CN101831136A - High-strength high-toughness flame-resistant ABS (Acrylonitrile Butadiene Styrene) composite material and preparation method thereof - Google Patents
High-strength high-toughness flame-resistant ABS (Acrylonitrile Butadiene Styrene) composite material and preparation method thereof Download PDFInfo
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- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title claims abstract description 69
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000002131 composite material Substances 0.000 title abstract description 5
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 title abstract 6
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 title abstract 6
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 claims abstract description 34
- 239000003063 flame retardant Substances 0.000 claims abstract description 33
- 239000000314 lubricant Substances 0.000 claims abstract description 24
- 239000011159 matrix material Substances 0.000 claims abstract description 22
- 229920003023 plastic Polymers 0.000 claims abstract description 18
- 239000004033 plastic Substances 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- 239000003381 stabilizer Substances 0.000 claims description 22
- 238000005469 granulation Methods 0.000 claims description 10
- 230000003179 granulation Effects 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 10
- 238000005303 weighing Methods 0.000 claims description 9
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 8
- CMQUQOHNANGDOR-UHFFFAOYSA-N 2,3-dibromo-4-(2,4-dibromo-5-hydroxyphenyl)phenol Chemical group BrC1=C(Br)C(O)=CC=C1C1=CC(O)=C(Br)C=C1Br CMQUQOHNANGDOR-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 4
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 238000012662 bulk polymerization Methods 0.000 claims description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 5
- 239000011347 resin Substances 0.000 abstract description 3
- 229920005989 resin Polymers 0.000 abstract description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- 230000002349 favourable effect Effects 0.000 abstract 2
- 239000012745 toughening agent Substances 0.000 abstract 2
- -1 PolyEthylene Terephthalate Polymers 0.000 abstract 1
- 239000012760 heat stabilizer Substances 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract 1
- 239000005020 polyethylene terephthalate Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 6
- 230000035939 shock Effects 0.000 description 5
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 229920001887 crystalline plastic Polymers 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
Abstract
The invention discloses a high-strength high-toughness flame-resistant ABS (Acrylonitrile Butadiene Styrene) composite material and a preparation method thereof. The high-strength high-toughness flame-resistant ABS composite material is prepared from the following components in percentage by weight: 45-75 percent of ABS resin, 5-25 percent of PETG (PolyEthylene Terephthalate Glycol) plastics, 15-24 percent of flame retardant, 3-6 percent of toughener, 0.3-1 percent of heat stabilizer and 0.5-1.0 percent of lubricant. In the invention, the ABS resin is used as matrix resin, second plastic PETG is introduced to provide favorable tensile strength and the PETG plastics, the ABS resin and the toughener provide favorable impact strength. The preparation production process is simple and controllable and the production is easy to operate. The high-strength high-toughness flame-resistant ABS composite material can be widely applied to the fields of electronic electrical appliances, household electrical appliances, automobile parts, and the like.
Description
[technical field]
The present invention relates to technical field of polymer materials, relate in particular to a kind of high-strength high-toughness flame-resistant ABS matrix material and preparation method thereof.
[background technology]
Generally speaking, the tensile strength of flame-proof ABS and shock strength are difficult to reach balance, because fire retardant makes product properties become fragile easily, shock strength was low when the flame-proof ABS tensile strength was high, poor tensile strength when shock strength is high.General flame-proof ABS, as the 765A of Qi Mei company, the 312A tensile strength of LG Corp of South Korea has only 42MPa, and shock strength is 220J/M, and the above index of home-made flame-proof ABS all is difficult to reach.
[summary of the invention]
The performance that the technical problem to be solved in the present invention provides a kind of tensile strength and impelling strength is isostatic high-strength high-toughness flame-resistant ABS matrix material comparatively.
The technical problem to be solved in the present invention provides a kind of preparation method of high-strength high-toughness flame-resistant ABS matrix material.
