CN101720341A - Composite wood board - Google Patents

Composite wood board Download PDF

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Publication number
CN101720341A
CN101720341A CN200780050375A CN200780050375A CN101720341A CN 101720341 A CN101720341 A CN 101720341A CN 200780050375 A CN200780050375 A CN 200780050375A CN 200780050375 A CN200780050375 A CN 200780050375A CN 101720341 A CN101720341 A CN 101720341A
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binding agent
wood board
acid
composite wood
plate
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CN101720341B (en
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R·杰克逊
T·爱恩道尔
G·拜布特
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Knauf Insulation Ltd
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Knauf Insulation Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/002—Manufacture of substantially flat articles, e.g. boards, from particles or fibres characterised by the type of binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
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  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Forests & Forestry (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Inorganic Chemistry (AREA)
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Abstract

In a stack of composite wood boards, the wood boards comprise wood particles and an organic binder.

Description

Composite wood board
Technical field
The present invention relates to composite wood board, shaving board (particle board) for example, oriented wood chipboard (orientated strand board) and wood-fiber board (wood fibre board), and be particularly related to the composite wood board that comprises bio-resin (bioresin) and/or have low formaldehyde or formaldehyde-free binder.
Background technology
Bio-resin is to create to be used to describe derived from the resin of biogenetic derivation or the term of resin preparaton.Therefore, many traditional resins are for example based on proteinic soybean, collagen or casein, perhaps from the carbohydrate derivates of Mierocrystalline cellulose or starch, can all classify as bio-resin based on the tackiness agent of natural rubber and natural phenolic tackiness agent such as tannin or xylogen.They are reproducible polymkeric substance and have low environmental influence power, are representing the substitute of the system that drives for existing oil.
To the interest of bio-resin system mainly to increasing regulation of nonpollution environment and public attention, and to demand based on the sustainable substitute of the product in limited petrochemical complex source.The preparation of commercial thermosetting resin and use are faced with mainly owing to the such regulation of monomer component that forms the preparaton basis.Overwhelmingly, these resins are based on melamine, phenol, urea, formaldehyde, vinylbenzene or isocyanic ester parent material.
For the installation that in the manufacturing of shaving board (PB), oriented wood chipboard (OSB), medium-density fiberboard (MDF) and wood-fiber board, relates to, the discharging of formaldehyde, phenol and isocyanic ester is subjected to control usually, they are in Pollution Prevention and Control Regulations (2000) at England and Wales, under the management of SI19.To airborne emission limit set at 5mg/m 3Especially, the manual recording operator should use the resin of minimum as far as possible formaldehyde emission.Used resin choice should be assessed continuously to guarantee the generation of minimum discharging.Problem may exist high levels of formaldehyde of paying close attention in the working space and the formaldehyde that slowly discharges from plate product itself, particularly when the beginning of product time limit of service.
The bio-resin product can provide alternative, the renewable source of thermosetting resin, and they will begin to solve the tcam-exhaustion of limited resources and have better discharging and distribute (profile), particularly when preparing formaldehydelessly.Though formaldehydeless material, for example siisocyanate and tannin resin have become and can obtain, and about 85% among the MDF of preparation used formaldehyde resin at present, is about 200 ten thousand tons/year corresponding to the European market.In these resins, although realized the minimizing of formaldehyde content recent years, the cost of paying is long process period, by inside bonding and the reduction of flexural strength and the increase of swelling and moisture absorption of the plate product of their preparations.Therefore, have the clear and definite demand for the more friendly resin of novel environmental now in market, described resin is in price, performance and can adapt to aspect the existing composite material manufacturing technology competitive.
Summary of the invention
According to an aspect, the invention provides a kind of composite wood board as limiting in the claim 1.Others are limited in other independent claim.Define preferred and/or optional characteristic in the dependent claims.
Different with the plank that laboratory test is made, this composite wood board is preferably the composite wood board that industry is made.This composite wood board can have the size of 30cm * 30cm at least, and it can have the size of 50cm * 80cm at least, might be 1m * 2m at least.
This composite wood board can have and is trimmed and/or the edge of cutting and/or mechanical workout.
The packing that this composite wood board can be used as the plank that comprises a plurality of arrangements and/or bond together provides, for example in order to help transportation; It can also comprise wrap film, for example plastic material.This packing can comprise pallet, and it can adapt to by handling via machinery rising equipment and/or fork truck formula truck.
This composite sheet can have at least 11mm, 12mm or the nominal thickness of 15mm at least at least.
Be preferably the set time of this composite wood board and be less than 25 minutes.
Binding agent can:
Based on reducing sugar; And/or
Based on reductosis; And/or
Based on the sugar that contains aldehyde; And/or
At least a reaction product that comprises carbohydrate reactant and amine reactant; And/or
At least a reaction product that comprises reducing sugar and amine reactant; And/or
At least a reaction product that comprises carbohydrate reactant and polybasic carboxylic acid ammonium salt reactant; And/or
Comprise at least a reaction product that obtains by mailland reaction (Maillard reaction).
The accompanying drawing summary
The non-limiting example that relates to laboratory scale test of the present invention is described with reference to the following drawings:
Fig. 1 shows the cutting mode of sheet material among the embodiment 2
Fig. 2 shows the influence of press time for the IB of the shaving board that has the BS1 resin among the embodiment 2
Fig. 3 shows the influence of press time for the IB of the shaving board that has the BS1-SOK resin among the embodiment 2
Fig. 4 shows relevant to embodiment 2 20 ℃ of thickness swell after following 24 hours
Fig. 5 shows relevant to embodiment 2 20 ℃ of moisture absorption after following 24 hours
Fig. 6 shows the influence of press time for the IB of the oriented wood chipboard with BS1 resin relevant with embodiment 2
Fig. 7 shows the many illustrative reactants that are used to prepare melanoidin
Fig. 8 has illustrated the synoptic diagram of mailland reaction when making the reaction of reducing sugar and aminocompound
Embodiment
Embodiment 1a:
Be used to construct the preparation of the polycarboxylic acid ammonium-sugared binding agent of wood-fiber board composition
Aqueous citric acid three ammoniums-glucose (1: 6) binding agent prepares by following general program: the Glucose monohydrate of powder mix powder (915g) and pulverous Citric Acid, usp, Anhydrous Powder (152.5g) in 1 gallon reaction vessel, and to the distilled water that wherein adds 880g.Under agitation 19% of adding 265g ammoniacal liquor in this mixture stirs continuous several minutes to realize that solid dissolves fully.Add the solution (use pH test paper) of the SILQUEST A-1101 silane of 3.3g with preparation pH value-8-9 in the solution that obtains, wherein this solution comprises about 50% dissolved Glucose monohydrate and dissolved ammonium citrate solid (as the per-cent of total solution weight); The sample of this solution of 2g was 400 following thermofixations 30 minutes, and it can produce 30% solid (dehydration during weight loss forms owing to thermosetting adhesive).Wherein silane rather than SILQUEST A-1101 are included in Triammonium citrate-glucose (1: 6) binding agent, replace with SILQUEST A-187 silane, HYDROSIL 2627 silane or Z-6020 silane.When additive being comprised in Triammonium citrate-glucose (1: 6) binding agent, this standardized solution is distributed in the bottle of 300g aliquots containig, then to wherein supplying various additives with preparation binding agent variant.
Figure 1 shows that the FT-IR spectrum of exsiccant (uncured) Triammonium citrate-glucose (1: 6) binding agent, wherein this spectrum as from 10g in a vacuum the binding agent sample of exsiccant 30% (dissolved binding agent solid) micro-film (microscopic film) and obtain.Figure 2 shows that the FT-IR spectrum of solidified Triammonium citrate-glucose (1: 6) plum rad binding agent, wherein this spectrum obtains as the micro-film of the binding agent sample of 30% (dissolved binding agent solid) after solidifying from 10g.When polycarboxylic acid that will be except that citric acid, sugar except that glucose and/or additive are used to prepare aqueous polycarboxylic acid ammonium-sugared binding agent variant, use to be used to prepare the identical general program of aqueous citric acid three ammoniums-glucose (1: 6) binding agent as described above.For polycarboxylic acid ammonium-sugared binding agent variant, be necessary to regulate so that adapt to di-carboxylic acid that for example replaces citric acid or the polymkeric substance polycarboxylic acid that comprises, perhaps adapt to the triose that for example replaces glucose that comprises, perhaps adapt to for example one or more additives that comprise.This adjusting comprises, for example, adjusting must be used to generate the volume of the ammoniacal liquor of ammonium salt, and adjusting must be used to the gram number of the polycarboxylic acid ammonium that obtains to expect and the reactant of the mol ratio of sugar, and/or comprises the additive of the weight percent that is in expectation.
Several method is used for preparing with the bonding wood-fiber board/sheet material of this Triammonium citrate-glucose (1: 6) binding agent.A kind of typical method is as follows, and this method has prepared blocky, uniform sample: the timber that will be in various pine wood shavings and sawdust form is bought by local farm supply store.With as when receiving state timber and be separated into wood shavings and the material preparation wood-fiber board sample of sawdust component, at first in baking oven, spend the night at about 200 following desiccated woods, cause removing the moisture of 14-15% for this drying of wooden shavings, and remove about 11% moisture for sawdust.Afterwards, exsiccant timber is placed in inch wide * 10.5, the 8 inches high * 12 inch dark plastic containers (general size).Prepare Triammonium citrate-glucose (1: 6) binding agent (36% binding agent solid) according to the method described above, and afterwards on the 400g wood sample that container is sprayed on the 160g binding agent during from vertical direction inclination 30-40 degree and slowly rotation (approximately 5-15rpm) by hydraulic efficiency pressure nozzle the plastic containers.During this processing, timber is leniently rolled, it becomes and evenly is coated with simultaneously.
Be placed on the wood sample of plastic resin treatment (resinated) in the foldable frame and between the pressing plate of heating, compress under the following conditions: the wooden shavings of plastic resin treatment, 300psi; The sawdust of plastic resin treatment, 600psi.For the sample of each plastic resin treatment, condition of cure is 350 following 25-30 minutes.Resulting sample panel is that about 10 inches long * 10 are inch wide, and before finishing be about 0.4 inch thick, inner bonding good, smooth surface and when on band saw, repairing, carry out clearcut (clean cut).The finishing sample rate and the size of every kind of finishing sample panel of preparation are as follows: from the sample panel of wooden shavings, and density～54pcf, inch wide * 0.36, inch long * 9, size～8.3 is inch thick; From the sample panel of sawdust, density～44pcf, inch wide * 0.41, inch long * 8.8, size～8.7 is inch thick.The binder content of the estimation of every kind of sample panel is～12.6%.
Embodiment 1b:
Test following sample so that the flexural strength and the tensile strength of the like product of the novel test adhesive preparation of contrast standard shaving board and oriented wood chipboard and use:
1/2 inch commercially available shaving board by Builders Lumber purchase
Commercially available 1/2 inch oriented wood chipboard (OSB) by Builders Lumber purchase
Test wood particulate plate according to above-mentioned preparation
8.75 * 8.87 * 0.414371.9gm.44.1lbs 312.6% binding agent
Test wooden shavings plate (shavings board) according to above-mentioned preparation
8.37 * 9 * 0.336361.2gm.54.4lbs 312.6% binding agent
The sheet material of test respectively does for oneself about 8 3/4Square inch.Sheet material from builders when buying is about 2ft * 4ft.These sheet materials are cut into about 8 3/4Square inch, so that as one man collect sample from various products.
Test-results is listed among the table 1-5:
The result of table 1 general introduction
Figure G2007800503757D00051
Table 2 detailed data-standard shaving board (shop purchase)
Figure G2007800503757D00061
The shaving board of table 3 detailed data-test
Figure G2007800503757D00062
Table 4 detailed data-standard orientation shaving board (shop purchase)
Figure G2007800503757D00071
The oriented wood chipboard of table 5 detailed data-test
Figure G2007800503757D00072
Embodiment 2
Use two kinds of experiment resins, BS1 and BS1-SOK (50% solids content).Make shaving board (PB), oriented wood chipboard (OSB) and medium-density fiberboard (MDF) with these two kinds of resin systems.
The manufacturing of test shaving board
Make single-layer particle board.The wood chip that is used to make shaving board is to be used for the wood chip that commercial shaving board is made, and these wood chips are made up of the mixture of wood type material and are thought that it mainly is made up of the timber of regenerating.Before using wood chip it is sieved to remove excessive material and fragment.Before the plastic resin treatment, dried wood chips is to constant moisture content (MC).Hereinafter, moisture content will be expressed as the per-cent of weight in the timber weight of oven drying that is included in the moisture in the timber.
Resin with 12% or 14% joins (weight of the weight relatively dry timber of resin solid) in the wood chip.In Kenwood or Drum blender with resin with wood chip blend be in the same place.Measure the moisture content of dried wood chips and through the moisture content of spraying wood chip; These information have been summed up in the table 6.In order to obtain 650kg/m 3Target density, adjust the wood chip quality of every block of sheet material according to moisture content.
After resin, additive and wood chip blend, transfer in the working chamber with resulting " batching " and compression lightly before the hot pressing that is used for final set and resin solidification.
Use 220 ℃ target platen temperature and total compacting time pressed sheet of 5-12 minute.Sheet material be 500mm * 500mm or 300mm * 300mm square and for 12mm thick.After from hot pressing, removing, give sheet material labelled and cooling back finished edge.
The manufacturing of the oriented wood chipboard of test
Screen thin slice and be separated into core and surface sheets.Large-sized thin slice is used for upper layer, the undersized core layer that is used for.
In two blender with the BS1 resin (resin that is used for timber is based on dry weight) and the water blend of surfacing and 14%.Resin is mixed by static mixer with water.Add water so that reduce the viscosity of resin and the MC of thin slice is increased to 12%.
In single blender with the BS1 resin and the water blend of core material and 12%.The MC of target core thin slice is 10-12%.
The material of blend is sent to three shaping positions, surface, core and surface.The shaping surface device is parallel to the machine direction aligning flakes, and the core former is perpendicular to the machine direction aligning flakes.The arrangement of thin slice realizes by a series of blades in the shaping position or roller.
The information that has shown sheet material in the table 7.PB-1 is to PB-11 BS1 resins, and PB12 is to PB14 BS1-SOK resins.
Table 6 shaving board information
Figure G2007800503757D00091
Table 7 oriented wood chipboard information
Figure G2007800503757D00092
The manufacturing of test medium-density fiberboard:
Use standard starting material: by the shred cork (mainly being dragon spruce) of Kronospan acquisition.
BS1 resin with 12% adds among the MDF (weight of the weight relatively dry fiber of resin solid).MC is respectively 8.26% and 16.23% before the blend and after the blend.
Use 220 ℃ target platen temperature and total compacting time pressed sheet of 10 minutes.
The preparation of the sample that is used to test
After the cooling every kind of sheet material is cut into the pattern of regulation, details is referring to Fig. 1.
Sample size (position 1-12) is 50mm * 50mm square, and position 13 and 14 sample width are 50mm.
For the inside bonding strength of every kind of sheet material, according to the thickness swell and the moisture absorption of EN317 test six ( positions 2,4,6,7,9 and 11) according to EN319 six samples of test ( position 1,3,5,8,10 and 12).According to two bending elastic modulus and the flexural strength of EN310 test from position 13 and 14.
Test
Inner bonding strength
Horizontal inner bonding strength.(be EN 319 and be EN 300) for OSB for PB.
Shui Fenxishou ﹠amp; Thickness swell
In water 20 ℃ of thickness swell (EN 317) after following 24 hours
In water 20 ℃ of moisture absorption after following 24 hours
Bending elastic modulus and flexural strength
Young's modulus (MOE), (EN 310)
Flexural strength (MOR)
The test-results of shaving board
Table 8 has been summed up the result of the inner bonding strength of shaving board (IB).
Fig. 2 and 3 has shown the influence of press time to IB.Can notice that PB-3 has shared identical processing (temperature and time) and IB changes to PB-9 in limit of error, so comprise 0.43N/mm among Fig. 2 with STD0.03 2Mean value.Fig. 2 and 3 shows that also the common requirement for IB from standard substance is 0.4N/mm 2
Clearly, suppressed among PB-1 and the PB-12 5 minutes resin because and inadequate press time and do not produce significant bonding strength, bonding strength is improved when being increased to 9 minutes the press time when (PB-2 and PB-13), for the PB with BS1 resin (PB-3 is to PB-9), in the time further will being increased to 10 minutes the press time, obtained to be higher than the bonding strength of standard value.But the sample with BS1-SOK resin system, IB (PB14) is lower than standard-required.
For the PB-10 that has wherein added wax, look that it does not have remarkable influence for IB.
For the PB-11 with resin loading capacity (higher by 2% than other sheet material) of 14%, its IB is 0.5N/mm 2This increase that shows the resin loading capacity will improve bonding strength.
The inside bonding strength of table 8 sheet material
Figure G2007800503757D00111
Figure 4 and 5 have been summed up the test-results of thickness swell and moisture absorption.
PB-8,9 processes under identical temperature and time with 10, and the difference between the PB-8,9 and 10 only is to have added wax, 0.8% wax in PB-10.
Do not having marked difference aspect thickness swell and the moisture absorption between PB-8 and the PB-9, thickness swell and the moisture absorption all height than standard-required are a lot, shown in solid line among Fig. 6.Added wax and obviously had marked difference, sample has minimum thickness swell and moisture absorption, its also substandard requirement.This shows that use wax helps to improve thickness swell and moisture absorption.
Bending elastic modulus and flexural strength
Only the sheet material (PB-8 and PB-9) of suppressing preparation in 10 minutes down at 220 ℃ Young's modulus and flexural strength have been tested.Mean value for MOE is 2314N/mm 2, it has 257.68 STD, and this is than the 1800N/mm of standard-required 2High a lot.This means that sheet material wants hard place many.Mean value for MOR is 10.4N/mm 2, this is than the 14N/mm that requires 2Low.In order to improve MOR to adapt to requirement, correct method can be the loading capacity that increases resin.
The result of oriented wood chipboard (OSB)
Fig. 6 has summed up the bonding result in inside of oriented wood chipboard, and solid line shows that requiring it for OSB standard (EN 300) is 0.28N/mm 2
IB always is lower than required value, in order to improve the bonding strength of the OSB sheet material with BS1 resin, should consider machined parameters and/or resin loading capacity.
Bending elastic modulus and flexural strength
The MOR of test panels OSB-2 and OSB-3 and MOE the results are summarized in the table 9.They are 18N/mm for standard-required 2And 2500N/mm 2Though IB is lower, OSB-2 and OSB-3 have than being used for desired higher MOR of general purposes sheet material and MOE.Not only bonding strength between fiber and the resin but also fiber size and orientation all help MOR and MOE.
