CN101905621B - Method for preparing coating transfer film for decoration - Google Patents
Method for preparing coating transfer film for decoration Download PDFInfo
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- CN101905621B CN101905621B CN 200910052387 CN200910052387A CN101905621B CN 101905621 B CN101905621 B CN 101905621B CN 200910052387 CN200910052387 CN 200910052387 CN 200910052387 A CN200910052387 A CN 200910052387A CN 101905621 B CN101905621 B CN 101905621B
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Abstract
The invention discloses a coating transfer film, in particular relates to a coating transfer film for decoration and a preparation method thereof. The coating transfer film consists of a support layer, a parting layer, a printing layer, a coating layer and a bonding layer from outside to inside in turn. In the coating transfer film, a coating which is suitable for machine coating is coated to nonpolar resin materials such as PET, BOPP, PP and the like directly, and by utilizing the difficult bonding performance of the nonpolar materials, a coating dry film is transferred to a wall surface directly by taking water or rubber latex as an adhesive, so the wall surface to which the coating film is transferred has the characteristics of cleanness, beauty, environmental protection, high abrasion and scrubbing resistance, elegant appearance, convenient construction, cost conservation and the like. In addition, personalized patterns such as embossing, stamping and the like can be manufactured according to the requirements of different customers, and various vector patterns can also be engraved by a die cutting machine or a carving machine, so that the originally single wall surface is bright-colored and beautiful, and indoor environment is more beautiful and colorful.
Description
Technical field
The present invention relates to a kind of coating transfer film, be specially a kind of preparation method of coating transfer film for decoration.
Background technology
As everyone knows, indoor and outdoor is decorated and is be unable to do without coating and wallpaper, and they not only can be beautified the environment, but also can play special-effects such as protection against the tide, noise reduction, fire prevention, are one of the most basic ornament materials of decoration industry.Traditional construction method is in metope with the coating direct brushing; This construction method is not only wasted coating, is taken time and effort, the metope effect is single; And in formulation for coating material in order to satisfy the requirement of this brushing technique; Must increase suitable auxiliary material (such as for levelling with the construction climatic environment and the various surfactants that add etc.), increased the cost of manufacture of raw material virtually, increased client's burden; Though defectives such as wallpaper has the attractive in appearance and diversified characteristics of decorative effect, and cost that it is high and environmental protection and weather resistance are relatively poor have also limited its use.
Summary of the invention
The objective of the invention is for a kind of coating transfer film for decoration is provided, complicated with the brushing paint construction technology that solves prior art, decorative effect is single and the wallpaper cost of manufacture high, the problem of environmental protection and weatherability difference.
The object of the invention can be realized through following technical scheme.
A kind of preparation method of coating transfer film,, be followed successively by from outside to inside: five layers of formation such as bearing bed, release layer, printed layers, dope layer and adhesive layer; Its concrete preparation process is following:
Releasing layer coating is applied on the thick bearing bed base material of 0.012～0.1mm, after the oven dry rolling, utilizes intaglio press that the picture and text mirror image is printed in coated face; After waiting to dry rolling, utilize coating machine that dope layer is applied on the printed layers again, coating thickness reaches 98% above shading rate with paint film and is as the criterion, and can be coated with multipass according to the difference of coating method; After treating to dry fully, adhesive layer coating is coated on the dope layer oven dry back rolling; Through cutting into finished product again behind the embossing machine compacting decorative pattern.
The inventive method is applicable to the transfer membrane of multiple effects such as making is colour printed, monochromatic, embossing, cross cutting.Need not to carry out the printed layers technological operation if manufacture monochromatic transfer membrane.Need not carry out the embossing technique operation if make smooth effect.
