CN102002226A - Flame-resistant PC (Polycarbonate)/PBT (Polybutylene Terephathalate)/PET (Polyethylene Terephathalate) alloy and preparation method thereof - Google Patents
Flame-resistant PC (Polycarbonate)/PBT (Polybutylene Terephathalate)/PET (Polyethylene Terephathalate) alloy and preparation method thereof Download PDFInfo
- Publication number
- CN102002226A CN102002226A CN201010583034XA CN201010583034A CN102002226A CN 102002226 A CN102002226 A CN 102002226A CN 201010583034X A CN201010583034X A CN 201010583034XA CN 201010583034 A CN201010583034 A CN 201010583034A CN 102002226 A CN102002226 A CN 102002226A
- Authority
- CN
- China
- Prior art keywords
- pbt
- pet
- districts
- alloy
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0022—Combinations of extrusion moulding with other shaping operations combined with cutting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
Abstract
The invention relates to a flame-resistant PC (Polycarbonate)/PBT (Polybutylene Terephathalate)/PET (Polyethylene Terephathalate) alloy and a preparation method thereof. The alloy is prepared from the following components in percentage by weight: 30-50 percent of PC, 10-30 percent of PBT, 10-20 percent of PET, 3-8 percent of toughening compatibilizer, 9-15 percent of flame retardant, 4-8 percent of flame-resistant synergistic agent, 0.4-1 percent of antioxidant and 0.4-1 percent of processing aids, wherein the flame retardant is one of bromine brominated epoxy resin, brominated polystyrene and decabromodiphenylethane, the toughening compatibilizer is an ethane-methyl acrylate copolymer and (or) an ethane-methyl acrylate-methacrylic acid glycidyl ester copolymer. The preparation method of the flame-resistant PC/PBT/PET alloy comprises the following steps of: drying raw materials; fully mixing; stirring for 10-20min at a room temperature; and melting, blending and extruding. The alloy phase has excellent comprehensive performance and high performance price ratio, reaches the flame-resistant level of UL94-V0 and can meet the special use requirements of a certain places.
Description
Technical field
The invention belongs to polymeric material field, particularly the thermoplastic macromolecule material modification technology relates to a kind of fire retardation PC/PBT/PET Alloy And Preparation Method that is widely used in the high performance engineering plastics in fields such as automobile, electronic apparatus, daily necessities.
Background technology
Polycarbonate, English name Polycarbonate is called for short PC.PC is colourless or little yellow thermoplastic engineering plastic of a kind of unformed, odorless, nontoxic, highly transparent, has excellent physical and mechanical properties, shock-resistance excellence especially, tensile strength, flexural strength, compressive strength height; Creep properties is little, dimensional stabilizing.PC also has good thermotolerance and lower temperature resistance, has stable mechanical property in wide temperature range, dimensional stability, and electrical property and flame retardant resistance can be at-60～120 ℃ of following life-time service; No sharp melting point is molten state at 220～230 ℃; Because the molecular chain rigidity is big, resin melt viscosity is big; Water-intake rate is little, and shrinking percentage is little, the dimensional precision height, and dimensional stability is good, and the film ventilation property is little; Belong to self-extinguishing; Stable to light, but ultraviolet resistance not, good weatherability; Oil resistant, acidproof, not anti-highly basic, oxidizing acid and amine, ketone are dissolved in chlorinated hydrocarbons and aromatic solvent, easily cause hydrolysis and cracking for a long time in water, and shortcoming is poor because of fatigue resistance, is easy to generate stress cracking, and good solubility-resistence is poor, and wear resistance is not good enough.
With PC and PBT blend, both can overcome deficiencies such as the PC chemical proofing is poor, forming process is not good, remedy the not high shortcoming of PBT shock strength again simultaneously, can obtain good comprehensive performances.PC/PBT alloy ubiquity in the market rigidity and the not good problem of thermotolerance, though can reach result of use by the content that improves PC, cost increases.
Polybutylene terephthalate (PBT) has high heat resistance, toughness, resistance to fatigue, self-lubricating, low-friction coefficient, and weathering resistance, water-intake rate are low, only be 0.1%, in wet environment, still keep various rerum naturas (comprising electrical property), electrical insulating property, but volume resistance, dielectric loss are big.Heat-resisting water, bases, acids, oils but hydrolytic resistance is poor, crystallization rapidly under the low temperature, good forming ability.Shortcoming is that notched Izod impact strength is low, and molding shrinkage is big.Polyethylene terephthalate (PET) has similar structure with PBT, except that chemical resistance that possesses PBT and favorable mechanical performance, its rigidity and life-time service temperature will be higher than PBT, but the second-order transition temperature height of PET, crystallization velocity is slow, molding cycle is long, shaping cycle is long, and molding shrinkage is big, poor dimensional stability, the moulding of crystallization is fragility, and thermotolerance is low etc.
