CN101949067A - Anti-ultraviolet anti-sunburn nano elemental fabric body-building protective clothes - Google Patents
Anti-ultraviolet anti-sunburn nano elemental fabric body-building protective clothes Download PDFInfo
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- CN101949067A CN101949067A CN2010101896865A CN201010189686A CN101949067A CN 101949067 A CN101949067 A CN 101949067A CN 2010101896865 A CN2010101896865 A CN 2010101896865A CN 201010189686 A CN201010189686 A CN 201010189686A CN 101949067 A CN101949067 A CN 101949067A
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Abstract
The invention relates to anti-ultraviolet anti-sunburn nano elemental fabric body-building protective clothes belonging to the technical field of functional healthy fabrics clothing production. The parts, i.e. exposed skin, a face, a neck, limbs, and the like, of a sailor, a shipman and a yardman who have maximum body injury caused by long-time solar radiation have obvious dryness, coarseness, desquamation, chromatosis, analosis, wrinkles and inelasticity and even have cancerization caused by sunlight. In the invention, rich and overall honey series mixtures, i.e. trace element vitamins and the like, are added to fiber production spinning solutions, i.e. the traditional ultraviolet absorption conditioner JCJ-966 and CJ-939 and the like; nano selenium and germanium closely contact with a work clothes through human body skin so as to continuously release the trace elements and nutrient substances into a human body and sufficiently regulate, supplement and antagonize internal element balance and enhance the immunity and the resistance. Thus the anti-ultraviolet anti-sunburn nano elemental fabric body-building protective clothes achieves the purposes of body building and cancer prevention.
Description
Technical field:
Antiultraviolet of the present invention is prevented Exposure to Sunlight nano-element fabric body-building protective clothing, belongs to functional health textiles dress ornament garment production technical field.
Background technology:
Ultraviolet ray can be divided into three kinds of long wave ultraviolet (UVA), ultraviolet B radiation (UVB) and short wave ultraviolets (UVC) according to wavelength, and wavelength is long more, and penetration capacity is strong more.(UVA) wavelength is 320-400nm, has very strong penetration power, can penetrate materials such as glass, water.Daily contact skin to ultraviolet ray be the UVA long wave ultraviolet more than 95%.Therefore long-term numerous personnel at outside work; UVA is maximum to the skin injury of human body; UVA can attack skin corium by epidermis; make ossein and elastin laminin in the skin be inflicted heavy losses on; because the dermal cell self-protection ability is relatively poor, even very a spot of long wave ultraviolet (UVA) also can make skin cause great injury.In the course of time, skin will relax, wrinkle, tiny blood vessels, melanin pigmentation, makes skin darkening, lacks gloss.Long-term chronic lasting infringement makes skin early ageing.UVB ultraviolet B radiation wavelength 280-320nm; can make the lipid layer oxidation that has protective effect in the epidermis; make skin exsiccation, furfur, easily grow the acarid disease; cause mite infection; and then make nucleic acid protein sex change in the epidermal cell; produce the impatient dermatitis of sunburn, make rubefaction sore, being exposed to the sun for a long time also causes the canceration of skin easily.The UVB ultraviolet B radiation also can cause the variation of melanin, cell, causes the sun spot that is difficult to eliminate.The wavelength 100-280nm of short wave ultraviolet (UVC) had just been absorbed by ozone layer before arriving ground, and is therefore fewer to the influence of human body skin.The UVA section is called tanned section again, and it is that permanent accumulating over a long period forms to the injury of human body skin.The UVB section is called shines red section, and its penetration power can reach epidermal area, and the infringement that it causes skin is instant with serious, can make the skin sunburn, flush, cusalgia and bubble, and this is the main wave band that people need prevent.
The irradiation one side also useful of middle long wave ultraviolet to the effect of human body, as making the deoxidation cholesterol in the skin change vitamin D into, can strengthen calcium, the phosphorus absorption in vivo, help helping skeletal growth to be grown, the prevention rickets, can also treat rheumatoid arthritis, psoriasis, chorionitis, leucoderma, skin disease such as cellularity lymph pain under pityriasis rosea and the skin, to the danger of lupus erythematosus with ultraviolet therapy and remarkable mitigation symptoms and minimizing complication, ultraviolet ray also can make nucleic acid in the microbial cell, magma albumen generation chemical change, killing microorganisms is to air, water, pollute the object surfaces sterilization that carries out disinfection.
