CN101781487A - Environmental protection type anti-pollution paint - Google Patents
Environmental protection type anti-pollution paint Download PDFInfo
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- CN101781487A CN101781487A CN 201010129965 CN201010129965A CN101781487A CN 101781487 A CN101781487 A CN 101781487A CN 201010129965 CN201010129965 CN 201010129965 CN 201010129965 A CN201010129965 A CN 201010129965A CN 101781487 A CN101781487 A CN 101781487A
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Abstract
The invention relates to a nontoxic long-acting broad-spectrum environmental protection type anti-pollution paint which is characterized by comprising the following raw materials in parts by weight: 10 to 15 parts of thermoplastic acrylic polymer, 12 to 16 parts of rosin polymer, 3 to 5 parts of fluorine resin, 30 to 40 parts of N-2, 4, 6 trichlorobenzene maleimide, 10 to 20 parts of iron oxide red, 1 to 5 parts of nano TiO2, 10 to 12 parts of nano zinc oxide, 1 to 3 parts of isophorone, 1 to 3 parts of methyl isobutyl ketone, 1 to 3 parts of No.200 char solvent oil and 2 to 5 parts of xylene.
Description
Technical field
The invention belongs to the antifouling paint field, especially a kind of environmental protection antifouling paint of nontoxic, long-acting, wide spectrum, it is mainly used in marine artificial facility immersion such as naval vessel, ocean, port facilities, offshore drilling platform position.
Background technology
In the human society process, since the shipbuilding activity of own literature record, the application of marine antifouling measure has just been arranged.And along with the development and progress of society, antifouling paint has become the speciality coating that uses in the ocean environment, it is coated in the naval vessel hull bottom, the sea prevents that marine attaching organism is in its surface growth on the facility down, thereby avoided naval vessel hull bottom, underwater facility surface being caused damage, so the application antifouling paint has become Modern Ships, Offshore Units prevents the main means that marine organisms adhere to because of marine organisms adhere to.
From the mid-1960s in last century, China begins oneself development antifouling paint.Through a large amount of research and screenings, the fs serves as that the antifouling paint that poison is expected is brought into use with inorganic copper, mercury, and has obtained good anti-fouling effect.Sterilization, sterilants such as DDT, phenyl-hexachloride in addition that contemporaneity uses pretty good antifouling effect is also arranged, but the general addition of these stain control agents are bigger, and antifouling actual effect is generally 1.5-2.Owing to mercurous poison material causes severe contamination to be forbidden to the ocean basin, be eliminated gradually.To the 70-80 age in last century, discover DDT very difficult degradation in environment, and can in animal tallow, accumulate, cause birds not hatch, are highly toxic substances to fish, so DDT also is eliminated gradually.
Subordinate phase is used organometallic compound, and for example: organotin, organoarsenic, organic mercury, as the stain control agent of antifouling paint, its antifouling phase imitates and can reach 3-5.But because of organoarsenic, mercury, toxicity is bigger, seriously polluted and abandoned, and the antifouling paint that contains organotin obtains using widely rapidly.To the 80-90 age in last century, find organometallic compounds such as organotin after deliberation, teratogenesis, carinogenicity height, and have toxicity accumulation can cause damage to the neural system of human body, have had a strong impact on the marine eco-environment and human existence at self with healthy.Marine Environmental Protection Committee (MPEC) regulation under the International Maritime Organizaton (IMO), be on January 1st, 2008 the final working life of containing the antifouling paint of organotin.
At present, mostly the stain control agent of widespread use is to contain the compound stain control agent of Red copper oxide.Red copper oxide is the patent of U.S.'s the fifties in last century, uses to have advanced so far 60 years.Red copper oxide has the effect of solidifying the organism internal protein, thereby reaches antifouling purpose.Along with the deterioration of mankind itself's living environment to the improving constantly of environmental requirement, and day being becoming tight of heavy metal resources, be on January 1st, 2010 the final working life that International Maritime Organizaton (IMO) regulation contains the antifouling paint of Red copper oxide.
