CN101750240A - Method and device for pre-treating samples in moveable-type soil detection - Google Patents

Method and device for pre-treating samples in moveable-type soil detection Download PDF

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Publication number
CN101750240A
CN101750240A CN 200910156632 CN200910156632A CN101750240A CN 101750240 A CN101750240 A CN 101750240A CN 200910156632 CN200910156632 CN 200910156632 CN 200910156632 A CN200910156632 A CN 200910156632A CN 101750240 A CN101750240 A CN 101750240A
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China
Prior art keywords
pedotheque
well heater
sieve
grinding unit
grinding
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CN 200910156632
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CN101750240B (en
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***
寿淼钧
王健
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FOCUSED PHOTONICS (HANGZHOU) Inc
Hangzhou Juguang Environmental Prot Technology Co ltd
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Focused Photonics Hangzhou Inc
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Publication of CN101750240B publication Critical patent/CN101750240B/en
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Abstract

The invention relates to a method for pre-treating samples in moveable-type soil detection. The method comprises the following steps: a. obtaining a soil sample at a soil measuring point, and putting the soil sample on a heater, wherein the heater is arranged on a grinding unit; b. drying the soil sample by the heater; c. moving the heater or a sieve to guide the soil sample into the grinding unit, and grinding the soil sample inside the grinding unit by the grinding unit; and d. overturning the grinding unit while the sieve is in a working condition, so as to sieve the ground soil sample. The invention further discloses a device for pre-treating samples in moveable-type soil detection. The invention has the advantages of compact structure, high portability, simple and rapid operation and the like.

Description

A kind of pre-treating samples in moveable-type soil detection and device
Technical field
The present invention relates to a kind of The pretreatment, especially a kind of pre-treating samples in moveable-type soil detection and device.
Background technology
In recent years, because the population sharp increase, industrial fast development, solid waste is constantly stacked and is toppled over to soil surface, and harmful waste water constantly permeates in soil, and harmful gas in the atmosphere and floating dust also constantly drop in the soil with rainwater, have caused soil pollution.Soil pollution directly influences the 26S Proteasome Structure and Function of soil ecosystem, will ecological safety and people's health be constituted a threat at last.
Soil pollution pollutes to go wrong from generation and can lag behind the long period usually, and therefore, the soil pollution problem is much accounted of not too easily.The control soil pollution generally is with " putting prevention first ", and this just need pollute ambient soil and carry out assessment surveys, is subjected to the great attention of countries in the world environmental administration.
Along with development of technology, small-sized portable soil analytical instrument has appearred on the market, and the type instrumentation is simple, and is easy to carry.But humidity has remarkable influence to measurement, and humidity is big more, and is big more to the influence of determinand characteristic spectral line and scattered ray; In addition, the particle of measuring samples unevenness too big and particle can produce granularity effect and inhomogeneous broadening effect, thereby the accuracy of measuring is exerted an influence.
If will reduce measuring error, then need carry out before soil detects pedotheque being carried out pre-service.Generally be earlier pedotheque to be carried out dried to reduce in the sample moisture to the influence of measurement result, grind then and Screening Treatment, grinding makes the particle of sample become less, can guarantee that sample particle is even and sieve, the soil powder that filters out different-grain diameter simultaneously is to satisfy different analysis requirements.
Existing portable soil analyser generally is equipped with the soil treatment accessory bag, for realizing the pre-service to pedotheque, must be equipped with the sample drying device in the accessory bag, grind device and screening device etc.Do the preprocessing process that can realize before soil detects like this,, but also have following problem with elimination humidity, granularity and unevenness effect:
1, annex many and scattered, carry inconvenience.
Be equipped with dry device in the soil treatment accessory bag, grind device and screening device, annex is many, and more scattered, and it is bigger to take up space, and carries inconvenience; The more meeting of annex simultaneously increases the weight of portable soil detecting instrument, has increased field operation institute on-load amount.
2, troublesome poeration.
Because dry device, grinding device and screening device are separate, make and grind again in the process of screening from drying to, pedotheque will be transferred to the grinding device from dry device successively and transfer on the screening device again, make manually-operated cumbersome, prolong the pretreated time of pedotheque, reduced detection efficiency.
3, increased the contaminated chance of pedotheque.
The transfer of pedotheque between different components makes the pollution source of pedotheque contact more, increased the contaminated chance of pedotheque, brings error for the detection of pedotheque.