Because a large amount of uses in carbon fluorine series solvent and fluorine Lyons make earth's ozone layer suffer serious destruction, the ultraviolet ray that reaches ground constantly increases, as not noticing that the injury to health is very serious at present.According to the interrelated data introduction, the every minimizing 1% of ozone layer, then the intensity of ultraviolet radiation just increases 2%.Long-term solar radiation is caused the sailor that the human injury is maximum, the crewman, countryside work geology prospector, peasant and sportsman etc., the skin that they expose, face, neck, the chest trigonum, skins such as four limbs exposure place are dry significantly, coarse, furfur, pigmentation, atrophy, wrinkle, follow the string and gloss, easily by sun-induced canceration disease---the face that solar keratosis is impaired in early stage, ear, hand, symptom mostly is excipuliform papule single or that the minority grain of rice to broad bean grain differs in size and exceeds skin surface, there is dry cutin crust on the surface, be difficult for stripping off, strip off by force and the flush seepage surface promptly occurs, very easily hemorrhage, also have telangiectasis on every side, this disease have 20% may develop into cutaneum carcinoma.Certain some disease such as albino's whole skin, hair, eyes for want of melanin are protected and are tanned severely easily; make that sb.'s illness took a turn for the worse; also have chloasma faciei, be common in one of summer and southern daylight paathogenic factor, strong sunshine also can make the people easily suffer from cataractous one of the main reasons.
Summary of the invention:
Ultraviolet ray shines the last branch of fabric and is absorbed, a part is reflected, some sees through fabric skin is exerted an influence, ultraviolet in the ordinary course of things percent of pass+reflectivity+absorptivity=100%, therefore absorptivity and reflectivity increase, percent of pass just reduces, and its barrier propterty is just superior so.The Ultraviolet rays protection principle adopts ultraviolet light screener that fiber, yarn or fabric are handled exactly, effectively prevents the purpose of ultraviolet ray to the human injury thereby reach.The fabric ability and ultraviolet resistance mainly is the ability that depends on the shielding ultraviolet rays of fabric own, fabric has the surface of more complicated usually, they are except absorbing light, also has the effect of scattering and reflection ray, scattering and reflex are mainly considered the structural thickness and the tightness of the various factors such as the fabric of fabric itself, structure is tight, coverage coefficient is big, ultraviolet transmittance is low, protective action to human body is just big, otherwise then little, the thickness of fabric is thick more, the radiance of antiultraviolet is good more, the density of fabric etc.
Has the composition that the emission or the inorganic matter of fringence effect have kaolin, calcium carbonate, talcum powder, iron oxide, zinc oxide, titanium dioxide, medical stone to contain, silica, alchlor, ferric oxide etc., their security performance is good, can launch or the scattering wavelength, the ultraviolet ray that scope is wider, and the general particulate that does not have color and luster import it in fiber of fabric, because of its light reflex and scattered power are big, can make fiber have the effect of good shielding ultraviolet rays.Nano material is brand-new superfine solid material, and mean particle dia 100nm is with interior or 0.5-10um.Because the dimensional effect and the skin effect of nano material, its surperficial atomicity increases, surface energy improves, thereby has a very high chemism, and has a unexistent performance of many traditional materials, in the nano material that improves fabric ultraviolet radiation preventing performance, that at present the most frequently used is zinc oxide ZnO, titanium dioxide TiO
2Particle, nano-ZnO are inexpensive, nontoxic, the wide 240-400nm of the scope of shielding ultraviolet rays, and in wavelength 350-400nm scope, the shielding rate of ZnO is apparently higher than TiO
2, ZnO also has certain sterilization, deodorization except having good anti-ultraviolet function agent, zinc element deficiency in the added body, and the ability of enhancing immunity of organisms and resist the disease, it has absorption and distributes ultraviolet double properties.Titanium dioxide TiO
2Ultraviolet scattering is better than zinc oxide ZnO, and suspended dispersed is good in base-material, ZnO and TiO
2All have the ability of reflected infrared ray concurrently.The nanoscale ultraviolet light screener has UV resistant irradiation, heat-resisting, nontoxic, characteristics such as stability is strong, and its function is that ultraviolet screener is reflexed to beyond the fabric, and ultraviolet power conversion is not released in fabric, nano-TiO
2Has higher chemical stability." nano titanium oxide (the TiO that succeeds in developing by Shanghai Communications University
2) ultraviolet prevention fiber " and fabric have higher rate of ultraviolet shield.All have active gene by Beijing clean you ultra-violet absorber UV-120 and these two kinds of ultra-violet absorbers of SCJ-996 of the exploitation of refreshing High Seience Technology Co., Ltd., can react with hydroxyl on the cellulose and the amino on the polyamide fiber, has good fast light and washing fastness, long-time antiultraviolet irradiation, can not cause molecular breakdown yet, have good sublimation reliability and thermal fixation performance.JLSUN
Anti-ultraviolet finishing agent SCJ-966 and low temperature sticking agent SCJ-939, be applicable to the antiultraviolet arrangement of cotton and wash/fabrics such as cotton, common fabric after the processing has the effect of good absorption conversion, reflection and scattering to the ultraviolet ray of 180-400nm wave band (particularly UVA wavelength 320-400nm, UVB wavelength 280-320nm).
