CN101786844A - Light heat-preserving brick and fabrication method thereof - Google Patents

Light heat-preserving brick and fabrication method thereof Download PDF

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Publication number
CN101786844A
CN101786844A CN201010300654A CN201010300654A CN101786844A CN 101786844 A CN101786844 A CN 101786844A CN 201010300654 A CN201010300654 A CN 201010300654A CN 201010300654 A CN201010300654 A CN 201010300654A CN 101786844 A CN101786844 A CN 101786844A
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glaze
ground
coat enamel
light
carbonate
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CN101786844B (en
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林再添
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SANRONG CERAMIC DEVELOPMENT Co Ltd XIAMEN CITY
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SANRONG CERAMIC DEVELOPMENT Co Ltd XIAMEN CITY
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Abstract

The invention discloses a light heat-preserving brick and a fabrication method thereof. The light heat-preserving brick comprises a green body layer and can also comprises a glaze layer which can totally or partly cover the green body layer, wherein the green body layer includes the following compositions, by weight: 60.0-70.0 pyrophyllite, 3.0-8.0 clay, 20.0-25.0 white talc, 3.5-5.0 feldspar, 0.5-1.4 glass and 0.3-0.8 carbonate. The method includes the steps of fabricating the green body layer, fabricating the ground glaze and fabricating the spot glaze. The light heat-preserving brick has the advantages of light weight, heat preservation property, big strength and attractive appearance.

Description

A kind of light-weight insulating brick and manufacture method thereof
Technical field
The present invention relates to a kind of material of construction, relate to a kind of light-weight insulating brick and manufacture method thereof that is used for the roof particularly.
Background technology
Along with social development, the requirement of building energy conservation is more and more higher, and is correspondingly, also more and more higher to the insulation and the heat insulating function requirement of material of construction.For body of wall, can adopt modes such as hollow brick to carry out heat-insulation and heat-preservation, and for the roof, rested on the brick with the concrete blocks of bulk usually in the past, utilize the space between concrete blocks and the roof heat insulation.Yet this concrete blocks has that materials are many, and weight is big, outward appearance is not attractive in appearance wait not enough.
More existing insulating bricks though the weight ratio concrete blocks is light, owing to often adopt organism such as wood chip, can produce cigarette during sintering, be unfavorable for environmental protection, and mostly be crude green body greatly that appearance is not attractive in appearance.
Summary of the invention
The object of the present invention is to provide a kind of light-weight insulating brick that is used for the roof, lighter, the high insulating effect of its weight.
Another object of the present invention is to provide a kind of light-weight insulating brick that is used for the roof, its intensity is big, and specious.
Technical scheme provided by the invention is as follows:
A kind of light-weight insulating brick comprises green body layer, and wherein this green body layer comprises following components in part by weight:
Agalmatolite 60.0~70.0, clay 3.0~8.0,
Whiten stone 20.0~25.0, feldspar 3.5~5.0,
Glass 0.5~1.4 and carbonate 0.3~0.8.
More preferably, this green body layer comprises following components in part by weight:
Agalmatolite 67.0, clay 5.0,
Whiten stone 22.5, feldspar 4.5,
Water mill glass 1.0 and salt of wormwood or yellow soda ash 0.5.
Pyrophyllite is a hydrous alumino silicates, mainly is made up of quartz, kaolin, sericite, and contains foreign material such as ferric oxide, calcium oxide, magnesium oxide, potassium oxide.The pyrophyllite main component is quartzy, is inert material, has the fire-resistant premium properties of Denging, and the pyrophyllite among the present invention is made the main raw material of insulation adobe body.
The main body chemical ingredients of clay mineral is sieve and silica-sesquioxide and water, it is characterized in that having plasticity-, can become the hard sintered compact with certain humidity after the walk burning with plastic making.Clay plays in insulating brick carcass forming process of the present invention and improves base substrate plasticity-and fusible effect.
The talcum main component is aqueous Petimin, belongs to oblique system.Whiten stone granulate (piece) is one of important source material of pottery and refractory materials.Also as the main raw material of base substrate, in addition, talcum reduces the firing temperature of product in the present invention also as flux material to whiten stone among the present invention; Can control the thermal expansivity of base substrate effectively as the batching talcum.