The preparation method of described release layer, concrete steps are: by proportioning pigment is progressively added under 300 rev/mins stirring in the entry, then mixing speed is risen to 1000 rev/mins, stirred 20-30 minute, treat that pigment disperses the back subsequent use fully; The said emulsion of prescription is progressively mixed under 200-300 rev/min stirring by the prescription order; Under 1000 rev/mins state, stirred 10-20 minute, treat that emulsion mixes fully after, with 300 order screen cloths filtration one time; Placed 4 hours, and treated the coating that promptly is available on the machine behind the complete froth breaking.Generally require every square metre of coating of weight in wet base 30-100 gram.
Described dope layer preparation method; Concrete steps are: by proportioning polyvinyl alcohol (adhesive) and water are inserted in the agitated reactor; Under the stirring that per minute 80-100 changes; Be heated to about 95 ℃, kept 30-40 minute, treat that polyvinyl alcohol dissolves back subsequent use (emulsion adhesive need not carry out this technological operation) fully; Opacifier is added water puts in the container, with 1500 rev/mins mixing speed disperse 30-40 minute subsequent use; Filler is added water puts in the container, with 1000 rev/mins mixing speed disperse 10-15 minute subsequent use; Cetyl trimethyl ammonia bromide (surfactant) is added water put in the container, under 300 rev/mins of stirrings, be heated to 100 ℃, treat that it dissolves back subsequent use (the emulsion-type surfactant need not carry out this technological operation) fully; Pigment is progressively added under 300 rev/mins stirring in the entry, then mixing speed is risen to 1000 rev/mins, stirred 20-30 minute, treat that pigment disperses the back subsequent use fully; Above dissolving or scattered liquid are progressively mixed under 200-300 rev/min state; Under 1000 rev/mins state, stirring the 30-40 branch plants; After treating that solution mixes fully; Filter twice with 300 order screen cloths, place after 8 hours, treat the coating that promptly is available on the machine behind the complete froth breaking of solution.Generally require every square metre of coating of weight in wet base 200-500 gram.
The preparation method of described adhesive layer, concrete steps are following: aqueous binder added water put in the agitated reactor by prescription, under the stirring that per minute 80-100 changes, be heated to 80 ℃-90 ℃, kept 30-40 minute, treat that adhesive dissolves fully or gelatinization after subsequent use; Progressively mix under 200-300 rev/min stirring by prescription order and share; Under 1000 rev/mins state, stirring the 10-20 branch plants; After treating that solution mixes fully, filter one time, place and treated the coating that promptly is available on the machine behind the complete froth breaking in 4 hours with 300 order screen cloths.Generally require every square metre of coating of weight in wet base 50-80 gram.
Described bearing bed is a kind of base material among PET, BOPP or the PP; Described release layer comprises following component and proportioning by weight: water-resistant adhesives 40-90 part, mould release 3-20 part, UV resistant agent 0.1-1.4 part, surfactant 0.1-3 part, pigment 0-4 part and deionized water 5-30 part; Described dope layer comprises following component and proportioning by weight: adhesive 5-35 part, opacifier and filler 6-30 part, anti-oxidant 0.2-2 part, mould inhibitor 0.2-1 part, surfactant 0.1-3 part, pigment 0-2 part, deionized water 60-120 part; Described adhesive layer comprises following component and proportioning by weight: aqueous binder 70-95 part, mould inhibitor 0-1 part, surfactant 0.1-1 part, deionized water 10-30 part.
Described water-resistant adhesives is one or more in acrylic acid emulsion, pure-acrylic emulsion, ethene-vinyl acetate copolymer emulsion, aqueous polyurethane emulsion and the aqueous epoxy resin emulsion.
Described mould release is one or more of water-based wax emulsion, acrylic emulsion and pure-acrylic emulsion kind.
Described UV resistant agent is a kind of among UV-531, He Te HTUV-150 and the vapour crust BT-202.
Described surfactant is one or more in CTAB, OP-10, paregal O and the organic silicon surfactant.
Described pigment is one or more of phthalocyanine blue, chrome yellow, chrome red and ultramarine.
Described adhesive is one or more in polyvinyl alcohol, acrylic emulsion, pure-acrylic emulsion, ethene-vinyl acetate copolymer emulsion and the aqueous polyurethane emulsion.