In order to solve the problems of the technologies described above, the technical solution used in the present invention is, a kind of high-strength high-toughness flame-resistant ABS matrix material is made up of following component by weight percentage:
ABS resin 45～75%
PETG plastics 5～25%
Fire retardant 15～24%
Toughner 3～6%
Thermo-stabilizer 0.3～1%
Lubricant 0.5～1.0%.
Wherein, ABS resin is the ABS resin of emulsion polymerization or mass polymerization or body-suspension method manufacturing.In the described PETG plastics, the 1,4 cyclohexane dimethanol monomer content is at 30-40%.Described fire retardant is tetrabromo-bisphenol, antimonous oxide, chlorinatedpolyethylene compound, and three's ratio is 3.5～5: 1.2～1.5: 1.Described toughner is the ABS high glue powder.Described thermo-stabilizer is oxidation inhibitor N, N '-two-(3-(3, the 5-di-tert-butyl-hydroxy phenyl) propionyl) hexanediamine.Described lubricant is the vinyl bis-stearamides.
Above-described high-strength high-toughness flame-resistant ABS matrix material, can form by following component by weight percentage:
ABS resin 60～65%
PETG plastics 9～13%
Fire retardant 20～23%
Toughner 3～5%
Thermo-stabilizer 0.3～0.5%
Lubricant 0.5～1.0%.
A kind of preparation method's of above-mentioned high-strength high-toughness flame-resistant ABS matrix material technical scheme is may further comprise the steps:
(1) takes by weighing ABS resin, PETG plastics, toughner, thermo-stabilizer, lubricant, fire retardant by above-mentioned weight percent;
(2) ABS resin, PETG plastics, toughner, thermo-stabilizer, lubricant, fire retardant were mixed in moderate-speed mixers 3-7 minute;
(3) the mixed raw material of step (2) is melt extruded granulation through twin screw extruder; The twin screw extruder processing condition are: twin screw extruder one district's temperature is 160～220 ℃, two district's temperature are 160～220 ℃, and three district's temperature are 160～220 ℃, and four district's temperature are 160～220 ℃, 160～220 ℃ in five districts, compound time of delivery in screw rod is 1～2 minute.
The present invention is matrix resin with the ABS resin, introduces second kind of plastics PETG, and the solubility parameter of PETG and the solubility parameter of ABS are very approaching, thereby the consistency of two kinds of resins is very good, can add compatilizer and just can reach well compatible.In this formula system, PETG provides good tensile strength (general PETG tensile strength can reach 53MPa, and the tensile strength of ABS resin is 42MPa), and the shock strength that PETG plastics, ABS resin, toughner provide.Because of PETG is a kind of high transparent plastics, the PETG plastics also provide high glossiness in formula system.The present invention adopts auxiliary agents such as toughner, thermo-stabilizer, lubricant, fire retardant that ABS is carried out the modification processing and makes ABS matrix material acquisition high toughness; Wherein adding toughner can make matrix material not ftracture when playing screw; It is non-yellowing that thermo-stabilizer can suppress goods; Lubricant makes product surface bright and clean; Fire retardant makes goods that flame retardant properties be arranged.Above-mentioned auxiliary agent is the commercial goods, need not special preparation or processing, has reduced production cost, makes the product that makes have competitive edge.The present invention prepares the production technique simple controllable, produces easy to operate.High-strength high-toughness flame-resistant ABS matrix material of the present invention can be widely used in fields such as field of electronics, field of household appliances, auto parts machinery.