The effect of feldspar in the porcelain base: the same with quartz all is non-plastic raw material, can speed blank drying in base, reduces dry shrinkage and distortion.The same with talcum, feldspar can reduce the firing temperature of product as flux material.This is to generate the ability that glass state material has other material of fusion more than 1100 ℃ after the fusion because feldspar is heated to, and can impel kaolin and other particle, and diffusion interpenetrates mutually, thereby quickens the generation and the growth of base substrate mullite crystal.
Carbonate of the present invention produces carbonic acid gas as filler during pyrolytic decomposition, make the interior distribution bubble of base substrate of fusing, produces fine pore after burning till, and reaches the light thermal-insulation effect.Preferably, employed carbonate is salt of wormwood and yellow soda ash.
Glass also is used as filler and carbonate in the present invention, moulds the base substrate space, reaches the light thermal-insulation effect.Through experiment, adopt the best results of water mill glass, help moulding the intravital air pocket of brick.
Light-weight insulating brick of the present invention also comprises glazed layer, and described glazed layer can the described green body layer of all or part of covering,
Aforementioned glazed layer comprises ground-coat enamel, and described ground-coat enamel comprises following composition by weight: albite 35~45, kaolin 9~15, washing ball clay 3~7, rhombspar 6~10, lime carbonate 7~13, barium carbonate 2~6, Strontium carbonate powder 1~5, aluminum oxide 3~7, zirconium silicate 7~13, praseodymium yellow 0.2~0.4 and gold palm fibre 0.6~0.8.
Aforementioned glazed layer also comprises the some glaze that is distributed on the ground-coat enamel, described some glaze comprises stain, and described stain comprises the component of following weight part: albite 35~45, kaolin 9~15, washing ball clay 3~7, rhombspar 6~10, lime carbonate 7~13, barium carbonate 2~6, Strontium carbonate powder 1~5, aluminum oxide 3~7, praseodymium yellow 1 and cobalt black 2~6.
More preferably, described stain comprises the component of following weight part: albite 40, kaolin 12, washing ball clay 5, rhombspar 8, lime carbonate 10, barium carbonate 4, Strontium carbonate powder 3, aluminum oxide 5, praseodymium yellow 1 and cobalt black 4.
Some glaze on the described glazed layer also comprises red point, and described red point comprises the component of following weight part: albite 35~45, kaolin 9~15, washing ball clay 3~7, rhombspar 6~10, lime carbonate 7~13, barium carbonate 2~6, Strontium carbonate powder 1~5, aluminum oxide 3~7, praseodymium yellow 0.9~1.1 and zirconium iron pink 2~6.
More preferably, described red point comprises the component of following weight part: albite 40, kaolin 12, washing ball clay 5, rhombspar 8, lime carbonate 10, barium carbonate 4, Strontium carbonate powder 3, aluminum oxide 5, praseodymium yellow 1 and zirconium iron pink 4.
The point glaze of described glazed layer also comprises pale brown point, and described red point comprises the component of following weight part: albite 35~45, kaolin 9~15, washing ball clay 3~7, rhombspar 6~10, lime carbonate 7~13, barium carbonate 2~6, Strontium carbonate powder 1~5, aluminum oxide 3~7, praseodymium yellow 1~3, gold palm fibre 1~3 and cobalt black 0.4~0.6.
More preferably, described pale brown point comprises the component of following weight part: albite 40, kaolin 12, washing ball clay 5, rhombspar 8, lime carbonate 10, barium carbonate 4, Strontium carbonate powder 3, aluminum oxide 5, praseodymium yellow 2, gold palm fibre 2 and cobalt black 0.5.