PC and PBT, PET blend both can be overcome deficiencies such as the PC chemical proofing is poor, forming process is not good, remedied simultaneously PBT, shortcoming that the PET shock strength is not high again, can obtain good comprehensive performances.PC/PBT/PET is typically unformed/crystallization/semi-crystalline polymer system, though be all polyester certain consistency is arranged, and directly there is crystallinity difference in the blend meeting, and consistency is suppressed; Need to add the consistency that suitable toughness reinforcing compatibility performance improves ternary system greatly, to improve shock strength; In addition PC belongs to self-extinguishing, though so alloy also has certain flame retardant resistance, flame retardant rating is difficult to reach service requirements, therefore be necessary ternary alloy is carried out flame-retardant modified, with satisfied result of use under given conditions.
?
Summary of the invention
The present invention for solve exist in the prior art or problem such as cost height or alloy flame retardant resistance be relatively poor, and the PC/PBT/PET Alloy And Preparation Method that a kind of cost is moderate and environmental protection flame retardant, dimensional stability, rigidity, toughness and heat-drawn wire are high is proposed.
The present invention is achieved by the following scheme:
Above-mentioned fire retardation PC/PBT/PET alloy is to be made of following components in weight percentage:
PC 30~50%；
PBT 10～30%；
PET 10～20%；
Toughness reinforcing compatilizer 3～8%;
Fire retardant: 9 ~ 15%;
Fire retarding synergist: 4 ~ 8%;
Oxidation inhibitor 0.4～1%;
Processing aid: 0.4～1%;
Described fire retardant is a kind of in brominated epoxy resin bromine, brominated Polystyrene and the TDE; Described toughness reinforcing compatilizer be ethylene-methyl acrylate copolymer and (or) ethylene-methyl acrylate-glycidyl methacrylate copolymer.
Described fire retardation PC/PBT/PET alloy, wherein: described fire retarding synergist be antimonous oxide and (or) zinc borate.Described PC is that molecular weight is 20000 ~ 40000 bisphenol A polycarbonate; The limiting viscosity 0.86 ~ 1.2 of described PBT; The limiting viscosity 0.83 ~ 0.96 of described PET; Described oxidation inhibitor is any two kinds of combinations in four [β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid octadecyl ester and tricresyl phosphite (24-di-tert-butyl-phenyl) ester.Described processing aid is one or more in lubricant ethylene bis-fatty acid amides, tetramethylolmethane stearate and mutual-phenenyl two acid bromide two alcohol ester's the cyclic oligomer.
The preparation method of above-mentioned fire retardation PC/PBT/PET alloy:
A, raw material drying pre-treatment, PC, PET and PBT exsiccant temperature are controlled at 110～130 ℃, and time of drying is more than 4 hours; The drying conditions of other raw materials is 70 ℃ * 12 hours;
B, above-mentioned dried feed is joined thorough mixing in the high-speed mixer by proportioning, stirring at normal temperature 10～20 minutes.
C, melt blending are extruded, water-cooled, air-dry, pelletizing, oven dry.
The preparation method of described fire retardation PC/PBT/PET alloy, wherein: described melt blending is extruded the employing parallel double-screw extruder, screw diameter 35-75mm; This twin screw extruder has a district to eight district, the temperature setting in each district is respectively: 200～210 ℃ in a district, 210～220 ℃ in two districts, 220～230 ℃ in three districts, 230～240 ℃ in four districts, 240～250 ℃ in five districts, 240～250 ℃ in six districts, 240～250 ℃ in seven districts, 240～250 ℃ in eight districts, 240～250 ℃ of head temperatures; The screw speed of this forcing machine is controlled at 200～350rPm.
The present invention is adopting suitable prescription and technology, and is equipped with suitable flame-retardant system, prepares the power PC/PBT/PET tertiary blending alloy of environmental protection flame retardant.This fire-retardant ternary alloy is having outstanding advantage than the PC/PBT flame-retardant alloy aspect rigidity, toughness, heat resisting temperature and the dimensional stability.Price is low than fire retardation PC/PBT simultaneously, and cost performance is higher; And, can improve the processing fluidity of PC/PET than fire retardation PC/PET, shorten shaping cycle; The alloy that this environmental-friendly fire-retardant PC/PBT/PET is a kind of excellent combination property, cost performance is high.Select the brominated epoxy resin of bisphenol A-type structure in the preparation of this alloy for use, TDE and brominated Polystyrene etc. and three kinds of thermoplastic polyester consistencies are fire retardant preferably all, make the ternary system alloy reach the flame retardant rating of UL94-V0, to satisfy the place that special user demand is arranged.