[embodiment]
Below in conjunction with embodiment the present invention is done detailed explanation:
ABS is commercially available common ABS, need not select high gloss ABS, is because high gloss ABS market price is very high, common ABS cost performance height.Preferential 750 of inexpensive Shanghai Gaoqiao petrochemical industry ABS or the Lanzhou petrochemical industry of selecting; The PETG plastics are the graceful product of her generation Z6002; 1,4 cyclohexane dimethanol (CHDM) monomer content is 32%; Toughner is the ABS high glue powder, and other toughner effects are relatively poor, and needs the deal of interpolation bigger, to heat-resisting influential, selects for use Korea S's brocade lake chemistry to produce HR181 among the embodiment; Thermo-stabilizer is the antioxidant 1010 (N, N '-two-(3-(3, the 5-di-tert-butyl-hydroxy phenyl) propionyl) hexanediamine) of Ciba.The thermostable effect of this thermo-stabilizer in the ABS goods is fine; Lubricant is home-made fatty acid amide (EBS); Fire retardant is the compound of tetrabromo-bisphenol, chlorinatedpolyethylene, antimonous oxide, the weight proportion of three kinds of materials is 13.5: 4.5: 3.3, tetrabromo-bisphenol is the safe star production in Jinan, and chlorinatedpolyethylene is Weifang AsiaSat production, and antimonous oxide is that the Dongguan Jeff produces.Main flame retardant also can be selected other brominated flame-retardants such as bromination epoxy, brominated Polystyrene, TDE etc.Above-mentioned brominated flame-retardant price comparison costliness, it is low to be added among the ABS/PETG cost performance.Add tetrabromo-bisphenol flame retarding efficiency height in the ABS/PETG alloy through learning after a large amount of experiments, the fire retardant total amount can reach flame retardant resistance and mechanical and physical performance preferably more after a little while.In the specific embodiment consumption of fire retardant is fixed on 21.3% below, and the consumption of toughner, lubricant, PETG is set forth as variable.
Embodiment 1, take by weighing raw material: ABS 750 65.9% by weight percentage, PETG 5%, thermo-stabilizer (1010) 0.3%, toughner (HR181) 3%, lubricant (EBS) 0.5%, fire retardant 21.3%, middling speed stirrer for mixing 5 minutes, be that 160--220 ℃ of twin screw extruder extruded granulation through melt temperature.Wherein each zone temperatures is: 160 ℃ in a district, and 180 ℃ in two districts, 200 ℃ in three districts, 210 ℃ in four districts, 220 ℃ in five districts, the residence time was 90 seconds.
Embodiment 2, take by weighing raw material: ABS 750 68.2% by weight percentage, PETG 7%, thermo-stabilizer (1010) 0.3%, toughner (HR181) 3%, lubricant (EBS) 0.6%, fire retardant 21.3%, middling speed stirrer for mixing 5 minutes, be that 160--220 ℃ of twin screw extruder extruded granulation through melt temperature.Wherein each zone temperatures is: 160 ℃ in a district, and 180 ℃ in two districts, 200 ℃ in three districts, 210 ℃ in four districts, 220 ℃ in five districts, the residence time was 90 seconds.
Embodiment 3, take by weighing raw material: ABS 75064.7% by weight percentage, PETG 9%, thermo-stabilizer (1010) 0.3%, toughner (HR181) 4%, lubricant (EBS) 0.7%, fire retardant 21.3%, middling speed stirrer for mixing 5 minutes, be that 160--220 ℃ of twin screw extruder extruded granulation through melt temperature.Wherein each zone temperatures is: 160 ℃ in a district, and 180 ℃ in two districts, 200 ℃ in three districts, 210 ℃ in four districts, 220 ℃ in five districts, the residence time was 90 seconds.
Embodiment 4, take by weighing raw material: ABS 750 62.6% by weight percentage, PETG 11%, thermo-stabilizer (1010) 0.3%, toughner (HR181) 4%, lubricant (EBS) 0.8%, fire retardant 21.3%, middling speed stirrer for mixing 5 minutes, be that 160--220 ℃ of twin screw extruder extruded granulation through melt temperature.Wherein each zone temperatures is: 160 ℃ in a district, and 180 ℃ in two districts, 200 ℃ in three districts, 210 ℃ in four districts, 220 ℃ in five districts, the residence time was 90 seconds.