Described opacifier and filler are one or more in titanium white powder, calcium carbonate, talcum powder, silica and the alundum (Al.
Described mould inhibitor is 5-chloro-2-methyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone and 1,3-dihydroxymethyl-5, a kind of in the 5-dimethyl hydantoin.
Described anti-oxidant is one or more in antioxidant 1076, antioxidant 1010 and the antioxidant 264.
Described aqueous binder is one or more in polyvinyl alcohol, modified starch and the ethene-vinyl acetate copolymer emulsion.
The coating transfer film that technical scheme of the present invention prepares is that the coating that is suitable for the machine coating is directly coated on the non-polar resin materials such as PET, BOPP, PP; Utilize the difficult bond performance of non-polar material, as adhesive the coating dry film is directly transferred on the metope with water or latex.Metope after shifting has bright and clean beautiful, environmental protection, wear-resisting and characteristics such as scrub performance is strong, elegant in appearance, easy construction, saving cost.But also can be made into personalized patterns such as embossing, stamp according to different clients' demand, and also can cut out various vector pattern, thereby make original single metope tone become gorgeous colorful through cross cutting or carving machine, make indoor environment beautiful more various.
Description of drawings
Fig. 1 is the layer structure sketch map of transfer membrane of the present invention;
Among the figure: 1, adhesive layer 2, dope layer 3, printed layers 4, release layer 5, bearing bed.
The specific embodiment
Below in conjunction with specific embodiment, further set forth key points in design of the present invention.
Embodiment 1-3, the preparation of adhesive layer
(1), polyvinyl alcohol (10% solution) 70-95 part
5-chloro-2-methyl-4-isothiazoline-3-ketone 0.2-1 part
Ethene-vinyl acetate polymer emulsion 5-12 part
OP-10 1-2 part
Deionized water 10-20 part
(2), modified starch (5% solution) 70-90 part
2-methyl-4-isothiazoline-3-ketone 0.5-1 part
Ethene-vinyl acetate polymer emulsion 5-15 part
Paregal O 1-2 part
Deionized water 5-20 part
(3), polyvinyl alcohol (10% solution) 40-60 part
Modified starch (5% solution) 50-60 part
1,3-dihydroxymethyl-5,5-dimethyl hydantoin 0.8-1.5 part
Organic silicon surfactant 0.2-0.8 part
Deionized water 10-20 part
Compound method:
Polyvinyl alcohol 10kg is added water 90kg to agitated reactor, under the stirring that per minute 80-100 changes, be heated to about 95 ℃, kept 30-40 minute, treat that polyvinyl alcohol is subsequent use after dissolving fully;
Modified starch 5kg is added water 95kgz to agitated reactor, under the stirring that per minute 80-100 changes, be heated to 80 ℃, kept 30-40 minute, treat after the complete gelatinization of starch subsequent use;
The said emulsion of above-mentioned prescription is progressively mixed under 200-300 rev/min stirring by prescription order and share; Under 1000 rev/mins state, stirring the 10-20 branch plants; After treating that solution mixes fully; Filter one time with 300 order screen cloths, place and treated the coating that promptly is available on the machine behind the complete froth breaking in 4 hours.Generally require every square metre of coating of weight in wet base 50-80 gram.