?
Embodiment
Fire retardation PC of the present invention/PBT/PET alloy is to be made of following components in weight percentage:
PC 30~50%
PBT 10～30%
PET 10～20%
Toughness reinforcing compatilizer 3～8%
Fire retardant: 9 ~ 15%
Fire retarding synergist: 4 ~ 8%
Oxidation inhibitor 0.4～1%
Processing aid: 0.4～1%
Wherein: toughness reinforcing compatilizer is at least a in ethylene-methyl acrylate copolymer (EMA) and the ethylene-methyl acrylate-glycidyl methacrylate copolymer (EMA-GMA);
Fire retardant is a kind of in brominated epoxy resin bromine, brominated Polystyrene and the TDE;
Fire retarding synergist is one or both in antimonous oxide and the zinc borate;
PC is that molecular weight is 20000 ~ 40000 bisphenol A polycarbonate;
The limiting viscosity 0.86 ~ 1.2 of PBT;
The limiting viscosity 0.83 ~ 0.96 of PET;
Oxidation inhibitor can be selected four [β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester (1010), β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid octadecyl ester (1076) and tricresyl phosphite (24-di-tert-butyl-phenyl) ester (168) two kinds of oxidation inhibitor collocation wherein use;
Processing aid is one or more in lubricant ethylene bis-fatty acid amides (TAF), tetramethylolmethane stearate (PETS) and mutual-phenenyl two acid bromide two alcohol ester's the cyclic oligomer (CBT).
PC, PBT, three kinds of polyester of PET have similar structure, be the compatible system of part, but unformed PC and crystalline PBT, PET exist amorphous/crystalline phase system, make the consistency variation, suitable transesterify can make it produce chemical reaction, and consistency is improved; As in order to suitable toughness reinforcing compatilizer, again with suitable ratio blend, just can obtain the ternary system alloy of toughness, excellent combination property.The present invention selects the brominated epoxy resin of bisphenol A-type structure for use, TDE and brominated Polystyrene etc. and three kinds of thermoplastic polyester consistencies are fire retardant preferably all, make the ternary system alloy reach the flame retardant rating of UL94-V0, to satisfy the place that special user demand is arranged.
The preparation method of fire retardation PC of the present invention/PBT/PET alloy is as follows:
1, the pre-treatment of raw material
Therefore the easy moisture absorption of PC, PET and PBT, must carry out drying treatment to it before blending and modifying, the exsiccant temperature is controlled at 110～130 ℃, and time of drying is more than 4 hours.The drying conditions of other raw materials is 70 ℃ * 12 hours.
2, batching and premix
By proportioning load weighted raw material and auxiliary agent are joined thorough mixing in the high-speed mixer together, stirred at normal temperatures 10～20 minutes.
3, blend extruding pelletization
A, equipment adopt parallel double-screw extruder, screw diameter 35-75mm;
B, this twin screw extruder have a district to eight district, the temperature setting in each district is respectively: 200～210 ℃ in a district, 210～220 ℃ in two districts, 220～230 ℃ in three districts, 230～240 ℃ in four districts, 240～250 ℃ in five districts, 240～250 ℃ in six districts, 240～250 ℃ in seven districts, 240～250 ℃ in eight districts, 240～250 ℃ of head temperatures;
The screw speed of C, this forcing machine is controlled at 200～350rPm.Double-screw melt blending is extruded, and through water-cooled, air-dry, pelletizing, drying and packaging is a finished product.
Further describe the present invention below in conjunction with specific embodiment:
Embodiment one
With PC, PET and PBT 110 ℃ dry 6 hours down, remaining auxiliary agent 70 ℃ dry 12 hours down.
Above-mentioned dried raw material is weighed by proportioning, take by weighing: 30kg PC, 20kg PET, 23.2kg PBT, 5kg EMA-GMA, 3kg EMA, 0.2kg antioxidant 1010 and 0.2kg 168,0.4kg lubricant TAF, the flame retardant brominated Resins, epoxy of 10kg, 8kg zinc borate; In high-speed mixer, mixed 10 minutes then.
The above-mentioned material that mixes is joined in the hopper of twin screw extruder, control each section temperature and exist: 210 ℃ in a district, 220 ℃ in two districts, 230 ℃ in three districts, 240 ℃ in four districts, 250 ℃ in five districts, 240 ℃ in six districts, 240 ℃ in seven districts, 250 ℃ in eight districts, 250 ℃ of head temperatures; Screw speed is controlled at 300rpm, through the twin screw extruder melt blending extrude, water-cooled, air-dry, pelletizing, last bag becomes fire retardation PC/PBT/PET alloy finished product.
