be further processed into non-woven fabrics it
The result that gained non-woven fabrics is tested afterwards.In the table, sample 1, sample 2, sample 3, sample 4, sample 5 are respectively using embodiment 1, implement
Example 2, embodiment 3, embodiment 4, the ES non-woven fabrics manufactured by more than 5 hydrophilic finish of embodiment.
ES non-woven fabrics hydrophilicities compare
Test method:
The multiple time of penetration test method of ES non-woven fabrics refers to WSP70.7《standard test method for
non-woven caver-stock multiple liquid strike-through time using
simulatedurine》。
As can be seen from the above table:This five sample oil applying rates of sample 1, sample 2, sample 3, sample 4, sample 5 are controlled in 0.35-0.45%
Between, meet manufacturing technique requirent, and its first time time of penetration nearly 1s, rear four sub-percolations time nearly 3s is shown excellent
Multiple hydrophilicity meets the multiple hydrophilic standard of national health articles for use.
Several specific implementation modes of the present invention are above are only, but the design concept of the present invention is not limited thereto, all profits
With the change for the unsubstantiality that this design carries out the present invention, the behavior for invading the scope of the present invention should all be belonged to.
Claims (6)
1. a kind of ES fibers are without the multiple hydrophilic finish of silicon, it is characterised in that:It is mixed by the component of following weight percentage
It forms:7% emulsifier, 5% wetting agent 1,5% wetting agent 2,10.45-15.95% antistatic agents, 7-13% sulfopropyl beets
Alkali, distilled water add to 100%.The azochlorosulfonate propyl lycine is 3- sulfopropyl dodecyldimethylammonium hydroxide inner salts, and structure is as follows:
Wherein, n=10.
2. ES fibers according to claim 1 are without the multiple hydrophilic finish of silicon, which is characterized in that the emulsifier is tween
60。
3. ES fibers according to claim 1 are without the multiple hydrophilic finish of silicon, which is characterized in that the wetting agent 1 is isomery
The fatty alcohol alkyl chain carbon atomicity of fatty alcohol polyoxyethylene ether, the isomery fatty alcohol polyoxyethylene ether is 13, polyoxy second
Alkene (EO) adduct number is 8.
4. ES fibers according to claim 1 are without the multiple hydrophilic finish of silicon, which is characterized in that the wetting agent 2 is straight chain
The fatty alcohol alkyl chain carbon atomicity of fatty alcohol polyoxyethylene ether, the straight-chain fatty alcohol polyoxyethylene ether is 12, polyoxy second
Alkene (EO) addition is 5.
5. ES fibers according to claim 1 are without the multiple hydrophilic finish of silicon, which is characterized in that the antistatic agent is fat
Alcohol polyoxyethylene ether phosphate sylvite.The fatty alcohol alkyl chain carbon atomicity of the aliphatic alcohol polyoxyvinethene phosphate sylvite is
12, polyoxyethylene (EO) adduct number is 5.
6. according to claim 1-5 any one of them ES fibers without the multiple hydrophilic finish of silicon, which is characterized in that preparation method is such as
Under:By the weight percent, reaction is added in emulsifier, wetting agent, antistatic agent, azochlorosulfonate propyl lycine, distilled water successively
In kettle, it is heated to 80 DEG C;Start stirring, speed of agitator is 200 revs/min, stirs 30 minutes, each component is made to be uniformly mixed;It is cold
But to room temperature, discharging.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110744899A (en) * | 2019-10-29 | 2020-02-04 | 江苏金荣泰新材料科技有限公司 | Novel stretch-proofing non-woven fabrics |
CN111235881A (en) * | 2020-03-17 | 2020-06-05 | 上海申欧企业发展有限公司 | Hydrophilic finishing method for ES fiber non-woven fabric of sanitary towel surface coating |
CN114318874A (en) * | 2022-01-26 | 2022-04-12 | 浙江鹿达科技有限公司 | Non-woven fabric hydrophilic oil containing dicarboxylate and preparation method and application thereof |
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CN105316944A (en) * | 2015-11-26 | 2016-02-10 | 常州市灵达化学品有限公司 | Longitudinal permeation type multiple-time hydrophilc agent of polyolefin non-woven fabric |
CN105332278A (en) * | 2015-11-26 | 2016-02-17 | 常州市灵达化学品有限公司 | Environment-friendly multi-time hydrophilic finishing agent for polyolefin non-woven fabric |
CN105714555A (en) * | 2015-12-28 | 2016-06-29 | 福建恒安集团有限公司 | Polypropylene spunbonded nonwoven after going through surface hydrophilic treatment |
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WO2007137609A1 (en) * | 2006-05-25 | 2007-12-06 | Tesalca-99, S.A. | Asymmetric multilayered non woven fabric |
CN104903509A (en) * | 2012-11-06 | 2015-09-09 | 希尔和塞拉彻有限公司 | Composition for permanently hydrophilizing polyolefin fibers and use thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110744899A (en) * | 2019-10-29 | 2020-02-04 | 江苏金荣泰新材料科技有限公司 | Novel stretch-proofing non-woven fabrics |
CN111235881A (en) * | 2020-03-17 | 2020-06-05 | 上海申欧企业发展有限公司 | Hydrophilic finishing method for ES fiber non-woven fabric of sanitary towel surface coating |
CN114318874A (en) * | 2022-01-26 | 2022-04-12 | 浙江鹿达科技有限公司 | Non-woven fabric hydrophilic oil containing dicarboxylate and preparation method and application thereof |
CN114318874B (en) * | 2022-01-26 | 2023-08-29 | 浙江鹿达科技有限公司 | Non-woven fabric hydrophilic oiling agent containing dicarboxylic acid ester and preparation method and application thereof |
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Application publication date: 20181002 |