Embodiment 5, take by weighing raw material: ABS 750 60.5% by weight percentage, PETG 13%, thermo-stabilizer (1010) 0.3%, toughner (HR181) 4%, lubricant (EBS) 0.9%, fire retardant 21.3%, middling speed stirrer for mixing 5 minutes, be that 160--220 ℃ of twin screw extruder extruded granulation through melt temperature.Wherein each zone temperatures is: 160 ℃ in a district, and 180 ℃ in two districts, 200 ℃ in three districts, 210 ℃ in four districts, 220 ℃ in five districts, the residence time was 90 seconds.
Embodiment 6, take by weighing raw material: ABS 750 57.4% by weight percentage, PETG 15%, thermo-stabilizer (1010) 0.3%, toughner (HR181) 5%, lubricant (EBS) 1.0%, fire retardant 21.3%, middling speed stirrer for mixing 5 minutes, be that 160--220 ℃ of twin screw extruder extruded granulation through melt temperature.Wherein each zone temperatures is: 160 ℃ in a district, and 180 ℃ in two districts, 200 ℃ in three districts, 210 ℃ in four districts, 220 ℃ in five districts, the residence time was 90 seconds.
Embodiment 7, take by weighing raw material: ABS 750 51.4% by weight percentage, PETG 20%, thermo-stabilizer (1010) 0.3%, toughner (HR181) 6%, lubricant (EBS) 1.0%, fire retardant 21.3%, middling speed stirrer for mixing 5 minutes, be that 160--220 ℃ of twin screw extruder extruded granulation through melt temperature.Wherein each zone temperatures is: 160 ℃ in a district, and 180 ℃ in two districts, 200 ℃ in three districts, 210 ℃ in four districts, 220 ℃ in five districts, the residence time was 90 seconds.
Performance evaluation mode and implementation standard
The particle that above-mentioned 7 embodiment are finished granulation dry 4-～6 hour in 80--90 ℃ convection oven again with the injection moulding sample preparation on the 80T injection moulding machine of exsiccant particle, keep the mould temperature between 70--～100 ℃ in the sample making course.
Tensile strength is tested by GB/T 1040 standards., specimen types is the I type, batten size (mm): 170 (length) * (20 ± 0.2) (end width) * (4 ± 0.2) (thickness), and draw speed is 50mm/min; Flexural strength and modulus in flexure are tested by GB 9341/T standard.Specimen types is specimen size (mm): (80 ± 2) * (10 ± 0.2) * (4 ± 0.2), rate of bending are 20mm/mi n; Notched Izod impact strength is tested by GB/T 1043 standards.Specimen types is the I type, specimen size (mm): (80 ± 2) * (10 ± 0.2) * (4 ± 0.2); The breach type is a category-A, and the breach residual thickness is 3.2mm; Heat-drawn wire is tested by GB/T 1634.2 standards, and load is 100mm for the 1.80MPa. span.
The composite property table that embodiment 1-9 raw material weight percentage is when made
| Form (%) | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 |
| ??ABS | ??69.9 | ??68.2 | ??64.7 | ??62.6 | ??60.5 | ??57.4 | ??51.4 |
| ??PETG | ??5 | ??7 | ??9 | ??11 | ??13 | ??15 | ??20 |
| Thermo-stabilizer | ??0.3 | ??0.3 | ??0.3 | ??0.3 | ??0.3 | ??0.3 | ??0.3 |
| Lubricant | ??0.5 | ??0.6 | ??0.7 | ??0.8 | ??0.9 | ??1.0 | ??1.0 |
| Toughner | ??3 | ??3 | ??4 | ??4 | ??4 | ??5 | ??6 |
| Fire retardant | ??21.3 | ??21.3 | ??21.3 | ??21.3 | ??21.3 | ??21.3 | ??21.3 |
| Heat-drawn wire | ??80 | ??78 | ??76 | ??74 | ??73 | ??72 | ??70 |
| Notched Izod impact strength | ??230 | ??225 | ??235 | ??230 | ??230 | ??235 | ??240 |
| Tensile strength | ??42 | ??42.5 | ??42.8 | ??44 | ??44.5 | ??45.6 | ??46 |
| Modulus in flexure | ??2100 | ??2150 | ??2210 | ??2280 | ??2300 | ??2320 | ??2400 |
| Surface gloss | Difference | Difference | Better | Good | Good | Good | Good |
By last table, we can see, high-strength high-toughness flame-resistant ABS matrix material tensile strength among the embodiment 1 to 7 or notched Izod impact strength can be widely used in fields such as field of electronics, field of household appliances, auto parts machinery all apparently higher than the 312A of 765A of Qi Mei company and LG Corp of South Korea.
