CN101787780A - Silicate enhanced macromolecule coating sheet - Google Patents
Silicate enhanced macromolecule coating sheet Download PDFInfo
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- CN101787780A CN101787780A CN201010103436A CN201010103436A CN101787780A CN 101787780 A CN101787780 A CN 101787780A CN 201010103436 A CN201010103436 A CN 201010103436A CN 201010103436 A CN201010103436 A CN 201010103436A CN 101787780 A CN101787780 A CN 101787780A
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Abstract
The invention relates to a silicate enhanced macromolecule coating sheet, which is characterized in that a macromolecule material enhanced by a silicate solidfied material is used as a coating for a film former; the coating is prepared into a coating film with the thickness of 0.01-7mm serving as a master slice by coating methods such as spraying, smearing, roll coating and the like; the master slice is prepared into varisized regular tablets or varisized irregular tablets by a cutting device and a breaking plant; and the tablets serve as the additive for granite coating and as a novel material used by a rock-like tapestry brick for stickup adornment. Since the silicate enhanced material exists in the product of the invention, the waterproof performance and aging resistence of the sheet are greatly improved.
Description
Technical field
The present invention relates to the constructional materials manufacturing technology, particularly the preparation of building and ornament materials and application
Background technology
Coating sheet, claim compound sliver, the color sheet of coating, resin sheet, imitative stone paster, flexible binding face tile etc. again, by synthetic resin with make coating after filler, pigment, auxiliary agent mix, forming thickness by methods such as spraying, trowelling, blade coating, roller coating is filming of 0.01-7mm, is made into rule or irregular sheet material with cutting or disintegrating apparatus again.Not only directly gluing ornamental does to decorate the use of subsides material, and the additive that the tiny sheet material that has also can be used as sand textured coating is applied in filming as the formation granite on the wall.Because manufacture craft is simple, with environmental friendliness, the finished product thing is not that stone material but is better than stone material, obtains extensive favorable comment in recent years.Application number is that 011045493 the disclosed technical scheme of patented technology is the acrylic acid series synthetic resin emulsion by 32kg weight, the natural aggregate of 40kg weight, the artificial aggregate of 10kg weight, the extender pigment of 10kg weight, the clear water of the additive of 3kg weight and 5kg weight is made behind the coating as raw material, but be sprayed on the smooth demoulding masterplate with spray gun, peel after the drying, become filming of thickness 1.2-2.5mm, make length-diameter part then and be divided into 2-7mm, the polyester sheet of particle flat ratio ÷ particle thickness more than 4, learn that by on probation this material is touched and gelatinization by moisture in the coating and auxiliary agent corruption after being incorporated in the sand textured coating sometimes, be unable to undergo to stir and fragmentation, make coating quality accident occur.In view of this reason, application number is 2008100600857 patent, proposing improved prescription is: water-base resin 60-65kg, coalescents 5-8kg, natural ore powder 30-35kg, the PVC that the resin demand of this prescription is recognized well beyond the Design of Coatings Formulation master's master (pigment) joins this principle, making resin in the coating sheet occur depositing cash resembles, the actual effect that generation wastes energy is unfavorable for energy-conservationly, reduces discharging the enforcement of big policy.
Goal of the invention: first purpose of the present invention is reasonably to control the consumption of macromolecule filming thing in the coating sheet, and guarantees the quality of coating sheet; Second purpose of the present invention is material is carried out the science collocation, replaces the macromolecule filming thing of a part of high energy consumption with silicate coagulated material good and cheap, environmental protection, reaches the saving cost, improves the quality, and reduces the purpose of energy consumption.
Technical solution: in a period, itself have the water of chance juvenescence greatly after macromolecule filming thing (the particularly high molecular synthetic resin emulsion) film forming, be unable to undergo in water, particularly in the medium-term and long-term immersion of the coating that contains the cosolvent composition.Reason is that the whole cross-linking reaction process of synthetic resin dry solidification be it is generally acknowledged under normal temperature (22-25 ℃) condition needed just can finish in 14-28 days, and present building engineering construction progress is fast, hand over the room sense of urgency strong, fail to wait coating sheet just to come into operation by the cross-linking reaction phase fully sometimes.Even strengthen the use amount of expensive synthetic resin in this case, also cannot say for sure the quality of coating sheet.