Above-mentioned fire retardation PC/PBT/PET alloy is injection molded into standard test specimen, and test performance sees Table 1.
Embodiment two
With PC, PET and PBT 110 ℃ dry 6 hours down, remaining auxiliary agent 70 ℃ dry 12 hours down.
Above-mentioned dried raw material is weighed by proportioning, take by weighing: 45kg PC, 15kg PET, 15kg PBT, 4kg EMA-GMA, 3kg EMA, 0.2kg antioxidant 1010 and 0.3kg 168,0.5kg lubricant TAF, the flame retardant brominated Resins, epoxy of 11kg, 3kg antimonous oxide, 3kg zinc borate; In high-speed mixer, mixed 10 minutes then.
The above-mentioned material that mixes is joined in the hopper of twin screw extruder, control each section temperature and exist: 200 ℃ in a district, 210 ℃ in two districts, 220 ℃ in three districts, 230 ℃ in four districts, 240 ℃ in five districts, 250 ℃ in six districts, 250 ℃ in seven districts, 240 ℃ in eight districts, 240 ℃ of head temperatures; Screw speed is controlled at 250rpm, through the twin screw extruder melt blending extrude, water-cooled, air-dry, pelletizing, last bag becomes fire retardation PC/PBT/PET alloy finished product.
Above-mentioned fire retardation PC/PBT/PET alloy is injection molded into standard test specimen, and test performance sees Table 1.
Embodiment three
With PC, PET and PBT 120 ℃ dry 5 hours down, remaining auxiliary agent 70 ℃ dry 12 hours down.
Above-mentioned dried raw material is weighed by proportioning, take by weighing: 45kgPC, 15kgPET, 17.8kg PBT, 6kg EMA-GMA, 0.3kg antioxidant 1076 and 0.3kg 168,0.6kg lubricant PETS, the flame retardant brominated Resins, epoxy of 10kg, 5kg antimonous oxide; In high-speed mixer, mixed 10 minutes then.
The above-mentioned material that mixes is joined in the hopper of twin screw extruder, control each section temperature and exist: 210 ℃ in a district, 220 ℃ in two districts, 230 ℃ in three districts, 240 ℃ in four districts, 250 ℃ in five districts, 240 ℃ in six districts, 240 ℃ in seven districts, 240 ℃ in eight districts, 250 ℃ of head temperatures; Screw speed is controlled at 250rpm, through the twin screw extruder melt blending extrude, water-cooled, air-dry, pelletizing, last bag becomes fire retardation PC/PBT/PET alloy finished product.
Above-mentioned fire retardation PC/PBT/PET alloy is injection molded into standard test specimen, and test performance sees Table 1.
Embodiment four
With PC, PET and PBT 120 ℃ dry 5 hours down, remaining auxiliary agent 70 ℃ dry 12 hours down.
Above-mentioned dried raw material is weighed by proportioning, take by weighing: 32.6kg PC, 10kg PET, 30kg PBT, 6kg EMA, 0.5kg antioxidant 1076 and 0.5kg 168,0.2kg lubricant TAF, 0.2kg PETS, 15kg flame retardant brominated polystyrene, 5kg antimonous oxide; In high-speed mixer, mixed 10 minutes then.
The above-mentioned material that mixes is joined in the hopper of twin screw extruder, control each section temperature and exist: 200 ℃ in a district, 220 ℃ in two districts, 230 ℃ in three districts, 240 ℃ in four districts, 250 ℃ in five districts, 240 ℃ in six districts, 240 ℃ in seven districts, 250 ℃ in eight districts, 250 ℃ of head temperatures; Screw speed is controlled at 350rpm, through the twin screw extruder melt blending extrude, water-cooled, air-dry, pelletizing, last bag becomes fire retardation PC/PBT/PET alloy finished product.
Above-mentioned fire retardation PC/PBT/PET alloy is injection molded into standard test specimen, and test performance sees Table 1.
Embodiment five
With PC, PET and PBT 130 ℃ dry 4 hours down, remaining auxiliary agent 70 ℃ dry 12 hours down.
Above-mentioned dried raw material is weighed by proportioning, take by weighing: 50kg PC, 20kg PET, 10kg PBT, 3kg EMA-GMA, 1.5kg EMA, 0.2kg antioxidant 1010 and 0.3kg 168,1kg lubricant CBT, 9kg TDE, 5kg antimonous oxide; In high-speed mixer, mixed 10 minutes then.