Add in the fibre-forming polymer polymerization process or under the molten condition and have ultraviolet screener performance composition, promptly select two kinds of elements of important element selenium, germanium, the medical stone nano powder of the cancer-resisting of a kind of suitable ultraviolet light screener and earth rareness.Because it contains the necessary multiple macro micro element of human body, and water purification effect with mystery, the moisture of the 60-70% that can make human body effectively and contained is purified, purifying, activation, make the cell of human body obtain effectively washing clearly, multiple the element that must want of stripping human body, poisonous and harmful heavy metallic material in the absorption human body, make the nano-powder of health, and the multiple material mixture that contains far infrared character material makes the antiultraviolet copolymer with the monomer copolymerization of fiber-forming polymer, be spun into ultraviolet prevention fiber then, also the method for the direct esterification of available routine or ester exchange aftercondensated makes the antiultraviolet polyester slice, melt spinning method by routine is spun into fiber again, perhaps ceramic made from mixed material and polymer chips are mixed and made into master batch and carry out spinning again, the protective clothing of the antiultraviolet of making injury.Owing to contain the multiple macro micro element of needed by human, constantly rub by skin and clothes, its trace element is penetrated in the human body by skin, pore, pore, capillary, reach continuous adjusting, additional, antagonist interior element balance, thereby reach the immunity that improves human body, strengthen the ability of resist the disease, effectively anti-cancer, anticancer, improve the health,, antifatigue, antiultraviolet, sun-resistant nano-element fabric body-building protective clothing.
The present invention is further described below in conjunction with examples of implementation:
Embodiment one: nano-element antiultraviolet shield hybrid thing %
1. honeybee series is mixed nano powder 20%
2. organic selenium or nanometer selenium 10%
3. organic germanium drying mycelium nano powder 8%
4. the medical stone nano powder 30%
⑤ZnO、TiO
2、FeO 32%
Embodiment two: contain UV-120 agent titanium dioxide ultraviolet prevention fiber %
1. nano-element antiultraviolet shield hybrid thing 10%
2. ultra-violet absorber UV-120 3%
3. nano titanium oxide (TiO
2) ultraviolet prevention fiber 20%
4. linen-cotton (hemp, peaceful fiber crops, flax), wool, brocade, nitrile, wash, in the polypropylene fibre viscose spinning solution 67%
Embodiment three: the fiber % that contains the SCJ-966 ultra-violet absorber
1. micro-antiultraviolet shield hybrid thing 10%
2. ultra-violet absorber SCJ-966 5%
3. in terylene, polyamide fibre and blending thereof, cotton, the wool fibre spinning solution 85%
Embodiment four: singly contain UV-120 ultraviolet prevention fiber %
1. micro-antiultraviolet shield hybrid thing 10%
2. JLSUN
Anti-ultraviolet finishing agent UV-120 2%
3. cotton, fiber crops, silk, wool, brocade, nitrile, wash, in the fiber spinning solution such as polypropylene fibre 88%
Embodiment five: contain SCJ-999,939 ultraviolet prevention fiber %
1. micro-antiultraviolet shield hybrid thing 10%
4. in the fiber spinning solutions such as cotton, fiber crops, wool, polyamide fibre, acrylic fibers, terylene, polypropylene fibre 86%
Claims (5)