Titanium white powder 8-14 part
Precipitated calcium carbonate 10-16 part
Talcum powder 5-7 part
Acrylic acid emulsion 16-25 part
Polyvinyl alcohol (10% solution) 40-60 part
UV-531 UV resistant agent 0.5-0.8 part
CTAB 0.4-0.6 part
1,3-dihydroxymethyl-5,5-dimethyl hydantoin 0.4-0.8 part
Antioxidant 1076 0.6-1.2 part
Pigment 0-2 part
Deionized water 60-80 part
Compound method:
Polyvinyl alcohol 10kg is added water 90kg to agitated reactor, under the stirring that per minute 80-100 changes, heat about 95 ℃, kept 30-40 minute, treat that polyvinyl alcohol is subsequent use after dissolving fully;
Titanium white powder is added water 30-35kg to container, with 1500 rev/mins mixing speed disperse 30-40 minute subsequent use;
Precipitated calcium carbonate, talcum powder are added water 45-60kg to container, with 1000 rev/mins mixing speed disperse 10-15 minute subsequent use;
CTAB adds water 5-10kg to container, under 300 rev/mins of stirrings, is heated to 100 ℃, treats that it is subsequent use after dissolving fully;
0-2 part pigment is progressively added under 300 rev/mins stirring in the entry, then mixing speed is risen to 1000 rev/mins, stirred 20-30 minute, treat that pigment disperses the back subsequent use fully;
Above dissolving or scattered liquid are progressively mixed under 200-300 rev/min state by the said share of prescription by other emulsion described in share described in the prescription and the above-mentioned prescription; Under 1000 rev/mins state, stirring the 30-40 branch plants; After treating that solution mixes fully; Filter twice with 300 order screen cloths, place after 8 hours, treat the coating that promptly is available on the machine behind the complete froth breaking of solution.Generally require every square metre of coating of weight in wet base 200-400 gram.
Titanium white powder 8-15 part
Alundum (Al 10-25 part
Aqueous polyurethane emulsion 10-25 part
Polyvinyl alcohol (10% solution) 40-60 part
Ethene-vinyl acetate copolymer emulsion 10-15 part
Vapour crust BT-202 UV resistant agent 0.4-0.6 part
CTAB 0.6-1.2 part
5-chloro-2-methyl-4-isothiazoline-3-ketone 0.2-0.5 part
Antioxidant 1010 0.2-0.8 part
Pigment 0-2 part
Deionized water 95-120 part
Compound method:
Polyvinyl alcohol 10kg is added water 90kg to agitated reactor, under the stirring that per minute 80-100 changes, be heated to about 95 ℃, kept 30-40 minute, treat that polyvinyl alcohol is subsequent use after dissolving fully;
Titanium white powder is added water 30-40kg to container, with 1500 rev/mins mixing speed disperse 30-40 minute subsequent use;
Precipitated calcium carbonate is added water 50-60kg to container, with 1000 rev/mins mixing speed disperse 10-15 minute subsequent use;
CTAB adds water 5-15kg to container, under 300 rev/mins of stirrings, is heated to 100 ℃, treats that it is subsequent use after dissolving fully;
0-2 part pigment is progressively added under 300 rev/mins stirring in the entry, then mixing speed is risen to 1000 rev/mins, stirred 20-30 minute, treat that pigment disperses the back subsequent use fully;
Above dissolving or scattered liquid are progressively mixed under 200-300 rev/min state by the said share of prescription by other emulsion described in share described in the prescription and the above-mentioned prescription; Under 1000 rev/mins state, stirring the 30-40 branch plants; After treating that solution mixes fully; Filter twice with 300 order screen cloths, place after 8 hours, treat the coating that promptly is available on the machine behind the complete froth breaking of solution.Generally require every square metre of coating of weight in wet base 300-500 gram.
Embodiment 6, the preparation of dope layer:
Titanium white powder 10-15 part
Pure-acrylic emulsion 20-30 part
Polyvinyl alcohol (10% solution) 40-60 part
He Te HTUV-150 UV resistant agent 0.3-0.8 part
Op-10 1-2 part
Organic silicon surfactant 0.2-0.6 part
2-methyl-4-isothiazoline-3-ketone 0.6-1 part
Antioxidant 264 0.6-1 part
Pigment 0-2 part
Deionized water 60-120 part
Compound method:
Polyvinyl alcohol 10kg is added water 90kg to agitated reactor, under the stirring that per minute 80-100 changes, be heated to about 95 ℃, kept 30-40 minute, treat that polyvinyl alcohol is subsequent use after dissolving fully;
Titanium white powder is added water 40-50kg to container, with 1500 rev/mins mixing speed disperse 30-40 minute subsequent use;
Silica is added water 50-80kg to container, with 1000 rev/mins mixing speed disperse 10-15 minute subsequent use;
0-2 part pigment is progressively added under 300 rev/mins stirring in the entry, then mixing speed is risen to 1000 rev/mins, stirred 20-30 minute, treat that pigment disperses the back subsequent use fully;
Above dissolving or scattered liquid are progressively mixed under 200-300 rev/min state by the said share of prescription by other emulsion described in share described in the prescription and the above-mentioned prescription; Under 1000 rev/mins state, stirring the 30-40 branch plants; After treating that solution mixes fully; Filter twice with 300 order screen cloths, place after 8 hours, treat the coating that promptly is available on the machine behind the complete froth breaking of solution.Generally require every square metre of coating of weight in wet base 300-400 gram.