A kind of manufacture method of light-weight insulating brick may further comprise the steps:
(1), powder is made: take by weighing corresponding raw material according to aforesaid green body layer ratio, join ball mill grinding, milling time 20-26 hour, after ball milling finishes, unload mud, mud is crossed 200 purpose filter screens, then mud is injected spray tower by pipeline, under 600-800 ℃ of temperature, mud is transformed into powder;
(2), base substrate compacting: in 1500T-2000T press die cavity, powder under high pressure becomes figurate base substrate with the even cloth of powder;
(3), body drying: the base substrate that suppresses is sent into drying kiln for drying by transfer limes, the moisture of base substrate is reduced to below 1%;
(4), ground-coat enamel is made: the ratio according to the ground-coat enamel prescription takes by weighing corresponding raw material, joins ball mill grinding, and milling time 15-20 hour, ball milling unloaded glaze slip after finishing, and glaze slip is crossed 250 purpose filter screens;
(5), execute ground-coat enamel: utilize professional dotting machine that the ground-coat enamel of making is beaten on base substrate uniformly;
(6), making: working method is with " ground-coat enamel making " this procedure;
(7), get ready: working method is beaten the point of different stains, red point, pale brown color as requested with " executing ground-coat enamel " this procedure;
(8), high temperature burns till: the base substrate after will getting ready is sent high temperature kiln to by transfer limes, through 1200 ℃~1300 ℃ high temperature, burns till the light thermal-insulation brick product in 60~75 minutes.
By foregoing description as can be known, the invention provides a kind of light-weight insulating brick, by the insulating brick that prescription of the present invention and method are made, product weight is light, and its proportion is compared with traditional concrete blocks less than 1, can alleviate the buildings load-bearing greatly; Its firing time is short, only needs 60~75 minutes at 1200~1300 ℃ of sintering, helps producing in enormous quantities; Organic content is few in the prescription, and basic smokeless and no toxic gas discharges when meeting fire burns; Because carry out ground-coat enamel and the making of some glaze outside base substrate, ground-coat enamel can be strengthened the intensity of base substrate on the one hand, and the insulating brick product strength is strengthened, it is specious on the other hand, the put a spot cooperation of glaze has improved the class of insulating brick greatly, is suitable for using in the high place of various appearance requirement.Thereby, the invention provides a kind of roof building material that integrates heat-insulation and heat-preservation, waterproof leakproof, attractive and durable, rational in infrastructure, many characteristics such as construction is simple.
Description of drawings
Fig. 1 is a process flow diagram of the present invention.
Embodiment
Embodiment 1
Table one body recipe
Material name Weight ratio
Agalmatolite ??67
Clay ??5
Whiten stone ??22.5
Feldspar ??4.5
Water mill glass ??1
Salt of wormwood ??0.5
Table 2 glaze point prescription (weight ratio):
Ground-coat enamel Stain Red point Pale brown point
Albite ??40 ??40 ??40 ??40
Longyan kaolin ??12 ??12 ??12 ??12
The washing ball clay ??5 ??5 ??5 ??5
Ground-coat enamel Stain Red point Pale brown point
Rhombspar ??8 ??8 ??8 ??8
Lime carbonate ??10 ??10 ??10 ??10
Barium carbonate ??4 ??4 ??4 ??4
Strontium carbonate powder ??3 ??3 ??3 ??3
Aluminum oxide ??5 ??5 ??5 ??5
Zirconium silicate ??10 ??/ ??/ ??/
Praseodymium yellow ??0.3 ??1 ??1 ??2
The gold palm fibre ??0.7 ??/ ??/ ??2
Cobalt black ??/ ??4 ??/ ??0.5
Zirconium iron pink ??/ ??/ ??4 ??/
With reference to accompanying drawing 1, a kind of light-weight insulating brick technology of the present invention is as follows:
1, powder is made: the ratio according to table one body recipe takes by weighing corresponding raw material, joins ball mill grinding, milling time 23 hours, ball milling unloads mud after finishing, and mud is crossed 200 purpose filter screens, then mud is injected spray tower by pipeline, under 700 ℃ of temperature, mud is transformed into powder.
2, base substrate compacting: in 1500T-2000T press die cavity, powder under high pressure becomes figurate base substrate with the even cloth of powder.
3, body drying: the base substrate that suppresses is sent in the dry kiln by transfer limes, the moisture of base substrate is reduced to below 1%, this can strengthen blank strength, and is unlikely on production line because of vibrations and collision base substrate to be broken.
4, ground-coat enamel is made: the ratio according to table two ground-coat enamel prescription takes by weighing corresponding raw material, joins ball mill grinding, and milling time 15-20 hour, ball milling unloaded glaze slip after finishing, and glaze slip is crossed 250 purpose filter screens.