Currency also is higher than for the 20N/mm that is used under dry and the wet condition 2And 3500N/mm 2The requirement of bearing plate, still, be lower than 28N/mm for heavy bearing plate 2And 4800N/mm 2Requirement.
MOR and the MOE result of table 9OSB
??MOR，N/mm 2 ??STD ??MOE，N/mm 2 ??STD
??OSB-2 ??26.47 ??4.11 ??4158.0 ??564.58
??OSB-3 ??24.89 ??2.42 ??3861.9 ??428.73
The result of intermediate density plate
Inner bonding strength
Only show an experiment of intermediate density plate.Press temperature is that 220 ℃ and press time are 10 minutes.The mean value of IB is 0.43N/mm 2, it has 0.03 STD, and this is higher than the 0.4N/mm of standard-required 2
Bending elastic modulus and flexural strength
Mean value for MOR is 22.26N/mm 2, it has 1.31 STD, and this is than the 14N/mm of standard-required 2High by 60%.Mean value for MOE is 2771.62N/mm 2, it has 204.17 STD, and this is than the 1800N/mm that requires 2High more than 50%.
That notice is 14N/mm 2And 1800N/mm 2It is requirement for the general purposes sheet material that under drying conditions, uses.For the bearing plate that uses under drying or wet condition, this requires to be 18N/mm 2And 2500N/mm 2, and 0.45N/mm 2IB.Though IB is lower slightly, current MOR and MOE value are higher than this requirement.But, adopt the optimization of processing, MDF must reach all for bearing plate or or even for the requirement of heavy bearing plate.
Discussion from the result of embodiment 2:
Press time and resin loading capacity play an important role in the IB with the shaving board of BS1 resins, and IB increases along with the increase of press time and resin loading capacity.But for the shaving board with the BS1-SOK resins, IB changes along with the increase of press time, and its also always substandard requirement.The optimization of expectation machined parameters is to bring improvement.
Thickness swell and moisture absorption have been improved, the substandard requirement of described value by in shaving board, adding wax.Optimization can bring improvement.
Oriented wood chipboard with the BS1 resins has the IB lower than standard-required, but has MOR and the MOE higher than standard-required.IB depends on the bonding strength between fiber and the matrix consumingly, and still, MOR and MOE will benefit from fiber size and orientation.
By using the BS1 resin, medium-density fiberboard has shown the mechanical properties higher than the requirement of general purposes sheet material, might reach the requirement that is used for bearing plate by optimizing processing.
Problem with oriented wood chipboard of BS1 resin is lower IB, and in order to improve this performance, correct working direction can be the loading capacity that increases resin.
Intermediate density sheet material with BS1 resin shows good performance, and the optimization of processing can be satisfied bearing plate or even the requirement of heavy bearing plate.
Although specific binding agent is used for embodiment, other binding agent binding agent particularly discussed below can be used for context of the present invention.
The discussion of binding agent:
Spendable solidified relevant with the present invention or uncured binding agent can comprise the combination of one or more or they in the following feature.In addition, material according to the invention can comprise the combination of one or more or they in the following feature.
Should be understood that at first this binding agent can be used for multiple manufacturing and use to produce or to promote the force of cohesion of the material aggregate of non-set or loose set.Aggregate comprises two or more components.Binding agent produces at least two kinds of components of aggregate or has promoted force of cohesion.For example, the theme binding agent can make the aggregate of material keep together, and makes material bonding to resist isolating mode.Binding agent described herein can be used for the manufacturing of any material.
A kind of potential of binding agent of the present invention is characterised in that they do not contain formaldehyde.Therefore, binding agent configuration material thereon also can be not contain formaldehyde.In addition, binding agent of the present invention is compared the Trimethylamine content that can have reduction with other known binding agent.Chemistry about binding agent of the present invention constitutes, and they can comprise ester and/or petchem.This binding agent can comprise that ester and/or petchem are together with vegetables oil soybean oil for example.In addition, this binding agent can comprise that ester and/or petchem are together with the organic acid sodium salt.This binding agent can comprise the sodium salt of mineral acid.This binding agent can also comprise organic acid sylvite.And this binding agent can comprise the sylvite of mineral acid.The binding agent of describing can comprise that ester and/or petchem are together with for example polynite of clay additive.
In addition, binding agent of the present invention can comprise the product of mailland reaction.For example, referring to Fig. 8.As shown in Figure 8, mailland reaction has produced melanoidin, i.e. high molecular, furan nucleus and nitrogenous polymkeric substance, and it depends on reactant and their preparation condition and different structures is arranged.Melanoidin shows the C along with the temperature and time increase of heating: N ratio, degree of unsaturation and chemical aromaticity.(referring to Ames, J.M.TheMaillard Browning Reaction-upgraded edition, Chemistry and Industry (GreatBritain), 1988,7,558-561, wherein disclosed content is incorporated the present invention by reference into).Therefore therefore, the theme binding agent can be by the mailland reaction manufacturing and is contained melanoidin.Should be understood that the theme binding agent can comprise melanoidin, perhaps other mailland reaction product, described product produces by independent method and adds to simply then in the composition that constitutes binding agent.Melanoidin in the binding agent can be water-insoluble.In addition, this binding agent can be a thermosetting adhesive.
The mailland reaction thing of preparation melanoidin can comprise the amine reactant with reducing sugar carbohydrate reactant reaction.For example, the ammonium salt of monomeric polycarboxylic acid can with the monose of (i) aldose or ketose form or (ii) polysaccharide or (iii) their composite reaction.In another kind distortion, the ammonium salt of polymkeric substance polycarboxylic acid can with the monose of (i) aldose or ketose form or (ii) polysaccharide, or (iii) their combination contact.In another distortion, amino acid can with the monose of (i) aldose or ketose form or (ii) polysaccharide, or (iii) their combination contact.In addition, peptide can with the monose of (i) aldose or ketose form or (ii) polysaccharide, or (iii) their combination contact.And, protein can with the monose of (i) aldose or ketose form or (ii) polysaccharide, or (iii) their combination contact.
It is to be further understood that binding agent can be included in the melanoidin for preparing in the non-sugared variant of mailland reaction.In these reactions, amine reactant contacts with non-carbohydrate carbonyl reaction thing.In an illustrative variant, the ammonium salt of monomeric polycarboxylic acid contacts with non-carbohydrate carbonyl reaction thing, pyruvic aldehyde for example, acetaldehyde, crotonic aldehyde, 2-furfural, quinone, xitix or analogue, or their combination.In another distortion, the ammonium salt of polymkeric substance polycarboxylic acid can contact with non-carbohydrate carbonyl reaction thing, pyruvic aldehyde for example, acetaldehyde, crotonic aldehyde, 2-furfural, quinone, xitix or analogue, or their combination.Also in another illustrative variant, amino acid can contact with non-carbohydrate carbonyl reaction thing, pyruvic aldehyde for example, acetaldehyde, crotonic aldehyde, 2-furfural, quinone, xitix or analogue, or their combination.In another illustrative variant, peptide can contact with non-carbohydrate carbonyl reaction thing, pyruvic aldehyde for example, acetaldehyde, crotonic aldehyde, 2-furfural, quinone, xitix or analogue, or their combination.Still in another illustrative variant, protein can contact with non-carbohydrate carbonyl reaction thing, pyruvic aldehyde for example, acetaldehyde, crotonic aldehyde, 2-furfural, quinone, xitix or analogue, or their combination.
Melanoidin discussed here can be generated by the melanoidin reactant compound.These reactant compounds are configured in the aqueous solution under the alkaline pH value and are not corrosive therefore.That is, basic solution stops or the corrosion or the wearing and tearing of the material (for example metal) that suppressed to be caused by the decomposition that for example acid brings.Reactant compound can comprise reducing sugar carbohydrate reactant and amine reactant.In addition, reactant compound can comprise non-carbohydrate carbonyl reaction thing and amine reactant.
It is to be further understood that binding agent described herein can be prepared by melanoidin reactant compound itself.That is, in case mixed the mailland reaction thing, this mixture can play the effect of binding agent of the present invention.These binding agents can be used to make uncured formaldehydeless material, for example fibrous material.
In scheme optionally, can solidify by the binding agent of the reactant manufacturing of mailland reaction.These binding agents can be used to make the formaldehydeless material of solidified, for example, and the fibering composition.These compositions are water-proof, as what point out above, comprise the water-insoluble protein melanocyte.
Should be understood that binding agent described herein can be used for manufacturing a product from the aggregate of the material of non-set or loose set.For example, these binding agents can be used to make fiber product.In an illustrative embodiment, binding agent can be used to prepare cellulose composition.About cellulose composition, binding agent can be used for the plain material of bondable fibers with Production Example as having the wood-fiber board of expectation physical properties (for example physical strength).
One embodiment of the invention relate to the method that a kind of aggregate of the material by non-set or loose set manufactures a product.This method can comprise makes fiber contact with heat-setting aqueous binders.This binding agent can comprise (i) polybasic carboxylic acid ammonium salt reactant and (ii) reducing sugar carbohydrate reactant.These two kinds of reactants are melanoidin reactant (that is, these reactants produce melanoidins when reacting under the condition that is causing mailland reaction).This method may further include from binding agent that fiber contacts remove moisture (that is, binding agent dewaters).This method can also comprise makes the adhesive cures (for example, making the binding agent thermofixation) that contacts with fiber.
Make embodiment in this way be the manufacturing cellulose materials.This method can comprise makes cellulose materials (for example, cellulosic fibre) contact with heat-setting, aqueous binders.This binding agent can comprise (i) polybasic carboxylic acid ammonium salt reactant and (ii) reducing sugar carbohydrate reactant.As already pointed out, these two kinds of reactants are melanoidin reactant compounds.This method can also comprise from binding agent that cellulose materials contacts remove moisture.As aforementioned, this method can also comprise makes adhesive cures (for example, thermofixation).
Described the fibering product, it comprises the binding agent that contacts with cellulosic fibre, for example those materials in the felt of wooden shavings or sawdust.Described felt can be processed to form one type or polytype wood-fiber board product.In a variant, binding agent is uncured.In this variant, uncured binding agent can be used for cellulosic fibre is kept together.In scheme optionally, the solidified binding agent can be used for cellulosic fibre is kept together.
As used herein, " formaldehydeless " this phrase represents as drying and/or solidified result, and binding agent or the material that combines binding agent discharge less than the about formaldehyde of 1ppm.This 1ppm is based on the weight that is used to measure the sample that formaldehyde discharges.
To such an extent as to solidifying the explanation binding agent has been exposed under the condition that causes chemical transformation.The example of these chemical transformation includes but not limited to (i) covalency keyed jointing, the (ii) hydrogen bonded of binder component, and the chemically crosslinked of polymkeric substance in binding agent and/or oligopolymer.Compare with uncured binding agent, these variations can increase the weather resistance and the solvent resistance of binding agent.Cured binders can cause forming thermosetting material.In addition, curing can comprise the generation of melanoidin.These melanoidins can be generated from the no compound of melanoidin reaction by mailland reaction.In addition, compare with uncured binding agent, the solidified binding agent can cause adherent increase between the material in the aggregate.Curing can be by for example heat, and electromagnetic radiation or electron beam cause.
Chemical transformation in binding agent causes in the situation that water discharges, for example polymerization and crosslinked, and curing can be measured by the water yield that only is higher than the release that is produced by drying.Be used to measure the water yield that discharges between dry epoch and be commonly known in the art than the technology of the water yield that discharges when the cured binders.
According to above paragraph, uncured binding agent is the binding agent that is not cured.
As used herein, term " alkalescence " expression has the solution more than or equal to about 7 pH value.For example, the pH value of solution can be less than or equal to about 10.In addition, solution can have about 7 to about 10 pH value, or about 8 to about 10, or about 9 to about 10.
As used herein, term " ammonium " includes but not limited to +NH 4, +NH 3R 1With +NH 2R 1R 2, R wherein 1And R 2Independently be selected from separately +NH 2R 1R 2, and R wherein 1And R 2Be selected from alkyl, cycloalkyl, thiazolinyl, cycloalkenyl group, heterocyclic radical, aryl and heteroaryl.
Term " alkyl " refers to the saturated unit price chain of carbon atom, and it can randomly be a branching; Term " cycloalkyl " refers to the unit price chain of carbon atom, and a part wherein forms ring; Term " thiazolinyl " refers to the unsaturated unit price chain of carbon atom that comprises at least one two key, and it can randomly be a branching; Term " cycloalkenyl group " refers to the unsaturated unit price chain of carbon atom, and a part wherein forms ring; Term " heterocyclic radical " refers to carbon atom and heteroatomic unit price chain, and wherein heteroatoms is selected from nitrogen, oxygen and sulphur, forms ring comprising at least one heteroatomic part; Term " aryl " refers to the aromatic monocyclic or the polycyclic ring of carbon atom, phenyl for example, naphthyl and similar group; And term " heteroaryl " refers to carbon atom and at least one is selected from the heteroatomic aromatic monocyclic or the polycyclic ring of nitrogen, oxygen and sulphur, for example pyridyl, pyrimidyl, indyl, benzoxazolyl and similar group.Be understandable that each group that can randomly independently be selected in alkyl, cycloalkyl, thiazolinyl, cycloalkenyl group and the heterocyclic radical (for example alkyl, haloalkyl, hydroxyalkyl, aminoalkyl group, carboxylic acid and its derivative, comprise ester, acid amides and nitrile, hydroxyl, alkoxyl group, acyloxy, amino, alkyl and dialkyl amido, amido, sulfo-and similar group, and their combination) replace.Can be understood that further that in aryl and the heteroaryl each can randomly be replaced by one or more substituting groups of independently selecting, halogen for example, hydroxyl; amino, alkyl or dialkyl group nitrogen base, alkoxyl group; alkyl sulphonyl, cyano group, nitro and similar group.
Just as used herein, term " polycarboxylic acid " expression di-carboxylic acid, tribasic carboxylic acid, quaternary carboxylic acid, five yuan of carboxylic acids and similar monomeric polycarboxylic acid, and acid anhydrides and their combination also have the polymkeric substance polycarboxylic acid, acid anhydrides, multipolymer and their combination.On the one hand, the polybasic carboxylic acid ammonium salt reactant is enough nonvolatile so that its maintenance can be obtained to be used for maximized with the carbohydrate reactant reaction of mailland reaction (following discussion).On the other hand, the polybasic carboxylic acid ammonium salt reactant can be replaced by other chemical functional group.Illustrative ground, monomeric polycarboxylic acid can be a di-carboxylic acid, includes but not limited to the unsaturated aliphatic di-carboxylic acid, the radical of saturated aliphatic di-carboxylic acid, aromatic dicarboxylate, unsaturated cyclic di-carboxylic acid, the saturated cyclic di-carboxylic acid, derivative and analogue that their hydroxyl replaces.Perhaps, illustrative ground, polycarboxylic acid (one or more) itself can be a tribasic carboxylic acid, include but not limited to the unsaturated aliphatic tribasic carboxylic acid, the radical of saturated aliphatic tribasic carboxylic acid, aromatics tribasic carboxylic acid, unsaturated cyclic tribasic carboxylic acid, the saturated cyclic tribasic carboxylic acid, derivative and analogue that their hydroxyl replaces.Be to be understood that any this polycarboxylic acid can be randomly to replace, for example use hydroxyl, halogen, alkyl, alkoxyl group and similar group replace.In a variant, polycarboxylic acid is the radical of saturated aliphatic tribasic carboxylic acid, citric acid.Other suitable polycarboxylic acid expection includes but not limited to equisetic acid, hexanodioic acid, nonane diacid, the BTCA dihydride, butane tricarboxylic acid, chlorendic acid, citraconic acid, Dicyclopentadiene (DCPD)-toxilic acid adducts, diethylene triaminepentaacetic acid(DTPA), the adducts of limonene and toxilic acid, ethylenediamine tetraacetic acid (EDTA) (EDTA), the rosin of maleinization fully, the ready denier oil acid of maleinization, fumaric acid, pentanedioic acid, m-phthalic acid, methylene-succinic acid is oxidized to alcohol with Potassium peroxide, the rosin of the maleinization of carboxylic acid then, toxilic acid, oxysuccinic acid, methylfumaric acid is by KOLBE-Schmidt reaction and dihydroxyphenyl propane or the Bisphenol F of carbon dioxide reaction with 3-4 carboxyl of introducing, oxalic acid, phthalic acid, sebacic acid, succsinic acid, tartrate, terephthalic acid, tetrabromophthalate, tetrachlorophthalic acid, tetrahydrophthalic acid, trimellitic acid, trimesic acid and analogue, and acid anhydrides and their combination.
Illustrative ground, polymkeric substance polycarboxylic acid can be acid, for example polyacrylic acid, polymethyl acrylic acid, polymaleic acid and similar polymkeric substance polycarboxylic acid, their multipolymer, their acid anhydrides and their mixture.Commercially available polyacrylic example comprises AQUASET-529 (Rohm ﹠amp; Haas, Philadelphia, PA, USA), CRITERION 2000 (Kemira, Helsinki, Finland, Europe), NF1 (H.B.Fuler, St.Paul, MN, USA) and SOKALAN (BASF, Ludwigshafen, Germany, Europe).About SOKALAN, it is the water-soluble polypropylene acid copolymer of a kind of vinylformic acid and toxilic acid, has about 4000 molecular weight.AQUASET-529 is a kind of comprising with the crosslinked polyacrylic composition of glycerol, and it also comprises sodium hypophosphite as catalyzer.CRITERION 2000 is the salifiable acidic solutions of a kind of polyacrylic acid part, has about 2000 molecular weight.About NF1, this is a kind of unitary multipolymer that comprises carboxylic functionality and hydroxy functionality and do not have functionality, and NF1 also comprises chain-transfer agent, for example sodium hypophosphite or organic phosphoric acid salt catalyst.
In addition, the composition that comprises the polymkeric substance polycarboxylic acid also expects and can be used for preparing binding agent described herein, U.S. patent Nos.5 for example, 318,990,5,661,213,6,136, those compositions of describing in 916 and 6,331,350, wherein disclosed content is incorporated the present invention by reference into.Especially, at U.S. patent Nos.5, in 318,990 and 6,331,350, the aqueous solution of a kind of polymkeric substance polycarboxylic acid, polyvalent alcohol and catalyzer has been described.