4, cleaning trouble.
In order to eliminate last time pre-service to back time pretreated influence, reduce the mutual pollution between the sample, before each pre-service, device to be cleaned.Because device is more, clean inconvenient.Simultaneously, each device is all cleaned, also can waste a lot of detection times, make the detection efficiency of pedotheque lower.
Summary of the invention
In order to solve above-mentioned deficiency of the prior art, the invention provides a kind of preprocess method and device of the pedotheque that integrates the soil oven dry, grinds and screen.
For achieving the above object, the present invention adopts following technical scheme:
A kind of pre-treating samples in moveable-type soil detection may further comprise the steps:
A, obtain pedotheque at soil surveying point place, and place it on the well heater, described well heater is arranged on the grinding unit;
B, described well heater oven dry pedotheque;
C, pedotheque is imported grinding unit;
Utilize grinding unit to grind its inner pedotheque;
D, sieve is mounted to desired location, the described grinding unit that overturns sieves the pedotheque after grinding.
Further, by translation or rotate described well heater or sieve, thereby pedotheque is imported grinding unit.
Further, in said method, by the upset well heater, or in former plane of living in, rotate described well heater or sieve, thereby pedotheque is imported grinding unit and makes sieve in running order.
As preferably, remove described well heater, sieve is covered on the grinding unit, thereby make sieve in running order.
As preferably, described grinding unit comprises mortar and pestle.
The present invention also provides The pretreatment device in a kind of moveable-type soil detection, and be characterized in: described pretreatment unit comprises:
The grinding unit that is used for splendid attire and grinding pedotheque;
Be used to screen the sieve that grinds the back pedotheque;
Be used to place, heat the well heater of pedotheque;
Described well heater and sieve are arranged on the grinding unit.
Further, in said apparatus, described well heater and/or sieve have rotating shaft, are used for the upset or the rotation of well heater and/or sieve.
Further, described well heater is arranged in the slide rail, and slide rail is arranged on the grinding unit.
Further, in said apparatus, described well heater and sieve are arranged on the mount pad, and described mount pad is installed in the top of grinding unit.
Further, in said apparatus, described well heater is arranged on the mount pad, and described sieve is arranged on the top of grinding unit.
Further, in said apparatus, be provided with clean-up scraper, in the relatively rotating of well heater and sieve, the pedotheque on the well heater imported grinding unit.
As preferably, described grinding unit comprises mortar and pestle.
The present invention compared with prior art has following beneficial effect:
1, compact conformation, be convenient for carrying.
Total profile of pretreatment unit of the present invention and common mortar size are similar, the space of having saved heating box and sieve, and the pretreatment unit compact conformation conveniently goes out to carry, and has reduced field operation institute on-load amount.
2, simple and efficient to handle.
The present invention has adopted integrated design, makes to grind to screening from drying to again, and operation is simple, easy and simple to handle, has saved total operating time, has improved efficiency of measurement.
3, reduced the contaminated chance of pedotheque.
Pedotheque is ground to screening from drying to, all is to finish in an integrated device, has reduced the contaminated chance of pedotheque, has got rid of more disturbing factor, and it is more accurate to make the detection of pedotheque.
4, dry run intelligence.
Adopt temperature control circuit that drying course is implemented control among the present invention, make baking temperature all the time in the temperature of setting, and by Thermal Cutoffs in case high fault is crossed in short circuit, temperature
5, good security.
The present invention has taken into full account the anti-scald design, and grinding unit and mount pad that people's physical efficiency is touched adopt the bad medium of thermal conductivity, can reduce the chance of human body contact high temperature effectively, in case human body is scalded.
6, applied range
Involved in the present invention to equipment have wide range of applications, can be applicable in the pre-service of all types soil test sample.
7, easy to clean.
Device structure involved in the present invention is simple, and is convenient for cleaning, and each operation back only needs can finish cleaning with alcohol or clean cleansing tissue.
Description of drawings
Fig. 1 is the structural representation of pretreatment unit among the embodiment 1;
Fig. 2-Fig. 4 be among the embodiment 1 pretreatment unit at the synoptic diagram of diverse location;
Fig. 5-Fig. 6 be among the embodiment 2 pretreatment unit at the synoptic diagram of diverse location;
Fig. 7-Fig. 9 be among the embodiment 3 pretreatment unit at the synoptic diagram of diverse location;
Figure 10-Figure 11 be among the embodiment 5 pretreatment unit at the synoptic diagram of diverse location;
Figure 12 is the structural representation of pretreatment unit among the embodiment 6;
Figure 13 is the structural representation of pretreatment unit among the embodiment 7.