5, execute ground-coat enamel: utilize professional dotting machine that the ground-coat enamel of making is beaten on ground-coat enamel uniformly.As required, can cover fully, or only cover the part of base substrate.Executing the ground-coat enamel purpose is: can increase the intensity of light-weight insulating brick on the one hand, can make things convenient for the follow-up operation of getting ready on the other hand, point just can be attached to above the brick by ground-coat enamel, and the third aspect can increase the aesthetic effect of brick.
6, making: working method is with " ground-coat enamel making " this procedure, and prescription sees Table two.
7, get ready: working method is with " executing ground-coat enamel " this procedure.This requires together to get is a little, is not that whole face all covers.Purpose: strengthen brick face aesthetic effect.Can beat the point (as stain, red point, pale brown point etc.) and the metallic particles bright spot of distinct colors as requested.Metallic particles (bright spot) can directly be bought and obtain, and need not preparation.
8, high temperature burns till: the base substrate after will getting ready is sent high temperature kiln to by transfer limes, burns till fast 63 minutes through 1204 ℃~1220 ℃ high temperature, and light-weight insulating brick (finished product) completes.
Embodiment 2
Except that prescription was different with embodiment 1, present embodiment technology was substantially the same manner as Example 1.
Ratio according to table three body recipe takes by weighing corresponding raw material, joins ball mill grinding, milling time 26 hours, ball milling unloads mud after finishing, and mud is crossed 200 purpose filter screens, then mud is injected spray tower by pipeline, under 600 ℃ of temperature, mud is transformed into powder.Base substrate is made identical with embodiment 1 to getting technology ready afterwards.The sintering temperature of present embodiment is that 1200 ℃ of high temperature burnt till 75 minutes fast.
Table three body recipe
Figure G201010300654820100125D000051
Figure G201010300654820100125D000061
Table four glaze point prescription (weight ratio):
Ground-coat enamel Stain Red point Pale brown point
Albite ??35 ??35 ??35 ??35
Longyan kaolin ??9 ??9 ??9 ??9
The washing ball clay ??7 ??7 ??7 ??7
Rhombspar ??6 ??6 ??6 ??6
Lime carbonate ??13 ??13 ??13 ??13
Barium carbonate ??2 ??2 ??2 ??2
Strontium carbonate powder ??5 ??5 ??5 ??5
Aluminum oxide ??3 ??3 ??3 ??3
Zirconium silicate ??13 ??/ ??/ ??/
Praseodymium yellow ??0.2 ??1 ??0.9 ??1
Ground-coat enamel Stain Red point Pale brown point
The gold palm fibre ??0.6 ??/ ??/ ??3
Cobalt black ??/ ??6 ??/ ??0.4
Zirconium iron pink ??/ ??/ ??6 ??/
Embodiment 3
Except that prescription was different with embodiment 1, present embodiment technology was identical with embodiment 1.
Ratio according to table five body recipe takes by weighing corresponding raw material, joins ball mill grinding, milling time 20 hours, ball milling unloads mud after finishing, and mud is crossed 200 purpose filter screens, then mud is injected spray tower by pipeline, under 800 ℃ of temperature, mud is transformed into powder.Base substrate is made identical with embodiment 1 to getting technology ready afterwards.The sintering temperature of present embodiment is that 1300 ℃ of high temperature burnt till 60 minutes fast.
Table five body recipe
Material name Weight ratio
Agalmatolite ??70
Clay ??8
Whiten stone ??25
Feldspar ??5.0
Water mill glass ??1.4
Salt of wormwood ??0.8
Table six glaze point prescription (weight ratio):
Ground-coat enamel Stain Red point Pale brown point
Albite ??45 ??45 ??45 ??45
Longyan kaolin ??15 ??15 ??15 ??15
The washing ball clay ??3 ??3 ??3 ??3
Rhombspar ??10 ??10 ??10 ??10
Lime carbonate ??7 ??7 ??7 ??7
Ground-coat enamel Stain Red point Pale brown point
Barium carbonate ??6 ??6 ??6 ??6
Strontium carbonate powder ??1 ??1 ??1 ??1
Aluminum oxide ??7 ??7 ??7 ??7
Zirconium silicate ??7 ??/ ??/ ??/
Praseodymium yellow ??0.4 ??1 ??1.1 ??3
The gold palm fibre ??0.6 ??/ ??/ ??1
Cobalt black ??/ ??2 ??/ ??0.6
Zirconium iron pink ??/ ??/ ??2 ??/
Above-mentioned only is a specific embodiment of the present invention, but design concept of the present invention is not limited thereto, and allly utilizes this design that the present invention is carried out the change of unsubstantiality, all should belong to the behavior of invading protection domain of the present invention.