The use of fire retardant in the present invention can be done quantitative use.Too many fire retardant makes product properties become fragile easily, and is difficult to disperse in goods, adds lubricant fire retardant is dispersed in the goods, can suppress fire retardant and precipitate into product surface.Along with the increase surface gloss raising of PETG, heat-drawn wire descends, and is because PETG is a crystalline plastics, and under the situation of not adding nucleator and glass, heat-drawn wire is about 60 degree.
Data above comprehensive, embodiment 4 performances are best. be most preferred embodiment of the present invention.
Claims (9)
1. a high-strength high-toughness flame-resistant ABS matrix material is characterized in that, is made up of following component by weight percentage:
ABS resin 45～75%
PETG plastics 5～25%
Fire retardant 15～24%
Toughner 3～6%
Thermo-stabilizer 0.3～1%
Lubricant 0.5～1.0%.
2. high-strength high-toughness flame-resistant ABS matrix material according to claim 1 is characterized in that, ABS resin is the ABS resin of emulsion polymerization or mass polymerization or body-suspension method manufacturing.
3. high-strength high-toughness flame-resistant ABS matrix material according to claim 1 is characterized in that in the described PETG plastics, the 1,4 cyclohexane dimethanol monomer content is at 30-40%.
4. high-strength high-toughness flame-resistant ABS matrix material according to claim 1 is characterized in that, described fire retardant is tetrabromo-bisphenol, antimonous oxide, chlorinatedpolyethylene compound, and three's ratio is 3.5～5: 1.2～1.5: 1.
5. high-strength high-toughness flame-resistant ABS matrix material according to claim 1 is characterized in that described toughner is the ABS high glue powder.
6. high-strength high-toughness flame-resistant ABS matrix material according to claim 1 is characterized in that described thermo-stabilizer is oxidation inhibitor N, N '-two-(3-(3, the 5-di-tert-butyl-hydroxy phenyl) propionyl) hexanediamine.
7. high-strength high-toughness flame-resistant ABS matrix material according to claim 1 is characterized in that described lubricant is the vinyl bis-stearamides.
8. high-strength high-toughness flame-resistant ABS matrix material according to claim 1 is characterized in that, is made up of following component by weight percentage:
ABS resin 60～65%
PETG plastics 9～13%
Fire retardant 20～23%
Toughner 3～5%
Thermo-stabilizer 0.3～0.5%
Lubricant 0.5～1.0%.