1. antiultraviolet is prevented Exposure to Sunlight nano-element fabric body-building protective clothing, and it is characterized in that: nano-element antiultraviolet shield hybrid thing is by following proportioning %
1. honeybee series is mixed nano powder 15-25%
2. organic selenium or nanometer selenium 5-15%
3. the dry mycelium nano powder of organic germanium 3-13%
4. medical stone nano powder 25-35%
⑤ZnO、TiO
2、FeO 27-37%
2. according to claims 1, antiultraviolet is prevented Exposure to Sunlight nano-element fabric body-building protective clothing, it is characterized in that: contain UV-120 agent titanium dioxide ultraviolet prevention fiber %
1. nano-element antiultraviolet shield hybrid thing 5-15%
2. ultra-violet absorber UV-120 1-5%
3. nano titanium oxide (TiO
2) ultraviolet prevention fiber 15-25%
4. linen-cotton (hemp, peaceful fiber crops, flax), wool, brocade, nitrile, wash, 62-72% in the polypropylene fibre viscose spinning solution
3. according to claims 1,2, antiultraviolet is prevented Exposure to Sunlight nano-element fabric body-building protective clothing, it is characterized in that: the fiber % that contains the SCJ-966 ultra-violet absorber
1. micro-antiultraviolet shield hybrid thing 5-15%
2. ultra-violet absorber SCJ-966 1-10%
3. 80-90% in terylene, polyamide fibre and blending thereof, cotton, the wool fibre spinning solution
4. according to claims 1,2,3, antiultraviolet is prevented Exposure to Sunlight nano-element fabric body-building protective clothing, it is characterized in that: singly contain UV-120 ultraviolet prevention fiber %
1. micro-antiultraviolet shield hybrid thing 5-15%
3. linen-cotton, silk, wool, brocade, nitrile, wash, 83-93% in the fiber spinning solution such as polypropylene fibre
5. according to claims 1,2,3,4, antiultraviolet is prevented Exposure to Sunlight nano-element fabric body-building protective clothing, it is characterized in that: contain SCJ-999,939 ultraviolet prevention fiber %
1. micro-antiultraviolet shield hybrid thing 5-15%
4. 80-92% in the fiber spinning solutions such as cotton, fiber crops, wool, polyamide fibre, acrylic fibers, terylene, polypropylene fibre
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102754929A (en) * | 2012-06-21 | 2012-10-31 | 昆山市周市镇吉盛服装厂 | Novel ultraviolet detecting clothing |
CN103160944A (en) * | 2013-03-26 | 2013-06-19 | 成进学 | Summer protective clothing made of selenium-germanium-enriched chitin natural fiber fabric |
CN103230110A (en) * | 2013-04-19 | 2013-08-07 | 成进学 | Superactive inflame-retarding body building protection suit |
CN103255487A (en) * | 2013-04-19 | 2013-08-21 | 成进学 | Nano element natural fiber fitness protective clothing for teenagers |
CN103397397A (en) * | 2013-08-06 | 2013-11-20 | 陈欣荣 | Summer element fiber body-building protective suit for ship repairing and building personnel |
CN103668979A (en) * | 2013-12-03 | 2014-03-26 | 苏州爱马仕服饰有限公司 | Preparation process for anti-ultraviolet fabric |
CN103911728A (en) * | 2014-02-18 | 2014-07-09 | 江苏鸿顺合纤科技有限公司 | Polyamide fiber fabric with ultraviolet prevention function |
CN105821649A (en) * | 2016-04-16 | 2016-08-03 | 南通蛇类治疗研究所 | Sun-protection anticancer workout clothes |
CN105970345A (en) * | 2016-05-17 | 2016-09-28 | 南通蛇类治疗研究所 | Natural, green, ecological and environment-friendly functional fiber textile |
CN106637577A (en) * | 2016-12-04 | 2017-05-10 | 广西大学 | Anti-ultraviolet warm-keeping textile fabric and making method thereof |