The above-mentioned material that mixes is joined in the hopper of twin screw extruder, control each section temperature and exist: 210 ℃ in a district, 210 ℃ in two districts, 220 ℃ in three districts, 240 ℃ in four districts, 250 ℃ in five districts, 240 ℃ in six districts, 240 ℃ in seven districts, 240 ℃ in eight districts, 250 ℃ of head temperatures; Screw speed is controlled at 200rpm, through the twin screw extruder melt blending extrude, water-cooled, air-dry, pelletizing, last bag becomes fire retardation PC/PBT/PET alloy finished product.
Above-mentioned fire retardation PC/PBT/PET alloy is injection molded into standard test specimen, and test performance sees Table 1.
Embodiment six
With PC, PET and PBT 130 ℃ dry 4 hours down, remaining auxiliary agent 70 ℃ dry 12 hours down.
Above-mentioned dried raw material is weighed by proportioning, take by weighing: 50kg PC, 22kg PET, 10kg PBT, 3kg EMA-GMA, 0.2kg antioxidant 1076 and 0.3kg 168,0.5kg lubricant CBT, the flame retardant brominated Resins, epoxy of 10kg, 4kg antimonous oxide; In high-speed mixer, mixed 10 minutes then.
The above-mentioned material that mixes is joined in the hopper of twin screw extruder, control each section temperature and exist: 210 ℃ in a district, 220 ℃ in two districts, 230 ℃ in three districts, 240 ℃ in four districts, 250 ℃ in five districts, 240 ℃ in six districts, 240 ℃ in seven districts, 240 ℃ in eight districts, 250 ℃ of head temperatures; Screw speed is controlled at 250rpm, through the twin screw extruder melt blending extrude, water-cooled, air-dry, pelletizing, last bag becomes fire retardation PC/PBT/PET alloy finished product.
Above-mentioned fire retardation PC/PBT/PET alloy is injection molded into standard test specimen, and test performance sees Table 1.
Table 1 fire retardation PC/PBT/PET alloy property table
| Performance | Technical requirements | 1 | 2 | 3 | 4 | 5 | 6 |
| Density/g.cm -2 | 1.28 | 1.286 | 1.282 | 1.28 | 1.26 | 1.252 | |
| Tensile strength/MPa | 52 | 53.3 | 54 | 50.2 | 54.3 | 56.2 | |
| Elongation at break/% | 21 | 20 | 22 | 18.2 | 25 | 32.3 | |
| Flexural strength/MPa | 72 | 78 | 72 | 74 | 74.6 | 82 | |
| Modulus in flexure/MPa | 1936 | 2022 | 2128 | 1869 | 2253 | 2355 | |
| Notched Izod impact strength/Kj.m -2 | 26 | 32 | 29 | 31 | 30 | 33 | |
| Heat-drawn wire/℃ | 0.45MPa | 106 | 110 | 113 | 101 | 112 | 116 |
| UL94 | 1.6mm | V0 | V0 | V0 | V0 | V0 | V0 |
Consolidated statement 1 as can be seen, PC/PBT/PET alloy of the present invention has the characteristics of environmental protection flame retardant and excellent size stability, and rigidity, toughness and heat-drawn wire, and cost is moderate, is a kind of high comprehensive performance, alloy that cost performance is high.
Non-so limitation protection scope of the present invention so use the equivalence techniques variation that specification sheets of the present invention and diagramatic content do such as, all is contained in protection scope of the present invention.
Claims (9)
1. fire retardation PC/PBT/PET alloy is to be made of following components in weight percentage:
PC 30~50%；
PBT 10～30%；
PET 10～20%；
Toughness reinforcing compatilizer 3～8%;
Fire retardant: 9 ~ 15%;
Fire retarding synergist: 4 ~ 8%;
Oxidation inhibitor 0.4～1%;
Processing aid: 0.4～1%;
Described fire retardant is the brominated epoxy resin bromine, change a kind of in polystyrene and the TDE; Described toughness reinforcing compatilizer be ethylene-methyl acrylate copolymer and (or) ethylene-methyl acrylate-glycidyl methacrylate copolymer.
2. fire retardation PC as claimed in claim 1/PBT/PET alloy is characterized in that: described fire retarding synergist be antimonous oxide and (or) zinc borate.
3. fire retardation PC as claimed in claim 1/PBT/PET alloy is characterized in that: described PC is that molecular weight is 20000 ~ 40000 bisphenol A polycarbonate.
4. fire retardation PC as claimed in claim 1/PBT/PET alloy is characterized in that: the limiting viscosity 0.86 ~ 1.2 of described PBT.