9. the preparation method of the described high-strength high-toughness flame-resistant ABS of claim 1 matrix material is characterized in that, may further comprise the steps:
(1) takes by weighing ABS resin, PETG plastics, toughner, thermo-stabilizer, lubricant, fire retardant by the described weight percent of claim 1;
(2) ABS resin, PETG plastics, toughner, thermo-stabilizer, lubricant, fire retardant were mixed in moderate-speed mixers 3-7 minute;
(3) the mixed raw material of step (2) is melt extruded granulation through twin screw extruder; The twin screw extruder processing condition are: twin screw extruder one district's temperature is 160～220 ℃, two district's temperature are 160～220 ℃, and three district's temperature are 160～220 ℃, and four district's temperature are 160～220 ℃, 160～220 ℃ in five districts, compound time of delivery in screw rod is 1～2 minute.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101581009A CN101831136B (en) | 2010-04-21 | 2010-04-21 | High-strength high-toughness flame-resistant ABS (Acrylonitrile Butadiene Styrene) composite material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101581009A CN101831136B (en) | 2010-04-21 | 2010-04-21 | High-strength high-toughness flame-resistant ABS (Acrylonitrile Butadiene Styrene) composite material and preparation method thereof |
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| CN101831136B CN101831136B (en) | 2012-08-08 |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102030966A (en) * | 2010-12-23 | 2011-04-27 | 余林华 | Mineral filled flame-retardant ABS composite material and preparation method thereof |
| CN102108181A (en) * | 2010-12-30 | 2011-06-29 | 金发科技股份有限公司 | Thermoplastic alloy and preparation method thereof |
| CN102675816A (en) * | 2012-05-22 | 2012-09-19 | 苏州新区华士达工程塑胶有限公司 | Formula of heat-resistant ABS (acrylonitrile-butadiene-styrene) |
| CN102746607A (en) * | 2012-07-05 | 2012-10-24 | 浙江富丽新材料有限公司 | Insulated and heat conducting environment-friendly flame-retardant ABS (Acrylonitrile Butadiene Styrene) resin and preparation method thereof |
| CN103421281A (en) * | 2013-04-26 | 2013-12-04 | 彭朕财 | Toughening and warming agent for PET/PETG |
| CN103524998A (en) * | 2013-10-09 | 2014-01-22 | 青岛颐世保塑料有限公司 | ABS antibacterial dedicated master batch |
| CN104672756A (en) * | 2015-02-11 | 2015-06-03 | 深圳市兴盛迪新材料有限公司 | ABS composite flame resistant material and preparation method thereof |
| CN104817814A (en) * | 2015-05-21 | 2015-08-05 | 广东威林工程塑料有限公司 | Flame-retardant ABS (acrylonitrile-butadiene-styrene) material capable of stably passing through 750-DEG C glowing filament without ignition and preparation method thereof |
| CN107793691A (en) * | 2016-08-29 | 2018-03-13 | 合肥杰事杰新材料股份有限公司 | A kind of bloom chemicals-resistant ABS/ copolyester alloy materials and preparation method thereof |
| CN108676312A (en) * | 2018-04-09 | 2018-10-19 | 南通德瑞森复合材料有限公司 | A kind of cable glass fiber reinforced plastic sheath material and preparation method thereof |
| WO2019007829A1 (en) * | 2017-07-04 | 2019-01-10 | Arcelik Anonim Sirketi | A refrigerator comprising a plastic inner lining |
| CN109206832A (en) * | 2018-09-30 | 2019-01-15 | 金旸（厦门）新材料科技有限公司 | A kind of ABS material and preparation method thereof of the extremely low warpage of 3D printing without cracking |
| CN109651769A (en) * | 2017-10-12 | 2019-04-19 | 天津星瑞包装科技有限公司 | A kind of ABS/PETG composite material and preparation method that high heat resistance enhancing is modified |
| CN109912920A (en) * | 2019-03-05 | 2019-06-21 | 腾龙特种树脂(厦门)有限公司 | Electrodepositable ABS/ polyester blend alloy and preparation method thereof |
| CN112011146A (en) * | 2019-05-29 | 2020-12-01 | 浙江钦堂钙业股份有限公司 | High-performance flame-retardant ABS/CPE composite material and preparation method thereof |
| CN112143162A (en) * | 2020-09-22 | 2020-12-29 | 上海金发科技发展有限公司 | ABS composite material and preparation method thereof |