The scientific research of silicate material is in recent years advanced by leaps and bounds, scientific achievement seemingly springs up like mushrooms, the intermiscibility problem of silicate material and synthetic resin progressively is resolved, the silicates coagulated material has the characteristics that promote resin crosslinks, drying, make sheet material produce water-fast, ageing-resistant function in advance, simultaneously the fragility shortcoming of silicate material is by being overcome with cooperating of synthetic resin, so its purposes is constantly expanded.
The present invention carries out macromolecule filming thing and silicate solidification material compound in prescription, and the water resistance of their formed coating sheets is increased substantially, and can also strengthen its resistance to ag(e)ing and corrosion resistance, the right property of resistance.
The present invention discloses a kind of consumption that neither increases the macromolecule filming thing, the preparation method of the coating sheet that can improve the quality of products again: one: Design of Coatings Formulation:
1. clear water is an amount of
2. auxiliary agent 1-20 part
3. filler 20-80 part
4. pigment is an amount of
5. high molecular synthetic resin film forming matter 10-40 part
6. strengthen part with powdered silicate salt material 1-40
Above-described macromolecule filming thing by oil synthetic resin as: the mixture of one or more in benzene emulsion, pure-acrylic emulsion, Silicone acrylic emulsion, fluoro-silicone emulsion, uncle's acrylic emulsion, mylar, acrylate and vinyl acetate emulsion, elastic emulsion, solvent-borne type synthetic resin, natural polymer and the derivative redispersable latex powder thereof is formed.Described filler is paint field and concrete field filler and admixture commonly used.Described powdered silicate salt material is formed by one or more the mixture in cement, gypsum, calcium oxide powdery silicate of soda and their derivative.Described coating additive is formed by in the auxiliary agent commonly used in paint field and the concrete field one or more.Described pigment is formed by in organic pigment, inorganic pigment, the natural pigment one or more.
Manufacture craft: 1. 2. 3. 4. 5. drop in the coating cylinder successively above-mentioned material, make the coating of pulpous state through stirring, add when making is filmed to strengthen and use the powdered silicate salt material, use according to the requirement of design thickness then and spray, trowelling, the roller coating method is made film (masterbatch of sheet material) of 0.01-10mm thickness: then through cutting, crushing process is made the described sheet material of claim 9 or is used the collection coating, floating, moulding, oven dry, the integrated equipment of film-making is made into sheet material as claimed in claim 9, through after the road handle and the sorting classification after store for future use, extract as required during use.
Its two: Design of Coatings Formulation:
1. clear water is an amount of
2. auxiliary agent 1-20 part
3. filler 20-80 part
4. pigment is an amount of
5. macromolecule filming thing 10-40 part
6. strengthen with aqueous silicate material 1-20 part
Described aqueous silicate material is formed by in silicate of soda, potassium silicate, lithium metasilicate, zinc silicate, the silicon sol solution one or more.
During coating that making is filmed, as long as 1., 2., 3., 4., 5. dropping into successively in the above-mentioned material added liquid silicon hydrochlorate reinforcing material when a mixing bowl stirs back adjustment PH=9-10, mix and be method such as available spraying, trowelling, roller coating or use collection coating, coating floating, that oven dry is made 0.01-10mm thickness as the automation equipment of one with this coating to film, then with cut or disintegrating apparatus that sheet material is made into needed size is standby.
The invention has the advantages that; Do not increase under the prerequisite of consumption of expensive macromolecule filming thing, 100 days chip-proof performances of not gelatinization are soaked in 200 days, ethylene glycol resistant, propane diols, 12 lipidols, No. 200 solvent naphthas to make coating sheet have soaking-resistant, have improved the quality scale of sheet material greatly.Owing in coating, added the silicate reinforcing material, make coating sheet increase inorganic nature, so its weatherability corrosion resistance hinder the also raising greatly of right property.
The embodiment of the invention:
Embodiment one: formulation for coating material: (1) clear water 10kg, (2) hydroxyethylcellulose is an amount of, (3) coating dispersant 0.6kg, (4) pure-acrylic emulsion 30kg, (5) coalescents is an amount of, (6) paint antifoaming agent is an amount of, (7) the coating mould inhibitor is an amount of, (8) the coating softening agent is an amount of, (9) coating levelling agent is an amount of, (10) the coating wetting agent is an amount of, the mineral powder of (11) 400 order fineness is an amount of, (12) the black natural stone-powder is an amount of, (13) the PH conditioning agent is an amount of, (14) Ludox 5kg.