Therefore, antifouling paint must develop to low toxicity, nontoxic direction.And antifouling paint filmogen kind is limited at present, so screen nontoxic, long lasting stain control agent, utilizes existing filmogen optimization of C, will become the most important thing of research.But the stain control agent that meets long-acting, wide spectrum, environmental requirement is very few.Present stage, the compound stain control agent of the many employings of most of antifouling paint has reached the effect of wide spectrum antibiosis.And it is very few especially to use single stain control agent just can reach the environmental protection antifouling paint of compound stain control agent effect.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of environmental protection type anti-pollution paint nontoxic, long-acting, the single stain control agent of broad spectrum type that uses.
Technical scheme of the present invention is: environmental protection type anti-pollution paint is characterized in that being made up of the raw material of following weight part:
Thermoplastic acrylic copolymer 10-15 part, rosin polymer 12-16 part, fluorine resin 3-5 part, N-2,4,6 trichlorophenyl maleimide 30-40 parts, red iron oxide 10-20 part, nano-TiO
21-5 part, nano zine oxide 10-12 part, isophorone 1-3 part, hexone 1-3 part, 200# coal tar solvent oil 1-3 part, dimethylbenzene 2-5 part.
Preferably, form: thermoplastic acrylic copolymer 11-12 part, rosin polymer 12-14 part, fluorine resin 3-4 part, N-2,4,6 trichlorophenyl maleimide 30-35 parts, red iron oxide 10-15 part, nano-TiO by the raw material of following weight part
21-3 part, nano zine oxide 10-11 part, isophorone 1-1.5 part, hexone 1.5-2.5 part, 200# coal tar solvent oil 1.5-2.5 part, dimethylbenzene 3-4 part.
Effect of the present invention is: the single stain control agent that the present invention adopts is TCPM (N-2,4,6 trichlorophenyl maleimides), it is a kind of organic compound of synthetic, do not contain heavy metal, can not cause that galvanic corrosion and heavy metal assemble to pollute, nontoxic (manufacturer provides the toxicity test report of product toxicity weight supervision and inspection station, Shanghai City: per os LD50＞5000mg/kg), non-stimulated.Nontoxic to human body and higher animal, but mushroom, algae, marine attaching organism are had the good antifouling effect.Antifouling paint of the present invention applies the rear surface and forms the larva of unsuitable marine attaching organism and the rejection coating of spore growth, thereby reaches antifouling purpose.
The employed stain control agent TCPM of environmental protection antifouling paint of the present invention (N-2,4,6 trichlorophenyl maleimides) is water insoluble, dissolves in organic solvents such as benzene class and derivative thereof, ketone, alcohols, haloalkane hydro carbons.The present invention is used for thermoplastic propene's acids system, also can be applicable to the system of other film forming matters such as chlorinated rubber class, pitch class, vinyl, epoxies, and good consistency is arranged.
Environmental protection antifouling paint of the present invention took up research from 2002, formulate, test link plate, patch test of paints on ship hull through preliminary screening, prescription, had obtained good effect.At present, put into production, come into the market.Antifouling paint of the present invention is the third generation antifouling paint after promptly containing the antifouling paint of inorganic copper, the compound poison material of mercury and containing the organotin antifouling paint, can substitute the conventional composite type antifouling paint that contains organotin and Red copper oxide fully.And antifouling paint of the present invention uses single stain control agent, and its production technique is simple, raw material is easy to get, and economic benefit is considerable, and market outlook are wide.
The present invention is described further below in conjunction with not limiting embodiment.
