CN101660267A - Tea saponin textile auxiliary agent and production technology thereof - Google Patents
Tea saponin textile auxiliary agent and production technology thereof Download PDFInfo
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- CN101660267A CN101660267A CN200910102257A CN200910102257A CN101660267A CN 101660267 A CN101660267 A CN 101660267A CN 200910102257 A CN200910102257 A CN 200910102257A CN 200910102257 A CN200910102257 A CN 200910102257A CN 101660267 A CN101660267 A CN 101660267A
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- tea saponin
- auxiliary agent
- textile auxiliary
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- fatty alcohol
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Abstract
The invention discloses a tea saponin textile auxiliary agent which consists of the following raw materials by weight percent: 2-20% of refined tea saponin, 4-33% of surface active agent, 0.69-3% of additive and the balance of deionized water; and the invention also discloses a production technology thereof. The tea saponin textile auxiliary agent has good application effectiveness of high cleaning and bleaching actions, strong decontamination and deodorization capacities, environmental protection, cleanness and the like.
Description
Technical field
The present invention relates to a kind of textile auxiliary in the field of fine chemical, being specifically related to a kind of is tea saponin textile auxiliary agent and the production technology that additive is made with the pure natural ecological composition.
Background technology
Along with the formulation of Law on Environmental Protection and the enforcement of environmental protection engineering, those have the use that can progressively be under an embargo of the textile auxiliary of severe contamination to environment, and on the contrary, the environmental type product will demonstrate great vitality.Tea Saponin is a kind of natural glycoside compound, is to extract the natural surfactant that obtains from degreasing tea seed grouts.Pure Tea Saponin is a colorless prismatic crystal, and molecular formula is C
57H
90O
28, fusing point is 224 ℃, is soluble in hot water, methyl alcohol, hydrous ethanol and n-butanol.
Tea Saponin is a kind of good natural non-ionic surface active agent, has abilities such as good emulsifying, dispersion, foaming, infiltration, decontamination.At present, China publication CN200610032396.3,200710030244.4 and 200810143505.8 is the relevant report of Tea Saponin shampoo, compares with common shampoo, and it not only has good dirt-removing power, and ecological, environmental protective, also have fungistatic effect; Patent about tea saponin textile auxiliary agent does not also occur.
Summary of the invention
The object of the present invention is to provide a kind of Tea Saponin weaving washing assisant and production technology, extract Tea Saponin the tea cake that the present invention produces behind natural camellia seed expressed oil, then with itself and some other surfactant compound, the textile auxiliary that makes has good effects such as clean discoloration height, decontamination and deodorant ability are strong, environment-protecting clean.
For reaching above-mentioned purpose, the present invention adopts following technical scheme,
A kind of tea saponin textile auxiliary agent, form by following raw materials by weight percent:
Refined theasapogenin 2-20%;
Surfactant 4-33%;
Additive 0.69-3%;
The surplus deionized water.
Described surfactant adopts a kind of or its mixture in dodecyl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol and the sodium alkyl benzene sulfonate, a kind of or its mixture and cocoanut fatty acid diethanolamide in polyoxyethylated alkyl phenol and the fatty alcohol-polyoxyethylene ether.
Described additive is anti redeposition agent CMC and essence.
The molecular formula of described sodium sulfate of polyethenoxy ether of fatty alcohol is RO (CH
2CH
2O) nSO
3Na, wherein R=C
12-C
15N=2-3.
The molecular formula of described sodium alkyl benzene sulfonate is R-C
6H
4-SO
3Na, wherein R=C
10-C
13
The molecular formula of described polyoxyethylated alkyl phenol is R-C
6H
4(OC
2H
4) nOH, R=8 wherein, 9,12; N=1-150, wherein n generally gets 10.
The molecular formula of described fatty alcohol-polyoxyethylene ether is C
12H
25O (CH
2CH
2O)
nH, n=3 wherein, 5,7,9,15,20.