Preparation method: above-mentioned (1)-(13) material is dropped in the mixed cylinder, and levelling PH=9-10 is standby when reaching the requirement fineness through being uniformly dispersed and be below 50 microns.During use Ludox and above-mentioned slurry mixing, and it is sprayed on the masterplate with demoulding function, THICKNESS CONTROL is in the scope of 0.01-0.5mm, take off after the drying, pulverize through disintegrating apparatus, make erose one-piece flat area and be the sheet material between the 0.02-30mm, for preventing adhesion mutually between the sheet material, handle back classification keeping with the powder interleaving agent and make the color sheet (additive) of stone-like coating and use, newly having filmed of this stone-like coating exactly likes effect as the granite.
Embodiment two: formulation for coating material: (1) clear water is an amount of, (2) synthetic resin emulsion 1.5kg, (3) defoamer is an amount of, (4) dispersing agent is an amount of, (5) fungusproof anti-corrosion agent is an amount of, (6) softening agent is an amount of, (7) emulsifier is an amount of, (8) slag powders is an amount of, (9) 400 order barium sulfate are an amount of, (10) titanium dioxide is an amount of, (11) styrene-butadiene latex 30kg, (12) sulphate aluminium cement 5kg.
Preparation method: above-mentioned material (1)-(11) are dropped in the coating cylinder successively, be uniformly dispersed, add then to strengthen and use sulphate aluminium cement 5kg, but stir in back three hours with the spraying method spraying give on the demoulding template, THICKNESS CONTROL is in the 0.02-0.6mm scope, be ground into specification after the drying by designing requirement, the color sheet (additive) of making stone-like coating uses, and newly the filming of formation can produce and exactly like effect as the granite.
Embodiment three: formulation for coating material: (1) styrene-propene acid synthetic resin emulsion 32kg, (2) coalescents 1.5kg, (3) defoamer is an amount of, (4) dispersing agent is an amount of, (5) ethylene glycol is an amount of, (6) propane diols is an amount of, (7) softening agent is an amount of, (8) second class powered coal ash 30kg, (9) 600 coarse whitings are an amount of, (10) titanium dioxide is an amount of, (11) ferric oxide red colorant is an amount of, (12) enhancing silicate of soda 0.5kg, (13) enhancing portland-type cement 5kg, (14) condensation of aluminum phosphate 0.05kg.
Preparation method: above-mentioned material (1)-(12) are dropped into successively disperse to be uniformly dispersed in the cylinder, when recording fineness and be below 60 microns, package spare.Add the reinforcing agent portland-type cement 5kg in the prescription during use, stir with condensation of aluminum phosphate 0.05kg and to coat on the template of demoulding functions with the method for trowelling immediately, THICKNESS CONTROL is between 0.2-1mm, demoulding after drying, with mill it is ground into the small pieces of defined, and use by the color sheet (additive) of making stone-like coating after the specification screening, newly the filming of formation has the decorative pattern as the granite.
Embodiment four: formulation for coating material: the auxiliary agent that (1) polyvinyl acetate emulsion 25kg, (2) this area are commonly used is an amount of, (3) 400 order phosphorus slag powder 30kg, (4) iron oxide pigment is an amount of, (5) electrolyte treatment agent is an amount of, (6) 10% aluminum sulfate liquid are an amount of, (7) strengthen to strengthen with calcium hydroxide 3kg, (8) and use plaster of paris 1kg.
Preparation method: raw material (1)-(8) are added coating successively disperse to stir in the cylinder, add during use and with the strickling of belt-type automatic charging, drying integrated equipment coating is made into thick the filming of 3mm after the plaster of paris is transferred all, be cut to the sheet material of 50mm * 100mm then, make imitative ceramic tile and paste material decoration stickup metope.
Embodiment five: formulation for coating material: (1) pure acrylate elastic emulsion 25kg, (2) this area usual auxiliaries are an amount of, (3) 500 order kilns ash is an amount of, (4) quartz sand 20kg, (5) steel-making slag powder 3kg, (6) strengthen to strengthen with potassium silicate 0.3kg, (7) and use portland cement 5kg.