As U.S. patent Nos.5,318,990 and 6,331, described in 350, the polymkeric substance polycarboxylic acid comprises organic polymer or the oligopolymer that comprises more than a side extension carboxyl.This polymkeric substance polycarboxylic acid can be homopolymer or the multipolymer by the unsaturated carboxylic acid preparation, comprise but and the unnecessary vinylformic acid that is limited to, methacrylic acid, Ba Dousuan, iso-crotonic acid, toxilic acid, styracin, 2-methyl-maleic acid, methylene-succinic acid, 2-methyl methylene-succinic acid, α, β-methylene radical pentanedioic acid and analogue.Optionally, the polymkeric substance polycarboxylic acid can be prepared by unsaturated acid anhydride, comprise but and the unnecessary maleic anhydride that is limited to, itaconic anhydride, acrylic anhydride, methacrylic anhydride and analogue also have their mixture.The polymerization process of these acid and acid anhydrides is known in the chemical field.This polymkeric substance polycarboxylic acid can comprise the multipolymer of one or more aforementioned unsaturated carboxylic acids or acid anhydrides and one or more vinyl compounds extraly, comprise but and the unnecessary vinylbenzene that is limited to, alpha-methyl styrene, vinyl cyanide, methacrylonitrile, methyl acrylate, ethyl propenoate, n-butyl acrylate, isobutyl acrylate, methyl methacrylate, n-BMA, Propenoic acid, 2-methyl, isobutyl ester, glycidyl methacrylate, vinyl methyl ether, vinyl-acetic ester and analogue.The method for preparing these multipolymers is commonly known in the art.This polymkeric substance polycarboxylic acid can comprise polyacrylic homopolymer and multipolymer.The molecular weight of this polymkeric substance polycarboxylic acid, particularly acrylic acid polymer can less than 5000, perhaps be approximately 3000 or littler less than 10000.For example, its molecular weight can be 2000.
As U.S. patent Nos.5,318,990 and 6,331, described in 350, polyvalent alcohol (in the composition that comprises the polymkeric substance polycarboxylic acid) comprises at least two hydroxyls.This polyvalent alcohol should be enough nonvolatile, makes it will keep basically obtaining being used for during heating and curing operation reacting with the polymkeric substance polycarboxylic acid of composition.This polyvalent alcohol can be the molecular weight that has at least two hydroxyls less than about 1000 compound, ethylene glycol for example, glycerol, tetramethylolmethane, TriMethylolPropane(TMP), sorbyl alcohol, sucrose, glucose, Resorcinol, catechol, pyrogallol, oxyacetic acid urea, 1, the 4-cyclohexane diol, diethanolamine, trolamine and some reactive polyvalent alcohol, for example, beta-hydroxy alkylamide, two [N, N-two (beta-hydroxyethyl)] adipamides are for example arranged for instance, and perhaps it can be the addition polymer that contains at least two hydroxyls, polyvinyl alcohol for example, the polyvinyl acetate of partial hydrolysis and hydroxyethyl (methyl) acrylate, the homopolymer of hydroxypropyl (methyl) acrylate or multipolymer and similar material.
As U.S. patent Nos.5,318,990 and 6,331, described in 350, catalyzer (in the composition that comprises the polymkeric substance polycarboxylic acid) is for can being molecular weight less than the phosphorus accelerator of about 1000 compound, for example, alkali metal polyphosphates, basic metal dihydrogen orthophosphate, Tripyrophosphoric acid and alkyl Hypophosporous Acid, 50, perhaps it can be oligopolymer or the polymkeric substance that has phosphorus-containing groups, the addition polymer that in the presence of sodium hypophosphite, forms of vinylformic acid and/or toxilic acid for example, the addition polymer that in the presence of microcosmic salt chain-transfer agent or terminator, prepares by ethylenically unsaturated monomer, and the addition polymer that contains the acid functional monomers residue, for example, the phosphoethyl methacrylic ester of copolymerization, and similar phosphonic acid ester, the vinyl sulfonic acid monomer of copolymerization and their salt.Based on the gross weight of polymkeric substance polycarboxylic acid and polyvalent alcohol, phosphorus accelerator can be used under the level of about 40% weight about 1%.Based on the gross weight of polymkeric substance polycarboxylic acid and polyvalent alcohol, can use about 2.5% phosphorus accelerator to about 10% weight level.The example of this catalyzer includes but not limited to sodium hypophosphite, sodium phosphite, potassium phosphite, disodium pyrophosphate, tetrasodium pyrophosphate, tripoly phosphate sodium STPP, Sodium hexametaphosphate 99, potassiumphosphate, Potassium polymetaphosphate, potassium polyphosphate, Potassium tripolyphosphate, Trisodium trimetaphosphate and four sodium-metaphosphates and their mixture.U.S. patent Nos.5,661,213 and 6,136, the composition that comprises the polymkeric substance polycarboxylic acid that the expection of describing in 916 is used to prepare binding agent described herein comprises the polymkeric substance polycarboxylic acid, comprises the polyvalent alcohol of at least two hydroxyls and the aqueous solution of phosphorus accelerator, and wherein the equivalents of hydroxy-acid group is about 1: 0.01 to about 1: 3 with the ratio of the equivalents of hydroxyl.
As U.S. patent Nos.5, disclosed in 661,213 and 6,136,916, the polymkeric substance polycarboxylic acid can be carboxylic acid functionalized monomeric addition polymer or the oligopolymer that contains the polyester of at least two hydroxy-acid groups or contain at least two kinds of copolymerization.The polymkeric substance polycarboxylic acid is preferably the addition polymer that is formed by at least a ethylenically unsaturated monomer.Addition polymer can be the solution form of addition polymer in water-bearing media, for example is dissolved in the alkali soluble resins of alkaline medium; The form of aqueous dispersion, for example, the dispersion of letex polymerization; Or the form of aqueous suspension.Addition polymer must contain at least two hydroxy-acid groups, anhydride group or their salt.Ethylenically unsaturated carboxylic acids, methacrylic acid for example, vinylformic acid, Ba Dousuan, fumaric acid, toxilic acid, 2-methyl-maleic acid, methylene-succinic acid, 2-methyl methylene-succinic acid, α, β-methylene radical pentanedioic acid, monoalkyl maleic acid ester and fumaric acid mono alkyl ester; The ethylenic unsaturated acid acid anhydride, for example, maleic anhydride, itaconic anhydride, acrylic anhydride and methacrylic anhydride, and their salt, based on the weight of addition polymer, operable level is about 1% to 100%.Other ethylenically unsaturated monomer can comprise acrylate monomer, comprise methyl acrylate, ethyl propenoate, butyl acrylate, 2-EHA, decyl acrylate, methyl methacrylate, butyl methacrylate, isodecyl methacrylate, hydroxyethyl acrylate, methacrylic acid hydroxyethyl ester and hydroxypropyl methacrylate; The acrylamide of acrylamide or replacement; The vinylbenzene of vinylbenzene or replacement; Divinyl; Vinyl-acetic ester or other vinyl ester; Vinyl cyanide or methacrylonitrile and analogue.The addition polymer that comprises at least two hydroxy-acid groups, anhydride group or their salt can have about 300 to about molecular weight of 10,000,000.Also can use about 1000 to about 250,000 molecular weight.When addition polymer is when having the alkali soluble resins of carboxylic acid, acid anhydrides or their salt, based on the gross weight of addition polymer, can use about 5% to about 30% content, and about 10,000 to about 100,000 molecular weight.The method for preparing these addition polymers is commonly known in the art.
As U.S. patent Nos.5,661,213 and 6,136, describe in 916, polyvalent alcohol (in the composition that comprises the polymkeric substance polycarboxylic acid) comprises at least two hydroxyls and should be enough nonvolatile, makes it keep basically obtaining being used for during heating and curing operation reacting with the polymkeric substance polycarboxylic acid of composition.This polyvalent alcohol can be the molecular weight that has at least two hydroxyls less than about 1000 compound, ethylene glycol for example, glycerol, tetramethylolmethane, TriMethylolPropane(TMP), sorbyl alcohol, sucrose, glucose, Resorcinol, catechol, pyrogallol, oxyacetic acid urea, 1,4-cyclohexane diol, diethanolamine, trolamine and some reactive polyvalent alcohol, for example, beta-hydroxy alkylamide, for example, two [N, N-two (beta-hydroxyethyl)] adipamide, two [N, N-two (β-hydroxypropyl)] azelaoyl amine, two [N, N-two (β-hydroxypropyl)] adipamide, two [N, N-two (β-hydroxypropyl)] glutaramide, two [N, N-two (β-hydroxypropyl)] succinic diamide and two [N-methyl-N-(beta-hydroxyethyl)] oxamide, perhaps it can be the addition polymer that contains at least two hydroxyls, polyvinyl alcohol for example, the polyvinyl acetate of partial hydrolysis and hydroxyethyl (methyl) acrylate, the homopolymer of hydroxypropyl (methyl) acrylate or multipolymer and similar material.
As U.S. patent Nos.5,661,213 and 6,136, describe in 916, phosphorus accelerator (in the composition that comprises the polymkeric substance polycarboxylic acid) can be a molecular weight less than about 1000 compound, alkalt metal hypophophite for example, basic metal phosphite, alkali metal polyphosphates, the basic metal dihydrogen orthophosphate, Tripyrophosphoric acid and alkyl Hypophosporous Acid, 50, perhaps it can be oligopolymer or the polymkeric substance that has phosphorus-containing groups, for example the addition polymer that forms in the presence of sodium hypophosphite of vinylformic acid and/or toxilic acid, the addition polymer that in the presence of microcosmic salt chain-transfer agent or terminator, prepares by ethylenically unsaturated monomer, and the addition polymer that contains the acid functional monomers residue, for example, the phosphoethyl methacrylic ester of copolymerization, and similar phosphonic acid ester, the vinyl sulfonic acid monomer of copolymerization and their salt.Based on the gross weight of polyprotonic acid and polyvalent alcohol, phosphorus accelerator can be used under the level of about 40% weight about 1%.Based on the gross weight of polyprotonic acid and polyvalent alcohol, can use about 2.5% phosphorus accelerator to about 10% weight level.
As used herein, term " amine alkali " includes but not limited to ammonia, primary amine, i.e. NH 2R 1, and secondary amine, i.e. NHR 1R 2, R wherein 1And R 2Separately independently at NHR 1R 2In select and R wherein 1And R 2Be selected from alkyl, cycloalkyl, thiazolinyl, cycloalkenyl group, heterocyclic radical, aryl and heteroaryl, just as herein defined.Illustrative ground, amine alkali is being enough to promote hot setting adhesive to be volatile basically or to be nonvolatile basically under the condition that forms during the thermofixation.Illustrative ground, amine alkali can be volatile alkali basically, for example, ammonia, ethamine, diethylamine, dimethylamine and ethyl propyl amine.Optionally, amine alkali can be non-volatile alkali basically, aniline for example, naphthalidine, 2-naphthylamines and p-aminophenol.
As used herein, reducing sugar represents that one or more contain the sugar of aldehyde radical, perhaps can be isomerized, and is promptly tautomeric, so that comprise aldehyde radical, described group reacts with amino under the mailland reaction condition, and described group can be used for example Cu + 2Oxidation is to provide carboxylic acid.It is to be further understood that any this carbohydrate reactant can randomly replace, for example with hydroxyl, halogen, alkyl, alkoxyl group and similarly group replacement.What further will also be understood that is in any this carbohydrate reactant, has one or more chiral centres, and two kinds of possible optical isomers that are expected at each chiral centre place are included among the present invention described here.In addition, it is to be further understood that different mixtures, comprise racemic mixture, or other non-corresponding isomer mixture of the different optical isomer of any this carbohydrate reactant, and their different geometrical isomers may be used in one or several embodiment described herein.
Fig. 7 represents to be used for the example of the reactant of mailland reaction.The example of amine reactant comprises protein, peptide, amino acid, the ammonium salt of polymkeric substance polycarboxylic acid and the ammonium salt of monomeric polycarboxylic acid.As shown in the figure, ammonium can be [ +NH 4] x, [ +NH 3R 1] x[ +NH 2R 1R 2] x, wherein x is about at least 1.For +NH 2R 1R 2, R 1And R 2Select independently of one another.In addition, R 1And R 2Be selected from alkyl, cycloalkyl, thiazolinyl, cycloalkenyl group, heterocyclic radical, aryl and heteroaryl, just as described above.Fig. 1 also for example understands the example of the reducing sugar reaction thing be used to prepare melanoidin, comprises monose, polysaccharide or their combination of aldose or ketose form.The non-carbohydrate carbonyl reaction thing that is used to illustrative to prepare melanoidin and comprises different aldehyde also as shown in fig. 1, for example pyruvic aldehyde and furfural, and the compound of xitix and quinone for example.
Fig. 8 has shown the synoptic diagram of mailland reaction, and it culminates in the preparation of melanoidin.In its starting stage, mailland reaction relates to the carbohydrate reactant, for example, and reducing sugar (note carbohydrate reactant can from the material that can under the mailland reaction condition, produce reducing sugar).This reaction also comprises condensation carbohydrate reactant (for example reducing sugar) and amine reactant, promptly has amino compound.In other words, carbohydrate reactant and amine reactant are the melanoidin reactants that is used for mailland reaction.The condensation of these two kinds of compositions has produced the glycosylamine that N-replaces.For the more detailed description mailland reaction, referring to Hodge, J.E.Chemistry of Browning Reactions in Model Systems J.Agric.Food Chem.1953,1,928-943, wherein disclosed content is incorporated the present invention by reference into.The compound that has free amine group in mailland reaction can exist with amino acid whose form.Free amine group can also be from protein, wherein free amino for example the form of the epsilon-amino of the alpha-amino group of lysine residue and/or end amino acid obtain.
Described hereinly carry out being on the other hand of mailland reaction, initial, just as described above, the mailland reaction thing aqueous solution (it also is binding agent) has the alkaline pH value.But, in case with this solution allocation on the aggregate of the material of non-set or loose set, and cause to solidify, this pH value is decline (that is, binding agent becomes tart) just.Should be understood that when manufactured materials, compare that the amount that contacts between the mechanical component of (that is, when binder solution is alkalescence) binding agent and use in the mill is bigger before curing with (that is, when binding agent is acidity) after the adhesive cures.Alkaline compositions is littler than the corrodibility of acidic composition.Therefore, the corrodibility of manufacturing processed reduces.
Should be understood that by using the mailland reaction thing aqueous solution described herein the machinery that is used for making glass fibre is not exposed to acidic solution, because just as described above, the pH value of mailland reaction thing solution is alkaline.In addition, during manufacture, only produce acidic conditions in the time after binding agent is put on fiber.In case binding agent is put on fiber, to compare with the time before binding agent being put on fiber, binding agent relatively less contacts with mechanical component with the material that combines binding agent.Therefore, the corrodibility of making glass fibre (and manufacturing of other material) reduces.
Not bound by theory, the covalent reaction of the polybasic carboxylic acid ammonium salt of mailland reaction and reducing sugar reaction thing (this reaction is as described herein to be taken place in curing process basically with the brown polymer with nitrogen that produces different structure and the melanoidin of multipolymer) is believed to comprise the initial mailland reaction of aldehyde structure part of ammonia and reducing sugar carbohydrate reactant so that N-to be provided the glycosylamine of replacement, as shown in Figure 8.Ammonia so consumes (wherein ammonia and reducing sugar carbohydrate reactant binding substances play latent acid catalyst) and causes the pH value to reduce expection, and this reduction thinks that the esterification process that promoted polycarboxylic acid and/or dehydration are to provide its corresponding anhydride ester derivs.In pH value＜7 o'clock, the Amadori rearrangement product of the glycosylamine that N-replaces, promptly 1-amino-1-deoxidation-2-ketose will expect and mainly be experienced 1, the 2-enolization, the prelude that produces as melanoidin is when for example, form furfural when relating to pentose, or ought for example form hydroxymethylfurfural when relating to hexose.With the generation of melanoidin concurrently, side by side or sequentially, can relate to the esterification process of melanoidin, polycarboxylic acid and/or its corresponding anhydride ester derivs and residual carbon hydrate, this process causes crosslinked widely.Follow sugared dehydration reaction, can experience the polymeric conjugated double bond so produce, produce the water-fast thermosetting adhesive of being made up of the polyester adducts, this polyester adducts is by the single bonded network interworking of carbon-to-carbon.Consistent with above-mentioned reaction, the 1734cm in the FT-IR of cured binders described herein spectrogram -1Near the generation absorbs by force, and this is absorbed in the 1750-1730cm that is expected to be ester carbonyl group C-O vibration -1Scope within.
Below discuss the example relate to (i) carbohydrate and amine reactant, they can be used for mailland reaction and (ii) how with these reactant combinations.At first, should be appreciated that and to serve as any carbohydrate of the reactant in the mailland reaction and/or to have uncle or the compound of secondary amino group can be used for binding agent of the present invention.This compounds can adopt criterion disclosed herein to determine and use by those of ordinary skills.
As for exemplary reactant, it will also be appreciated that the ammonium salt that uses polycarboxylic acid is an effecting reaction thing in the mailland reaction as amine reactant.The ammonium salt of polycarboxylic acid can produce with acidic group by using in the amine alkali, thereby produces the polybasic carboxylic acid ammonium salt group.Neutralization completely (that is, based on equivalent calculate about 100%) can get rid of before binding agent forms any with acidic group titration in the polycarboxylic acid (one or more) or part neutral needs.Yet, can be contemplated that to be lower than the formation that neutralization fully can not suppress binding agent.Should point out, with in the acidic group of polycarboxylic acid (one or more) and can polycarboxylic acid (one or more) with carry out before or after carbohydrate (one or more) mixes.
As for the carbohydrate reactant, it can comprise one or more reactants that contain one or more reducing sugars.In one aspect, any carbohydrate reactant should be enough nonvolatile so that its maintenance can obtain to be used for the maximized of reacting with the polybasic carboxylic acid ammonium salt reactant.This carbohydrate reactant can be the monose that is its aldose or ketose form, comprises triose, tetrose, pentose, hexose or heptose; Or polysaccharide; Or their binding substances.The carbohydrate reactant can be a reducing sugar, or can produce the reactant of one or more reducing sugars under the thermofixation condition on the spot.For example, when triose serves as the carbohydrate reactant, or when being used in combination, aldotriose or acetone sugar be can use, Glycerose and otan for example are respectively with other reducing sugar and/or polysaccharide.When tetrose serves as the carbohydrate reactant, or when being used in combination, can use aldotetrose, for example erythrose and threose with other reducing sugar and/or polysaccharide; And ketotetrose, as erythrulose.When pentose serves as the carbohydrate reactant, or when being used in combination, can use aldopentose, as ribose, pectinose, wood sugar and lyxose with other reducing sugar and/or polysaccharide; And ketopentose, as ribulose, arabulose, xylulose and lyxulose.When hexose serves as the carbohydrate reactant, or when being used in combination, can use aldohexose, as glucose (that is dextrose), seminose, semi-lactosi, allose, altrose, talose, gulose and idose with other reducing sugar and/or polysaccharide; And tagatose, as fructose, psicose, sorbose and tagatose.When heptose serves as the carbohydrate reactant, or when being used in combination, can use ketoheptose such as sedoheptulose with other reducing sugar and/or polysaccharide.Even also thinking, unknown naturally occurring other steric isomer of this type of carbohydrate reactant can be used for preparing adhesive composition described here.When polysaccharide serves as carbohydrate, or when being used in combination, can use sucrose, lactose, maltose, starch and Mierocrystalline cellulose with monose.