In the described surfactant, percentage by weight a kind of or that its mixture adopts in dodecyl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol and the sodium alkyl benzene sulfonate is the 1-15% of total raw material weight, percentage by weight a kind of or that its mixture adopts in polyoxyethylated alkyl phenol and the fatty alcohol-polyoxyethylene ether is the 2-10% of total raw material weight, the percentage by weight that cocoanut fatty acid diethanolamide adopts is the 1-8% of total raw material weight
In the described additive, the percentage by weight that anti redeposition agent CMC adopts is the 0.5-2% of total raw material weight, and the percentage by weight that essence adopts is the 0.19-1% of total raw material weight.
A kind of production technology of tea saponin textile auxiliary agent comprises the steps:
(1) earlier the leached tea oil slag cake is thoroughly pulverized after, with organic solvent separated and dissolved repeatedly, the decolouring back is dry, promptly gets refined theasapogenin (saponin content 〉=95%);
(2) by weight percentage for the 50-80% deionized water adds emulsion tank, heat to 60-70 ℃;
(3) be the 2-20% refined theasapogenin with percentage by weight, a kind of or its mixture in 1-15% dodecyl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol and the sodium alkyl benzene sulfonate, a kind of or its mixture in 2-10% polyoxyethylated alkyl phenol and the fatty alcohol-polyoxyethylene ether, the 1-8% cocoanut fatty acid diethanolamide adds emulsion tank together, and 60-70 ℃ is mixed stirring 30-60min down;
(4) emulsion of (3) gained is cooled to room temperature after, add 0.5-2% anti redeposition agent CMC, 0.19-1% essence promptly gets tea saponin textile auxiliary agent after leaving standstill froth breaking after stirring.
Described organic solvent adopts ethanol or acetone.
The invention has the beneficial effects as follows: 1, Tea Saponin belongs to the pentacyclic triterpenoid saponin compounds, is a kind of nonionic surface active agent, has stronger foaming, emulsification, dispersion, wetting action, and the influence that changed by water hardness.
2, tea saponin textile auxiliary agent is that natural tea saponin comprehensive utilization another is used for industrial new results, utilize that the Tea Saponin performance is soft, the aqueous solution is slightly acidic feature, be re-dubbed tea saponin textile auxiliary agent, this auxiliary agent is to protein cellulose class non-invasi, make it give full play to superiority aspect the washings such as hair, silk, eider down, be particularly suitable for containing the washing of the thing such as silk, hair of native protein; Be to be used for a kind of low bubble that wool spinning produces, good special purpose detergent efficiently, has stronger dirt-removing power, characteristics such as do not damage fiber, the performance of deoiling is good, clean the whiteness height, penetrability is strong have remedied and have now washed shortcomings such as afterwards fabric is not soft, color and luster is not bright-coloured with lotion because degreasing crosses to force.And Tea Saponin easily is degraded to innocuous substance, and the textile auxiliary of production can reduce the pollution to environment widely.
The specific embodiment
Embodiment 1
In the emulsion tank that present embodiment joins 74.35% deionized water by weight percentage and be warming up to 60 ℃, after the leached tea oil slag cake thoroughly pulverized,, obtain refined theasapogenin (saponin content 〉=95%) after the drying of decolouring back with organic solvent ethanol separated and dissolved repeatedly; Add emulsion tank together by 10% refined theasapogenin, 1% dodecyl sodium sulfate, 7% polyoxyethylene nonylphenol ether and 6% cocoanut fatty acid diethanolamide (purchasing) in Shanghai De Mao chemical industry Co., Ltd, adjusting temperature is 75 ℃, 60 ℃ and insulated and stirred 30min, after being cooled to room temperature, add 0.8% anti redeposition agent CMC (purchasing) and 0.85% essence (purchasing), promptly get product after leaving standstill froth breaking after stirring in Guangzhou Bai Sen spices and essence Co., Ltd in Zibo sea billows chemical industry Co., Ltd.
Embodiment 2
In the emulsion tank that present embodiment joins 64.24% deionized water by weight percentage and be warming up to 70 ℃, after the thorough pulverizing of leached tea oil slag cake, with organic solvent-acetone separated and dissolved repeatedly, obtain refined theasapogenin, (saponin content 〉=95%) after the drying of decolouring back; (AEO is the abbreviation of fatty alcohol-polyoxyethylene ether by 13% refined theasapogenin, 13% neopelex, 5% fatty alcohol-polyoxyethylene ether, wherein 9 is numbers of representing the oxygen ethyl) and 3% cocoanut fatty acid diethanolamide (purchasing) in Shanghai De Mao chemical industry Co., Ltd add emulsion tank together, 70 ℃ of insulated and stirred 40min, after being cooled to room temperature, add 1.5% anti redeposition agent CMC (purchasing) and 0.26% essence (purchasing), promptly get product after leaving standstill froth breaking after stirring in Guangzhou Bai Sen spices and essence Co., Ltd in Zibo sea billows chemical industry Co., Ltd.