Embodiment
Embodiment 1
See also Fig. 1, Fig. 2, Fig. 3 and Fig. 4, The pretreatment device during a kind of moveable-type soil detects comprises well heater 11, sieve 21, mount pad 51 and grinding unit.
Described grinding unit comprises the mortar 31 of splendid attire pedotheque, the pestle 41 of grinding pedotheque, and mount pad 51 is installed in the top of mortar 31.Mortar 31 materials are selected agate for use, and mount pad 51 is selected teflon for use, can not bring pollution to pedotheque, can reduce the chance of human body contact high temperature simultaneously effectively, in case scalded.
Described well heater 11 is installed on the mount pad 51, is used for placing and the heating pedotheque; One side of well heater 11 has rotation axis 61, and rotation axis 61 is in the same plane with well heater 11, along with the rotation of well heater 11 around rotation axis 61, thereby will be placed on during pedotheque on the well heater 11 imports in the grinding unit.Well heater 11 can be selected for use heating plate or silica gel well heater to be bonded on the metal material and make, and adopt temperature control circuit that drying course is implemented control, make the temperature of oven dry pedotheque all the time in the temperature of setting, and by Thermal Cutoffs in case high fault is crossed in short circuit, temperature.
Described sieve 21 is fixedly mounted on the mount pad 51, is used to screen the pedotheque after the grinding.Sieve 21 can be selected different apertures for use, and to satisfy different analysis requirements, present embodiment is selected 0.25mm (60 order) stainless steel sift for use, to be used for the detection of field soil element.
Therefore the volume of above-mentioned pretreatment unit and common mortar are similar, and compact conformation conveniently goes out to carry, and have reduced field operation institute on-load amount.
Present embodiment also provides a kind of pre-treating samples in moveable-type soil detection, may further comprise the steps:
A, obtain pedotheque at soil surveying point place;
Well heater 11 is rotated to position shown in Figure 2, pedotheque is placed on the well heater 11;
Foreign material such as the brick and tile in the pedotheque, stone, grit, plant and animal residues are sorted out;
B, pedotheque is wipeed off, well heater 11 energisings, oven dry pedotheque;
In well heater 11 galvanizations, the temperature of utilizing temperature control circuit to come control heater is to guarantee drying the temperature of pedotheque all the time 100 ℃ of design temperatures;
C, well heater 11 moving axis 61 that rotates is overturn clockwise, from position shown in Figure 2 to position shown in Figure 3, thereby pedotheque is imported mortar 31;
Upset well heater 11 to position shown in Figure 2, is used the pedotheque in the pestle 41 grinding mortars 31 from position shown in Figure 3 counterclockwise;
D, take out pestle 41, the well heater 11 that overturns clockwise, from position shown in Figure 2 to position shown in Figure 3, and fixing well heater 11, upset mortar 31 is to position shown in Figure 4, make pedotheque after the grinding by sieve 21, analyze the soil powder that requires thereby be met.
The present invention has adopted integrated design, makes to grind to screening from drying to again, and operation is simple, easy and simple to handle, has saved the running time, has improved pre-service efficient.
Simultaneously, pedotheque is ground to screening from drying to, all is to finish in an integrated device, has reduced the contaminated chance of pedotheque, has got rid of more disturbing factor, makes that follow-up detection to pedotheque is more accurate.
Embodiment 2
As Fig. 3, Fig. 5-shown in Figure 6, The pretreatment device during a kind of moveable-type soil detects is not both with embodiment 1:
Described sieve 21 has rotation axis, is convenient to the rotation of sieve 21, rotation axis 61 conllinear of this rotation axis and well heater 11.