Preparation method: above-mentioned material (1)-(6) are dropped into successively package spare after being uniformly dispersed in the coating cylinder, in above-mentioned coating, add during use behind material (7) (portland cement) 5kg its trowelling on the template of concavo-convex moulding with demoulding functions, THICKNESS CONTROL is 4mm, uncover from mould half-dried back, advance the drying room oven dry, cut into the tile-like size according to designing requirement then, its finished product can be used as wall body decoration and pastes the material use.Its leftover bits and pieces sieves the additive use of keeping as stone-like coating after being ground into irregular small pieces with mill.
Embodiment six: formulation for coating material is: (1) clear water is an amount of, (2) hydroxyethylcellulose an amount of, (3) styrene butadiene rubber latex 10kg, (4) this area usual auxiliaries are an amount of, (5) mineral powder 15kg, (6) colored sand 45kg, (7) pigment are an amount of, (8) Silicone acrylic emulsion 15kg, (9) strengthen and use high alumina cement 8kg.
Preparation method: above-mentioned material (1)-(8) are added coating successively disperse in the cylinder, after being uniformly dispersed, add high alumina cement 8kg, after mixing well immediately with spray gun with paint spay-coating on template with demoulding functions, THICKNESS CONTROL is at 2-5mm, oven dry is taken off from template, then the imitative stone paster decorating objects use of sheet material do that will film and make the tile-like flat horizontal surface with cutting machine.
Embodiment seven: formulation for coating material is: (1) (solvent-borne type) hydroxyl acrylic acid resin 20kg, (2) this area usual auxiliaries are an amount of, (3) coarse whiting 15kg, (4) quartz sand 35kg, (5) French chalk 1kg, (6) barium sulfate are an amount of, (7) slag powders 5kg, (8) iron oxide red pigment 0.1kg, (9) strengthen with white cement 4kg, (10) curing compound 2kg.
Preparation method: above-mentioned material (1)-(8) are dropped into coating successively disperse in the cylinder, be uniformly dispersed and drop into white cement 4kg and curing compound 2kg, mix well the back with trowel with the coating trowelling on template with demoulding functions, THICKNESS CONTROL is below 3mm, take off on template half-dried back, makes its automatic curing, then sheet material is sent into cutting machine, be cut to the size of mosaic size, make mosaic ornament material and use.
Embodiment eight: formulation for coating material: (1) acrylate and vinyl acetate emulsion 20kg, (2) lithium metasilicate 2kg, (3) zinc silicate 0.5kg, (4) this area usual auxiliaries is an amount of, the following hollow glass micropearl of (5) ￠ 3mm is an amount of, (6) coarse whiting 10kg, (7) 100 order natural sands are an amount of, (8) ￠ 4mm plastic foam particle is an amount of, (9) enhancing Portland fly ash cement 5kg.
Preparation method: above-mentioned (1) material is dropped in the coating cylinder successively, be uniformly dispersed, when filming, making adds Portland fly ash cement, after continuing to stir slurry is encased in the integrated automation equipment of collection coating, floating, oven dry, section, THICKNESS CONTROL is in 3-7mm,, the surface of exterior wall in this sheet material Pasting is decorated makes it produce the texture of imitative stone material and imitative ceramic tile.
Embodiment nine: the coating sheet that example one, two, three is obtained and classified, reach the coating fragment of pressing embodiment five gained, by joining in the sand textured coating after the required color collocation, the back that stirs is the artificial granite decorative coveringn with spray gun spraying or trowel trowelling at decoration basal plane.
Embodiment ten: the imitative porcelain silicate enhanced macromolecule sheet material of the imitative stone that will make by embodiment 4-8 is affixed on the ornament surface with the bonding adhesive of polymer and cement mixing and can presents and imitate the decorative cover that stone material is imitated the ceramic tile effect.
Claims (11)
1. silicate enhanced macromolecule coating sheet is characterized in that: with the silicate solidification material to macromolecule filming thing and filler, pigment, auxiliary agent mixed coating strengthen after spraying, trowelling, roller coating coats or use collection coating, floating, moulding, the integrated pipelining equipment method of oven dry to make thickness is master slice as the paint film of 0.01-10mm.Being made into the rule of certain size or irregular a kind of small pieces with cutting, disintegrating apparatus then makes the metope that artificial grantie films as the additive of granite-simulating paint and pastes a kind of new material that ornamental imitative stone material, imitative tile decorative surface brick use.
2. silicate enhanced macromolecule coating sheet is characterized in that: macromolecular material as claimed in claim 1 by: oil synthesized polymer material, natural resin macromolecular material as: the mixture of one or more in synthetic resin adhesive, native cellulose ether, natural rubber, natural resin and their derivative thereof is formed.