Embodiment 7-9, the preparation of release layer.
(7) water-based acrylic acid emulsion 80-90 part
Water-based wax emulsion 3-6 part
Ethene-vinyl acetate copolymer emulsion 5-9 part
UV-531 UV resistant agent 0.3-0.6 part
OP-10 0.5-2 part
Pigment 0-2 part (requiring to add) according to color
Deionized water 5-10 part
(8) aqueous epoxy emulsion 75-95 part
Water-based wax emulsion 5-8 part
Aqueous polyurethane emulsion 10-20 part
Vapour BT-202 UV resistant agent 0.2-0.4
Organic silicon surfactant 0.2-0.3 part
Pigment 0-2 part (requiring to add) according to color
Deionized water 10-15 part
(9) pure-acrylic emulsion 80-90 part
Water-based wax emulsion 5-10 part
Ethene-vinyl acetate polymer emulsion 3-12 part
He Te HTUV-150 UV resistant agent 0.3-0.6 part
Paregal O 0.8-1.2 part
Pigment 0-2 part (requiring to add) according to color
Deionized water 5-15 part
Compound method:
0-2 part pigment is progressively added under 300 rev/mins stirring, then mixing speed is risen to 1000 rev/mins, stirred 20-30 minute, treat that pigment disperses the back subsequent use fully;
The said emulsion of above-mentioned prescription is progressively mixed under 200-300 rev/min stirring by the prescription order; Under 1000 rev/mins state, stirring the 10-20 branch plants; After treating that emulsion mixes fully; Filter one time with 300 order screen cloths, place and treated the coating that promptly is available on the machine behind the complete froth breaking in 4 hours.Generally require every square metre of coating of weight in wet base 30-100 gram.
Coating transfer film mainly is made up of for five layers bearing bed, release layer, printed layers, dope layer and tack coat etc.Be applicable to the transfer membrane of multiple effects such as making is colour printed, monochromatic, embossing, cross cutting.
At first releasing layer coating is applied on the thick PET of 0.012～0.1mm, BOPP, PP a kind of base material wherein; After the oven dry rolling; Utilize intaglio press that the picture and text mirror image is printed in coated face, after waiting to dry rolling, utilize coating machine that dope layer is applied on the printed layers again; Coating thickness reaches 98% above shading rate with paint film and is as the criterion, and can be coated with multipass according to the difference of coating method.After treating to dry fully, adhesive layer coating is coated on the dope layer, oven dry back rolling is if cut after needing the embossing effect also should pass through embossing machine compacting decorative pattern again.Need not to carry out the printed layers technological operation if manufacture monochromatic transfer membrane, need not carry out the embossing technique operation if make smooth effect.
During use, coating transfer film directly was soaked in the water 1～2 minute, directly is affixed on the metope that has coated putty after the taking-up, directly peel off surface protection film after 4 hours and get final product.