Embodiment 3
In the emulsion tank that present embodiment joins 64.24% deionized water by weight percentage and be warming up to 65 ℃, after the thorough pulverizing of leached tea oil slag cake, with organic solvent ethanol separated and dissolved repeatedly, obtain refined theasapogenin, (saponin content 〉=95%) after the drying of decolouring back; By 13% refined theasapogenin, 12% sodium sulfate of polyethenoxy ether of fatty alcohol (C
12H
25O (CH
2CH
2O)
2SO
3Na), 3% dodecyl phenol polyethenoxy ether, 3% fatty alcohol-polyoxyethylene ether (AEO-20) and 3% cocoanut fatty acid diethanolamide (purchasing in Shanghai De Mao chemical industry Co., Ltd) add emulsion tank together, 65 ℃ of insulated and stirred 40min, after being cooled to room temperature, add 1.5% anti redeposition agent CMC (purchasing) and 0.26% essence (purchasing), promptly get product after leaving standstill froth breaking after stirring in Guangzhou Bai Sen spices and essence Co., Ltd in Zibo sea billows chemical industry Co., Ltd.
Embodiment 4
In the emulsion tank that present embodiment joins 71.5% deionized water by weight percentage and be warming up to 65 ℃, after the leached tea oil slag cake thoroughly pulverized,, obtain refined theasapogenin, (saponin content 〉=95%) after the drying of decolouring back with organic solvent-acetone separated and dissolved repeatedly; By 2% refined theasapogenin, 8% sodium sulfate of polyethenoxy ether of fatty alcohol (C
12H
25O (CH
2CH
2O)
3SO
3Na), 5% neopelex, 5% OPEO and 7% cocoanut fatty acid diethanolamide (purchasing in Shanghai De Mao chemical industry Co., Ltd) add emulsion tank together, 65 ℃ of insulated and stirred 40min, after being cooled to room temperature, add 1% anti redeposition agent CMC (purchasing) and 0.5% essence (purchasing), promptly get product after leaving standstill froth breaking after stirring in Guangzhou Bai Sen spices and essence Co., Ltd in Zibo sea billows chemical industry Co., Ltd.
Embodiment 5
In the emulsion tank that present embodiment joins 65.31% deionized water by weight percentage and be warming up to 60 ℃, after the thorough pulverizing of leached tea oil slag cake, with organic solvent ethanol separated and dissolved repeatedly, obtain refined theasapogenin, (saponin content 〉=95%) after the drying of decolouring back; By 7% refined theasapogenin, 10% dodecyl sodium sulfate, 5% sodium sulfate of polyethenoxy ether of fatty alcohol (C
12H
25O (CH
2CH
2O)
3SO
3Na), 10% polyoxyethylene nonylphenol ether and 2% cocoanut fatty acid diethanolamide (purchasing in Shanghai De Mao chemical industry Co., Ltd) add emulsion tank together, 60 ℃ of insulated and stirred 40min, after being cooled to room temperature, add 0.5% anti redeposition agent CMC (purchasing) and 0.19% essence (purchasing), promptly get product after leaving standstill froth breaking after stirring in Guangzhou Bai Sen spices and essence Co., Ltd in Zibo sea billows chemical industry Co., Ltd.