In addition, the carbohydrate reactant in the mailland reaction can be used in combination with non-carbohydrate is polyhydroxy reactant.Can include but not limited to the polyvinyl acetate of TriMethylolPropane(TMP), glycerine, tetramethylolmethane, polyvinyl alcohol, partial hydrolysis, the polyvinyl acetate of complete hydrolysis and their mixture with the polyhydroxy reactant example of the non-carbohydrate that described carbohydrate reactant is used in combination.In one aspect, this non-carbohydrate is polyhydroxy reactant to be enough nonvolatile so that its reservation can obtain to be used for the maximized of reacting with monomer or polymkeric substance polycarboxylic acid reactant.Should understand, the polyhydroxy reactant hydrophobicity of non-carbohydrate can be to determine as a factor of the physicals of the binding agent of said preparation.
When the polyvinyl acetate of partial hydrolysis serves as non-carbohydrate when polyhydroxy reactant, can use the polyvinyl acetate of commercially available compound such as 87-89% hydrolysis, as DuPont ELVANOL 51-05.It is about 22 that DuPont ELVANOL 51-05 has, 000-26, the molecular weight of 000Da and the about viscosity of 5.0-6.0 centipoise.Think that the polyvinyl acetate of the other parts hydrolysis that can be used for preparing adhesive composition described here includes but not limited to, the polyvinyl acetate of the 87-89% hydrolysis that molecular weight is different with ELVANOL 51-05 with viscosity is as DuPont ELVANOL 51-04, ELVANOL 51-08, ELVANOL 50-14, ELVANOL 52-22, ELVANOL 50-26, ELVANOL 50-42; With the polyvinyl acetate of molecular weight, viscosity and/or degree of hydrolysis and the hydrolysis of ELVANOL 51-05 distinct portions, for example DuPont ELVANOL51-03 (86-89% hydrolysis), ELVANOL 70-14 (95.0-97.0% hydrolysis), ELVANOL70-27 (95.5-96.5% hydrolysis), ELVANOL 60-30 (90-93% hydrolysis).Think that the polyvinyl acetate of the other parts hydrolysis that can be used for preparing adhesive composition described here includes but not limited to, Clariant MOWIOL 15-79, MOWIOL 3-83, MOWIOL 4-88, MOWIOL 5-88, MOWIOL 8-88, MOWIOL 18-88, MOWIOL 23-88, MOWIOL 26-88, MOWIOL 40-88, MOWIOL 47-88 and MOWIOL 30-92, and Celanese CELVOL 203, CELVOL 205, CELVOL 502, CELVOL504, CELVOL 513, CELVOL 523, CELVOL 523TV, CELVOL 530, CELVOL 540, CELVOL540TV, CELVOL 418, CELVOL 425 and CELVOL 443.Also thinking usefully can be from the similar or similar partial hydrolysis polyvinyl acetate of other commercial supplier acquisition.
When the polyvinyl acetate of complete hydrolysis serves as non-carbohydrate when polyhydroxy reactant, it is about 27 can using molecular weight, the Clariant MOWIOL 4-98 of 000Da.Think that the polyvinyl acetate of useful other complete hydrolysis includes but not limited to, DuPont ELVANOL 70-03 (98.0-98.8% hydrolysis), ELVANOL 70-04 (98.0-98.8% hydrolysis), ELVANOL 70-06 (98.5-99.2% hydrolysis), ELVANOL90-50 (99.0-99.8% hydrolysis), ELVANOL 70-20 (98.5-99.2% hydrolysis), ELVANOL70-30 (98.5-99.2% hydrolysis), ELVANOL 71-30 (99.0-99.8% hydrolysis), ELVANOL70-62 (98.4-99.8% hydrolysis), ELVANOL 70-63 (98.5-99.2% hydrolysis), ELVANOL70-75 (98.5-99.2% hydrolysis), Clariant MOWIOL 3-98, MOWIOL 6-98, MOWIOL 10-98, MOWIOL 20-98, MOWIOL 56-98, MOWIOL 28-99 and Celanese CELVOL 103, CELVOL107, CELVOL 305, CELVOL 310, CELVOL 325, CELVOL 325LA and CELVOL 350, and the similar or similar complete hydrolysis polyvinyl acetate that derives from other commercial supplier.
Above-mentioned mailland reaction thing can be in conjunction with preparing the aqueous composition that comprises carbohydrate reactant and amine reactant.These aqueous binders are represented the example of uncured adhesive.As discussed below, these aqueous compositions can be used as binding agent of the present invention.These binding agents are formaldehydeless, curable, alkaline, aqueous binders compositions.In addition, as noted before, the carbohydrate reactant of mailland reaction thing can be used in combination with non-carbohydrate is polyhydroxy reactant.Therefore, whenever mention the carbohydrate reactant, be to be understood that it can be used in combination with non-carbohydrate is polyhydroxy reactant.
In an exemplary embodiment, the aqueous solution of mailland reaction thing can comprise the ammonium salt reactant of (i) one or more polycarboxylic acids and (ii) contain one or more carbohydrate reactants of reducing sugar.Allow it with treat that matrix material contacts before, the pH value of this solution can be more than or equal to about 7.In addition, this solution can have and is less than or equal to about 10 pH value.The ratio of the mole number of the mole number of polycarboxylic acid reactant (one or more) and carbohydrate reactant (one or more) can be about 1: about 1: 15 of 4-.In an example, the ratio of the mole number of the mole number of the polycarboxylic acid reactant (one or more) in the adhesive composition and carbohydrate reactant (one or more) is about 1: 5.In another example, the ratio of the mole number of the mole number of polycarboxylic acid reactant (one or more) and carbohydrate reactant (one or more) is about 1: 6.In another example, the ratio of the mole number of the mole number of polycarboxylic acid reactant (one or more) and carbohydrate reactant (one or more) is about 1: 7.
As mentioned above, the aqueous binders composition comprises the ammonium salt reactant of (i) one or more polycarboxylic acids and (ii) contains one or more carbon aquation combination reactants of reducing sugar.It should be understood that the molar equivalent of ammonium ion can equal maybe can be not equal to the molar equivalent of the acid salt group (acid salt group) that exists on the polycarboxylic acid when the ammonium salt of monomer or polymkeric substance polycarboxylic acid is used as amine reactant.In an exemplary example, when tribasic carboxylic acid was used as the polycarboxylic acid reactant, ammonium salt can be that a replacement (monobasic), two replaces (dibasic) or three replacements (tribasic).Therefore, the molar equivalent of ammonium ion can by less than or the amount that is substantially equal to the molar equivalent of the acid salt group that exists in the polycarboxylic acid exist.Therefore, when the polycarboxylic acid reactant was di-carboxylic acid, this salt can be a replacement or dibasic.In addition, the molar equivalent of ammonium ion can by less than or the amount that is substantially equal to the molar equivalent of the acid salt group that exists in the polymkeric substance polycarboxylic acid exist, or the like.When using the primary salt of di-carboxylic acid, maybe when using the dibasic salt of tribasic carboxylic acid, or when the molar equivalent of ammonium ion existed by the amount of the molar equivalent of the acid salt group that exists in less than the polymkeric substance polycarboxylic acid, the pH value of adhesive composition can require to be adjusted to and reach alkalescence.
Described uncured, formaldehydeless, thermal curable, alkalescence, aqueous binders composition can be used for making many different materials.Specifically, contact, can use described binding agent in the material of non-set or loose set, to produce or promote force of cohesion by these binding agents are placed with treating the agglutinating material.Many technology of knowing can be used for this aqueous binders placed with treating the agglutinating material and contact.For example, can be via roller coating device with this aqueous binders spraying (for example in adhesive glass fiber process) or apply.Can in the preparation process of fiber insulation product, these aqueous binders be applied on the felt of glass fibre (for example, spraying on this felt).In case allow this aqueous binders contact with glass fibre, residual heat from this glass fibre (should be pointed out, therefore this glass fibre is made by melten glass and is comprised residual heat) and the airflow that passes this fibrefelt will make water from binding agent, evaporate (that is, removing).Water is removed the remaining ingredient that makes binding agent to be stayed on the fiber as the coating protection of viscosity or half viscosity high solid liquid.The coating of this viscosity or half viscosity high solid liquid plays the binding agent effect.At this moment, this fibrefelt also is not cured.In other words, this uncured binding agent glass fibre in this felt that is used for boning.
In addition, should be appreciated that and above-described aqueous binders can be solidified.For example, any above-described aqueous binders can dispose (for example, spraying) and treat on the agglutinating material, heating then.For example, under the situation of preparation fiber insulation product, after being applied to aqueous binders on the fibrefelt, the fibrefelt of this adhesive coated is transferred in the curing oven.In this curing oven, this felt is heated (for example, about 300 °F-about 600 °F) and solidifies this binding agent.This solidified binding agent is formaldehydeless, the water tolerance hot setting adhesive that the glass fibre with this felt bonds together.Should point out, can carry out drying and thermofixation sequentially, side by side or concurrently.
As for making the water-insoluble binding agent, when solidified, it should be understood that the molar equivalent number of the acid salt group that polycarboxylic acid reactant (one or more) upward exists and the ratio that carbohydrate reactant (one or more) is gone up the molar equivalent number of the hydroxyl that exists can be about 0.04: about 0.15: 1 of 1-.After curing, these preparatons produce the water tolerance thermosetting adhesive.In a variant, the molar equivalent number of the hydroxyl that carbohydrate reactant (one or more) go up to exist is about 25 times of polycarboxylic acid reactant (one or more) the molar equivalent number of going up the acid salt group that exists.In another variant, the molar equivalent number of the hydroxyl that carbohydrate reactant (one or more) go up to exist is about ten times of polycarboxylic acid reactant (one or more) the molar equivalent number of going up the acid salt group that exists.In another variant, the molar equivalent number of the hydroxyl that carbohydrate reactant (one or more) go up to exist is about six times of polycarboxylic acid reactant (one or more) the molar equivalent number of going up the acid salt group that exists.
In other embodiments of the present invention, the binding agent that has cured can be configured in to be treated on the agglutinating material.As noted before, most of solidified binding agents will comprise the water-insoluble protein melanocyte usually.Therefore, these binding agents also will be water-proof thermosetting adhesives.
As discussed below, various additives can be introduced in the adhesive composition.These additives are given additional desirable characteristic for binding agent of the present invention.For example, binding agent can comprise and contains silicone couplet.Many silicone couplets that contain can be from Dow-Corning Corporation, and Petrarch Systems is purchased and is purchased by General Electric Company.Exemplarily, contain silicone couplet and comprise compound for example silyl ether (silyl ether) and alkyl silyl ether (alkylsilyl ether), each in them can randomly replace, for example by replacements such as halogen, alkoxyl group, amino.In a variant, this silicon-containing compound is the silane of amino-replacement, for example γ-An Bingjisanyiyangjiguiwan (GeneralElectric Silicones, SILQUEST A-1101; Wilton, CT; USA).In another variant, silicon-containing compound is the silane of amino-replacement, for example, and aminoethyl aminopropyl trimethoxysilane (Dow Z-6020; Dow Chemical, Midland, MI; USA).In another variant, silicon-containing compound is γ-glycidoxypropyltrimewasxysilane (General Electric Silicones, SILQUEST A-187).In another variant, silicon-containing compound is n-propyl amine silane (Creanova (being HulsAmerica in the past) HYDROSIL 2627; Creanova; Somerset, NJ.; U.S.A.).
Based on dissolved binding agent solid, the described silicone couplet that contains is present in this binding agent (that is, based on the solid weight of adding in the aqueous solution, about 0.1%-about 1%) by the about 1wt% of about 0.1wt%-usually.In an application, in these silicon-containing compounds one or more can be added in the moisture uncured binding agent.Then this binding agent is applied to and treats on the agglutinating material.Afterwards, if necessary, can be with adhesive cures.These compounds that contain siloxanes have improved the ability that this binding agent adheres to the material (for example glass fibre) that disposes this binding agent thereon.For example, improving ability that this binding agent adheres to this material has improved it produced or promoted the ability of force of cohesion in the material (one or more) of non-set or loose set.
Comprise that the binding agent that contains the siloxanes coupling agent can be prepared as follows: the aqueous solution of the aqueous solution (with neutralization of amine alkali or neutralization on the spot) of the about 50wt% of about 10-of one or more polycarboxylic acid reactants and about 10-50wt% of one or more carbohydrate reactants that contain reducing sugar and significant quantity are contained silicone couplet mix.In a variant, one or more polycarboxylic acid reactants and one or more carbohydrate reactants (latter is contained reducing sugar) can be used as solid bond, mix with water, use aqueous amine alkali (with one or more polycarboxylic acid reactants that neutralize) and this mixture of siliceous coupling agent treatment aqueous solution then with the 10-50wt% that produces each polycarboxylic acid reactant and each carbohydrate reactant.
In another exemplary embodiment, binding agent of the present invention can comprise one or more inhibiter.These inhibiter stop or have suppressed by the caused material of decomposition such as corrosion of metal or wearing and tearing, and this decomposition is caused by acid.When inhibiter is included in the binding agent of the present invention, do not compare with wherein there not being the corrodibility of the binding agent of inhibiter, reduced the corrodibility of this binding agent.In one embodiment, these inhibiter can be used for reducing the corrodibility that contains the composition of glass fibre described herein.Exemplarily, inhibiter comprises one or more in the following material: dedusting oil, or monoammonium phosphate, Starso pentahydrate, melamine, tin oxalate (II) and/or methyl hydrogen-containing siloxane fluid emulsion (methylhydrogen siliconefluid emulsion).In the time of in being included in binding agent of the present invention, based on dissolved binding agent solid, inhibiter is present in this binding agent by the about 2wt% of about 0.5wt%-usually.
By following disclosed criterion, those of ordinary skills can change the concentration of reactants of aqueous binders to prepare various adhesive compositions.Specifically, the aqueous binders composition can have the alkaline pH value through preparation.For example, the pH value is to being less than or equal to about 10 more than or equal to about 7.The example of the binding agent reactant that can be controlled comprises (i) polycarboxylic acid reactant (one or more), (ii) amine alkali, and (iii) carbohydrate reactant (one or more) (iv) contains silicone couplet and (V) corrosion inhibitor compound.Allow the pH value of aqueous binders of the present invention (for example uncured binding agent) in alkaline range, suppress the material that contacts with this binding agent, for example the corrosion of the machine that uses in the manufacture method (for example, in making glass fibre).Should point out that when the corrodibility of acid binding agent was compared with binding agent of the present invention, situation was especially true.Therefore, " time limit of service " of mechanical means increases, and the maintenance cost of these machines reduces simultaneously.In addition, standard equipment can use with binding agent of the present invention, rather than the machine component than erosion resistance that must use will contact with acid binding agent, for example stainless steel assembly.Therefore, binding agent disclosed herein has reduced the manufacturing cost of institute's matrix material.

Claims (20)

1. composite wood board that comprises wood particle and organic binder bond.
2. according to the composite wood board of claim 1, wherein the essentially no formaldehyde of this binding agent is preferably formaldehydeless.
3. according to the composite wood board of aforementioned each claim, wherein this plate has 1800N/mm at least 2Young's modulus (MOE).
4. according to the composite wood board of aforementioned each claim, wherein this plate has 2500N/mm at least 2Young's modulus (ME).
5. according to the composite wood board of aforementioned each claim, wherein this plate has 14N/mm at least 2Flexural strength (MOR).
6. according to the composite wood board of aforementioned each claim, wherein this plate has 18N/mm at least 2Flexural strength (MOR).
7. according to the composite wood board of aforementioned each claim, wherein this plate has 0.028N/mm at least 2Inside bonding strength (IB).
8. according to the composite wood board of aforementioned each claim, wherein this plate has 0.4N/mm at least 2Inside bonding strength (IB).
9. according to the composite wood board of aforementioned each claim, wherein this plate has in the thickness swell that is less than or equal to 12% under 20 ℃ in water after 24 hours, preferably is less than or equal to 10%.
10. according to the composite wood board of aforementioned each claim, wherein this plate has in the moisture absorption that is less than or equal to 40% under 20 ℃ in water after 24 hours, preferably is less than or equal to 30%.
11. according to the composite wood board of aforementioned each claim, wherein this plate is the wood particulate plate.
12. according to the composite wood board of aforementioned each claim, wherein this plate is an oriented wood chipboard.
13. according to the composite wood board of aforementioned each claim, wherein this plate is a fiberboard, is preferably medium-density fiberboard.
14. according to the composite wood board of aforementioned each claim, wherein this plate has the resin content (dry resin weight relatively dry wood particle weight) in the 8-18% weight range, is preferably 10-16% weight, more preferably 12-14% weight.
15. according to the composite wood board of aforementioned each claim, wherein this plate has the binding agent based on reducing sugar.
16. according to the composite wood board of aforementioned each claim, wherein this plate has the binding agent that comprises at least a mailland reaction product.
17. according to the composite wood board of aforementioned each claim, wherein this plate has binding agent, the reaction product that this binding agent obtains based on the aqueous solution that comprises citric acid, ammonia and glucose by curing.
18. according to the composite wood board of aforementioned each claim, wherein this plate comprises wax.
19. according to the composite wood board of claim 18, wherein this plate is included in the wax in the 0.1-2% weight range, is preferably 0.5-1% weight.
20. according to the composite wood board of aforementioned each claim, wherein this binding agent is a bio-resin.