Present embodiment also provides a kind of pre-treating samples in moveable-type soil detection, may further comprise the steps:
A, obtain pedotheque at soil surveying point place;
Well heater 11 moving axis 61 that rotates is overturn clockwise, to position shown in Figure 3 and fixing, pedotheque is placed on the well heater 11;
Foreign material such as the brick and tile in the pedotheque, stone, grit, plant and animal residues are sorted out;
B, pedotheque is wipeed off, well heater 11 energisings, oven dry pedotheque;
In well heater 11 galvanizations, utilize temperature control circuit to come temperature on the control heater 11, to guarantee drying the temperature of pedotheque all the time 100 ℃ of design temperatures;
C, the well heater 11 that overturns clockwise to position shown in Figure 5, import mortar 31 with pedotheque;
With the pedotheque in the pestle 41 grinding mortars 31;
D, take out pestle 41, sieve 21 moving axis that rotates is overturn clockwise, to position shown in Figure 6 and fix, upset mortar 31 makes pedotheque after the grinding by sieve 21, analyzes the soil powder that requires thereby be met.
Embodiment 3
See also Fig. 7-Fig. 9, The pretreatment device during a kind of moveable-type soil detects, as different from Example 1:
1, at the middle part of well heater 12 rotation axis 62 is set, being convenient to well heater 12 can be around these rotation axis 62 upset, and rotation axis 62 is in the same plane with well heater 12;
2, mount pad 52 and sieve 22 are installed in the top of mortar 32 by hinge, and mount pad 52 and sieve 22 can rotate freely, realize with mortar 31 between fastening and open.
Present embodiment also provides a kind of pre-treating samples in moveable-type soil detection, may further comprise the steps:
A, obtain pedotheque at soil surveying point place;
Well heater 12 is on the mount pad 52, and is level, as shown in Figure 7;
Pedotheque is placed on the well heater 12;
Foreign material such as the brick and tile in the pedotheque, stone, grit, plant and animal residues are sorted out;
B, pedotheque is wipeed off, well heater 12 energisings, oven dry pedotheque;
In well heater 11 galvanizations, utilize temperature control circuit to come temperature on the control heater 11, to guarantee drying the temperature of pedotheque all the time at design temperature;
C, make well heater 12 moving axis 62 upset that rotates, thereby pedotheque is imported mortar 32;
Clockwise direction upset mount pad 52 as shown in Figure 8, utilizes the pedotheque in the pestle 42 grinding mortars 32 to vertical position;
D, take out pestle 42, clockwise direction upset sieve 22 is buckled in sieve 22 on the mortar 32 and fixes, and as shown in Figure 9, upset mortar 32 makes pedotheque after the grinding by sieve 22, analyzes the soil powder that requires thereby be met.
Embodiment 4
The pretreatment device during a kind of moveable-type soil detects, as different from Example 3: mount pad directly is placed on the mortar, can take out arbitrarily and put back to.
Present embodiment also provides a kind of pre-treating samples in moveable-type soil detection, as different from Example 3, in step c, pedotheque imported mortar after, directly erecting frame is taken out, utilize pestle to grind pedotheque.
Embodiment 5
As Figure 10, shown in Figure 11, The pretreatment device during a kind of moveable-type soil detects, as different from Example 1:
1, sieve 23 is fixedly mounted on the mount pad 53, and well heater 13 is installed on the mount pad 53, and rotating shaft 63 rotations that can rotate, axle 63 planes perpendicular to well heater 13 places of walking around.
2, a side of sieve 23 is provided with clean-up scraper 73, is used for when well heater 13 and sieve 23 relatively rotate the pedotheque on the well heater 13 being imported mortar 33.
Present embodiment also provides a kind of pre-treating samples in moveable-type soil detection, may further comprise the steps:
A, obtain pedotheque at soil surveying point place;
Well heater 13 is rotated to position shown in Figure 10;
Pedotheque is placed on the well heater 13;
Foreign material such as the brick and tile in the pedotheque, stone, grit, plant and animal residues are sorted out;
B, pedotheque is wipeed off, well heater 13 energisings, oven dry pedotheque;
In well heater 13 galvanizations, utilize temperature control circuit to come temperature on the control heater 13, to guarantee drying the temperature of pedotheque all the time at design temperature;
C, rotative heater 13, as shown in figure 11, in well heater 13 rotary courses, the pedotheque that is placed on the well heater 13 is imported in the mortar 33 by clean-up scraper 73;
Utilize pestle 43 to grind pedotheque;
D, take out pestle 43, rotative heater 13 is to position shown in Figure 10, and upset mortar 33 makes pedotheque after the grinding by sieve 23, analyzes the soil powder that requires thereby be met.
Embodiment 6
As shown in figure 12, The pretreatment device during a kind of moveable-type soil detects, as different from Example 5: described well heater 13 is fixing, the sieve 23 moving axis rotation that rotates, clean-up scraper 73 is arranged on the well heater 13.