Embodiment 6
In the emulsion tank that present embodiment joins 51% deionized water by weight percentage and be warming up to 70 ℃, after the leached tea oil slag cake thoroughly pulverized,, obtain refined theasapogenin, (saponin content 〉=95%) after the drying of decolouring back with organic solvent-acetone separated and dissolved repeatedly; By 20% refined theasapogenin, 2% dodecyl sodium sulfate, 2% sodium sulfate of polyethenoxy ether of fatty alcohol (C
15H
31O (CH
2CH
2O)
3SO
3Na), 2% tridecyl benzene sulfonic acid sodium salt, 6% OPEO, 6% fatty alcohol-polyoxyethylene ether (AEO-3) and 8% cocoanut fatty acid diethanolamide (purchasing in Shanghai De Mao chemical industry Co., Ltd) add emulsion tank together, 70 ℃ of insulated and stirred 40min, after being cooled to room temperature, add 2% anti redeposition agent CMC (purchasing) and 1% essence (purchasing), promptly get product after leaving standstill froth breaking after stirring in Guangzhou Bai Sen spices and essence Co., Ltd in Zibo sea billows chemical industry Co., Ltd.
The above embodiments of the present invention are can not limit the present invention to explanation of the present invention, in implication suitable with claims of the present invention and any change and the combination in the scope, all should think in the scope of claims.
Claims (9)
1, a kind of tea saponin textile auxiliary agent is characterized in that being made up of following raw materials by weight percent:
Refined theasapogenin 2-20%;
Surfactant 4-33%;
Additive 0.69-3%;
The surplus deionized water.
2, tea saponin textile auxiliary agent as claimed in claim 1, it is characterized in that: described surfactant adopts a kind of or its mixture in dodecyl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol and the sodium alkyl benzene sulfonate, a kind of or its mixture and cocoanut fatty acid diethanolamide in polyoxyethylated alkyl phenol and the fatty alcohol-polyoxyethylene ether; Described additive adopts anti redeposition agent CMC and essence.
3, tea saponin textile auxiliary agent as claimed in claim 2 is characterized in that: the molecular formula of described sodium sulfate of polyethenoxy ether of fatty alcohol is RO (CH
2CH
2O) nSO
3Na, wherein R=C
12-C
15N=2-3.
4, tea saponin textile auxiliary agent as claimed in claim 2 is characterized in that: the molecular formula of described sodium alkyl benzene sulfonate is R-C
6H
4-SO
3Na, wherein R=C
10-C
13
5, tea saponin textile auxiliary agent as claimed in claim 2 is characterized in that: the molecular formula of described polyoxyethylated alkyl phenol is R-C
6H
4(OC
2H
4) nOH, R=8 wherein, 9,12; N=1-150.
6, tea saponin textile auxiliary agent as claimed in claim 2 is characterized in that: the molecular formula of described fatty alcohol-polyoxyethylene ether is C
12H
25O (CH
2CH
2O)
nH, n=3 wherein, 5,7,9,15,20.
7, tea saponin textile auxiliary agent as claimed in claim 2, it is characterized in that: described dodecyl sodium sulfate, percentage by weight a kind of or that its mixture adopts in sodium sulfate of polyethenoxy ether of fatty alcohol and the sodium alkyl benzene sulfonate is the 1-15% of total raw material weight, percentage by weight a kind of or that its mixture adopts in polyoxyethylated alkyl phenol and the fatty alcohol-polyoxyethylene ether is the 2-10% of total raw material weight, the percentage by weight that cocoanut fatty acid diethanolamide adopts is the 1-8% of total raw material weight, the percentage by weight that anti redeposition agent CMC adopts is the 0.5-2% of total raw material weight, and the percentage by weight that essence adopts is the 0.19-1% of total raw material weight.
8, a kind of production technology of tea saponin textile auxiliary agent as claimed in claim 1 is characterized in that comprising the steps:
(1) earlier the leached tea oil slag cake is thoroughly pulverized after, with organic solvent separated and dissolved repeatedly, the decolouring back is dry, promptly gets refined theasapogenin (saponin content 〉=95%);
(2) by weight percentage for the 50-80% deionized water adds emulsion tank, heat to 60-70 ℃;
(3) be the 2-20% refined theasapogenin with percentage by weight, a kind of or its mixture in 1-15% dodecyl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol and the sodium alkyl benzene sulfonate, a kind of or its mixture in 2-10% polyoxyethylated alkyl phenol and the fatty alcohol-polyoxyethylene ether, the 1-8% cocoanut fatty acid diethanolamide adds emulsion tank together, insulation mixes and stirs 30-60min;
(4) emulsion of (3) gained is cooled to room temperature after, add 0.5-2% anti redeposition agent CMC, 0.19-1% essence promptly gets tea saponin textile auxiliary agent after leaving standstill froth breaking after stirring.