Embodiment
Embodiment 1
Environmental protection type anti-pollution paint, form by the raw material of following weight part: the thermoplastic acrylic copolymer, its parts by weight are 10 parts; Rosin, its parts by weight are 12 parts; Stain control agent TCPM (N-2,4,6 trichlorophenyl maleimides), its parts by weight are 30 parts; Plasticizing adjuvant fluorine resin, its parts by weight are 3 parts; The functional stuffing nano-TiO
2, its parts by weight are 5 parts; Functional stuffing nano zine oxide, its parts by weight are 12 parts; Pigment red iron oxide, its parts by weight are 17 parts; Auxiliary agent isophorone, its parts by weight are 1.5 parts; Auxiliary agent hexone (MIBK), its parts by weight are 2.5 parts; Solvent 200# coal tar solvent oil, its parts by weight are 2 parts; Dimethylbenzene, its parts by weight are 5 parts.
Making method is: take by weighing each starting material by weight, starting material are mixed through high speed dispersion, utilize grinding plant to carry out dispersion treatment, milling time was controlled between 4-6 hour.
The technical parameter of this antifouling paint:
1, fineness is 45 μ m by GB/T 1724-1989 standard;
2, viscosity is 90s by GB/T 1723-1993 standard;
3, sticking power is 1 grade by GB/T 1720-1989 standard;
4, the drying varniss time is surface drying 0.5h by GB/T 1728-1989 standard, does solid work 16h.
Embodiment 2
Environmental protection type anti-pollution paint, form by the raw material of following weight part: the thermoplastic acrylic copolymer, its parts by weight are 11 parts; Rosin, its parts by weight are 12.5 parts; Stain control agent TCPM (N-2,4,6 trichlorophenyl maleimides), its parts by weight are 35 parts; Plasticizing adjuvant fluorine resin, its parts by weight are 3.5 parts; The functional stuffing nano-TiO
2, its parts by weight are 3 parts; Functional stuffing nano zine oxide, its parts by weight are 11 parts; Pigment red iron oxide, its parts by weight are 15 parts; Auxiliary agent isophorone, its parts by weight are 1.5 parts; Auxiliary agent hexone (MIBK), its parts by weight are 2.5 parts; Solvent 200# coal tar solvent oil, its parts by weight are 2.5 parts; Solvent xylene, its parts by weight are 4 parts.
Making method is: take by weighing each starting material by weight, starting material are mixed through high speed dispersion, utilize grinding plant to carry out dispersion treatment, milling time was controlled between 4-6 hour.
The technical parameter of this antifouling paint:
1, fineness is 45 μ m by GB/T 1724-1989 standard;
2, viscosity is 90s by GB/T 1723-1993 standard;
3, sticking power is 1 grade by GB/T 1720-1989 standard;
4, the drying varniss time is surface drying 0.5h by GB/T 1728-1989 standard, does solid work 16h.
Embodiment 3
Environmental protection type anti-pollution paint, form by the raw material of following weight part: the thermoplastic acrylic copolymer, its parts by weight are 15 parts; Rosin, its parts by weight are 15 parts; Stain control agent TCPM (N-2,4,6 trichlorophenyl maleimides), its parts by weight are 40 parts; Plasticizing adjuvant fluorine resin, its parts by weight are 5 parts; The functional stuffing nano-TiO
2, its parts by weight are 1 part; Functional stuffing nano zine oxide, its parts by weight are 10 parts; Pigment red iron oxide, its parts by weight are 10 parts; Auxiliary agent isophorone, its parts by weight are 1 part; Auxiliary agent hexone (MIBK), its parts by weight are 1.5 parts; Solvent 200# coal tar solvent oil, its parts by weight are 1.5 parts; Solvent xylene, its parts by weight are 3.5 parts.
Making method is: take by weighing each starting material by weight, starting material are mixed through high speed dispersion, utilize grinding plant to carry out dispersion treatment, milling time was controlled between 4-6 hour.
The technical parameter of this antifouling paint:
1, fineness is 45 μ m by GB/T 1724-1989 standard;
2, viscosity is 90s by GB/T 1723-1993 standard;
3, sticking power is 1 grade by GB/T 1720-1989 standard;
4, the drying varniss time is surface drying 0.5h by GB/T 1728-1989 standard, does solid work 16h.