Present embodiment also provides a kind of pre-treating samples in moveable-type soil detection, as different from Example 5:
Well heater 13 maintains static, and rotate moving axis rotation of sieve 23.
Embodiment 7:
As shown in figure 13, The pretreatment device during a kind of moveable-type soil detects, as different from Example 1:
Well heater 11 and sieve 21 are directly installed on the mortar 21, and wherein, sieve 21 is fixed on the mortar 21, and the rotation axis 61 of well heater 11 is arranged on the mortar 21.
Embodiment 8:
The pretreatment device during a kind of moveable-type soil detects, as different from Example 1: well heater is arranged in the chute, and chute is arranged on the mount pad, thus make well heater translation in chute.
Present embodiment also provides a kind of pre-treating samples in moveable-type soil detection, may further comprise the steps:
A, obtain pedotheque at soil surveying point place;
Extract well heater out, pedotheque is placed on the well heater;
Foreign material such as the brick and tile in the pedotheque, stone, grit, plant and animal residues are sorted out;
B, pedotheque is wipeed off, to the well heater energising, the oven dry pedotheque;
In the well heater galvanization, the temperature of utilizing temperature control circuit to come control heater is to guarantee drying the temperature of pedotheque all the time 100 ℃ of design temperatures;
C, operating personnel push the pedotheque on the well heater in the mortar;
With the pedotheque in the pestle grinding mortar;
D, take out pestle, thereby traveling heater is kept in the center well heater, well heater and sieve seal mortar substantially, and the upset mortar makes pedotheque after the grinding by sieve, analyzes the soil powder that requires thereby be met.
The present invention has adopted integrated design, makes to grind to screening from drying to again, and operation is simple, easy and simple to handle, has saved the running time, has improved pre-service efficient.
Simultaneously, pedotheque is ground to screening from drying to, all is to finish in an integrated device, has reduced the contaminated chance of pedotheque, has got rid of more disturbing factor, makes that follow-up detection to pedotheque is more accurate.
Above-mentioned embodiment should not be construed as limiting the scope of the invention.The present invention can also adopt the grinding unit of other form, and these all are the knowledge of this area, do not repeat them here.Key of the present invention is: oven dry, grinding and the screening of sample were integrated in one during soil was detected, and realized the pre-service to pedotheque in less size.Under the situation that does not break away from spirit of the present invention, any type of change that the present invention is made all should fall within protection scope of the present invention.

Claims (12)

1. pre-treating samples in moveable-type soil detection may further comprise the steps:
A, obtain pedotheque at soil surveying point place, and place it on the well heater, described well heater is arranged on the grinding unit;
B, described well heater oven dry pedotheque;
C, pedotheque is imported grinding unit;
Grind the pedotheque in the described grinding unit;
D, make sieve in running order, the described grinding unit that overturns sieves the pedotheque after grinding.
2. method according to claim 1 is characterized in that: translation or rotate described well heater or sieve, thus pedotheque is imported in the grinding unit.
3. method according to claim 1 is characterized in that: by the upset well heater, or rotate described well heater or sieve in former plane of living in, thereby pedotheque is imported grinding unit and makes sieve in running order.
4. method according to claim 1 is characterized in that: in steps d, remove described well heater, sieve is covered on the grinding unit, thereby make sieve in running order.
5. according to claim 1 or 2 or 3 or 4 described methods, it is characterized in that: described grinding unit comprises mortar and pestle.
6. The pretreatment device during a moveable-type soil detects, it is characterized in that: described pretreatment unit comprises:
The grinding unit that is used for splendid attire and grinding pedotheque;
Be used to screen the sieve that grinds the back pedotheque;
Be used to place, heat the well heater of pedotheque;
Described well heater and sieve are arranged on the grinding unit.
7. device according to claim 6 is characterized in that: described well heater and/or sieve have rotating shaft, are used for the upset or the rotation of well heater and/or sieve.
8. device according to claim 6 is characterized in that: described well heater is arranged in the slide rail, and slide rail is arranged on the grinding unit.
9. device according to claim 7 is characterized in that: described well heater and sieve are arranged on the mount pad, and described mount pad is installed in the top of grinding unit.
10. device according to claim 7 is characterized in that: be provided with clean-up scraper, in the relatively rotating of well heater and sieve, the pedotheque on the well heater imported grinding unit.