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103317586A (en) * 2012-03-21 2013-09-25 中南林业科技大学 Environment-friendly glue free particle board and preparation method thereof
CN104768720A (en) * 2012-08-17 2015-07-08 克瑙夫绝缘私人有限公司 Wood board and process for its production
CN105176460A (en) * 2010-05-07 2015-12-23 克瑙夫绝缘私人有限公司 Carbohydrate polyamine binders and materials made therewith
CN106232699A (en) * 2014-04-18 2016-12-14 株式会社Kcc Aqueous thermosetting adhesive composition and the method using said composition binder fibre shape material
CN108297221A (en) * 2017-01-11 2018-07-20 广东华润涂料有限公司 The water-borne dispersions of siloxanes reduce the application of the muscle that rises of wood substrate and the product containing the anti-muscle coating that rises
CN108884295A (en) * 2016-03-17 2018-11-23 塞斯泰克公司 Formaldehyde-free wood adhesive
CN110914030A (en) * 2017-11-14 2020-03-24 松下知识产权经营株式会社 Method for manufacturing wood composite board

Families Citing this family (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102766423B (en) 2005-07-26 2015-10-28 可耐福保温材料有限公司 Binding agent and material prepared therefrom
US20220267635A1 (en) * 2005-07-26 2022-08-25 Knauf Insulation, Inc. Binders and materials made therewith
WO2008089847A1 (en) 2007-01-25 2008-07-31 Knauf Insulation Limited Composite wood board
CN101668713B (en) 2007-01-25 2012-11-07 可耐福保温材料有限公司 Mineral fibre board
PT2108006T (en) 2007-01-25 2020-12-21 Knauf Insulation Gmbh Binders and materials made therewith
EP2137223B1 (en) 2007-04-13 2019-02-27 Knauf Insulation GmbH Composite maillard-resole binders
GB0715100D0 (en) 2007-08-03 2007-09-12 Knauf Insulation Ltd Binders
JP5472639B2 (en) * 2008-07-03 2014-04-16 国立大学法人京都大学 Composition that cures by heating and pressing
ES2704135T3 (en) * 2009-02-27 2019-03-14 Rohm & Haas Fast-curing carbohydrate composition
EP2223940B1 (en) * 2009-02-27 2019-06-05 Rohm and Haas Company Polymer modified carbohydrate curable binder composition
FR2947572B1 (en) * 2009-07-01 2011-08-26 Univ Nancy 1 Henri Poincare COMPOSITE MATERIAL BASED ON NATURAL FIBERS AND RESINS
WO2011015946A2 (en) 2009-08-07 2011-02-10 Knauf Insulation Molasses binder
US8372900B2 (en) 2009-08-19 2013-02-12 Johns Manville Cellulosic composite with binder comprising salt of inorganic acid
US9604878B2 (en) 2009-08-11 2017-03-28 Johns Manville Curable fiberglass binder comprising salt of inorganic acid
US9994482B2 (en) 2009-08-11 2018-06-12 Johns Manville Curable fiberglass binder
US9365963B2 (en) 2009-08-11 2016-06-14 Johns Manville Curable fiberglass binder
EP2386605B1 (en) 2010-04-22 2017-08-23 Rohm and Haas Company Durable thermosets from reducing sugars and primary polyamines
PL2386394T3 (en) 2010-04-22 2020-11-16 Rohm And Haas Company Durable thermoset binder compositions from 5-carbon reducing sugars and use as wood binders
WO2011138459A1 (en) 2010-05-07 2011-11-10 Knauf Insulation Carbohydrate binders and materials made therewith
US9045678B2 (en) 2010-05-17 2015-06-02 Georgia-Pacific Chemicals Llc Proppants for use in hydraulic fracturing of subterranean formations
WO2011154368A1 (en) 2010-06-07 2011-12-15 Knauf Insulation Fiber products having temperature control additives
WO2012037451A2 (en) * 2010-09-17 2012-03-22 Knauf Insulation Gmbh Organic acid carbohydrate binders and materials made therewith
JP5977015B2 (en) 2010-11-30 2016-08-24 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ Stable reactive thermosetting formulations of reducing sugars and amines
WO2012152731A1 (en) 2011-05-07 2012-11-15 Knauf Insulation Liquid high solids binder composition
GB201206193D0 (en) 2012-04-05 2012-05-23 Knauf Insulation Ltd Binders and associated products
US8980774B2 (en) 2012-06-15 2015-03-17 Hexion Inc. Compositions and methods for making polyesters and articles therefrom
ES2921601T3 (en) 2012-12-05 2022-08-30 Knauf Insulation Sprl Binder
WO2015092750A1 (en) * 2013-12-20 2015-06-25 New Zealand Forest Research Institute Limited Adhesive
MX2016010192A (en) 2014-02-07 2017-01-09 Knauf Insulation Inc Uncured articles with improved shelf-life.
GB201408909D0 (en) 2014-05-20 2014-07-02 Knauf Insulation Ltd Binders
KR101871542B1 (en) * 2014-06-10 2018-06-27 주식회사 케이씨씨 Aqueous binder composition allowing recycle of process water and method for binding fibrous materials by using the same
GB201412709D0 (en) * 2014-07-17 2014-09-03 Knauf Insulation And Knauf Insulation Ltd Improved binder compositions and uses thereof
GB201413402D0 (en) * 2014-07-29 2014-09-10 Knauf Insulation Ltd Laminates
HUE046879T2 (en) * 2015-03-27 2020-03-30 Basf Se Method for manufacturing wooden materials
KR102037839B1 (en) * 2015-05-20 2019-10-31 주식회사 케이씨씨 Binder composition and method for binding fibrous materials by using the same
GB201517882D0 (en) * 2015-10-09 2015-11-25 Knauf Insulation Ltd Wood particle boards
GB201517867D0 (en) 2015-10-09 2015-11-25 Knauf Insulation Ltd Wood particle boards
WO2017074841A1 (en) * 2015-10-27 2017-05-04 Purdue Research Foundation Protein-based adhesives and methods of making the same
RU2732337C2 (en) 2016-03-01 2020-09-15 Соленис Текнолоджиз, Л.П. Method of producing improved composite plates
GB201610063D0 (en) 2016-06-09 2016-07-27 Knauf Insulation Ltd Binders
GB201701569D0 (en) 2017-01-31 2017-03-15 Knauf Insulation Ltd Improved binder compositions and uses thereof
KR101922644B1 (en) * 2017-04-13 2018-11-27 씨제이제일제당 주식회사 Binder composition, Article and preparation method for article
WO2018204906A1 (en) * 2017-05-05 2018-11-08 Masonite Corporation Cellulosic articles made from cellulosic materials and methods therefor
GB201804906D0 (en) * 2018-03-27 2018-05-09 Knauf Insulation Ltd Wood boards
GB201804908D0 (en) 2018-03-27 2018-05-09 Knauf Insulation Ltd Binder compositions and uses thereof
GB201804907D0 (en) 2018-03-27 2018-05-09 Knauf Insulation Ltd Composite products
MX2020012343A (en) 2018-05-18 2021-01-29 Ocv Intellectual Capital Llc Nonwoven with two-part binder system.
GB201908324D0 (en) 2019-06-11 2019-07-24 Pennog Ltd Biocidal composite material
US20230082627A1 (en) * 2020-02-21 2023-03-16 Cargill, Incorporated Engineered wood adhesives and engineered wood therefrom
WO2022258513A1 (en) 2021-06-07 2022-12-15 Basf Se Process of producing a lignocellulosic composite, corresponding lignocellulosic composite, and use thereof
EP4144707A1 (en) 2021-09-07 2023-03-08 Biolac GmbH & Co. KG Mixture for the preparation of a shaped body with improved binder
WO2023102639A1 (en) * 2021-12-07 2023-06-15 Inca Renewable Technologies Inc. Methods for increasing absorption capacity of plant hurd material and products therefrom
EP4279518B1 (en) * 2022-05-18 2024-05-01 SWISS KRONO Tec AG Method for manufacturing an osb wooden panel
WO2024088944A1 (en) 2022-10-28 2024-05-02 Basf Se Process of producing a lignocellulosic composite and corresponding binder composition, lignocellulosic composite, kit and use

Family Cites Families (481)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1886353A (en) 1922-04-27 1932-11-01 John Stogdell Stokes Synthetic resin and method of making same
US1801052A (en) 1923-02-06 1931-04-14 Meigsoid Corp Resinous condensation product and process of making same
US1801053A (en) 1925-01-22 1931-04-14 Meigsoid Corp Carbohydrate product and process of making same
US1902948A (en) 1931-08-14 1933-03-28 A M Castle & Co Welding electrode
US1964263A (en) 1932-06-15 1934-06-26 Anker Holth Mfg Company Spraying fixture
BE420665A (en) 1936-03-20
US2261295A (en) 1936-09-30 1941-11-04 Walther H Duisberg Artificial textile materials
US2215825A (en) 1938-03-16 1940-09-24 Matilda Wallace Core binder
US2362086A (en) 1941-08-26 1944-11-07 Resinous Prod & Chemical Co Volume stabilized acid absorbing resin
US2371990A (en) 1942-02-18 1945-03-20 Du Pont Polymeric esters
BE471265A (en) 1942-04-02
BE472469A (en) 1942-06-16
US2500665A (en) 1944-03-30 1950-03-14 Owens Corning Fiberglass Corp High-temperature insulation and method of manufacture
BE472470A (en) 1945-07-11
GB770561A (en) 1954-11-17 1957-03-20 Corn Prod Refining Co Improvements in or relating to core for foundry purposes and process for producing the same
US2875073A (en) 1955-05-23 1959-02-24 Corn Prod Refining Co Core binder and process of making cores
GB809675A (en) 1955-05-23 1959-03-04 Corn Prod Refining Co Improvements in or relating to refractory insulating block and method of making same
US2947270A (en) 1955-12-19 1960-08-02 Singer Mfg Co Sewing machines
US2894920A (en) 1957-02-12 1959-07-14 Ramos Thomas Resinous composition comprising epoxy resin, curing agent and mixture of dextrines, maltose and dextrose and process for preparing
US2965504A (en) 1958-04-01 1960-12-20 Corn Products Co Process for preparation of refractory insulating blocks
GB890761A (en) * 1959-12-31 1962-03-07 Ici Ltd Copper articles coated with polypropylene compositions
GB979991A (en) 1960-01-14 1965-01-06 Polygram Casting Co Ltd Improvements in or relating to thermosetting compositions based on carbohydrates
US3038462A (en) 1960-07-21 1962-06-12 Gen Electric Oven liner
US3231349A (en) 1960-11-21 1966-01-25 Owens Corning Fiberglass Corp Production of vitreous fiber products
NL275294A (en) 1961-03-08 1900-01-01
US3138473A (en) 1962-01-26 1964-06-23 Gen Mills Inc Compositions and process to increase the wet strength of paper
US3222243A (en) 1962-07-11 1965-12-07 Owens Corning Fiberglass Corp Thermal insulation
DE1905054U (en) 1964-03-05 1964-11-26 Guenter Manzke Produktion Und COMPONENT FOR THE LATERAL TRACK BARRIER.
US3232821A (en) 1964-12-11 1966-02-01 Ferro Corp Felted fibrous mat and apparatus for manufacturing same
US3297419A (en) * 1965-08-17 1967-01-10 Fyr Tech Products Inc Synthetic fuel log and method of manufacture
DE1905054A1 (en) 1968-02-05 1969-08-21 Dierks Forests Inc Thermosetting saccharide-based binder
US3856606A (en) 1968-06-17 1974-12-24 Union Carbide Corp Coupling solid substrates using silyl peroxide compounds
US3551365A (en) 1968-11-29 1970-12-29 Ralph Matalon Composite cross - linking agent/resin former compositions and cold-setting and heat - setting resins prepared therefrom
SU374400A1 (en) 1970-07-09 1973-03-20 METHOD OF OBTAINING NONWAVE MATERIALS
US3867119A (en) 1970-07-20 1975-02-18 Paramount Glass Mfg Co Ltd Apparatus for manufacturing glass fibers
US3784408A (en) 1970-09-16 1974-01-08 Hoffmann La Roche Process for producing xylose
US3826767A (en) 1972-01-26 1974-07-30 Calgon Corp Anionic dextran graft copolymers
US3791807A (en) 1972-05-02 1974-02-12 Certain Teed Prod Corp Waste water reclamation in fiber glass operation
US3961081A (en) 1972-06-05 1976-06-01 Mckenzie Carl O Molasses feed block for animals and method of making same
US4144027A (en) 1972-07-07 1979-03-13 Milliken Research Corporation Product and process
IT971367B (en) 1972-11-30 1974-04-30 Sir Soc Italiana Resine Spa PROCEDURE FOR THE CONTINUOUS PREPARATION OF UNSATURATED POLYESTERS
US3955031A (en) 1973-01-18 1976-05-04 Owens-Corning Fiberglas Corporation Flame resistant building material
US4186053A (en) 1973-02-22 1980-01-29 Givaudan Corporation Insolubilized enzyme product
US4201857A (en) 1973-02-22 1980-05-06 Givaudan Corporation Novel condensation products having high activity to insolubilize proteins and protein-insolubilized products
CH579109A5 (en) 1973-02-22 1976-08-31 Givaudan & Cie Sa
US3802897A (en) 1973-02-23 1974-04-09 Anheuser Busch Water resistant starch adhesive
US3809664A (en) 1973-08-16 1974-05-07 Us Agriculture Method of preparing starch graft polymers
DE2360876A1 (en) 1973-12-06 1975-06-12 Bayer Ag CATIONIC COLORS
US4054713A (en) 1973-12-28 1977-10-18 Kao Soap Co., Ltd. Process for preparing glass fiber mats
SE7410542L (en) 1974-01-29 1976-01-12 Givaudan & Cie Sa CONDENSATION PRODUCTS.
GB1469331A (en) 1974-02-18 1977-04-06 Pfizer Ltd Flavouring agent
US4107379A (en) 1974-02-22 1978-08-15 John Stofko Bonding of solid lignocellulosic material
US4183997A (en) 1974-02-22 1980-01-15 John Jansky Bonding of solid lignocellulosic material
US4014726A (en) 1974-03-18 1977-03-29 Owens-Corning Fiberglas Corporation Production of glass fiber products
US3907724A (en) 1974-04-10 1975-09-23 Monsanto Co Phenolic binders for mineral fiber thermal insulation
US3919134A (en) 1974-04-10 1975-11-11 Monsanto Co Thermal insulation of mineral fiber matrix bound with phenolic resin
US3922466A (en) 1974-09-16 1975-11-25 Owens Corning Fiberglass Corp Silane coupling agents
US3956204A (en) 1975-03-10 1976-05-11 Monsanto Company Antipunking phenolic resin binder systems for mineral fiber thermal insulation
US4184986A (en) 1975-08-19 1980-01-22 Givaudan Corporation Novel condensation products having high activity to insolubilize proteins and protein-insolubilized products
CH594370A5 (en) 1975-08-26 1978-01-13 Maggi Ag
US4028290A (en) 1975-10-23 1977-06-07 Hercules Incorporated Highly absorbent modified polysaccharides
JPS52142736A (en) 1976-05-24 1977-11-28 Sumitomo Durez Co Method of accelerating hardening of phenolic adhesive
CA1090026A (en) 1976-07-22 1980-11-18 John P. Gibbons Carbohydrate-phenol based condensation resins incorporating nitrogen-containing compounds
US4048127A (en) 1976-07-22 1977-09-13 Cpc International Inc. Carbohydrate-based condensation resin
US4217414A (en) 1976-11-01 1980-08-12 Cpc International Inc. Process for separating and recovering vital wheat gluten from wheat flour and the like
US4148765A (en) 1977-01-10 1979-04-10 The Dow Chemical Company Polyester resins containing dicyclopentadiene
US4097427A (en) 1977-02-14 1978-06-27 Nalco Chemical Company Cationization of starch utilizing alkali metal hydroxide, cationic water-soluble polymer and oxidant for improved wet end strength
JPS5717850Y2 (en) 1977-02-16 1982-04-14
JPS53113784A (en) 1977-03-17 1978-10-04 Koei Chemical Co Scale removing agent
DE2721186C2 (en) 1977-05-11 1986-04-24 Bayer Ag, 5090 Leverkusen Process for the preparation of a mixture of low molecular weight polyhydroxyl compounds
US4201247A (en) 1977-06-29 1980-05-06 Owens-Corning Fiberglas Corporation Fibrous product and method and apparatus for producing same
AU530553B2 (en) 1978-05-09 1983-07-21 Commonwealth Scientific And Industrial Research Organisation Treatment of textile materials
DE2833138A1 (en) 1978-07-28 1980-02-07 Bayer Ag METHYLOLATED MONO AND OLIGOSACCHARIDES
US4333484A (en) 1978-08-02 1982-06-08 Philip Morris Incorporated Modified cellulosic smoking material and method for its preparation
US4506684A (en) 1978-08-02 1985-03-26 Philip Morris Incorporated Modified cellulosic smoking material and method for its preparation
HU186349B (en) 1979-01-23 1985-07-29 Magyar Tudomanyos Akademia Process for producing polymeres containing metals of side-groups in complex bond
US4265963A (en) 1979-01-26 1981-05-05 Arco Polymers, Inc. Flameproof and fireproof products containing monoethanolamine, diethylamine or morpholine
US4233432A (en) 1979-05-10 1980-11-11 United States Steel Corporation Dicyclopentadiene polyester resins
US4310585A (en) 1979-06-15 1982-01-12 Owens-Corning Fiberglas Corporation Fibrous product formed of layers of compressed fibers
US4296173A (en) 1979-09-13 1981-10-20 Ppg Industries, Inc. Glass fibers with reduced tendency to form gumming deposits and sizing composition comprising two starches with different amylose content
US4259190A (en) 1979-09-13 1981-03-31 Ppg Industries, Inc. Glass fibers with reduced tendency to form gumming deposits and sizing composition
US4246367A (en) 1979-09-24 1981-01-20 United States Steel Corporation Dicyclopentadiene polyester resins
US4278573A (en) 1980-04-07 1981-07-14 National Starch And Chemical Corporation Preparation of cationic starch graft copolymers from starch, N,N-methylenebisacrylamide, and polyamines
US4379101A (en) 1980-06-04 1983-04-05 Allen Industries, Inc. Forming apparatus and method
US4330443A (en) 1980-06-18 1982-05-18 The United States Of America As Represented By The Secretary Of Agriculture Dry chemical process for grafting acrylic and methyl acrylic ester and amide monomers onto starch-containing materials
GB2078805A (en) 1980-06-27 1982-01-13 Tba Industrial Products Ltd Fire and Weld Splash Resistant for Glass Fabric
EP0044614A3 (en) 1980-06-27 1982-05-19 TBA Industrial Products Limited Improvements in and relating to glass fabrics
US4361588A (en) 1980-07-30 1982-11-30 Nutrisearch Company Fabricated food products from textured protein particles
US4400496A (en) 1980-09-22 1983-08-23 University Of Florida Water-soluble graft copolymers of starch-acrylamide and uses therefor
JPS57101100U (en) 1980-12-12 1982-06-22
JPS57101100A (en) 1980-12-15 1982-06-23 Nitto Boseki Co Ltd Production of mineral fiberboard
JPS5811193B2 (en) 1981-02-02 1983-03-01 三菱瓦斯化学株式会社 Method for producing bacterial cells
US4396430A (en) 1981-02-04 1983-08-02 Ralph Matalon Novel foundry sand binding compositions
US4357194A (en) 1981-04-14 1982-11-02 John Stofko Steam bonding of solid lignocellulosic material
JPS5811193A (en) 1981-07-11 1983-01-21 Ricoh Co Ltd Thermo-sensitive recording material
US4393019A (en) 1981-11-30 1983-07-12 The United States Of America As Represented By The Secretary Of Agriculture Method of pressing reconstituted lignocellulosic materials
FR2529917A1 (en) 1982-07-06 1984-01-13 Saint Gobain Isover METHOD AND DEVICE FOR THE FORMATION OF FIBER FIBER CONTAINING AN ADDITIONAL PRODUCT
US4464523A (en) 1983-05-16 1984-08-07 National Starch And Chemical Corporation Process for the preparation of graft copolymers of cellulose derivatives and diallyl, dialkyl ammonium halides
US4668716A (en) 1983-09-30 1987-05-26 Union Carbide Corporation Novel fatty ethenoid acylaminoorganosilicon compounds and their use as a coupling agent
US4524164A (en) * 1983-12-02 1985-06-18 Chemical Process Corporation Thermosetting adhesive resins
US4654259A (en) 1984-02-14 1987-03-31 Carbocol Inc. Method and composition for bonding solid lignocellulosic material
FR2559793B1 (en) 1984-02-17 1986-12-19 Saint Gobain Isover PROCESS FOR PRODUCING MINERAL FIBER MATTRESS FROM MOLTEN MATERIAL
US4714727A (en) 1984-07-25 1987-12-22 H. B. Fuller Company Aqueous emulsion coating for individual fibers of a cellulosic sheet providing improved wet strength
GB2170208B (en) 1985-01-29 1988-06-22 Enigma Nv A formaldehyde binder