5. fire retardation PC as claimed in claim 1/PBT/PET alloy is characterized in that: the limiting viscosity 0.83 ~ 0.96 of described PET.
6. fire retardation PC as claimed in claim 1/PBT/PET alloy, it is characterized in that: described oxidation inhibitor is four [β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] any two kinds of combinations in pentaerythritol ester, β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid octadecyl ester and tricresyl phosphite (24-di-tert-butyl-phenyl) ester.
7. fire retardation PC as claimed in claim 1/PBT/PET alloy is characterized in that: described processing aid is one or more in lubricant ethylene bis-fatty acid amides, tetramethylolmethane stearate and mutual-phenenyl two acid bromide two alcohol ester's the cyclic oligomer.
8. the preparation method of fire retardation PC as claimed in claim 1/PBT/PET alloy:
A, raw material drying pre-treatment, PC, PET and PBT exsiccant temperature are controlled at 110～130 ℃, and time of drying is more than 4 hours; The drying conditions of other raw materials is 70 ℃ * 12 hours;
B, above-mentioned dried feed is joined thorough mixing in the high-speed mixer by proportioning, stirring at normal temperature 10～20 minutes;
C, melt blending are extruded, water-cooled, air-dry, pelletizing, oven dry.
9. the preparation method of fire retardation PC as claimed in claim 8/PBT/PET alloy is characterized in that: described melt blending is extruded the employing parallel double-screw extruder, screw diameter 35-75mm;
This twin screw extruder has a district to eight district, the temperature setting in each district is respectively: 200～210 ℃ in a district, 210～220 ℃ in two districts, 220～230 ℃ in three districts, 230～240 ℃ in four districts, 240～250 ℃ in five districts, 240～250 ℃ in six districts, 240～250 ℃ in seven districts, 240～250 ℃ in eight districts, 240～250 ℃ of head temperatures;
The screw speed of this forcing machine is controlled at 200～350rPm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010583034XA CN102002226A (en) | 2010-12-10 | 2010-12-10 | Flame-resistant PC (Polycarbonate)/PBT (Polybutylene Terephathalate)/PET (Polyethylene Terephathalate) alloy and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010583034XA CN102002226A (en) | 2010-12-10 | 2010-12-10 | Flame-resistant PC (Polycarbonate)/PBT (Polybutylene Terephathalate)/PET (Polyethylene Terephathalate) alloy and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102002226A true CN102002226A (en) | 2011-04-06 |
Family
ID=43809946
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010583034XA Pending CN102002226A (en) | 2010-12-10 | 2010-12-10 | Flame-resistant PC (Polycarbonate)/PBT (Polybutylene Terephathalate)/PET (Polyethylene Terephathalate) alloy and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102002226A (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102352092A (en) * | 2011-09-07 | 2012-02-15 | 上海日之升新技术发展有限公司 | Flame-retardant glass fiber reinforced polyethylene terephthalate (PET)/ polytrimethylene terephthalate (PTT)/ polybutylene terephthalate (PBT) alloy material and preparation method thereof |
| CN102898806A (en) * | 2012-11-06 | 2013-01-30 | 上海冠旗电子新材料股份有限公司 | Antistatic polycarbonate/polyester alloy material and preparation method thereof |
| CN103772934A (en) * | 2012-10-22 | 2014-05-07 | 黑龙江鑫达企业集团有限公司 | High-impact high-heat-resistance PC/PBT alloy material and preparation technology thereof |
| CN104031370A (en) * | 2013-03-04 | 2014-09-10 | 苏州宇度医疗器械有限责任公司 | Preparation method for flame-retardant polycarbonate ternary composite material |
| CN104031372A (en) * | 2013-03-04 | 2014-09-10 | 苏州宇度医疗器械有限责任公司 | Flame-retardant polycarbonate ternary composite material |
| CN104312109A (en) * | 2014-10-16 | 2015-01-28 | 惠州市沃特新材料有限公司 | Color master batch with pearl effect for polyester PET blow molding and preparation method of color master batch |
| CN104356625A (en) * | 2014-10-28 | 2015-02-18 | 佛山市思汗新材料有限公司 | Stress-cracking-resistant glass-fiber-reinforced polycarbonate material and preparation method thereof |
| CN104927335A (en) * | 2015-07-15 | 2015-09-23 | 上海锦湖日丽塑料有限公司 | High-tenacity high-heat-resistant PC/PBT resin combination and preparing method thereof |
