CN101982517A - Modified asphalt adhesive and preparation method thereof - Google Patents

Modified asphalt adhesive and preparation method thereof Download PDF

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Publication number
CN101982517A
CN101982517A CN2010105481122A CN201010548112A CN101982517A CN 101982517 A CN101982517 A CN 101982517A CN 2010105481122 A CN2010105481122 A CN 2010105481122A CN 201010548112 A CN201010548112 A CN 201010548112A CN 101982517 A CN101982517 A CN 101982517A
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China
Prior art keywords
stirring
sizing agent
pitch
powder
preparation
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CN2010105481122A
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Chinese (zh)
Inventor
张之秋
吕向阳
娄阁
邵明力
田希均
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BEIJING YAOXIN TECHNOLOGY DEVELOPMENT Co Ltd
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BEIJING YAOXIN TECHNOLOGY DEVELOPMENT Co Ltd
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Priority to CN2010105481122A priority Critical patent/CN101982517A/en
Publication of CN101982517A publication Critical patent/CN101982517A/en
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Abstract

The invention discloses a modified asphalt adhesive and a preparation method thereof. The preparation method comprises the following steps: pumping fused asphalt in a stirring kettle; starting a stirring paddle, wherein, the stirring speed is 60-200 revolutions/min, and the material temperature is 120-150 DEG C; stirring for 10-30min; adding styrene-butadiene block copolymer (SBS) and styrene butadiene rubber (SBR) and continuously stirring; heating to 160-180 DEG C; stirring for 1-2h; keeping the stirring temperature and the stirring speed; adding tackifier; continuously stirring for 30-60min; adding rubber powder and filler in sequence; continuously stirring for 30-60min; and grinding by a colloid mill to obtain the modified asphalt adhesive with good performance.