For evaluating the antifouling property of this antifouling paint, embodiment 1,2,3 is coated on precoating respectively to be crossed on the steel plate of anti-corrosion primer, steel plate specification 250mm * 100mm * 2mm, and in the Qingdao, Zhejiang San Men, Pingtan, Fujian, Haikou carry out board experiment, experimental result such as following table.
Claims (2)
1. environmental protection type anti-pollution paint, it is characterized in that forming: thermoplastic acrylic copolymer 10-15 part, rosin polymer 12-16 part, fluorine resin 3-5 part, N-2 by the raw material of following weight part, 4,6 trichlorophenyl maleimide 30-40 parts, red iron oxide 10-20 part, nano-TiO
21-5 part, nano zine oxide 10-12 part, isophorone 1-3 part, hexone 1-3 part, 200# coal tar solvent oil 1-3 part, dimethylbenzene 2-5 part.
2. environmental protection type anti-pollution paint according to claim 1, it is characterized in that forming: thermoplastic acrylic copolymer 11-12 part, rosin polymer 12-14 part, fluorine resin 3-4 part, N-2 by the raw material of following weight part, 4,6 trichlorophenyl maleimide 30-35 parts, red iron oxide 10-15 part, nano-TiO
21-3 part, nano zine oxide 10-11 part, isophorone 1-1.5 part, hexone 1.5-2.5 part, 200# coal tar solvent oil 1.5-2.5 part, dimethylbenzene 3-4 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010129965 CN101781487A (en) | 2010-03-23 | 2010-03-23 | Environmental protection type anti-pollution paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010129965 CN101781487A (en) | 2010-03-23 | 2010-03-23 | Environmental protection type anti-pollution paint |
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| Publication Number | Publication Date |
|---|---|
| CN101781487A true CN101781487A (en) | 2010-07-21 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 201010129965 Pending CN101781487A (en) | 2010-03-23 | 2010-03-23 | Environmental protection type anti-pollution paint |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102181206A (en) * | 2011-04-21 | 2011-09-14 | 浙江海洋学院 | Antifouling paint containing nano oxides |
| CN102226058A (en) * | 2011-04-22 | 2011-10-26 | 刘炳 | Production process of glass air purification coating and application thereof in bulb glass shell |
| CN106675240A (en) * | 2016-12-14 | 2017-05-17 | 刘兴旺 | Environment-friendly metal protective coating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1389529A (en) * | 2002-07-05 | 2003-01-08 | 江苏荣昌化工有限公司 | Decorative thermoplastic acrylic paint |
| CN1557896A (en) * | 2004-02-11 | 2004-12-29 | 国家***天津海水淡化与综合利用研 | Environmental protection composite antifouling paint |
| CN1990625A (en) * | 2005-12-30 | 2007-07-04 | 贾俊卿 | Nanometer antiseptic paint |
-
2010
- 2010-03-23 CN CN 201010129965 patent/CN101781487A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1389529A (en) * | 2002-07-05 | 2003-01-08 | 江苏荣昌化工有限公司 | Decorative thermoplastic acrylic paint |
| CN1557896A (en) * | 2004-02-11 | 2004-12-29 | 国家***天津海水淡化与综合利用研 | Environmental protection composite antifouling paint |
| CN1990625A (en) * | 2005-12-30 | 2007-07-04 | 贾俊卿 | Nanometer antiseptic paint |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102181206A (en) * | 2011-04-21 | 2011-09-14 | 浙江海洋学院 | Antifouling paint containing nano oxides |
| CN102226058A (en) * | 2011-04-22 | 2011-10-26 | 刘炳 | Production process of glass air purification coating and application thereof in bulb glass shell |
| CN102226058B (en) * | 2011-04-22 | 2013-10-02 | 刘炳 | Production process of glass air purification coating and application thereof in bulb glass shell |
| CN106675240A (en) * | 2016-12-14 | 2017-05-17 | 刘兴旺 | Environment-friendly metal protective coating |
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Open date: 20100721 |