| CN105802180A (en) * | 2016-05-09 | 2016-07-27 | 李红玉 | Polycarbonate thin-film material and preparation method thereof |
| CN107686637A (en) * | 2017-09-27 | 2018-02-13 | 宁波顶名科技有限公司 | High pressure resistant high temperature resistant composite and preparation method thereof |
| CN108164937A (en) * | 2017-12-27 | 2018-06-15 | 上海普利特复合材料股份有限公司 | A kind of new-energy automobile fiberglass reinforced high fire-retardance PC/PBT composite materials and preparation method thereof |
| CN108219420A (en) * | 2017-12-19 | 2018-06-29 | 宁波甬尚聚新材料有限公司 | A kind of polycarbonate styrene resinoid alloy and preparation method thereof |
| CN109337329A (en) * | 2018-09-07 | 2019-02-15 | 广东聚石化学股份有限公司 | A kind of cold-resistant fire retardation PC/PBT alloy and preparation method thereof |
| US10538620B2 (en) | 2016-08-31 | 2020-01-21 | Lg Chem, Ltd. | Method for preparing polycarbonate |
| CN115260711A (en) * | 2022-08-12 | 2022-11-01 | 横店集团得邦工程塑料有限公司 | Hydrolysis-resistant high-barrier-property biodegradable film and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101220199A (en) * | 2007-12-28 | 2008-07-16 | 深圳市科聚新材料有限公司 | Environment-protection flame-proof fiberglass reinforcing polyester alloy material and method for producing the same |
| CN101570628A (en) * | 2009-04-16 | 2009-11-04 | 从化市聚赛龙工程塑料有限公司 | Flame retardant PC/PET composite material and preparation method thereof |
| CN101875769A (en) * | 2010-03-31 | 2010-11-03 | 深圳市科聚新材料有限公司 | Halogen-free flame-retardant glassfiber reinforced PC/PBT alloy material and preparation method thereof |
-
2010
- 2010-12-10 CN CN201010583034XA patent/CN102002226A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101220199A (en) * | 2007-12-28 | 2008-07-16 | 深圳市科聚新材料有限公司 | Environment-protection flame-proof fiberglass reinforcing polyester alloy material and method for producing the same |
| CN101570628A (en) * | 2009-04-16 | 2009-11-04 | 从化市聚赛龙工程塑料有限公司 | Flame retardant PC/PET composite material and preparation method thereof |
| CN101875769A (en) * | 2010-03-31 | 2010-11-03 | 深圳市科聚新材料有限公司 | Halogen-free flame-retardant glassfiber reinforced PC/PBT alloy material and preparation method thereof |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102352092A (en) * | 2011-09-07 | 2012-02-15 | 上海日之升新技术发展有限公司 | Flame-retardant glass fiber reinforced polyethylene terephthalate (PET)/ polytrimethylene terephthalate (PTT)/ polybutylene terephthalate (PBT) alloy material and preparation method thereof |
| CN103772934A (en) * | 2012-10-22 | 2014-05-07 | 黑龙江鑫达企业集团有限公司 | High-impact high-heat-resistance PC/PBT alloy material and preparation technology thereof |
| CN102898806A (en) * | 2012-11-06 | 2013-01-30 | 上海冠旗电子新材料股份有限公司 | Antistatic polycarbonate/polyester alloy material and preparation method thereof |
| CN102898806B (en) * | 2012-11-06 | 2014-08-20 | 上海冠旗电子新材料股份有限公司 | Antistatic polycarbonate/polyester alloy material and preparation method thereof |
| CN104031370A (en) * | 2013-03-04 | 2014-09-10 | 苏州宇度医疗器械有限责任公司 | Preparation method for flame-retardant polycarbonate ternary composite material |
| CN104031372A (en) * | 2013-03-04 | 2014-09-10 | 苏州宇度医疗器械有限责任公司 | Flame-retardant polycarbonate ternary composite material |
| CN104312109B (en) * | 2014-10-16 | 2017-05-17 | 惠州市沃特新材料有限公司 | Color master batch with pearl effect for polyester PET blow molding and preparation method of color master batch |
| CN104312109A (en) * | 2014-10-16 | 2015-01-28 | 惠州市沃特新材料有限公司 | Color master batch with pearl effect for polyester PET blow molding and preparation method of color master batch |
| CN104356625A (en) * | 2014-10-28 | 2015-02-18 | 佛山市思汗新材料有限公司 | Stress-cracking-resistant glass-fiber-reinforced polycarbonate material and preparation method thereof |
| CN104927335A (en) * | 2015-07-15 | 2015-09-23 | 上海锦湖日丽塑料有限公司 | High-tenacity high-heat-resistant PC/PBT resin combination and preparing method thereof |
| CN105802180A (en) * | 2016-05-09 | 2016-07-27 | 李红玉 | Polycarbonate thin-film material and preparation method thereof |
| US10538620B2 (en) | 2016-08-31 | 2020-01-21 | Lg Chem, Ltd. | Method for preparing polycarbonate |