Coating transfer film is artistic diversity and the low cost of coating and a product of feature of environmental protection perfect adaptation with wallpaper.Its cost has only about 1/4th of wallpaper, can print and suppress floral designs, and the various vector pattern of computer lettering machine engraving system also capable of using make the office and the living environment of client's arbitrary decoration oneself in low-cost and environmental protection environment; In work progress, rejected the pollution of brushing technique, also greatly reduced the waste of coating simultaneously, made the thorough suitability for industrialized production of wall covering brushing technique, improved operating efficiency greatly, reduced construction cost construction environment; And because the use on a large scale of this transfer membrane, can make the corresponding reduction of synthesis technique index (will no longer receive the restriction of construction environment temperature, make its index range wideer) of coating common resins such as phenylpropyl alcohol, pure third gradegrade C stoste like film-forming temperature index in the stoste.
Claims (13)
1. the preparation method of a coating transfer film for decoration is characterized in that: be followed successively by from outside to inside: bearing bed, release layer, printed layers, dope layer and five layers of formation of adhesive layer; Its concrete preparation process is following:
Utilize coating machine to coat on the thick bearing bed base material of 0.012～0.1 ㎜ releasing layer coating, after the oven dry rolling, utilize intaglio press that the picture and text mirror image is printed in coated face; After waiting to dry rolling, utilize coating machine that dope layer is applied on the printed layers again, coating thickness reaches 98% above shading rate with paint film and is as the criterion, according to the difference coating multipass of coating method; After treating to dry fully, utilize coating machine to coat on the dope layer adhesive layer coating, oven dry back rolling; Through cutting into finished product again behind the embossing machine compacting decorative pattern;
During use, coating transfer film directly was soaked in the water 1～2 minute, directly is affixed on the metope that has coated putty after the taking-up, directly peel off bearing bed after 4 hours and get final product.
2. the preparation method of a kind of coating transfer film for decoration according to claim 1 is characterized in that:
The preparation method of described release layer, concrete steps are: by proportioning pigment is progressively added under 300 rev/mins stirring in the entry, then mixing speed is risen to 1000 rev/mins, stirred 20-30 minute, treat that pigment disperses the back subsequent use fully; Emulsion is progressively mixed under 200-300 rev/min stirring by the prescription order; Under 1000 rev/mins state, stirred 10-20 minute; After treating that emulsion mixes fully, filter one time, place and treated the coating that promptly is available on the machine behind the complete froth breaking in 4 hours with 300 order screen cloths; Require every square metre of coating of weight in wet base 30-100 gram;
Described dope layer preparation method, concrete steps are: by proportioning polyvinyl alcohol is added water and insert in the agitated reactor, under the stirring that per minute 80-100 changes, be heated to about 95 ℃, kept 30-40 minute, treat that polyvinyl alcohol is subsequent use after dissolving fully; Opacifier is added water puts in the container, with 1500 rev/mins mixing speed disperse 30-40 minute subsequent use; Filler is added water puts in the container, with 1000 rev/mins mixing speed disperse 10-15 minute subsequent use; CTAB adds water to be put in the container, under 300 rev/mins of stirrings, is heated to 100 ℃, treats that it is subsequent use after dissolving fully; Pigment is progressively added under 300 rev/mins stirring in the entry, then mixing speed is risen to 1000 rev/mins, stirred 20-30 minute, treat that pigment disperses the back subsequent use fully; Above dissolving or scattered liquid are progressively mixed under 200-300 rev/min state; Under 1000 rev/mins state, stirring the 30-40 branch plants; After treating that solution mixes fully; Filter twice with 300 order screen cloths, place after 8 hours, treat the coating that promptly is available on the machine behind the complete froth breaking of solution; Require every square metre of coating of weight in wet base 200-500 gram;
The preparation method of described adhesive layer, concrete steps are following: aqueous binder added water put in the agitated reactor by prescription, under the stirring that per minute 80-100 changes, be heated to 80 ℃-90 ℃, kept 30-40 minute, treat that adhesive dissolves fully or gelatinization after subsequent use; Progressively mix under 200-300 rev/min stirring by prescription order and share; Under 1000 rev/mins state, stirring the 10-20 branch plants; After treating that solution mixes fully, filter one time, place and treated the coating that promptly is available on the machine behind the complete froth breaking in 4 hours with 300 order screen cloths; Require every square metre of coating of weight in wet base 50-80 gram.