Description

A kind of modifying asphalt sizing agent and preparation method thereof
Technical field
The present invention relates to field of waterproof materials, a kind of modifying asphalt sizing agent of saying so more specifically with good adhesion, good high temperature resistant and resistance to low temperature.
Background technology
Along with greatly developing of national large foundation Facilities Construction and public works, waterproofing work becomes the most important thing in these engineerings, and waterproof problem receives much concern.Various waterproof materials emerge in an endless stream, and the quality of water-proof material performance directly has influence on the success or failure of waterproofing work, and then have influence on the functional quality of whole engineering, and therefore, the user is in waterproof construction, and is very prudent to the selection of water-proof material.Along with the requirement to waterproofing quality is more and more higher, simultaneously, also excited the development potentiality of field of waterproof materials, the development of water-proof material enters flourishing high-speed development period, at present, main waterproof roll is divided into asphalt felt class, high-polymer modified pitch base waterproof roll class and polymer membranes class on the market, and pitch class waterproof roll is withdrawn from the market gradually owing to environmental issue; Polymer modified bituminous waterproof sheet material is with its cheap cost, good performance and become the main flow in market; High score subclass waterproof roll mechanical property is very good, but cost is higher, and the commercial market is difficult to be popularized.Present all tabula rasa waterproof rolls, what realize in waterproofing work all is " raincoat formula " waterproof, and the fatal shortcoming that this waterproof roll exists is " string water " problem, and leak is easy-to-search not, is difficult for repairing; In order to realize " skin-type " waterproof, waterproof roll and base material are realized good applying, thoroughly solve " string water " problem, this waterproof roll surface needs compound one deck sizing agent, thereby realize the comprehensive excellent bonds of waterproof roll and base material, and become " skin " of base material, realize " skin-type " waterproof.At present, the shortcoming such as the cost height that exist of some sizing agents, bond properties is poor, high temperature is easy " trickling ", low temperature easy " embrittlement " etc.
Summary of the invention
The object of the invention is to overcome the shortcoming and defect of prior art, and a kind of modifying asphalt sizing agent with good bond properties, resistance to elevated temperatures, resistance to low temperature and cheap advantages such as cost is provided.
The technical scheme that the present invention solves described modifying asphalt sizing agent technical problem is: design a kind of modifying asphalt sizing agent, it is characterized in that this modifying asphalt sizing agent is made up of the following portions by weight material:
Pitch 45-65 part
Tackifier 10-30 part
SBS 3-15 part
SBR 1-10 part
Filler 5-20 part
Rubber powder 5-15 part
Described pitch is 90# pitch or 100# pitch or two kinds of asphalt mixtures;
Described tackifier are one or more compounds in terpine resin, aromatic hydrocarbon oil, the rosin;
Described SBS is a kind of among trade mark KTR-101, LG411, GF-6, YH-791 and the YH-792;
Described SBR is a kind of powder styrene butadiene rubber or several different trade mark powder styrene butadiene rubber compound;
Described filler is one or more compounds in talcum powder, lime carbonate, mica powder and the barium sulfate;
Described rubber powder is a using rubber powder of waste tire.
The technical scheme that the present invention solves described preparation method's technical problem is: design a kind of preparation method of modifying asphalt sizing agent, this preparation method is a foundation with the sizing agent of parts by weight material of the present invention, and adopts following technology:
Under the normal temperature, composition according to described sizing agent parts by weight, earlier fused pitch is got in the stirring tank by pump, stirring tank is the chuck stainless steel cauldron, heat by thermal oil, open stirring rake, stirring velocity is 60-200 rev/min, temperature of charge is 120-150 ℃, stirs 10-30 minute; Adding SBS, SBR continues to stir, and temperature is raised to 160-180 ℃, stirred 1-2 hour, keep whipping temp and stirring velocity, add tackifier, continue to stir 30-60 minute, add rubber powder and filler then successively, continue to stir 30-60 minute, after colloidal mill grinds, the modifying asphalt sizing agent that obtained performance is good.
Compared with prior art, modifying asphalt sizing agent of the present invention and preparation method thereof has following advantage:
1 with macromolecular material have excellent adhesion performance;
2 good high temperature resistant and resistance to low temperatures;
3 cheap costs, excellent performance has the stronger market competitiveness;
The employing of 4 waste Crumb rubbers has positive environmental protection and energy saving meaning.
Figure of description
Fig. 1 modifying asphalt sizing agent technological process of production figure
Embodiment:
Below in conjunction with embodiment the present invention is done further explaination.
Modifying asphalt sizing agent of the present invention (abbreviation sizing agent) is characterized in that the mixture that this sizing agent is made up of the following portions by weight material:
Pitch 45-65 part
Tackifier 10-30 part
SBS 3-15 part
SBR 1-10 part
Filler 5-20 part
Rubber powder 5-15 part
Described pitch is 90# pitch;
Described tackifier are the compound of the aromatic hydrocarbon oil of the terpine resin of 3-10 part and 10-20 part;
Described SBS is trade mark LG411;
Described SBR is a kind of powder styrene butadiene rubber GS-1;
Described filler is the talcum powder of 5-10 part and the compound of 1-10 part lime carbonate;
Described rubber powder is 60 order using rubber powder of waste tire.
The present invention has designed the preparation method (abbreviation preparation method) of described modifying asphalt sizing agent simultaneously.This preparation method is a foundation with the sizing agent of parts by weight material of the present invention, earlier the 90# pitch of fused 45-65 part is got in the stirring tank by pump, stirring tank is the chuck stainless steel cauldron, heat by thermal oil, open stirring rake, stirring velocity is 60-200 rev/min, and temperature of charge is 120-150 ℃, stirs 10-30 minute; Adding the LG411SBS of 3-15 part, the powder styrene butadiene rubber GS-1SBR of 1-10 part continues to stir, and temperature is raised to 160-180 ℃, stirred 1-2 hour, keep whipping temp and stirring velocity, add terpine resin of 3-10 part and the aromatic hydrocarbon oil of 10-20 part, continue to stir 30-60 minute, add the 60 order rubber powders of 5-15 part, the talcum powder of 5-10 part and the lime carbonate of 1-10 part then successively, continue to stir 30-60 minute, after colloidal mill grinds, the modifying asphalt sizing agent that obtained performance is good.
Provide specific embodiments of the invention below, these embodiment further specify of the present invention, do not constitute the restriction to claim protection domain of the present invention.
Embodiment 1:
Prescription and preparation method:
1, prescription:
Pitch 450kg
Tackifier 200kg
SBS 30kg
SBR 10kg
Filler 150kg
Rubber powder 100kg
2, preparation method:
Earlier the 90# pitch of fused 450kg is got in the stirring tank by pump, stirring tank is the chuck stainless steel cauldron, heats by thermal oil, opens stirring rake, and stirring velocity is 100 rev/mins, and temperature of charge is 130 ℃, stirs 20 minutes; The powder styrene butadiene rubber GS-1SBR that adds LG411SBS, the 10kg of 30kg continues to stir, and temperature is raised to 170 ℃, stirred 1.5 hours, keep whipping temp and stirring velocity, add the terpine resin of 50kg and the aromatic hydrocarbon oil of 150kg, continue to stir 40 minutes, add the 60 order rubber powders of 100kg, the talcum powder of 50kg and the lime carbonate of 100kg then successively, continue to stir 50 minutes, after colloidal mill grinds, the modifying asphalt sizing agent that obtained performance is good.
The salient features of the sizing agent that the present invention is prepared
Figure BSA00000349753500041
Embodiment 2:
Prescription and preparation method:
1, prescription:
Pitch 450kg
Tackifier 180kg
SBS 50kg
SBR 20kg
Filler 150kg
Rubber powder 100kg
2, preparation method:
Earlier the 90# pitch of fused 450kg is got in the stirring tank by pump, stirring tank is the chuck stainless steel cauldron, heats by thermal oil, opens stirring rake, and stirring velocity is 120 rev/mins, and temperature of charge is 130 ℃, stirs 30 minutes; The powder styrene butadiene rubber GS-1SBR that adds LG411SBS, the 20kg of 50kg continues to stir, and temperature is raised to 170 ℃, stirred 1.5 hours, keep whipping temp and stirring velocity, add the terpine resin of 80kg and the aromatic hydrocarbon oil of 100kg, continue to stir 40 minutes, add the 60 order rubber powders of 100kg, the talcum powder of 50kg and the lime carbonate of 100kg then successively, continue to stir 50 minutes, after colloidal mill grinds, the modifying asphalt sizing agent that obtained performance is good.
Embodiment 3:
Prescription and preparation method:
1, prescription:
Pitch 450kg
Tackifier 250kg
SBS 80kg
SBR 30kg
Filler 120kg
Rubber powder 80kg
2, preparation method:
Earlier the 90# pitch of fused 450kg is got in the stirring tank by pump, stirring tank is the chuck stainless steel cauldron, heats by thermal oil, opens stirring rake, and stirring velocity is 100 rev/mins, and temperature of charge is 130 ℃, stirs 20 minutes; The powder styrene butadiene rubber GS-1SBR that adds LG411SBS, the 30kg of 80kg continues to stir, and temperature is raised to 170 ℃, stirred 1.5 hours, keep whipping temp and stirring velocity, add the terpine resin of 100kg and the aromatic hydrocarbon oil of 150kg, continue to stir 40 minutes, add the 60 order rubber powders of 80kg, the talcum powder of 50kg and the lime carbonate of 70kg then successively, continue to stir 50 minutes, after colloidal mill grinds, the modifying asphalt sizing agent that obtained performance is good.
The performance comparison sheet
Project Embodiment 1 Embodiment 2 Embodiment 3
High thermal resistance 65 ℃, 8h do not trickle 80 ℃, 8h do not trickle 90 ℃, 8h do not trickle
Lower temperature resistance -20 ℃, 24h bend flawless -25 ℃, 24h bend flawless -35 ℃, 24h bend flawless
With the aluminium sheet cutting performance 3.8N/mm 4.6N/mm 6.1N/mm
With the aluminium sheet stripping performance 4.0N/mm 4.9N/mm 6.2N/mm
The present invention is not limited to the foregoing description, more than a part in the shown just preferred embodiment of the present invention, can not once limit the present invention's interest field, therefore, equivalent variations so that the present patent application claim is done still belongs to the scope that the present invention is contained.