3. according to claim 1, it is characterized in that filler by sand, mineral powder, slag, slag, flyash, kiln ash, phosphorus slag in the commonly used filler of paint field and the concrete field admixture commonly used, the mixture of one or more in the reconstituted product of industrial solid castoff, expanded perlite, plastic foam particle, hollow glass bead, the expanded vermiculite particle is formed.
4. silicate enhanced macromolecule coating sheet, it is characterized in that: pigment as claimed in claim 1 is paint field and concrete field pigment commonly used, forms as one or more the mixture in inorganic pigment, organic synthesis pigment, the natural pigment.
5. silicate enhanced macromolecule coating sheet, it is characterized in that: auxiliary agent as claimed in claim 1 is coating and concrete field auxiliary agent commonly used, as dispersing agent, defoamer, softening agent, coalescents, wetting agent, thickener, levelling agent, surfactant, ethylene glycol, propane diols, butanols, methyl alcohol, toluene, dimethylbenzene, the ring ethyl ketone, acetate butyl, isobutanol, acetone, the first ketone, ethyl acetate, No. 200 solvent naphthas, turpentine oil, the electrolyte remover, condensation of aluminum phosphate, the PH conditioning agent, fungusproof anti-corrosion agent, cellulose ether, cement water reducing agent, cement mortar, cement retarder, cement early strength agent, the mixture of one or more in the cement air entraining agent is formed.
6. silicate enhanced macromolecule coating sheet, it is characterized in that: described silicate solidification material comprises that one or more the mixture in lithium metasilicate, zinc silicate, potassium silicate, silicate of soda, Ludox, cement, gypsum, the calcium oxide is formed.
7. silicate enhanced macromolecule coating sheet is characterized in that: cement as claimed in claim 2 is formed by one or more the mixture in portland cement, sulfate cement, sulphate aluminium cement, ferrous aluminate cement, chemical cement and their derivative.
8. be the plaster of paris, gypsum as gypsum as described in the claim 2, described calcium oxide is: chemical lime, hydrated lime, quicklime.
9. silicate enhanced macromolecule coating sheet, it is characterized in that: the material mixture ratio of coating is according to claim 1: clear water 0-30kg, macromolecule filming thing 10-40kg, filler 20-80kg, pigment 0-20kg, auxiliary agent 1-20kg, silicate reinforcing material 0.01-40kg.
10. as a kind of silicate enhanced macromolecule coating sheet as described in the claim 1-9, flat horizontal surface is the rule of planomural shape or concavo-convex square, rectangle, rhombus, circle, ellipse and multi-angular shape or irregularly shaped.
11. a kind of according to claim 1 silicate enhanced macromolecule coating sheet, its soaking-resistant be in not gelatinization in 200 days, not broken, it is not broken that ethylene glycol resistant, propane diols, 12 lipidols, No. 200 solvent naphthas soak not gelatinization in 100 days.
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| CN102153369A (en) * | 2010-12-09 | 2011-08-17 | 东南大学 | Method for reinforcing autoclaved aerated concrete by using external reinforcing agent |
| CN102182130A (en) * | 2011-03-28 | 2011-09-14 | 中冶宝钢技术服务有限公司 | High-strength glass decorative steel slag concrete prefabricated art stone and manufacture method thereof |
| CN103214887A (en) * | 2013-02-20 | 2013-07-24 | 江苏吉福新材料有限公司 | Water-resistant paint |
| CN103321375A (en) * | 2013-06-14 | 2013-09-25 | 安徽省利德节能科技有限公司 | Composite inorganic thermal-insulation decoration plate and manufacturing method thereof |
| CN103788877A (en) * | 2014-01-28 | 2014-05-14 | 常熟市轻工装饰材料有限公司 | Colored decorative coating |
| CN104231757A (en) * | 2014-09-02 | 2014-12-24 | 三凯社（江苏）新材料有限公司 | Novel environment-friendly paint |
| CN104673088A (en) * | 2015-02-02 | 2015-06-03 | 安徽省东瑞装饰材料有限公司 | Waterproof coating for building roof and preparation method of waterproof coating |