| CN107686637A (en) * | 2017-09-27 | 2018-02-13 | 宁波顶名科技有限公司 | High pressure resistant high temperature resistant composite and preparation method thereof |
| CN107686637B (en) * | 2017-09-27 | 2020-08-18 | 宁波顶名科技有限公司 | Preparation method of high-pressure-resistant and high-temperature-resistant composite material |
| CN108219420A (en) * | 2017-12-19 | 2018-06-29 | 宁波甬尚聚新材料有限公司 | A kind of polycarbonate styrene resinoid alloy and preparation method thereof |
| CN108164937A (en) * | 2017-12-27 | 2018-06-15 | 上海普利特复合材料股份有限公司 | A kind of new-energy automobile fiberglass reinforced high fire-retardance PC/PBT composite materials and preparation method thereof |
| CN109337329A (en) * | 2018-09-07 | 2019-02-15 | 广东聚石化学股份有限公司 | A kind of cold-resistant fire retardation PC/PBT alloy and preparation method thereof |
| CN115260711A (en) * | 2022-08-12 | 2022-11-01 | 横店集团得邦工程塑料有限公司 | Hydrolysis-resistant high-barrier-property biodegradable film and preparation method thereof |
| CN115260711B (en) * | 2022-08-12 | 2024-01-05 | 横店集团得邦工程塑料有限公司 | Hydrolysis-resistant high-barrier biodegradable film and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102002226A (en) | Flame-resistant PC (Polycarbonate)/PBT (Polybutylene Terephathalate)/PET (Polyethylene Terephathalate) alloy and preparation method thereof | |
| CN101508834B (en) | PC/PBT alloy and method for producing the same | |
| CN102617997B (en) | Glass fiber-reinforced PBT/PET (Polybutylece Terephthalate/Polyethyleneglycol Terephthalate) composite material and preparation method thereof | |
| CN101195707B (en) | Glass fiber-reinforced nylon 6-polypropylene alloy material | |
| CN100590146C (en) | Preparation of halogen-free flame-proof nylon 66 having high-mechanical property and composite material | |
| CN102061076A (en) | Super-tough PC (polycarbonate)/PBT (Polybutylece Terephthalate)/PET (Polyethylene Glycol Terephthalate) alloy and preparation method thereof | |
| CN101362857B (en) | Non-halogen flame-retarding high performance polycarbonate engineering plastics and preparation method thereof | |
| CN102108181B (en) | Thermoplastic alloy and preparation method thereof | |
| CN102070884B (en) | Fire resistant glass fiber reinforced polyethylene terephthalate/polybutylece terephthalate alloy and preparation method thereof | |
| CN108117735B (en) | High-performance halogen-free flame-retardant polycarbonate material and preparation method thereof | |
| CN110229482A (en) | A kind of high-performance reinforced fire-retardant PBT material and preparation method thereof | |
| CN101805507A (en) | Polycarbonate resin composition for lampshades and preparation method thereof | |
| CN101838452B (en) | Polycarbonate resin composition and preparation method thereof | |
| CN105440628A (en) | Enhanced flame retardant PC/PPO composite material and preparation method thereof | |
| CN102558784A (en) | Anti-impact polyethylene glycol terephthalate composite material and preparation method thereof | |
| CN102020839A (en) | Halogen-free flaming retarding PC (polycarbonate)/PET (polyethylene terephthalate) composite material alloy and preparation method thereof | |
| CN101613525A (en) | A kind of polyphenylene oxide and polyethylene terephthalate blend and preparation method thereof | |
| CN111560164A (en) | High-toughness weather-resistant high-temperature-resistant halogen-free flame-retardant polyphenyl ether composite material and preparation method thereof | |
| CN102558844A (en) | Glass fiber reinforced nylon 6-polyethylene terephthalate alloy material and preparation method thereof | |
| CN103073855A (en) | Polyester composition, preparation method and applications thereof | |
| CN112662143A (en) | PBT composition with high elongation at break and preparation method thereof | |
| CN103073853B (en) | Environmental-protection fire retardation enhancement PBT/PET/PA6 alloy and manufacturing method thereof | |
| CN1315933C (en) | PP and ABS nano filler alloy and preparation method thereof | |
| CN104086971A (en) | High-flowability and flame-retardant polycarbonate and polystyrene composition and preparation method thereof | |
| CN102321347A (en) | High creepage trace index polyester composite and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20110406 |