Claims (2)

1. modifying asphalt sizing agent is characterized in that the mixture that this sizing agent is made up of the following portions by weight material:
Pitch 45-65 part
Tackifier 10-30 part
SBS 3-15 part
SBR 1-10 part
Filler 5-20 part
Rubber powder 5-15 part
Described pitch is 90# pitch or 100# pitch or two kinds of asphalt mixtures;
Described tackifier are one or more compounds in terpine resin, aromatic hydrocarbon oil, the rosin;
Described SBS is a kind of among trade mark KTR-101, LG411, GF-6, YH-791 and the YH-792;
Described SBR is a kind of powder styrene butadiene rubber or several different trade mark powder styrene butadiene rubber compound;
Described filler is one or more compounds in talcum powder, lime carbonate, mica powder and the barium sulfate;
Described rubber powder is a using rubber powder of waste tire.
2. preparation method according to the described sizing agent of claim 1, this preparation method is a foundation with the parts by weight ratio of sizing agent of the present invention, and adopts following technology:
Under the normal temperature, composition according to described sizing agent parts by weight, earlier fused pitch is got in the stirring tank by pump, stirring tank is the chuck stainless steel cauldron, heat by thermal oil, open stirring rake, stirring velocity is 60-200 rev/min, temperature of charge is 120-150 ℃, stirs 10-30 minute; Adding SBS, SBR continues to stir, and temperature is raised to 160-180 ℃, stirred 1-2 hour, keep whipping temp and stirring velocity, add tackifier, continue to stir 30-60 minute, add rubber powder and filler then successively, continue to stir 30-60 minute, after colloidal mill grinds, the modifying asphalt sizing agent that obtained performance is good.
CN2010105481122A 2010-11-18 2010-11-18 Modified asphalt adhesive and preparation method thereof Pending CN101982517A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN2010105481122A CN101982517A (en) 2010-11-18 2010-11-18 Modified asphalt adhesive and preparation method thereof