3. the preparation method of a kind of coating transfer film for decoration according to claim 1 is characterized in that:
Described bearing bed is a kind of base material among PET, BOPP or the PP; Described release layer comprises following component and proportioning by weight: water-resistant adhesives 40-90 part, mould release 3-20 part, UV resistant agent 0.1-1.4 part, surfactant 0.1-3 part, pigment 0-4 part and deionized water 5-30 part; Described dope layer comprises following component and proportioning by weight: adhesive 5-35 part, opacifier and filler 6-30 part, anti-oxidant 0.2-2 part, mould inhibitor 0.2-1 part, surfactant 0.1-3 part, pigment 0-2 part, deionized water 60-120 part; Described adhesive layer comprises following component and proportioning by weight: aqueous binder 70-95 part, mould inhibitor 0-1 part, surfactant 0.1-1 part, deionized water 10-30 part.
4. the preparation method of a kind of coating transfer film for decoration according to claim 3, it is characterized in that: water-resistant adhesives is one or more in acrylic emulsion, pure-acrylic emulsion, ethene-vinyl acetate copolymer emulsion, aqueous polyurethane emulsion and the aqueous epoxy resin emulsion.
5. the preparation method of a kind of coating transfer film for decoration according to claim 3, it is characterized in that: described mould release is one or more in water-based wax emulsion, acrylic emulsion and the pure-acrylic emulsion.
6. the preparation method of a kind of coating transfer film for decoration according to claim 3 is characterized in that: described UV resistant agent is a kind of among UV-531, He Te HTUV-150 and the vapour crust BT-202.
7. the preparation method of a kind of coating transfer film for decoration according to claim 3, it is characterized in that: described surfactant is one or more in CTAB, OP-10, paregal O and the organic silicon surfactant.
8. the preparation method of a kind of coating transfer film for decoration according to claim 3, it is characterized in that: described pigment is one or more of phthalocyanine blue, chrome yellow, chrome red and ultramarine.
9. the preparation method of a kind of coating transfer film for decoration according to claim 3, it is characterized in that: described adhesive is one or more in polyvinyl alcohol, acrylic emulsion, pure-acrylic emulsion, ethene-vinyl acetate copolymer emulsion and the aqueous polyurethane emulsion.
10. the preparation method of a kind of coating transfer film for decoration according to claim 3, it is characterized in that: described opacifier and filler are one or more in titanium white powder, calcium carbonate, talcum powder, silica and the alundum (Al.
11. the preparation method of a kind of coating transfer film for decoration according to claim 3; It is characterized in that: described mould inhibitor is 5-chloro-2-methyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone and 1; 3-dihydroxymethyl-5, a kind of in the 5-dimethyl hydantoin.
12. the preparation method of a kind of coating transfer film for decoration according to claim 3 is characterized in that: described anti-oxidant is one or more in antioxidant 1076, antioxidant 1010 and the antioxidant 264.
13. the preparation method of a kind of coating transfer film for decoration according to claim 3 is characterized in that: described aqueous binder is one or more in polyvinyl alcohol, modified starch and the ethene-vinyl acetate copolymer emulsion.
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| CN101235672A (en) * | 2008-03-06 | 2008-08-06 | 谭昊涯 | Ultraviolet light curing overlay film decorative board for wall and method for making same |
| CN101423001A (en) * | 2007-10-31 | 2009-05-06 | 焦作市卓立烫印材料有限公司 | Glass thermal transfer foil and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101423001A (en) * | 2007-10-31 | 2009-05-06 | 焦作市卓立烫印材料有限公司 | Glass thermal transfer foil and preparation method thereof |
| CN101235672A (en) * | 2008-03-06 | 2008-08-06 | 谭昊涯 | Ultraviolet light curing overlay film decorative board for wall and method for making same |
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