| CN105038601A (en) * | 2015-08-31 | 2015-11-11 | 贵州耐尔福顺成建材有限公司 | Rock slice paint and production method thereof |
| CN109852128A (en) * | 2018-12-21 | 2019-06-07 | 亚士创能新材料(滁州)有限公司 | A kind of flame retardant type flexible compound coloured silk piece and preparation method thereof |
| CN109943108A (en) * | 2019-03-18 | 2019-06-28 | 广东欧涂新材料有限公司 | A kind of outer wall inorganic coating and preparation method thereof that lasting uvioresistant is extra-weather-proof |
| CN110003726A (en) * | 2019-02-25 | 2019-07-12 | 马小良 | A kind of high compatible rubber interleaving agent |
| CN110396314A (en) * | 2019-07-17 | 2019-11-01 | 福州大学 | A kind of high durable steel surface quick dried environment protection protective coating |
| CN110654038A (en) * | 2019-09-29 | 2020-01-07 | 刘金江 | Preparation method of coating raw material rock slices |
| CN110670823A (en) * | 2019-09-23 | 2020-01-10 | 君旺节能科技股份有限公司 | Inorganic dry powder coating flexible patch and preparation method thereof |
| CN111117314A (en) * | 2020-01-06 | 2020-05-08 | 深圳市卓宝科技股份有限公司 | Cement waterproof coating and preparation method and application thereof |
| CN113443871A (en) * | 2021-06-18 | 2021-09-28 | 国网新源控股有限公司 | Concrete for filling gap between pressure steel pipe and underground surrounding rock |
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2010
- 2010-01-29 CN CN201010103436A patent/CN101787780A/en active Pending
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| CN102153369A (en) * | 2010-12-09 | 2011-08-17 | 东南大学 | Method for reinforcing autoclaved aerated concrete by using external reinforcing agent |
| CN102153369B (en) * | 2010-12-09 | 2012-09-26 | 东南大学 | Method for reinforcing autoclaved aerated concrete by using external reinforcing agent |
| CN102182130A (en) * | 2011-03-28 | 2011-09-14 | 中冶宝钢技术服务有限公司 | High-strength glass decorative steel slag concrete prefabricated art stone and manufacture method thereof |
| CN102182130B (en) * | 2011-03-28 | 2012-12-12 | 中冶宝钢技术服务有限公司 | High-strength glass decorative steel slag concrete prefabricated art stone and manufacture method thereof |
| CN103214887A (en) * | 2013-02-20 | 2013-07-24 | 江苏吉福新材料有限公司 | Water-resistant paint |
| CN103321375A (en) * | 2013-06-14 | 2013-09-25 | 安徽省利德节能科技有限公司 | Composite inorganic thermal-insulation decoration plate and manufacturing method thereof |
| CN103788877A (en) * | 2014-01-28 | 2014-05-14 | 常熟市轻工装饰材料有限公司 | Colored decorative coating |
| CN104231757A (en) * | 2014-09-02 | 2014-12-24 | 三凯社（江苏）新材料有限公司 | Novel environment-friendly paint |
| CN104673088A (en) * | 2015-02-02 | 2015-06-03 | 安徽省东瑞装饰材料有限公司 | Waterproof coating for building roof and preparation method of waterproof coating |
| CN105038601A (en) * | 2015-08-31 | 2015-11-11 | 贵州耐尔福顺成建材有限公司 | Rock slice paint and production method thereof |
| CN109852128A (en) * | 2018-12-21 | 2019-06-07 | 亚士创能新材料(滁州)有限公司 | A kind of flame retardant type flexible compound coloured silk piece and preparation method thereof |
| CN110003726A (en) * | 2019-02-25 | 2019-07-12 | 马小良 | A kind of high compatible rubber interleaving agent |
| CN109943108A (en) * | 2019-03-18 | 2019-06-28 | 广东欧涂新材料有限公司 | A kind of outer wall inorganic coating and preparation method thereof that lasting uvioresistant is extra-weather-proof |
| CN110396314A (en) * | 2019-07-17 | 2019-11-01 | 福州大学 | A kind of high durable steel surface quick dried environment protection protective coating |
| CN110396314B (en) * | 2019-07-17 | 2021-09-28 | 福州大学 | High-durability steel surface quick-drying environment-friendly protective coating |
| CN110670823A (en) * | 2019-09-23 | 2020-01-10 | 君旺节能科技股份有限公司 | Inorganic dry powder coating flexible patch and preparation method thereof |
| CN110654038A (en) * | 2019-09-29 | 2020-01-07 | 刘金江 | Preparation method of coating raw material rock slices |
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Application publication date: 20100728 |