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Publication Number Publication Date
CN101982517A true CN101982517A (en) 2011-03-02

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Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102504756A (en) * 2011-09-29 2012-06-20 广东辛美来亚科技实业有限公司 Road gap-filling cement and preparation method thereof
CN102604589A (en) * 2012-03-22 2012-07-25 云南光电辅料有限公司 Rubber for processing small lens, and preparation method of the rubber
CN102690629A (en) * 2011-03-22 2012-09-26 闫炳润 Rapid-welding self-curing crack pouring adhesive and application method thereof
CN102827572A (en) * 2012-09-17 2012-12-19 山东建筑大学 Rubber and plastic waterproof bonding modification asphalt mastic and preparation method of rubber and plastic waterproof bonding modification asphalt mastic
CN103013142A (en) * 2011-09-22 2013-04-03 北京嘉格伟业筑路科技有限公司 Waste tire rubber powder plant asphalt material and preparation method thereof
CN103087673A (en) * 2013-02-28 2013-05-08 衡水中铁建土工材料制造有限公司 Modified asphalt cold adhesive and preparation process thereof
CN103205227A (en) * 2013-04-28 2013-07-17 重庆市智翔铺道技术工程有限公司 Cementing compound for pavement layers
CN103465541A (en) * 2013-09-29 2013-12-25 河北豫旺百创防水材料有限公司 Waterproofing roll with self-adhesion POE modified bitumen
CN103802415A (en) * 2014-01-24 2014-05-21 郑家玉 Self-sticking waterproof coil and preparation method thereof
CN103951992A (en) * 2014-04-30 2014-07-30 昆山科顺防水材料有限公司 Wet-laid waterproof coiled material
CN104250444A (en) * 2013-06-27 2014-12-31 孙智宁 Polyolefin elastomer modified asphalt waterproof coiled material
CN104312467A (en) * 2014-10-29 2015-01-28 余云超 CNT heat effect rapid reaction adhesion type self-adhesive waterproof coiled material
CN104449557A (en) * 2014-12-30 2015-03-25 江苏健神生物农化有限公司 Stable asphalt mastic
CN105199666A (en) * 2015-11-05 2015-12-30 东莞市超逸建材有限公司 Production and construction technologies of road sealant
CN105400429A (en) * 2015-12-14 2016-03-16 刘冠麟 No-curing high-molecular modification asphalt waterproof paint and preparation method therefor
CN105694806A (en) * 2016-02-24 2016-06-22 栾海 Bridge-deck waterproof bonding layer material and preparation method thereof
CN106147257A (en) * 2016-07-01 2016-11-23 山东高速物资储运有限公司 A kind of environment-friendly type road-surface heating type sealant material and preparation method thereof and application
CN106957534A (en) * 2017-01-18 2017-07-18 盘锦禹王防水建材集团有限公司 A kind of low forming temperature high-polymer modified pitch glue and preparation method thereof
CN109575876A (en) * 2018-11-07 2019-04-05 河南公路卫士交通科技有限公司 A kind of Road sealant and preparation method thereof
CN109971419A (en) * 2019-04-02 2019-07-05 河南驼峰防水科技有限公司 A kind of self-adhesion waterproof sizing material and preparation method thereof applied on metal Roof
CN110746929A (en) * 2019-10-14 2020-02-04 四川东方雨虹建筑材料有限公司 Self-adhesive modified asphalt waterproof coiled material coating material, preparation method thereof and aluminum foil surface self-adhesive asphalt waterproof coiled material special for passive building
CN110746930A (en) * 2019-10-14 2020-02-04 四川东方雨虹建筑材料有限公司 Self-adhesive modified asphalt waterproof coiled material coating material, preparation method thereof and passive self-adhesive asphalt waterproof coiled material special for building
CN111019600A (en) * 2019-12-06 2020-04-17 河北长大交通科技有限公司 High-performance asphalt pavement crack pouring adhesive and preparation method thereof
CN112143401A (en) * 2020-09-24 2020-12-29 广西神宇新材料有限公司 SBSF 730-based novel self-adhesive waterproof roll and preparation method thereof