Claims (10)

1. a light-weight insulating brick comprises green body layer, it is characterized in that, this green body layer comprises following components in part by weight:
Agalmatolite 60.0~70.0, clay 3.0~8.0,
Whiten stone 20.0~25.0, feldspar 3.5~5.0,
Glass 0.5~1.4 and carbonate 0.3~0.8.
2. a kind of light-weight insulating brick as claimed in claim 1 is characterized in that, this green body layer comprises following components in part by weight:
Agalmatolite 67.0, clay 5.0,
Whiten stone 22.5, feldspar 4.5,
Water mill glass 1.0 and salt of wormwood or yellow soda ash 0.5.
3. a kind of light-weight insulating brick as claimed in claim 1 or 2, it is characterized in that: also comprise being positioned at the outer glazed layer of green body layer, described glazed layer can the described green body layer of all or part of covering, this glazed layer comprises ground-coat enamel, and described ground-coat enamel comprises following composition by weight: albite 35~45, kaolin 9~15, washing ball clay 3~7, rhombspar 6~10, lime carbonate 7~13, barium carbonate 2~6, Strontium carbonate powder 1~5, aluminum oxide 3~7, zirconium silicate 7~13, praseodymium yellow 0.2~0.4 and gold palm fibre 0.6~0.8.
4. a kind of light-weight insulating brick as claimed in claim 3, it is characterized in that: described glazed layer also comprises the some glaze that is distributed on the described ground-coat enamel, described some glaze comprises stain, and described stain comprises the component of following weight part: albite 35~45, kaolin 9~15, washing ball clay 3~7, rhombspar 6~10, lime carbonate 7~13, barium carbonate 2~6, Strontium carbonate powder 1~5, aluminum oxide 3~7, praseodymium yellow 1 and cobalt black 2~6.
5. a kind of light-weight insulating brick as claimed in claim 3, it is characterized in that: described glazed layer also comprises the some glaze that is distributed on the described ground-coat enamel, described some glaze comprises stain, and described stain comprises the component of following weight part: albite 40, kaolin 12, washing ball clay 5, rhombspar 8, lime carbonate 10, barium carbonate 4, Strontium carbonate powder 3, aluminum oxide 5, praseodymium yellow 1 and cobalt black 4.
6. a kind of light-weight insulating brick as claimed in claim 3, it is characterized in that: described glazed layer also comprises the some glaze that is distributed on the described ground-coat enamel, described some glaze comprises red point, and described red point comprises the component of following weight part: albite 35~45, kaolin 9~15, washing ball clay 3~7, rhombspar 6~10, lime carbonate 7~13, barium carbonate 2~6, Strontium carbonate powder 1~5, aluminum oxide 3~7, praseodymium yellow 0.9~1.1 and zirconium iron pink 2~6.
7. a kind of light-weight insulating brick as claimed in claim 3, it is characterized in that: described glazed layer also comprises the some glaze that is distributed on the described ground-coat enamel, described some glaze comprises red point, and described red point comprises the component of following weight part: albite 40, kaolin 12, washing ball clay 5, rhombspar 8, lime carbonate 10, barium carbonate 4, Strontium carbonate powder 3, aluminum oxide 5, praseodymium yellow 1 and zirconium iron pink 4.
8. a kind of light-weight insulating brick as claimed in claim 3, it is characterized in that: described glazed layer also comprises the some glaze that is distributed on the described ground-coat enamel, described some glaze comprises pale brown point, and described pale brown point comprises the component of following weight part: albite 35~45, kaolin 9~15, washing ball clay 3~7, rhombspar 6~10, lime carbonate 7~13, barium carbonate 2~6, Strontium carbonate powder 1~5, aluminum oxide 3~7, praseodymium yellow 1~3, gold palm fibre 1~3 and black 0.4~0.6.