JPS61195647A (en) 1985-02-27 1986-08-29 Kanebo Shokuhin Kk Production of bitter chocolate
US4754056A (en) 1985-04-05 1988-06-28 Desoto, Inc. Radiation-curable coatings containing reactive pigment dispersants
JPS61195647U (en) 1985-05-27 1986-12-05
SE8504501D0 (en) 1985-09-30 1985-09-30 Astra Meditec Ab METHOD OF FORMING AN IMPROVED HYDROPHILIC COATING ON A POLYMER SURFACE
US4828643A (en) 1986-02-19 1989-05-09 Masonite Corporation Liquified cellulosic fiber, resin binders and articles manufactured therewith, and method of manufacturing same
US4692478A (en) * 1986-03-14 1987-09-08 Chemical Process Corporation Process for preparation of resin and resin obtained
US4780339A (en) 1986-07-30 1988-10-25 National Starch And Chemical Corporation Sized glass fibers and method for production thereof
DE3629470A1 (en) 1986-08-29 1988-03-10 Basf Lacke & Farben CARBOXYL GROUPS AND TERTIAL AMINO GROUPS CONTAINING POLYCONDENSATION AND / OR ADDITION PRODUCT, COATING AGENTS BASED ON THE SAME AND THEIR USE
IL80298A (en) 1986-10-14 1993-01-31 Res & Dev Co Ltd Eye drops
US4720295A (en) 1986-10-20 1988-01-19 Boris Bronshtein Controlled process for making a chemically homogeneous melt for producing mineral wool insulation
US4734996A (en) 1986-12-15 1988-04-05 Owens-Corning Fiberglas Corporation Method and apparatus for heating mineral fibers
US5013405A (en) 1987-01-12 1991-05-07 Usg Interiors, Inc. Method of making a low density frothed mineral wool
GB8809486D0 (en) 1987-04-22 1988-05-25 Micropore International Ltd Procedure to manufacture thermal insulating material for use at high temperatures
US4845162A (en) 1987-06-01 1989-07-04 Allied-Signal Inc. Curable phenolic and polyamide blends
DE3734752A1 (en) 1987-10-14 1989-05-03 Basf Ag METHOD FOR THE PRODUCTION OF AQUEOUS (METH) ACRYLIC ACID ESTER COPOLYMER DISPERSIONS IN TWO STAGES AND THE USE THEREOF AS IMPREGNANT, COATING AND BINDING AGENT FOR FLAT FIBER FABRICS
SE464687B (en) 1987-11-10 1991-06-03 Biocarb Ab PROCEDURES FOR PREPARING A GEL PRODUCT
US5095054A (en) 1988-02-03 1992-03-10 Warner-Lambert Company Polymer compositions containing destructurized starch
FR2626578B1 (en) 1988-02-03 1992-02-21 Inst Francais Du Petrole AMINO-SUBSTITUTED POLYMERS AND THEIR USE AS ADDITIVES FOR MODIFYING THE COLD PROPERTIES OF MEDIUM HYDROCARBON DISTILLATES
US5441713A (en) 1988-04-29 1995-08-15 Nalco Fuel Tech Hardness suppression in urea solutions
JPH0299655A (en) 1988-08-03 1990-04-11 Sequa Chemicals Inc Starch group binder composition for fiber mat and manufacture thereof
US4988780A (en) 1988-08-15 1991-01-29 Allied-Signal Flame resistant article made of phenolic triazine and related method using a pure cyanato novolac
US4918861A (en) 1988-11-15 1990-04-24 Hobbs Bonded Fibers Plant growth bed with high loft textile fibers
DE3839171A1 (en) 1988-11-19 1990-05-23 Bayer Ag AQUEOUS COATING AGENT, A METHOD FOR PRODUCING IT AND ITS USE
GB8829405D0 (en) 1988-12-16 1989-02-01 Cerestar Holding Bv Process for the manufacture of mineral fibre compositions
US5371194A (en) * 1988-12-28 1994-12-06 Ferretti; Arthur Biomass derived thermosetting resin
CA2005321A1 (en) 1988-12-28 1990-06-28 Arthur Ferretti Thermosettable resin intermediate
US5582682A (en) 1988-12-28 1996-12-10 Ferretti; Arthur Process and a composition for making cellulosic composites
US4992519A (en) 1989-02-01 1991-02-12 Borden, Inc. Binder composition with low formaldehyde emission and process for its preparation
US5278222A (en) 1989-02-13 1994-01-11 Rohm And Haas Company Low viscosity, fast curing binder for cellulose
US5198492A (en) 1989-02-13 1993-03-30 Rohn And Haas Company Low viscosity, fast curing binder for cellulose
JPH0734023Y2 (en) 1989-04-17 1995-08-02 川崎重工業株式会社 Weighing and transporting device for powder and granules
AT393272B (en) 1989-06-07 1991-09-25 Rettenbacher Markus Dipl Ing METHOD FOR PRODUCING EXTRUDED, DIRECTLY EXPANDED BIOPOLYMER PRODUCTS AND WOOD FIBER PANELS, PACKAGING AND INSULATING MATERIALS
US5037930A (en) 1989-09-22 1991-08-06 Gaf Chemicals Corporation Heterocyclic quaternized nitrogen-containing cellulosic graft polymers
ES2014208T3 (en) 1989-11-08 1994-11-16 Shell Int Research FLEXIBLE AND SOFT POLYURETHANE FOAMS, A PROCEDURE FOR PREPARING THEM, AND A COMPOSITION OF POLIOL USEFUL IN SUCH PROCEDURE.
JP2515411B2 (en) 1989-12-01 1996-07-10 新王子製紙株式会社 Method for manufacturing thermal recording material
JP2926513B2 (en) 1989-12-11 1999-07-28 住友化学工業株式会社 Resin composition and method for producing the same
US5151465A (en) 1990-01-04 1992-09-29 Arco Chemical Technology, L.P. Polymer compositions and absorbent fibers produced therefrom
US5032431A (en) 1990-02-06 1991-07-16 Georgia-Pacific Resins, Inc. Glass fiber insulation binder
DE69111480T2 (en) 1990-02-14 1996-03-14 Shinsozai Sogo Kenkyusho Kk Filled and sealed, independent mixing container.
JP2574051B2 (en) 1990-02-28 1997-01-22 明治製菓株式会社 Gene encoding indole acetate biosynthesis enzyme
DE59103307D1 (en) 1990-03-03 1994-12-01 Basf Ag Molded body.
RU1765996C (en) 1990-06-11 1995-08-27 Назаров Петр Васильевич Method of making heat- and soundproofing articles
FR2663049B1 (en) 1990-06-12 1994-05-13 Isover Saint Gobain RECYCLING OF FIBROUS PRODUCTS IN A MATTRESS PRODUCTION LINE FROM FIBERS.
US5041595A (en) 1990-09-26 1991-08-20 Union Carbide Chemicals And Plastics Technology Corporation Method for manufacturing vinylalkoxysilanes
US6495656B1 (en) 1990-11-30 2002-12-17 Eastman Chemical Company Copolyesters and fibrous materials formed therefrom
DE69034003T2 (en) * 1990-12-28 2003-05-22 K C Shen Technology Internat L Thermosetting resin and composite made of lignocellulosic material
GB9100277D0 (en) 1991-01-07 1991-02-20 Courtaulds Fibres Ltd Adhesive
US5240498A (en) 1991-01-09 1993-08-31 Martin Marietta Magnesia Specialties Inc. Carbonaceous binder
US5217741A (en) 1991-01-25 1993-06-08 Snow Brand Milk Products Co., Ltd. Solution containing whey protein, whey protein gel, whey protein powder and processed food product produced by using the same
GB9105208D0 (en) 1991-03-12 1991-04-24 Cerestar Holding Bv Starch composition
GB9108604D0 (en) 1991-04-22 1991-06-05 Nadreph Ltd Gel products and a process for making them
US5143582A (en) 1991-05-06 1992-09-01 Rohm And Haas Company Heat-resistant nonwoven fabrics
US5128407A (en) 1991-07-25 1992-07-07 Miles Inc. Urea extended polyisocyanates
DE4127733A1 (en) 1991-08-22 1993-02-25 Basf Ag Graft polymers of natural substances containing saccharide structures or derivatives thereof and ethylenically unsaturated compounds and their use.
US5123949A (en) 1991-09-06 1992-06-23 Manville Corporation Method of introducing addivites to fibrous products
GB9126828D0 (en) 1991-12-18 1992-02-19 British American Tobacco Co Improvements relating to smoking articles
DE4142261A1 (en) 1991-12-20 1993-06-24 Man Technologie Gmbh Coating and infiltration of substrates in a short time - by heating substrate using body which matches the component contour at gas outflow side and opt. gas entry side
JPH05186635A (en) 1992-01-10 1993-07-27 Goyo Paper Working Co Ltd Packaging material
DE4202248A1 (en) 1992-01-28 1993-07-29 Belland Ag METHOD FOR RECOVERY OF POLYMERS SOLVED IN AQUEOUS ALKALINE OR ACID MILIEU
FR2688791B1 (en) 1992-03-20 1995-06-16 Roquette Freres BINDING COMPOSITION FOR THE PREPARATION OF A NEW AGGLOMERATE BASED ON FINELY DIVIDED MATERIALS, PROCESS USING THIS COMPOSITION AND NEW AGGLOMERATE OBTAINED.
US5550189A (en) 1992-04-17 1996-08-27 Kimberly-Clark Corporation Modified polysaccharides having improved absorbent properties and process for the preparation thereof
US5534612A (en) 1992-05-19 1996-07-09 Schuller International, Inc. Glass fiber binding compositions, process of making glass fiber binding compositions, process of binding glass fibers, and glass fiber compositions
US6077883A (en) 1992-05-19 2000-06-20 Johns Manville International, Inc. Emulsified furan resin based glass fiber binding compositions, process of binding glass fibers, and glass fiber compositions
AU5347294A (en) 1992-05-19 1994-01-04 Schuller International, Inc. Glass fiber binding compositions, process of binding glass fibers, and glass fiber compositions
US5389716A (en) 1992-06-26 1995-02-14 Georgia-Pacific Resins, Inc. Fire resistant cured binder for fibrous mats
US5661213A (en) 1992-08-06 1997-08-26 Rohm And Haas Company Curable aqueous composition and use as fiberglass nonwoven binder
US5582670A (en) 1992-08-11 1996-12-10 E. Khashoggi Industries Methods for the manufacture of sheets having a highly inorganically filled organic polymer matrix
US5434233A (en) 1992-08-12 1995-07-18 Kiely; Donald E. Polyaldaramide polymers useful for films and adhesives
US5352480A (en) 1992-08-17 1994-10-04 Weyerhaeuser Company Method for binding particles to fibers using reactivatable binders
US5589256A (en) 1992-08-17 1996-12-31 Weyerhaeuser Company Particle binders that enhance fiber densification
US5807364A (en) 1992-08-17 1998-09-15 Weyerhaeuser Company Binder treated fibrous webs and products
US5547541A (en) 1992-08-17 1996-08-20 Weyerhaeuser Company Method for densifying fibers using a densifying agent
DE69333678T2 (en) 1992-08-17 2005-03-03 Weyerhaeuser Co., Tacoma Binder for particles
US5641561A (en) 1992-08-17 1997-06-24 Weyerhaeuser Company Particle binding to fibers
US7144474B1 (en) 1992-08-17 2006-12-05 Weyerhaeuser Co. Method of binding particles to binder treated fibers
US5308896A (en) 1992-08-17 1994-05-03 Weyerhaeuser Company Particle binders for high bulk fibers
US6340411B1 (en) 1992-08-17 2002-01-22 Weyerhaeuser Company Fibrous product containing densifying agent
US5300192A (en) 1992-08-17 1994-04-05 Weyerhaeuser Company Wet laid fiber sheet manufacturing with reactivatable binders for binding particles to fibers
US5543215A (en) 1992-08-17 1996-08-06 Weyerhaeuser Company Polymeric binders for binding particles to fibers
US6391453B1 (en) 1992-08-17 2002-05-21 Weyernaeuser Company Binder treated particles
US5538783A (en) 1992-08-17 1996-07-23 Hansen; Michael R. Non-polymeric organic binders for binding particles to fibers
FR2694894B1 (en) 1992-08-20 1994-11-10 Coletica Use of a transacylation reaction between an esterified polysaccharide and a polyamine or polyhydroxylated substance for the manufacture of microparticles, process and composition.
US5367849A (en) 1992-09-08 1994-11-29 Bullock; Thomas W. Insulation configurations and method of installation
DE4233622C2 (en) 1992-10-06 2000-01-05 Rolf Hesch Pressing process for coating a workpiece and press for carrying out the process
FR2697023B1 (en) 1992-10-16 1994-12-30 Roquette Freres Low-calorie glucose soluble polymer and process for the preparation of this polymer.
US5300144A (en) 1992-11-02 1994-04-05 Martin Marietta Magnesia Specialties, Inc. Binder composition
US5376614A (en) 1992-12-11 1994-12-27 United Technologies Corporation Regenerable supported amine-polyol sorbent
EP0601417A3 (en) 1992-12-11 1998-07-01 Hoechst Aktiengesellschaft Physiologically compatible and degradable polymer-based carbohydrate receptor blockers, a method for their preparation and their use
US5545279A (en) 1992-12-30 1996-08-13 Hall; Herbert L. Method of making an insulation assembly
US5672659A (en) 1993-01-06 1997-09-30 Kinerton Limited Ionic molecular conjugates of biodegradable polyesters and bioactive polypeptides
US5863985A (en) 1995-06-29 1999-01-26 Kinerton Limited Ionic molecular conjugates of biodegradable polyesters and bioactive polypeptides
US6221958B1 (en) 1993-01-06 2001-04-24 Societe De Conseils De Recherches Et D'applications Scientifiques, Sas Ionic molecular conjugates of biodegradable polyesters and bioactive polypeptides
CA2154562A1 (en) 1993-01-23 1994-08-04 Helmut Schiwek Glass fiber manufacturing process and plant
IL104734A0 (en) 1993-02-15 1993-06-10 Univ Bar Ilan Bioactive conjugates of cellulose with amino compounds
US5387665A (en) 1993-02-26 1995-02-07 Mitsui Toatsu Chemicals, Inc. Resins for electrohotographic toners
US5554730A (en) 1993-03-09 1996-09-10 Middlesex Sciences, Inc. Method and kit for making a polysaccharide-protein conjugate
US5981719A (en) 1993-03-09 1999-11-09 Epic Therapeutics, Inc. Macromolecular microparticles and methods of production and use
US6090925A (en) 1993-03-09 2000-07-18 Epic Therapeutics, Inc. Macromolecular microparticles and methods of production and use
DE4308089B4 (en) 1993-03-13 2004-05-19 Basf Ag Formaldehyde-free binders for wood
US5929184A (en) 1993-06-02 1999-07-27 Geltex Pharmaceuticals, Inc. Hydrophilic nonamine-containing and amine-containing copolymers and their use as bile acid sequestrants
US6855337B1 (en) 1993-06-17 2005-02-15 Carle Development Foundation Bear derived isolate and method
US5340868A (en) 1993-06-21 1994-08-23 Owens-Corning Fiberglass Technology Inc. Fibrous glass binders
US5318990A (en) 1993-06-21 1994-06-07 Owens-Corning Fiberglas Technology Inc. Fibrous glass binders
JP3399588B2 (en) 1993-07-20 2003-04-21 東洋紡績株式会社 Ink for writing implements
PL183101B1 (en) 1993-09-29 2002-05-31 Grace W R & Co Improved cement additive product enabling to achieve better rheological properties and method of obtaining such additive product
US5416139A (en) 1993-10-07 1995-05-16 Zeiszler; Dennis E. Structural building materials or articles obtained from crop plants or residues therefrom and/or polyolefin materials
US5393849A (en) 1993-10-19 1995-02-28 Georgia-Pacific Resins, Inc. Curable polyester/polyamino compositions
JP2811540B2 (en) 1993-10-20 1998-10-15 呉羽化学工業株式会社 Gas barrier film and method for producing the same
US5503920A (en) 1993-12-27 1996-04-02 Owens-Corning Fiberglass Technology, Inc. Process for improving parting strength of fiberglass insulation
DE4406172C2 (en) 1994-02-25 2003-10-02 Sanol Arznei Schwarz Gmbh polyester
DE4408688A1 (en) 1994-03-15 1995-09-21 Basf Ag Formaldehyde-free binding, impregnating or coating compositions for fibrous webs
US5955448A (en) 1994-08-19 1999-09-21 Quadrant Holdings Cambridge Limited Method for stabilization of biological substances during drying and subsequent storage and compositions thereof
GB9411080D0 (en) 1994-06-02 1994-07-20 Unilever Plc Treatment
GB9412007D0 (en) 1994-06-15 1994-08-03 Rockwell International A S Production of mineral fibres
US5580856A (en) 1994-07-15 1996-12-03 Prestrelski; Steven J. Formulation of a reconstituted protein, and method and kit for the production thereof
US5492756A (en) 1994-07-22 1996-02-20 Mississippi State University Kenaf core board material
DE4432899A1 (en) 1994-09-15 1996-03-21 Wacker Chemie Gmbh Crosslinkable polymer powder compositions
DE19581850T1 (en) 1994-11-21 1997-10-16 Asahi Chemical Ind Polymer composite material
US6441122B1 (en) 1995-01-05 2002-08-27 Johns Manville International, Inc. Melamine in urea-extended phenol/formaldehyde fiberglass binders
EP0754656B1 (en) 1995-02-07 2004-09-15 Daicel-Degussa Ltd. Cement setting retarder and cement setting retarder sheet
KR19980702344A (en) 1995-02-20 1998-07-15 로버트 밴 바우닝 Manufacturing method of mineral wool product
ATE153681T1 (en) 1995-03-24 1997-06-15 Giulini Chemie AMPHOTERELIC POLYMER DISPERSION, METHOD FOR PRODUCTION AND USE THEREOF
US5919831A (en) 1995-05-01 1999-07-06 Philipp; Warren H. Process for making an ion exchange material
US5670585A (en) 1995-06-13 1997-09-23 Schuller International, Inc. Use of polyacrylic acid and other polymers as additives in fiberglass formaldehyde based binders
US5562740A (en) 1995-06-15 1996-10-08 The Procter & Gamble Company Process for preparing reduced odor and improved brightness individualized, polycarboxylic acid crosslinked fibers
US5720796A (en) 1995-08-08 1998-02-24 W. R. Grace & Co.-Conn. Process of using roll press grinding aid for granulated blast furnace slag
US5942123A (en) 1995-09-05 1999-08-24 Mcardle; Blaise Method of using a filter aid protein-polysaccharide complex composition
US5788423A (en) * 1995-09-08 1998-08-04 G.P. Industries, Inc. Masonry block retaining wall with attached keylock facing panels and method of constructing the same
JPH10513502A (en) 1995-11-28 1998-12-22 キンバリー クラーク ワールドワイド インコーポレイテッド Improved colorant stabilizer
JPH09157627A (en) 1995-12-13 1997-06-17 Sekisui Chem Co Ltd Water-soluble tacky adhesive agent composition
US6458889B1 (en) 1995-12-18 2002-10-01 Cohesion Technologies, Inc. Compositions and systems for forming crosslinked biomaterials and associated methods of preparation and use
US7883693B2 (en) 1995-12-18 2011-02-08 Angiodevice International Gmbh Compositions and systems for forming crosslinked biomaterials and methods of preparation of use
US6407225B1 (en) 1995-12-21 2002-06-18 The Dow Chemical Company Compositions comprising hydroxy-functional polymers
AU682630B2 (en) 1996-01-11 1997-10-09 Kowng Young Pharm. & Chem. Co., Ltd. Non-heating food binder
US5788243A (en) * 1996-01-23 1998-08-04 Harshaw; Bob F. Biodegradable target
DE19606394A1 (en) 1996-02-21 1997-08-28 Basf Ag Formaldehyde-free, aqueous binders
US6139619A (en) 1996-02-29 2000-10-31 Borden Chemical, Inc. Binders for cores and molds
US5922403A (en) 1996-03-12 1999-07-13 Tecle; Berhan Method for isolating ultrafine and fine particles
US6072086A (en) 1996-04-12 2000-06-06 Intergen Company Method and composition for controlling formaldehyde fixation by delayed quenching
WO1997039330A1 (en) 1996-04-12 1997-10-23 Oncor, Inc. Method and composition for controlling formaldehyde fixation by delayed quenching
DE19621573A1 (en) 1996-05-29 1997-12-04 Basf Ag Thermally curable, aqueous compositions
US5719092A (en) 1996-05-31 1998-02-17 Eastman Kodak Company Fiber/polymer composite for use as a photographic support
AU717229B2 (en) 1996-06-25 2000-03-23 Borden Chemical, Inc. Binders for cores and molds
US5733624A (en) 1996-07-22 1998-03-31 Guardian Fiberglass, Inc. Mineral fiber insulation batt impregnated with coextruded polymer layering system
CA2212470A1 (en) 1996-08-21 1998-02-21 Rohm And Haas Company A formaldehyde-free, accelerated cure aqueous composition for bonding glass fiber-heat resistant nonwovens
US6067821A (en) 1996-10-07 2000-05-30 Owens Corning Fiberglas Technology, Inc. Process for making mineral wool fibers from lumps of uncalcined raw bauxite
NL1004379C2 (en) 1996-10-29 1998-05-08 Borculo Cooep Weiprod Use of sugar amines and sugar amides as an adhesive, as well as new sugar amines and sugar amides.