CN107524010A (en) * | 2017-09-20 | 2017-12-29 | 安徽劲派纺织服饰有限公司 | Nylon fabric antiultraviolet inorganic agent is used in a kind of outdoor goods processing |
CN107752161A (en) * | 2017-11-23 | 2018-03-06 | 南通蛇类治疗研究所 | The anti-Exposure to Sunlight nano-element fabric outdoor sports coat of antiultraviolet |
CN108754655A (en) * | 2018-05-30 | 2018-11-06 | 景洪丽 | The preparation method of nanometer selenium regenerated celulose fibre |
CN110835788A (en) * | 2019-12-16 | 2020-02-25 | 新乡化纤股份有限公司 | Functional germanium viscose fiber and preparation method thereof |
CN114569475A (en) * | 2020-12-02 | 2022-06-03 | 常州慧硒涂层科技有限公司 | Improved ultraviolet-resistant material and preparation method thereof |
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- 2010-06-02 CN CN2010101896865A patent/CN101949067A/en active Pending
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102754929A (en) * | 2012-06-21 | 2012-10-31 | 昆山市周市镇吉盛服装厂 | Novel ultraviolet detecting clothing |
CN103160944A (en) * | 2013-03-26 | 2013-06-19 | 成进学 | Summer protective clothing made of selenium-germanium-enriched chitin natural fiber fabric |
CN103160944B (en) * | 2013-03-26 | 2015-11-18 | 成进学 | Rich selenium germanium chitosan natural fabric summer grade vest |
CN103255487B (en) * | 2013-04-19 | 2015-11-25 | 成进学 | Teenager's body-building protective clothing of nano-element natural fabric |
CN103230110A (en) * | 2013-04-19 | 2013-08-07 | 成进学 | Superactive inflame-retarding body building protection suit |
CN103255487A (en) * | 2013-04-19 | 2013-08-21 | 成进学 | Nano element natural fiber fitness protective clothing for teenagers |
CN103230110B (en) * | 2013-04-19 | 2015-03-25 | 成进学 | Superactive inflame-retarding body building protection suit |
CN103397397A (en) * | 2013-08-06 | 2013-11-20 | 陈欣荣 | Summer element fiber body-building protective suit for ship repairing and building personnel |
CN103397397B (en) * | 2013-08-06 | 2016-05-18 | 陈欣荣 | Build ship personnel summer grade element fabric safety clothes |
CN103668979A (en) * | 2013-12-03 | 2014-03-26 | 苏州爱马仕服饰有限公司 | Preparation process for anti-ultraviolet fabric |
CN103911728A (en) * | 2014-02-18 | 2014-07-09 | 江苏鸿顺合纤科技有限公司 | Polyamide fiber fabric with ultraviolet prevention function |
CN105821649A (en) * | 2016-04-16 | 2016-08-03 | 南通蛇类治疗研究所 | Sun-protection anticancer workout clothes |
CN105970345A (en) * | 2016-05-17 | 2016-09-28 | 南通蛇类治疗研究所 | Natural, green, ecological and environment-friendly functional fiber textile |
CN106637577A (en) * | 2016-12-04 | 2017-05-10 | 广西大学 | Anti-ultraviolet warm-keeping textile fabric and making method thereof |
CN107524010A (en) * | 2017-09-20 | 2017-12-29 | 安徽劲派纺织服饰有限公司 | Nylon fabric antiultraviolet inorganic agent is used in a kind of outdoor goods processing |
CN107752161A (en) * | 2017-11-23 | 2018-03-06 | 南通蛇类治疗研究所 | The anti-Exposure to Sunlight nano-element fabric outdoor sports coat of antiultraviolet |
CN108754655A (en) * | 2018-05-30 | 2018-11-06 | 景洪丽 | The preparation method of nanometer selenium regenerated celulose fibre |
CN110835788A (en) * | 2019-12-16 | 2020-02-25 | 新乡化纤股份有限公司 | Functional germanium viscose fiber and preparation method thereof |
CN114569475A (en) * | 2020-12-02 | 2022-06-03 | 常州慧硒涂层科技有限公司 | Improved ultraviolet-resistant material and preparation method thereof |
CN114569475B (en) * | 2020-12-02 | 2024-05-03 | 常州慧硒涂层科技有限公司 | Improved anti-ultraviolet material and preparation method thereof |
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Application publication date: 20110119 |