9. a kind of light-weight insulating brick as claimed in claim 3, it is characterized in that: described glazed layer also comprises the some glaze that is distributed on the described ground-coat enamel, described some glaze comprises pale brown point, and described pale brown point comprises the component of following weight part: albite 40, kaolin 12, washing ball clay 5, rhombspar 8, lime carbonate 10, barium carbonate 4, Strontium carbonate powder 3, aluminum oxide 5, praseodymium yellow 2, gold palm fibre 2 and black 0.5.
10. the manufacture method of a light-weight insulating brick is characterized in that, may further comprise the steps:
(1), powder is made: take by weighing corresponding raw material according to the described green body layer ratio of claim 1, join ball mill grinding, milling time 20-26 hour, after ball milling finishes, unload mud, mud is crossed 200 purpose filter screens, then mud is injected spray tower by pipeline, under 600-800 ℃ of temperature, mud is transformed into powder;
(2), base substrate compacting: in 1500T-2000T press die cavity, powder under high pressure becomes figurate base substrate with the even cloth of powder;
(3), body drying: the base substrate that suppresses is sent into drying kiln for drying by transfer limes, the moisture of base substrate is reduced to below 1%;
(4), ground-coat enamel is made: the ratio according to the ground-coat enamel prescription takes by weighing corresponding raw material, joins ball mill grinding, and milling time 15-20 hour, ball milling unloaded glaze slip after finishing, and glaze slip is crossed 250 purpose filter screens;
(5), execute ground-coat enamel: utilize professional dotting machine that the ground-coat enamel of making is beaten on base substrate uniformly;
(6), making: this procedure of the same step of working method (4) " ground-coat enamel making ";
(7), get ready: working method is with " executing ground-coat enamel " this procedure, beats the point of different colours as requested, as the point of stain, red point, pale brown color;
(8), high temperature burns till: the base substrate after will getting ready is sent high temperature kiln to by transfer limes, through 1200 ℃~1300 ℃ high temperature, burns till the light thermal-insulation brick product in 60~75 minutes.
CN2010103006548A 2010-01-25 2010-01-25 Light heat-preserving brick and fabrication method thereof Expired - Fee Related CN101786844B (en)

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CN104362319A (en) * 2014-11-21 2015-02-18 东莞市迈科科技有限公司 Preparation method of porous tin-carbon composite negative material
CN104557073A (en) * 2014-10-24 2015-04-29 叶香菲 Light refractory brick for high-temperature furnaces
CN104892012A (en) * 2015-05-26 2015-09-09 柳州市亿廷贸易有限责任公司 Dolomite refractory brick
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CN107352957A (en) * 2017-05-26 2017-11-17 如皋市磨头建设开发有限公司 A kind of light-weight insulating brick
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CN104557073B (en) * 2014-10-24 2016-08-17 叶香菲 High temperature kiln light fire brick
CN104362319A (en) * 2014-11-21 2015-02-18 东莞市迈科科技有限公司 Preparation method of porous tin-carbon composite negative material
CN104892012A (en) * 2015-05-26 2015-09-09 柳州市亿廷贸易有限责任公司 Dolomite refractory brick
CN105000865A (en) * 2015-07-08 2015-10-28 福建省晋江市丹豪陶瓷有限公司 Preparation method for large-sized ceramic tile
CN107352957A (en) * 2017-05-26 2017-11-17 如皋市磨头建设开发有限公司 A kind of light-weight insulating brick
CN107540344A (en) * 2017-09-30 2018-01-05 福建德胜新建材有限公司 A kind of 12 ° of sheen porcelain glazed bricks
CN107540344B (en) * 2017-09-30 2020-01-10 福建德胜新建材有限公司 12-degree soft porcelain glazed tile
CN110698220A (en) * 2019-11-12 2020-01-17 山东理工大学 Method for firing lightweight porcelain plate for exterior wall decoration by using roller kiln
CN110698220B (en) * 2019-11-12 2022-02-01 山东理工大学 Method for firing lightweight porcelain plate for exterior wall decoration by using roller kiln
CN111807701A (en) * 2020-07-08 2020-10-23 佛山市东鹏陶瓷有限公司 Preparation method of high-strength ceramic glazed tile and prepared high-strength ceramic glazed tile
CN111807701B (en) * 2020-07-08 2021-11-02 佛山市东鹏陶瓷有限公司 Preparation method of high-strength ceramic glazed tile and prepared high-strength ceramic glazed tile

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