11. device according to claim 7 is characterized in that: described well heater is arranged on the mount pad, and described sieve is arranged on the top of grinding unit.
12. according to the described device of arbitrary claim in the claim 6 to 11, it is characterized in that: described grinding unit comprises mortar and pestle.
CN 200910156632 2009-12-29 2009-12-29 Method and device for pre-treating samples in moveable-type soil detection Expired - Fee Related CN101750240B (en)

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CN103120979A (en) * 2012-12-28 2013-05-29 山东省农业科学院农业资源与环境研究所 Soil sample smashing device and working method thereof
CN103487301A (en) * 2013-09-23 2014-01-01 福建师范大学 Soil analysis sample screening-grinding movable all-in-one machine
CN104096624A (en) * 2013-04-11 2014-10-15 严昌荣 Soil sampling grinding and crushing apparatus and crushing method thereof
CN105043808A (en) * 2015-06-29 2015-11-11 中国科学院合肥物质科学研究院 Disc type soil drying device for soil sample collecting and pre-processing device
CN106628609A (en) * 2015-10-30 2017-05-10 邓全 Anti-counterfeit package making method, device, verification method and purposes of anti-counterfeit soil sample packages
CN107589132A (en) * 2017-10-12 2018-01-16 钦州学院 A kind of sample processing device before XRD detections
CN108126824A (en) * 2018-01-26 2018-06-08 中国科学院合肥物质科学研究院 A kind of soil automatic grinding apparatus control system and method
CN108507821A (en) * 2018-06-20 2018-09-07 温州新鸿检测技术有限公司 A kind of soil pollution detection method
CN108738605A (en) * 2018-04-29 2018-11-06 王典 A kind of soil detection and fertilization system automatically
CN111855335A (en) * 2019-04-24 2020-10-30 北京兰友科技有限公司 A smash grinder for soil sample
CN114018669A (en) * 2021-11-04 2022-02-08 北京兰友科技有限公司 Full-automatic soil sample preparation method
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US5876671A (en) * 1993-03-24 1999-03-02 The Regents Of The University Of California Office Of Technology Transfer Sonication standard laboratory module
CN2154482Y (en) * 1993-04-27 1994-01-26 祝学禹 Grind machine for analysing sample
CN101285761B (en) * 2008-05-19 2010-07-21 聚光科技(杭州)股份有限公司 Turnover mechanism
CN201569597U (en) * 2009-12-29 2010-09-01 聚光科技(杭州)股份有限公司 Moveable sample pretreatment device in soil testing

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Publication number Priority date Publication date Assignee Title
CN103120979A (en) * 2012-12-28 2013-05-29 山东省农业科学院农业资源与环境研究所 Soil sample smashing device and working method thereof
CN104096624A (en) * 2013-04-11 2014-10-15 严昌荣 Soil sampling grinding and crushing apparatus and crushing method thereof
CN103487301A (en) * 2013-09-23 2014-01-01 福建师范大学 Soil analysis sample screening-grinding movable all-in-one machine
CN105043808A (en) * 2015-06-29 2015-11-11 中国科学院合肥物质科学研究院 Disc type soil drying device for soil sample collecting and pre-processing device
CN105043808B (en) * 2015-06-29 2017-12-01 中国科学院合肥物质科学研究院 A kind of disc type soil drying unit for soil pattern collection pretreatment unit
CN106628609A (en) * 2015-10-30 2017-05-10 邓全 Anti-counterfeit package making method, device, verification method and purposes of anti-counterfeit soil sample packages
CN107589132A (en) * 2017-10-12 2018-01-16 钦州学院 A kind of sample processing device before XRD detections
CN108126824A (en) * 2018-01-26 2018-06-08 中国科学院合肥物质科学研究院 A kind of soil automatic grinding apparatus control system and method
CN108738605A (en) * 2018-04-29 2018-11-06 王典 A kind of soil detection and fertilization system automatically
CN108507821A (en) * 2018-06-20 2018-09-07 温州新鸿检测技术有限公司 A kind of soil pollution detection method
CN111855335A (en) * 2019-04-24 2020-10-30 北京兰友科技有限公司 A smash grinder for soil sample
CN114018669A (en) * 2021-11-04 2022-02-08 北京兰友科技有限公司 Full-automatic soil sample preparation method
CN115138425A (en) * 2022-07-21 2022-10-04 张勇 Solid useless regeneration is with construction waste impacted style comminution device

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