CN101981021A - 使用特定的吸收剂制备贫hf的氟化有机碳酸酯 - Google Patents

使用特定的吸收剂制备贫hf的氟化有机碳酸酯 Download PDF

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Publication number: CN101981021A
Authority: CN; China
Prior art keywords: fluorine; carbonate; organic carbonate; poor; fluoro
Prior art date: 2008-03-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

CN2009801107499A

Other languages

English (en)

Chinese (zh)

Inventor

延斯·奥尔席姆克

安德烈亚斯·格罗斯曼

克斯廷·艾希霍尔茨

斯特凡·帕尔谢姆

奥拉夫·伯泽

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Solvay Fluor GmbH

Original Assignee

Solvay Fluor und Derivate GmbH

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2008-03-27

Filing date

2009-03-26

Publication date

2011-02-23

2009-03-26 Application filed by Solvay Fluor und Derivate GmbH filed Critical Solvay Fluor und Derivate GmbH

2011-02-23 Publication of CN101981021A publication Critical patent/CN101981021A/zh

Status Pending legal-status Critical Current

Links

150000005677 organic carbonates Chemical class 0.000 title claims abstract description 31
238000002360 preparation method Methods 0.000 title description 2
230000002745 absorbent Effects 0.000 title 1
239000002250 absorbent Substances 0.000 title 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 62
238000000034 method Methods 0.000 claims abstract description 36
239000000377 silicon dioxide Substances 0.000 claims abstract description 24
SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical compound FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 claims abstract description 22
235000012239 silicon dioxide Nutrition 0.000 claims abstract description 19
239000000741 silica gel Substances 0.000 claims abstract description 12
229910002027 silica gel Inorganic materials 0.000 claims abstract description 12
229910052731 fluorine Inorganic materials 0.000 claims description 35
239000011737 fluorine Substances 0.000 claims description 29
229960001866 silicon dioxide Drugs 0.000 claims description 29
-1 alkylene carbonates Chemical class 0.000 claims description 26
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 25
239000000203 mixture Substances 0.000 claims description 24
238000004821 distillation Methods 0.000 claims description 10
239000007787 solid Substances 0.000 claims description 10
125000001153 fluoro group Chemical group F* 0.000 claims description 8
238000007130 inorganic reaction Methods 0.000 claims description 8
229910004298 SiO 2 Inorganic materials 0.000 claims description 6
125000000217 alkyl group Chemical group 0.000 claims description 5
150000002170 ethers Chemical class 0.000 claims description 5
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 4
125000001118 alkylidene group Chemical group 0.000 claims description 4
239000011324 bead Substances 0.000 claims description 4
MJIULRNAOLSIHL-UHFFFAOYSA-N carbonic acid;fluoroethene Chemical class FC=C.OC(O)=O MJIULRNAOLSIHL-UHFFFAOYSA-N 0.000 claims description 2
239000000470 constituent Substances 0.000 claims 2
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical class F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 abstract description 60
229910000040 hydrogen fluoride Inorganic materials 0.000 abstract description 58
239000002904 solvent Substances 0.000 abstract description 6
HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 abstract description 3
229910001416 lithium ion Inorganic materials 0.000 abstract description 3
239000003795 chemical substances by application Substances 0.000 abstract description 2
239000000654 additive Substances 0.000 abstract 1
230000000996 additive effect Effects 0.000 abstract 1
229910052681 coesite Inorganic materials 0.000 abstract 1
229910052906 cristobalite Inorganic materials 0.000 abstract 1
238000000746 purification Methods 0.000 abstract 1
229910052682 stishovite Inorganic materials 0.000 abstract 1
229910052905 tridymite Inorganic materials 0.000 abstract 1
150000001875 compounds Chemical class 0.000 description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 10
238000006243 chemical reaction Methods 0.000 description 9
239000007789 gas Substances 0.000 description 8
238000003682 fluorination reaction Methods 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
150000002148 esters Chemical class 0.000 description 6
239000000047 product Substances 0.000 description 6
OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 5
239000002253 acid Substances 0.000 description 4
239000000463 material Substances 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
238000007086 side reaction Methods 0.000 description 4
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 3
238000000354 decomposition reaction Methods 0.000 description 3
239000011521 glass Substances 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
150000002894 organic compounds Chemical class 0.000 description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
230000002939 deleterious effect Effects 0.000 description 2
230000000694 effects Effects 0.000 description 2
150000002221 fluorine Chemical class 0.000 description 2
239000007788 liquid Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
229920001343 polytetrafluoroethylene Polymers 0.000 description 2
RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
239000000376 reactant Substances 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000000243 solution Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
XRVAOYFWWWAYPZ-UHFFFAOYSA-N CF.C(O)(O)=O Chemical compound CF.C(O)(O)=O XRVAOYFWWWAYPZ-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
DTQVDTLACAAQTR-UHFFFAOYSA-M Trifluoroacetate Chemical compound [O-]C(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-M 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000006184 cosolvent Substances 0.000 description 1
238000005796 dehydrofluorination reaction Methods 0.000 description 1
VDGKFLGYHYBDQC-UHFFFAOYSA-N difluoromethyl methyl carbonate Chemical compound COC(=O)OC(F)F VDGKFLGYHYBDQC-UHFFFAOYSA-N 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000004334 fluoridation Methods 0.000 description 1
OMRRUNXAWXNVFW-UHFFFAOYSA-N fluoridochlorine Chemical compound ClF OMRRUNXAWXNVFW-UHFFFAOYSA-N 0.000 description 1
PIQRQRGUYXRTJJ-UHFFFAOYSA-N fluoromethyl methyl carbonate Chemical compound COC(=O)OCF PIQRQRGUYXRTJJ-UHFFFAOYSA-N 0.000 description 1
238000011010 flushing procedure Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 1
150000004702 methyl esters Chemical class 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
NBVXSUQYWXRMNV-UHFFFAOYSA-N monofluoromethane Natural products FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
238000002203 pretreatment Methods 0.000 description 1
OSFBJERFMQCEQY-UHFFFAOYSA-N propylidene Chemical group [CH]CC OSFBJERFMQCEQY-UHFFFAOYSA-N 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000029058 respiratory gaseous exchange Effects 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
239000002210 silicon-based material Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
230000008646 thermal stress Effects 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
- C07D317/32—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D317/34—Oxygen atoms
- C07D317/36—Alkylene carbonates; Substituted alkylene carbonates
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C68/00—Preparation of esters of carbonic or haloformic acids
- C07C68/08—Purification; Separation; Stabilisation
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
- C07D317/32—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D317/42—Halogen atoms or nitro radicals