BR9712860A (en) 1996-11-04 1999-12-07 Ici Plc Reactive composition with isocyanate, process for preparing rigid polyurethane or urethane modified polyisocyanurate foams, and rigid polyurethane or polyurethane foam modified with urethane
US20020161108A1 (en) 2000-03-09 2002-10-31 Stepan Company, A Corporation Of The State Of Delaware Emulsion polymerization process utilizing ethylenically unsaturated amine salts of sulfonic, phosphoric and carboxylic acids
US6310227B1 (en) 1997-01-31 2001-10-30 The Procter & Gamble Co. Reduced calorie cooking and frying oils having improved hydrolytic stability, and process for preparing
CZ293298B6 (en) 1997-02-03 2004-03-17 Isover Saint-Gobain Biding agent for mineral wool and product of mineral wool bonded thereby
US5932665A (en) 1997-02-06 1999-08-03 Johns Manville International, Inc. Polycarboxy polymer acid binders having reduced cure temperatures
JPH10234314A (en) 1997-02-24 1998-09-08 Miyoujiyou Shokuhin Kk Composition for giving scorch on food
CA2284911C (en) 1997-03-19 2006-10-24 Cultor Food Science, Inc. Polymerization of mono-and disaccharides using low levels of mineral acids
US6475552B1 (en) 1997-03-19 2002-11-05 Danisco Finland Oy Polymerization of mono and disaccharides using low levels of polycarboxylic acids
CN1089727C (en) 1997-04-11 2002-08-28 广州市环境保护科学研究所 Method for preparing cation/amphoteric graft polyacrylamide flocculating agent
TW408152B (en) 1997-04-25 2000-10-11 Rohm & Haas Formaldehyde-free curable composition and method for bonding heat-resistant fibers of a nonwoven material by using the composition
US6482875B2 (en) 1997-05-02 2002-11-19 Dorus Klebetechnik Gmbh & Co. Kg Thermoplastic composite material
US5954869A (en) 1997-05-07 1999-09-21 Bioshield Technologies, Inc. Water-stabilized organosilane compounds and methods for using the same
ES2171826T3 (en) 1997-05-15 2002-09-16 Nestle Sa PROCEDURE FOR PREPARATION AND EXTRACTION OF AROMAS.
DE19721691A1 (en) 1997-05-23 1998-11-26 Basf Ag Adhesives based on an aqueous polymer dispersion, process for their preparation and their use
IT1292024B1 (en) 1997-05-28 1999-01-25 Balzaretti Modigliani Spa PROCESS AND DEVICE FOR THE RECYCLING OF WASTE IN A PRODUCTION OF MINERAL FIBERS
DE19729161A1 (en) 1997-07-08 1999-01-14 Basf Ag Thermally curable, aqueous compositions
JP3188657B2 (en) 1997-07-24 2001-07-16 株式会社第一化成 Tablet or granular product
US5977232A (en) 1997-08-01 1999-11-02 Rohm And Haas Company Formaldehyde-free, accelerated cure, aqueous composition for bonding glass fiber heat-resistant nonwovens
DE19735959A1 (en) 1997-08-19 1999-02-25 Basf Ag Thermally curable, aqueous binding agent composition
US5895804A (en) 1997-10-27 1999-04-20 National Starch And Chemical Investment Holding Corporation Thermosetting polysaccharides
US5983586A (en) 1997-11-24 1999-11-16 Owens Corning Fiberglas Technology, Inc. Fibrous insulation having integrated mineral fibers and organic fibers, and building structures insulated with such fibrous insulation
US6171654B1 (en) 1997-11-28 2001-01-09 Seydel Research, Inc. Method for bonding glass fibers with cross-linkable polyester resins
JP3721530B2 (en) 1997-12-12 2005-11-30 昭和電工株式会社 Textile treatment composition
US6379814B1 (en) 1997-12-19 2002-04-30 Georgia-Pacific Resins, Inc. Cyclic urea-formaldehyde prepolymer for use in phenol-formaldehyde and melamine-formaldehyde resin-based binders
US6143243A (en) 1997-12-29 2000-11-07 Prestone Products Corporation Method of inhibiting cavitation-erosion corrosion of aluminum surfaces using carboxylic acid based compositions comprising polymerizable-acid graft polymers
NL1008041C2 (en) 1998-01-16 1999-07-19 Tidis B V I O Application of a water-soluble binder system for the production of glass or rock wool.
EP0933021A1 (en) 1998-02-02 1999-08-04 Rockwool International A/S Process for the manufacture of a mineral wool planth growth substrate and the obtainable mineral wool plant growth substrate
EP0936060A1 (en) 1998-02-13 1999-08-18 Rockwool International A/S Man-made vitreous fibre products and their use in fire protection systems
DE69909454T3 (en) 1998-03-19 2009-09-10 Rockwool International A/S Method and device for producing a mineral fiber product
US6140445A (en) 1998-04-17 2000-10-31 Crompton Corporation Silane functional oligomer
US6171444B1 (en) 1998-04-22 2001-01-09 Sri International Method and composition for the sizing of paper with a mixture of a polyacid and a polybase
US6291023B1 (en) 1998-04-22 2001-09-18 Sri International Method and composition for textile printing
ES2178428T5 (en) 1998-05-18 2011-01-27 Rockwool International A/S STABILIZED WATERPROOF PHENOLIC BINDER FOR MINERAL WOOL, AND PRODUCTION OF MINERAL WOOL PRODUCTS.
DE69841616D1 (en) 1998-05-18 2010-05-27 Knauf Fiber Glass Gmbh BINDER COMPOSITION FOR GLASS FIBER AND METHOD OF MANUFACTURING
WO1999061384A1 (en) 1998-05-28 1999-12-02 Owens Corning Corrosion inhibiting composition for polyacrylic acid based binders
CA2458333C (en) 1998-05-28 2005-08-09 Owens Corning Corrosion inhibiting composition for polyacrylic acid based binders
JP3907837B2 (en) 1998-06-12 2007-04-18 富士フイルム株式会社 Image recording material
US5993709A (en) * 1998-06-23 1999-11-30 Bonomo; Brian Method for making composite board using phenol formaldehyde binder
DE19833920A1 (en) 1998-07-28 2000-02-03 Basf Ag Textile fabrics
US6468668B1 (en) 1998-09-14 2002-10-22 Canon Kabushiki Kaisha Cellulosic composite product and a method of producing the same
US6331350B1 (en) 1998-10-02 2001-12-18 Johns Manville International, Inc. Polycarboxy/polyol fiberglass binder of low pH
EP0990727A1 (en) 1998-10-02 2000-04-05 Johns Manville International Inc. Polycarboxy/polyol fiberglass binder
US6231721B1 (en) 1998-10-09 2001-05-15 Weyerhaeuser Company Compressible wood pulp product
JP4554012B2 (en) 1998-10-13 2010-09-29 パナソニック株式会社 Aluminum electrolytic capacitor
CN1251738A (en) 1998-10-21 2000-05-03 朱国和 Medium product for soilless culture and its production method
US6214265B1 (en) * 1998-12-17 2001-04-10 Bayer Corporation Mixed PMDI/resole resin binders for the production of wood composite products
DE60039084D1 (en) 1999-03-19 2008-07-17 Saint Gobain Cultilene B V Substrate for ungodly culture
US6440204B1 (en) 1999-03-31 2002-08-27 Penford Corporation Packaging and structural materials comprising potato peel waste
US6210472B1 (en) 1999-04-08 2001-04-03 Marconi Data Systems Inc. Transparent coating for laser marking
JP4614541B2 (en) 1999-04-16 2011-01-19 三栄源エフ・エフ・アイ株式会社 Sucralose-containing composition and edible product containing the composition
US6331513B1 (en) 1999-04-28 2001-12-18 Jacam Chemicals L.L.C. Compositions for dissolving metal sulfates
EP1187875A1 (en) 1999-05-14 2002-03-20 The Dow Chemical Company Process for preparing starch and epoxy-based thermoplastic polymer compositions
DE19923118A1 (en) 1999-05-19 2000-11-23 Henkel Kgaa Polymerizable composition for the anticorrosion coating of metallic substrates contains an organic titanium, silicon or zirconium compound
JP2000327841A (en) 1999-05-24 2000-11-28 Canon Inc Molding comprising sugar chain polymer compound
US6194512B1 (en) 1999-06-28 2001-02-27 Owens Corning Fiberglas Technology, Inc. Phenol/formaldehyde and polyacrylic acid co-binder and low emissions process for making the same
DE19930555C1 (en) 1999-07-02 2001-01-18 Basf Coatings Ag Aqueous coating material, especially an aqueous filler or stone chip protection primer
US6133347A (en) 1999-07-09 2000-10-17 Mbt Holding Ag Oligomeric dispersant
EP1086932A1 (en) 1999-07-16 2001-03-28 Rockwool International A/S Resin for a mineral wool binder comprising the reaction product of an amine with a first and second anhydride
CA2379106C (en) 1999-07-26 2009-11-03 Minnesota Corn Processors Llc De-icing composition and method
US7814512B2 (en) 2002-09-27 2010-10-12 Microsoft Corporation Dynamic adjustment of EPG level of detail based on user behavior
US6306997B1 (en) 1999-07-29 2001-10-23 Iowa State University Research Foundation, Inc. Soybean-based adhesive resins and composite products utilizing such adhesives
US6281298B1 (en) 1999-08-20 2001-08-28 H. B. Fuller Licensing & Financing Inc. Water-based pressure sensitive adhesives having enhanced characteristics
US20030148084A1 (en) 2000-02-11 2003-08-07 Trocino Frank S. Vegetable protein adhesive compositions
CA2400747A1 (en) 2000-02-11 2001-08-16 Heartland Resource Technologies Llc Vegetable protein adhesive compositions
US20020028857A1 (en) 2000-03-31 2002-03-07 Holy Norman L. Compostable, degradable plastic compositions and articles thereof
US6410036B1 (en) 2000-05-04 2002-06-25 E-L Management Corp. Eutectic mixtures in cosmetic compositions
US20020096278A1 (en) 2000-05-24 2002-07-25 Armstrong World Industries, Inc. Durable acoustical panel and method of making the same
EP1164163A1 (en) 2000-06-16 2001-12-19 Rockwool International A/S Binder for mineral wool products
DE10030563B4 (en) 2000-06-21 2005-06-30 Agrolinz Melamin Gmbh Fiber composites high dimensional stability, weathering resistance and flame resistance, process for their preparation and their use
EP1170265A1 (en) 2000-07-04 2002-01-09 Rockwool International A/S Binder for mineral wool products
US6379739B1 (en) 2000-09-20 2002-04-30 Griffith Laboratories Worldwide, Inc. Acidulant system for marinades
DE60112527T2 (en) 2000-09-20 2006-06-01 Celanese International Corp., Dallas Crosslinker systems of monohydroxyalkylurea and polysaccharide
US6613378B1 (en) 2000-10-18 2003-09-02 The United States Of America As Represented By The Secretary Of Agriculture Sugar-based edible adhesives
US6525009B2 (en) 2000-12-07 2003-02-25 International Business Machines Corporation Polycarboxylates-based aqueous compositions for cleaning of screening apparatus
DE10101944A1 (en) 2001-01-17 2002-07-18 Basf Ag A new binder for finely divided materials, useful for preparation of flat-shaped articles from finely divided materials, comprises the reaction product of di or tricarboxylic acid or its anhydride with ammonia
FR2820736B1 (en) 2001-02-14 2003-11-14 Saint Gobain Isover PROCESS AND DEVICE FOR FORMING MINERAL WOOL
US7816514B2 (en) 2001-02-16 2010-10-19 Cargill, Incorporated Glucosamine and method of making glucosamine from microbial biomass
JP3750552B2 (en) 2001-03-28 2006-03-01 日東紡績株式会社 Method for producing glass fiber wound body and method for producing glass fiber fabric
US20020197352A1 (en) 2001-04-02 2002-12-26 Pacifichealth Laboratories, Inc. Sports drink composition for enhancing glucose uptake into the muscle and extending endurance during physical exercise
US6989171B2 (en) 2001-04-02 2006-01-24 Pacifichealth Laboratories, Inc. Sports drink composition for enhancing glucose uptake into the muscle and extending endurance during physical exercise
DE10116810A1 (en) 2001-04-04 2002-12-19 Wacker Chemie Gmbh Binders and their use in processes for the production of molded parts based on mineral fibers
US6821547B2 (en) 2001-04-10 2004-11-23 Danisco Usa, Inc. Polymerization of mono and disaccharides with monocarboxylic acids and lactones
NZ549563A (en) 2001-04-10 2008-01-31 Danisco Usa Inc Carbohydrate polymers prepared by the polymerization of mono and disaccharides with monocarboxylic acids and lactones
US20030040239A1 (en) 2001-05-17 2003-02-27 Certainteed Corporation Thermal insulation containing supplemental infrared radiation absorbing material
US7157524B2 (en) 2001-05-31 2007-01-02 Owens Corning Fiberglas Technology, Inc. Surfactant-containing insulation binder
NL1018568C2 (en) 2001-07-17 2003-01-21 Tno Extraction of polysaccharides from vegetable and microbial material.