Cited By (32)

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CN102690629A (en) * 2011-03-22 2012-09-26 闫炳润 Rapid-welding self-curing crack pouring adhesive and application method thereof
CN102690629B (en) * 2011-03-22 2013-10-02 闫炳润 Rapid-welding self-curing crack pouring adhesive and application method thereof
CN103013142A (en) * 2011-09-22 2013-04-03 北京嘉格伟业筑路科技有限公司 Waste tire rubber powder plant asphalt material and preparation method thereof
CN102504756A (en) * 2011-09-29 2012-06-20 广东辛美来亚科技实业有限公司 Road gap-filling cement and preparation method thereof
CN102604589A (en) * 2012-03-22 2012-07-25 云南光电辅料有限公司 Rubber for processing small lens, and preparation method of the rubber
CN102604589B (en) * 2012-03-22 2014-02-05 云南光电辅料有限公司 Rubber for processing small lens, and preparation method of rubber
CN102827572A (en) * 2012-09-17 2012-12-19 山东建筑大学 Rubber and plastic waterproof bonding modification asphalt mastic and preparation method of rubber and plastic waterproof bonding modification asphalt mastic
CN103087673A (en) * 2013-02-28 2013-05-08 衡水中铁建土工材料制造有限公司 Modified asphalt cold adhesive and preparation process thereof
CN103087673B (en) * 2013-02-28 2015-03-25 衡水中铁建土工材料制造有限公司 Modified asphalt cold adhesive and preparation process thereof
CN103205227A (en) * 2013-04-28 2013-07-17 重庆市智翔铺道技术工程有限公司 Cementing compound for pavement layers
CN103205227B (en) * 2013-04-28 2015-04-29 重庆市智翔铺道技术工程有限公司 Cementing compound for pavement layers
CN104250444A (en) * 2013-06-27 2014-12-31 孙智宁 Polyolefin elastomer modified asphalt waterproof coiled material
CN103465541A (en) * 2013-09-29 2013-12-25 河北豫旺百创防水材料有限公司 Waterproofing roll with self-adhesion POE modified bitumen
CN103802415A (en) * 2014-01-24 2014-05-21 郑家玉 Self-sticking waterproof coil and preparation method thereof
CN103802415B (en) * 2014-01-24 2016-08-24 郑家玉 A kind of self-adhesive waterproof web and preparation method thereof
CN103951992A (en) * 2014-04-30 2014-07-30 昆山科顺防水材料有限公司 Wet-laid waterproof coiled material
CN104312467A (en) * 2014-10-29 2015-01-28 余云超 CNT heat effect rapid reaction adhesion type self-adhesive waterproof coiled material
CN104449557A (en) * 2014-12-30 2015-03-25 江苏健神生物农化有限公司 Stable asphalt mastic
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CN105400429A (en) * 2015-12-14 2016-03-16 刘冠麟 No-curing high-molecular modification asphalt waterproof paint and preparation method therefor
CN105694806A (en) * 2016-02-24 2016-06-22 栾海 Bridge-deck waterproof bonding layer material and preparation method thereof
CN106147257A (en) * 2016-07-01 2016-11-23 山东高速物资储运有限公司 A kind of environment-friendly type road-surface heating type sealant material and preparation method thereof and application
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CN109971419A (en) * 2019-04-02 2019-07-05 河南驼峰防水科技有限公司 A kind of self-adhesion waterproof sizing material and preparation method thereof applied on metal Roof
CN110746929A (en) * 2019-10-14 2020-02-04 四川东方雨虹建筑材料有限公司 Self-adhesive modified asphalt waterproof coiled material coating material, preparation method thereof and aluminum foil surface self-adhesive asphalt waterproof coiled material special for passive building
CN110746930A (en) * 2019-10-14 2020-02-04 四川东方雨虹建筑材料有限公司 Self-adhesive modified asphalt waterproof coiled material coating material, preparation method thereof and passive self-adhesive asphalt waterproof coiled material special for building
CN110746929B (en) * 2019-10-14 2021-01-26 四川东方雨虹建筑材料有限公司 Self-adhesive modified asphalt waterproof coiled material coating material, preparation method thereof and aluminum foil surface self-adhesive asphalt waterproof coiled material special for passive building
CN111019600A (en) * 2019-12-06 2020-04-17 河北长大交通科技有限公司 High-performance asphalt pavement crack pouring adhesive and preparation method thereof
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Application publication date: 20110302