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CN2009801107499A 2008-03-27 2009-03-26 使用特定的吸收剂制备贫hf的氟化有机碳酸酯 Pending CN101981021A (zh)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
EP08153413		2008-03-27
EP08153413.3		2008-03-27
PCT/EP2009/053559 WO2009118368A1 (en)	2008-03-27	2009-03-26	Preparation of fluorinated organic carbonates depleted in hf using a specific absorbent

Publications (1)

Publication Number	Publication Date
CN101981021A true CN101981021A (zh)	2011-02-23

Family

ID=39766966

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CN2009801107499A Pending CN101981021A (zh)	2008-03-27	2009-03-26	使用特定的吸收剂制备贫hf的氟化有机碳酸酯

Country Status (5)

Country	Link
JP (1)	JP2011515446A (ja)
KR (1)	KR20100126562A (ja)
CN (1)	CN101981021A (ja)
TW (1)	TW201004933A (ja)
WO (1)	WO2009118368A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN103864078A (zh) *	2012-12-17	2014-06-18	沁阳市昊达实业有限公司	一种去除氟硅酸中残留氟化氢的方法
CN104072473A (zh) *	2014-07-08	2014-10-01	昆明合起工贸有限公司	一种用氟硅酸合成氟代碳酸乙烯酯的生产工艺
CN104718199A (zh) *	2012-10-09	2015-06-17	索尔维公司	用于纯化氟化的有机碳酸酯的方法

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
KR20100132988A (ko) *	2008-03-27	2010-12-20	솔베이 플루오르 게엠베하	Ｈｆ-함유 유기 카보네이트로부터 ｈｆ를 제거하는 방법
EP2454226B1 (en)	2009-07-16	2017-03-22	Solvay Fluor GmbH	Process for the preparation of fluoroalkyl (fluoro)alkyl carbonates
TW201121938A (en) *	2009-09-28	2011-07-01	Solvay Fluor Gmbh	Manufacture of difluoroethylene carbonate, trifluoroethylene carbonate and tetrafluoroethylene carbonate
WO2011048053A1 (en) *	2009-10-21	2011-04-28	Solvay Fluor Gmbh	Method for the manufacture of fluorinated ethylene carbonates
JP2015535845A (ja) *	2012-10-09	2015-12-17	ソルヴェイ（ソシエテアノニム）	精製フルオロ置換有機カーボネートの製造