JP2004060058A (en) 2002-07-24 2004-02-26 Mitsubishi Heavy Ind Ltd Fiber substrate for composite material
US6755938B2 (en) 2001-08-20 2004-06-29 Armstrong World Industries, Inc. Fibrous sheet binders
JP4135387B2 (en) 2001-08-31 2008-08-20 東洋製罐株式会社 Gas barrier material, production method thereof, coating liquid for forming gas barrier layer and packaging material provided with gas barrier material
US20040161993A1 (en) 2001-09-06 2004-08-19 Gary Tripp Inorganic fiber insulation made from glass fibers and polymer bonding fibers
TWI331526B (en) 2001-09-21 2010-10-11 Bristol Myers Squibb Pharma Co Lactam-containing compounds and derivatives thereof as factor xa inhibitors
US20030087095A1 (en) 2001-09-28 2003-05-08 Lewis Irwin Charles Sugar additive blend useful as a binder or impregnant for carbon products
US6592211B2 (en) 2001-10-17 2003-07-15 Hewlett-Packard Development Company, L.P. Electrostatic mechanism for inkjet printers resulting in improved image quality
WO2003035740A1 (en) 2001-10-24 2003-05-01 Temple-Inland Forest Products Corporation Saccharide-based resin for the preparation of composite products
US6858074B2 (en) 2001-11-05 2005-02-22 Construction Research & Technology Gmbh High early-strength cementitious composition
FR2832272B1 (en) 2001-11-09 2004-09-24 Commissariat Energie Atomique PASSIVE DEVICE FOR INCREASING TRANSMISSION EFFICIENCY OF RADIO FREQUENCY SYSTEMS
JP3787085B2 (en) 2001-12-04 2006-06-21 関東化学株式会社 Composition for removing photoresist residue
JP4464596B2 (en) 2002-02-15 2010-05-19 日本合成化学工業株式会社 binder
EP1483347B1 (en) 2002-02-20 2006-06-07 E.I. Du Pont De Nemours And Company Lacquers containing highly branched copolyester polyol
US20040087024A1 (en) 2002-02-22 2004-05-06 Insert Therapeutics, Inc. Carbohydrate-modified polymers, compositions and uses related thereto
US7195792B2 (en) 2002-02-22 2007-03-27 Genencor International, Inc. Browning agent
US6992203B2 (en) 2002-03-26 2006-01-31 Jh Biotech, Inc. Metal complexes produced by Maillard Reaction products
DE10218871A1 (en) 2002-04-26 2003-11-13 Degussa Process for impregnating porous mineral substrates
US6955844B2 (en) 2002-05-24 2005-10-18 Innovative Construction And Building Materials Construction materials containing surface modified fibers
FR2839966B1 (en) 2002-05-27 2004-07-23 Saint Gobain Isover FILTERING MEDIA COMPRISING MINERAL FIBERS OBTAINED BY CENTRIFUGATION
US20040034154A1 (en) 2002-06-06 2004-02-19 Georgia-Pacific Resins Corporation Epoxide-type formaldehyde free insulation binder
CN1668696A (en) 2002-06-18 2005-09-14 佐治亚-太平洋树脂公司 Polyester-type formaldehyde free insulation binder
US20040002567A1 (en) 2002-06-27 2004-01-01 Liang Chen Odor free molding media having a polycarboxylic acid binder
FR2842189B1 (en) 2002-07-12 2005-03-04 Saint Gobain Isover THERMALLY INSULATING PRODUCT AND MANUFACTURING METHOD THEREOF
EP1382642A1 (en) 2002-07-15 2004-01-21 Rockwool International A/S Formaldehyde-free aqueous binder composition for mineral fibers
US6887961B2 (en) 2002-07-26 2005-05-03 Kimberly-Clark Worldwide, Inc. Absorbent binder composition and method of making it
US6962714B2 (en) 2002-08-06 2005-11-08 Ecolab, Inc. Critical fluid antimicrobial compositions and their use and generation
US7384881B2 (en) 2002-08-16 2008-06-10 H.B. Fuller Licensing & Financing, Inc. Aqueous formaldehyde-free composition and fiberglass insulation including the same
US20040048531A1 (en) 2002-09-09 2004-03-11 Hector Belmares Low formaldehyde emission panel
US7090745B2 (en) 2002-09-13 2006-08-15 University Of Pittsburgh Method for increasing the strength of a cellulosic product
US7202326B2 (en) 2002-09-24 2007-04-10 Asahi Kasei Chemicals Corporation Glycolic acid copolymer and method for production thereof
WO2004033482A2 (en) 2002-10-08 2004-04-22 Genencor International, Inc. Phenolic binding peptides
US6818694B2 (en) 2002-10-10 2004-11-16 Johns Manville International, Inc. Filler extended fiberglass binder
US7201825B2 (en) 2002-10-25 2007-04-10 Weyerhaeuser Company Process for making a flowable and meterable densified fiber particle
US7141626B2 (en) 2002-10-29 2006-11-28 National Starch And Chemical Investment Holding Corporation Fiberglass non-woven catalyst
US6699945B1 (en) 2002-12-03 2004-03-02 Owens Corning Fiberglas Technology, Inc. Polycarboxylic acid based co-binder
US7026390B2 (en) 2002-12-19 2006-04-11 Owens Corning Fiberglas Technology, Inc. Extended binder compositions
US20040131874A1 (en) 2003-01-08 2004-07-08 Georgia-Pacific Resins, Inc. Reducing odor in fiberglass insulation bonded with urea-extended phenol-formaldehyde resins
US7201778B2 (en) 2003-01-13 2007-04-10 North Carolina State University Ionic cross-linking of ionic cotton with small molecular weight anionic or cationic molecules
US6884849B2 (en) 2003-02-21 2005-04-26 Owens-Corning Fiberglas Technology, Inc. Poly alcohol-based binder composition
US7265169B2 (en) 2003-03-20 2007-09-04 State of Oregon Acting by and trhough the State Board of Higher Education on Behalf of Oregon State University Adhesive compositions and methods of using and making the same
US7056563B2 (en) 2003-04-04 2006-06-06 Weyerhaeuser Company Hot cup made from an insulating paperboard
DE10317937A1 (en) 2003-04-17 2004-11-04 Saint-Gobain Isover G+H Ag Process for the production of pipe shells made of mineral wool and such pipe shells
FR2854626B1 (en) 2003-05-07 2006-12-15 Saint Gobain Isover MINERAL FIBER-BASED PRODUCT AND FIBER OBTAINING DEVICE
US7947766B2 (en) 2003-06-06 2011-05-24 The Procter & Gamble Company Crosslinking systems for hydroxyl polymers
CA2470783A1 (en) 2003-06-12 2004-12-12 National Starch And Chemical Investment Holding Corporation Fiberglass nonwoven binder
US20040254285A1 (en) 2003-06-12 2004-12-16 Rodrigues Klein A. Fiberglass nonwoven binder
US7807077B2 (en) 2003-06-16 2010-10-05 Voxeljet Technology Gmbh Methods and systems for the manufacture of layered three-dimensional forms
US8870814B2 (en) 2003-07-31 2014-10-28 Boston Scientific Scimed, Inc. Implantable or insertable medical devices containing silicone copolymer for controlled delivery of therapeutic agent
CN1251738C (en) 2003-08-05 2006-04-19 王春荣 Chinese medicine for treating ashen nail and its preparation method
AU2004201002B2 (en) 2003-08-26 2009-08-06 Rohm And Haas Company Curable aqueous composition and use as heat-resistant nonwoven binder
DE10342858A1 (en) 2003-09-15 2005-04-21 Basf Ag Use of formaldehyde-free aqueous binders for substrates
US20050059770A1 (en) 2003-09-15 2005-03-17 Georgia-Pacific Resins Corporation Formaldehyde free insulation binder
DE10344926B3 (en) 2003-09-25 2005-01-20 Dynea Erkner Gmbh Wooden components, eg boards, with one or more strand layers with a binding agent system, are produced by partial hardening during a first stage, and forming during a second stage
PL1678386T5 (en) 2003-10-06 2021-08-16 Saint-Gobain Isover Insulating material consisting of a web of mineral fibres for wedging between beams
EP1522642A1 (en) 2003-10-06 2005-04-13 Saint-Gobain Isover G+H Ag Insulating mat of mineral fibre wound in a roll for press fitting between beams
US20070009582A1 (en) 2003-10-07 2007-01-11 Madsen Niels J Composition useful as an adhesive and use of such a composition
EP1524282A1 (en) 2003-10-15 2005-04-20 Sika Technology AG Two-component polyurethane composition having high early strength
US20050208095A1 (en) 2003-11-20 2005-09-22 Angiotech International Ag Polymer compositions and methods for their use
US7297204B2 (en) 2004-02-18 2007-11-20 Meadwestvaco Corporation Water-in-oil bituminous dispersions and methods for producing paving compositions from the same
ZA200606788B (en) 2004-02-18 2007-12-27 Meadwestvaco Corp Method for producing bituminous compositions
US7833338B2 (en) 2004-02-18 2010-11-16 Meadwestvaco Packaging Systems, Llc Method for producing bitumen compositions
US7842382B2 (en) 2004-03-11 2010-11-30 Knauf Insulation Gmbh Binder compositions and associated methods
DE102004033561B4 (en) 2004-03-11 2007-09-13 German Carbon Teterow Gmbh Process for the preparation of form activated carbon
DE102004013390A1 (en) 2004-03-17 2005-10-06 Basf Ag roofing sheets
US20050215153A1 (en) 2004-03-23 2005-09-29 Cossement Marc R Dextrin binder composition for heat resistant non-wovens
JP4527435B2 (en) 2004-04-19 2010-08-18 関西ペイント株式会社 CURABLE COMPOSITION AND COATING METHOD USING THE COMPOSITION
US7404875B2 (en) 2004-04-28 2008-07-29 Georgia-Pacific Consumer Products Lp Modified creping adhesive composition and method of use thereof
US6977116B2 (en) 2004-04-29 2005-12-20 The Procter & Gamble Company Polymeric structures and method for making same
US8580953B2 (en) 2004-06-21 2013-11-12 Evonik Degussa Gmbh Water-absorbing polysaccharide and method for producing the same
US7781512B2 (en) 2004-07-09 2010-08-24 Johns Manville Control of product in curing ovens for formaldehyde-free glass fiber products
US20060044302A1 (en) 2004-08-25 2006-03-02 Wilson Chen Notebook DC power sharing arrangement
JP2008516071A (en) 2004-10-13 2008-05-15 クナーフ インシュレーション ゲーエムベーハー Polyester binding composition
DE102004051861A1 (en) 2004-10-26 2006-04-27 Degussa Ag Use of an aqueous dispersion based on an unsaturated, amorphous polyester based on certain dicidol isomers
US20060099870A1 (en) 2004-11-08 2006-05-11 Garcia Ruben G Fiber mat bound with a formaldehyde free binder, asphalt coated mat and method
US7514027B2 (en) 2005-02-17 2009-04-07 Saint-Gobain Isover Process for manufacturing products of mineral wool, in particular monolayer and multilayer products
FR2882366B1 (en) 2005-02-18 2008-04-18 Coletica Sa RETICULATED CARBOHYDRATE POLYMER, IN PARTICULAR BASED ON POLYSACCHARIDES AND / OR POLYOLS
KR100712970B1 (en) 2005-03-03 2007-05-02 롬 앤드 하아스 컴패니 Method for reducing corrosion
US20060231487A1 (en) 2005-04-13 2006-10-19 Bartley Stuart L Coated filter media
MX2007013887A (en) 2005-05-06 2008-04-04 Dynea Oy Poly (vinyl alcohol) - based formaldehyde-free curable aqueous composition.
DE102005023431A1 (en) 2005-05-20 2006-11-23 Juchem Gmbh Water-based solution for application to dough pieces useful for producing laugengebaeck comprises an alkali metal or ammonium carbonate or bicarbonate and a sugar
DE102005029479A1 (en) 2005-06-24 2007-01-04 Saint-Gobain Isover G+H Ag Process for producing bonded mineral wool and binder therefor
EP1741726A1 (en) 2005-07-08 2007-01-10 Rohm and Haas France SAS Curable aqueous composition and use as water repellant fiberglass nonwoven binder
CN102766423B (en) 2005-07-26 2015-10-28 可耐福保温材料有限公司 Binding agent and material prepared therefrom
WO2007024020A1 (en) 2005-08-26 2007-03-01 Asahi Fiber Glass Company, Limited Aqueous binder for inorganic fiber and thermal and/or acoustical insulation material using the same
ATE359315T1 (en) 2005-09-14 2007-05-15 Nat Starch Chem Invest NEW AQUEOUS ADHESIVES FOR COMMERCIAL APPLICATIONS
WO2007050964A1 (en) 2005-10-26 2007-05-03 Polymer Ventures, Inc. Grease and water resistant article
DE102005063381B4 (en) 2005-11-28 2009-11-19 Saint-Gobain Isover G+H Ag Process for the production of formaldehyde-free bonded mineral wool and mineral wool product
US7872088B2 (en) 2006-02-16 2011-01-18 Knauf Insulation Gmbh Low formaldehyde emission fiberglass
US20070270070A1 (en) 2006-05-19 2007-11-22 Hamed Othman A Chemically Stiffened Fibers In Sheet Form
US20070287018A1 (en) 2006-06-09 2007-12-13 Georgia-Pacific Resins, Inc. Fibrous mats having reduced formaldehyde emissions
US9169157B2 (en) 2006-06-16 2015-10-27 Georgia-Pacific Chemicals Llc Formaldehyde free binder
US7795354B2 (en) 2006-06-16 2010-09-14 Georgia-Pacific Chemicals Llc Formaldehyde free binder
US7803879B2 (en) 2006-06-16 2010-09-28 Georgia-Pacific Chemicals Llc Formaldehyde free binder
US8048257B2 (en) 2006-06-23 2011-11-01 Akzo Nobel Coating International B.V. Adhesive system and method of producing a wood based product
US7579289B2 (en) 2006-07-05 2009-08-25 Rohm And Haas Company Water repellant curable aqueous compositions
US7829611B2 (en) 2006-08-24 2010-11-09 Rohm And Haas Company Curable composition
US7749923B2 (en) 2006-09-07 2010-07-06 Johns Manville Facing and faced insulation products
WO2008053332A1 (en) 2006-11-03 2008-05-08 Dynea Oy Renewable binder for nonwoven materials
US20080160302A1 (en) 2006-12-27 2008-07-03 Jawed Asrar Modified fibers for use in the formation of thermoplastic fiber-reinforced composite articles and process
JP2008163178A (en) 2006-12-28 2008-07-17 Advics:Kk Friction material for brake
ES2945888T3 (en) 2007-01-25 2023-07-10 Knauf Insulation Method of manufacturing a mineral fiber insulation product
US20100084598A1 (en) 2007-01-25 2010-04-08 Roger Jackson Mineral fibre insulation
WO2008089847A1 (en) * 2007-01-25 2008-07-31 Knauf Insulation Limited Composite wood board
HUE043898T2 (en) 2007-01-25 2019-09-30 Knauf Insulation Hydroponics growing medium
CN101668713B (en) 2007-01-25 2012-11-07 可耐福保温材料有限公司 Mineral fibre board
PT2108006T (en) 2007-01-25 2020-12-21 Knauf Insulation Gmbh Binders and materials made therewith
EP2137223B1 (en) 2007-04-13 2019-02-27 Knauf Insulation GmbH Composite maillard-resole binders
WO2008141201A1 (en) 2007-05-10 2008-11-20 Fish Christopher N Composite materials
WO2009006532A1 (en) 2007-07-05 2009-01-08 Knauf Insulation Gmbh Hydroxymonocarboxylic acid-based maillard binder
DE102007035334A1 (en) 2007-07-27 2009-01-29 Boehringer Ingelheim Pharma Gmbh & Co. Kg Novel substituted arylsulfonylglycines, their preparation and their use as pharmaceuticals
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FR2924719B1 (en) 2007-12-05 2010-09-10 Saint Gobain Isover SIZING COMPOSITION FOR MINERAL WOOL COMPRISING MONOSACCHARIDE AND / OR POLYSACCHARIDE AND POLYCARBOXYLIC ORGANIC ACID, AND INSULATING PRODUCTS OBTAINED
JP4927066B2 (en) 2007-12-26 2012-05-09 ローム アンド ハース カンパニー Curable composition
JP4789995B2 (en) 2007-12-26 2011-10-12 ローム アンド ハース カンパニー Composite material and manufacturing method thereof
KR20110007190A (en) 2008-04-14 2011-01-21 다우 글로벌 테크놀로지스 인크. Use of filler that undergoes endothermic phase transition to lower the reaction exotherm of epoxy based compositions
PE20100438A1 (en) 2008-06-05 2010-07-14 Georgia Pacific Chemicals Llc COMPOSITION OF AQUEOUS SUSPENSION WITH PARTICLES OF VALUABLE MATERIALS AND IMPURITIES
JP5248954B2 (en) 2008-09-02 2013-07-31 スリーエム イノベイティブ プロパティズ カンパニー Abrasive products containing inclusion compounds
US8048332B2 (en) 2008-11-12 2011-11-01 Georgia-Pacific Chemicals Llc Method for inhibiting ice formation and accumulation
US8580375B2 (en) 2008-11-24 2013-11-12 Rohm And Haas Company Soy composite materials comprising a reducing sugar and methods of making the same
ES2704135T3 (en) 2009-02-27 2019-03-14 Rohm & Haas Fast-curing carbohydrate composition
DE102009021555B4 (en) 2009-05-15 2011-06-22 AGM Mader GmbH, 85221 Process for the preparation of a binder and use of such a binder for the production of a shaped body
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WO2011015946A2 (en) 2009-08-07 2011-02-10 Knauf Insulation Molasses binder
US8708162B2 (en) 2009-08-19 2014-04-29 Johns Manville Polymeric fiber webs with binder comprising salt of inorganic acid
US20110040010A1 (en) 2009-08-11 2011-02-17 Kiarash Alavi Shooshtari Curable fiberglass binder comprising salt of inorganic acid
WO2011019598A1 (en) 2009-08-11 2011-02-17 Johns Manville Curable fiberglass binder
US8377564B2 (en) 2009-08-19 2013-02-19 Johns Manville Cellulosic composite
US9365963B2 (en) 2009-08-11 2016-06-14 Johns Manville Curable fiberglass binder
US8372900B2 (en) 2009-08-19 2013-02-12 Johns Manville Cellulosic composite with binder comprising salt of inorganic acid
US9994482B2 (en) 2009-08-11 2018-06-12 Johns Manville Curable fiberglass binder
US8680224B2 (en) 2010-02-01 2014-03-25 Johns Manville Formaldehyde-free protein-containing binder compositions
CA2793795A1 (en) 2010-03-31 2011-10-06 Knauf Insulation Gmbh Insulation products having a non-aqueous moisturizer
EP2386605B1 (en) 2010-04-22 2017-08-23 Rohm and Haas Company Durable thermosets from reducing sugars and primary polyamines
PL2386394T3 (en) 2010-04-22 2020-11-16 Rohm And Haas Company Durable thermoset binder compositions from 5-carbon reducing sugars and use as wood binders
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WO2012037451A2 (en) 2010-09-17 2012-03-22 Knauf Insulation Gmbh Organic acid carbohydrate binders and materials made therewith
FR2978768B1 (en) 2011-08-05 2014-11-28 Saint Gobain Isover SINKING COMPOSITION FOR MINERAL WOOL BASED ON SUCROSE REDUCER AND HYDROGEN SACCHARIDE, AND INSULATING PRODUCTS OBTAINED
GB201120137D0 (en) 2011-11-22 2012-01-04 Dynea Oy Modified binder compositions
DE112012005805B4 (en) 2012-02-03 2024-01-04 Toyota Jidosha Kabushiki Kaisha Electrical storage system and method for determining a state of a plurality of electrical storage blocks
GB201206193D0 (en) 2012-04-05 2012-05-23 Knauf Insulation Ltd Binders and associated products
US10815593B2 (en) 2012-11-13 2020-10-27 Johns Manville Viscosity modified formaldehyde-free binder compositions

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Publication number Priority date Publication date Assignee Title
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CN108297221A (en) * 2017-01-11 2018-07-20 广东华润涂料有限公司 The water-borne dispersions of siloxanes reduce the application of the muscle that rises of wood substrate and the product containing the anti-muscle coating that rises
US11198230B2 (en) 2017-01-11 2021-12-14 Swimc Llc Use of aqueous dispersion of siloxane for reducing grain puffing of wood substrate and article comprising anti-grain puffing coating
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US20190338129A1 (en) 2019-11-07

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