| CN112280213A (en) * | 2020-10-23 | 2021-01-29 | 常德七星泰塑业有限公司 | Formula and production process of high-toughness high-strength PVC-u flame-retardant electrical casing |
| WO2021135570A1 (en) * | 2019-12-31 | 2021-07-08 | 金发科技股份有限公司 | Abs/polyester alloy composition and a preparation method therefor |
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| CN101418111A (en) * | 2008-11-14 | 2009-04-29 | 上海金发科技发展有限公司 | Weather resistant halogen-free flame retardant ABS resin and preparation process thereof |
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Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102030966A (en) * | 2010-12-23 | 2011-04-27 | 余林华 | Mineral filled flame-retardant ABS composite material and preparation method thereof |
| CN102108181A (en) * | 2010-12-30 | 2011-06-29 | 金发科技股份有限公司 | Thermoplastic alloy and preparation method thereof |
| CN102108181B (en) * | 2010-12-30 | 2013-02-20 | 金发科技股份有限公司 | Thermoplastic alloy and preparation method thereof |
| CN102675816A (en) * | 2012-05-22 | 2012-09-19 | 苏州新区华士达工程塑胶有限公司 | Formula of heat-resistant ABS (acrylonitrile-butadiene-styrene) |
| CN102746607A (en) * | 2012-07-05 | 2012-10-24 | 浙江富丽新材料有限公司 | Insulated and heat conducting environment-friendly flame-retardant ABS (Acrylonitrile Butadiene Styrene) resin and preparation method thereof |
| CN102746607B (en) * | 2012-07-05 | 2014-06-11 | 浙江富丽新材料有限公司 | Insulated and heat conducting environment-friendly flame-retardant ABS (Acrylonitrile Butadiene Styrene) resin and preparation method thereof |
| CN103421281A (en) * | 2013-04-26 | 2013-12-04 | 彭朕财 | Toughening and warming agent for PET/PETG |
| CN103421281B (en) * | 2013-04-26 | 2014-07-23 | 彭朕财 | Toughening and warming agent for PET/PETG |
| CN103524998A (en) * | 2013-10-09 | 2014-01-22 | 青岛颐世保塑料有限公司 | ABS antibacterial dedicated master batch |
| CN104672756A (en) * | 2015-02-11 | 2015-06-03 | 深圳市兴盛迪新材料有限公司 | ABS composite flame resistant material and preparation method thereof |
| CN104817814A (en) * | 2015-05-21 | 2015-08-05 | 广东威林工程塑料有限公司 | Flame-retardant ABS (acrylonitrile-butadiene-styrene) material capable of stably passing through 750-DEG C glowing filament without ignition and preparation method thereof |
| CN107793691A (en) * | 2016-08-29 | 2018-03-13 | 合肥杰事杰新材料股份有限公司 | A kind of bloom chemicals-resistant ABS/ copolyester alloy materials and preparation method thereof |
| WO2019007829A1 (en) * | 2017-07-04 | 2019-01-10 | Arcelik Anonim Sirketi | A refrigerator comprising a plastic inner lining |
| CN109651769A (en) * | 2017-10-12 | 2019-04-19 | 天津星瑞包装科技有限公司 | A kind of ABS/PETG composite material and preparation method that high heat resistance enhancing is modified |
| CN108676312A (en) * | 2018-04-09 | 2018-10-19 | 南通德瑞森复合材料有限公司 | A kind of cable glass fiber reinforced plastic sheath material and preparation method thereof |
| CN109206832A (en) * | 2018-09-30 | 2019-01-15 | 金旸（厦门）新材料科技有限公司 | A kind of ABS material and preparation method thereof of the extremely low warpage of 3D printing without cracking |
| CN109912920A (en) * | 2019-03-05 | 2019-06-21 | 腾龙特种树脂(厦门)有限公司 | Electrodepositable ABS/ polyester blend alloy and preparation method thereof |
| CN112011146A (en) * | 2019-05-29 | 2020-12-01 | 浙江钦堂钙业股份有限公司 | High-performance flame-retardant ABS/CPE composite material and preparation method thereof |
| WO2021135570A1 (en) * | 2019-12-31 | 2021-07-08 | 金发科技股份有限公司 | Abs/polyester alloy composition and a preparation method therefor |
| CN112143162A (en) * | 2020-09-22 | 2020-12-29 | 上海金发科技发展有限公司 | ABS composite material and preparation method thereof |
| CN112280213A (en) * | 2020-10-23 | 2021-01-29 | 常德七星泰塑业有限公司 | Formula and production process of high-toughness high-strength PVC-u flame-retardant electrical casing |
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