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EP0326054A1 (en) *	1988-01-23	1989-08-02	Daikin Industries, Limited	Process for purification of 2,2,3,3-tetrafluorooxetane
CN1075313A (zh) *	1992-02-12	1993-08-18	明尼苏达州采矿制造公司	氟化功能化合物的制备
CN1305446A (zh) *	1998-07-06	2001-07-25	索尔微氟及衍生物有限公司	贫氟化物有机化合物的制备
CN1810764A (zh) *	2005-01-24	2006-08-02	蔚山化学株式会社	碳酸4－氟亚乙酯的制造方法和装置

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US6252105B1 (en) *	1998-07-06	2001-06-26	Solvay Fluor Und Derivate Gmbh	Synthesis of low-fluoride organic compounds
JP4081884B2 (ja) *	1998-10-05	2008-04-30	三菱化学株式会社	電気二重層コンデンサ用非水電解液
DE10308149A1 (de) *	2003-02-26	2004-09-09	Solvay Fluor Und Derivate Gmbh	Verfahren zur Herstellung von 4-Fluor-1, 3-dioxolan-2-on
JP4848683B2 (ja) *	2005-06-28	2011-12-28	セントラル硝子株式会社	高純度の４−フルオロ−１，３−ジオキソラン−２−オンの製造方法
JP4758722B2 (ja) *	2005-09-30	2011-08-31	株式会社トクヤマ	塩化水素ガスの精製方法

2009
- 2009-03-26 CN CN2009801107499A patent/CN101981021A/zh active Pending
- 2009-03-26 JP JP2011501227A patent/JP2011515446A/ja active Pending
- 2009-03-26 TW TW098109970A patent/TW201004933A/zh unknown
- 2009-03-26 KR KR1020107023933A patent/KR20100126562A/ko not_active Application Discontinuation
- 2009-03-26 WO PCT/EP2009/053559 patent/WO2009118368A1/en active Application Filing

Patent Citations (4)

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Publication number	Priority date	Publication date	Assignee	Title
EP0326054A1 (en) *	1988-01-23	1989-08-02	Daikin Industries, Limited	Process for purification of 2,2,3,3-tetrafluorooxetane
CN1075313A (zh) *	1992-02-12	1993-08-18	明尼苏达州采矿制造公司	氟化功能化合物的制备
CN1305446A (zh) *	1998-07-06	2001-07-25	索尔微氟及衍生物有限公司	贫氟化物有机化合物的制备
CN1810764A (zh) *	2005-01-24	2006-08-02	蔚山化学株式会社	碳酸4－氟亚乙酯的制造方法和装置

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN104718199A (zh) *	2012-10-09	2015-06-17	索尔维公司	用于纯化氟化的有机碳酸酯的方法
CN103864078A (zh) *	2012-12-17	2014-06-18	沁阳市昊达实业有限公司	一种去除氟硅酸中残留氟化氢的方法
CN103864078B (zh) *	2012-12-17	2016-02-24	沁阳市昊达实业有限公司	一种去除氟硅酸中残留氟化氢的方法
CN104072473A (zh) *	2014-07-08	2014-10-01	昆明合起工贸有限公司	一种用氟硅酸合成氟代碳酸乙烯酯的生产工艺
CN104072473B (zh) *	2014-07-08	2016-04-06	昆明合起工贸有限公司	一种用氟硅酸合成氟代碳酸乙烯酯的生产工艺

Also Published As

Publication number	Publication date
JP2011515446A (ja)	2011-05-19
KR20100126562A (ko)	2010-12-01
WO2009118368A1 (en)	2009-10-01
TW201004933A (en)	2010-02-01

Legal Events

Date	Code	Title	Description
2011-02-23	C06	Publication
2011-02-23	PB01	Publication
2011-04-06	C10	Entry into substantive examination
2011-04-06	SE01	Entry into force of request for substantive examination
2013-08-28	C02	Deemed withdrawal of patent application after publication (patent law 2001)
2013-08-28	WD01	Invention patent application deemed withdrawn after publication	Application publication date: 20110223

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CN101981021A (zh)	2011-02-23	使用特定的吸收剂制备贫hf的氟化有机碳酸酯
US20120253058A1 (en)	2012-10-04	Manufacture of difluoroethylene carbonate, trifluoroethylene carbonate and tetrafluoroethylene carbonate
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JP3071393B2 (ja)	2000-07-31	リチウム電池用電解液の製造方法
JPH06298720A (ja)	1994-10-25	フルオロアルキルスルホン酸の精製方法
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