9, the production technology of tea saponin textile auxiliary agent as claimed in claim 8 is characterized in that: described organic solvent adopts ethanol or acetone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910102257A CN101660267A (en) | 2009-09-10 | 2009-09-10 | Tea saponin textile auxiliary agent and production technology thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910102257A CN101660267A (en) | 2009-09-10 | 2009-09-10 | Tea saponin textile auxiliary agent and production technology thereof |
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Family
ID=41788510
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914848A (en) * | 2010-08-12 | 2010-12-15 | 绍兴中纺院江南分院有限公司 | Pre-treatment auxiliary agent for cotton knitted fabrics, preparation method and application thereof |
| CN102150681A (en) * | 2010-11-19 | 2011-08-17 | 绍兴中纺院江南分院有限公司 | Mosquito-proof assistant agent, preparation method and application thereof |
| CN104099781A (en) * | 2014-07-11 | 2014-10-15 | 上海多纶化工有限公司 | Phosphorus-free textile scouring agent |
| CN104153193A (en) * | 2014-07-31 | 2014-11-19 | 杭州澳美印染有限公司 | Dyeing and finishing method suitable for all-cotton embroidery fabric or all-cotton voile |
| CN104389164A (en) * | 2014-11-28 | 2015-03-04 | 何庆堃 | Printing and dyeing pretreatment aid for silk fabric finishing |
| CN106087403A (en) * | 2016-06-02 | 2016-11-09 | 湖州市菱湖重兆金辉丝织厂 | A kind of wool fabric pest-control finishing agent |
| CN106480726A (en) * | 2016-10-14 | 2017-03-08 | 无锡市华诚印染剂厂 | Silk fabric scouring agent |
| CN106566691A (en) * | 2016-10-19 | 2017-04-19 | 湖南古洞春茶业有限公司 | A Daye tea extract product liquid detergent and a preparing method thereof |
| CN109023948A (en) * | 2018-08-23 | 2018-12-18 | 贵州凯里经济开发区鑫田民族服饰工艺品发展有限公司 | Miao ethnic group's embroidery dress ornament and preparation method thereof |
| CN110725122A (en) * | 2019-09-03 | 2020-01-24 | 无锡德冠生物科技有限公司 | Biomass pretreatment agent and preparation method thereof |
| CN111218350A (en) * | 2020-02-12 | 2020-06-02 | 陕西科技大学 | Fulvic acid feather cleaning agent and preparation method thereof |
-
2009
- 2009-09-10 CN CN200910102257A patent/CN101660267A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914848A (en) * | 2010-08-12 | 2010-12-15 | 绍兴中纺院江南分院有限公司 | Pre-treatment auxiliary agent for cotton knitted fabrics, preparation method and application thereof |
| CN102150681A (en) * | 2010-11-19 | 2011-08-17 | 绍兴中纺院江南分院有限公司 | Mosquito-proof assistant agent, preparation method and application thereof |
| CN104099781A (en) * | 2014-07-11 | 2014-10-15 | 上海多纶化工有限公司 | Phosphorus-free textile scouring agent |
| CN104099781B (en) * | 2014-07-11 | 2016-07-06 | 上海多纶化工有限公司 | Without phosphorus weaving scouring agent |
| CN104153193A (en) * | 2014-07-31 | 2014-11-19 | 杭州澳美印染有限公司 | Dyeing and finishing method suitable for all-cotton embroidery fabric or all-cotton voile |
| CN104389164A (en) * | 2014-11-28 | 2015-03-04 | 何庆堃 | Printing and dyeing pretreatment aid for silk fabric finishing |
| CN106087403A (en) * | 2016-06-02 | 2016-11-09 | 湖州市菱湖重兆金辉丝织厂 | A kind of wool fabric pest-control finishing agent |
| CN106480726A (en) * | 2016-10-14 | 2017-03-08 | 无锡市华诚印染剂厂 | Silk fabric scouring agent |
| CN106566691A (en) * | 2016-10-19 | 2017-04-19 | 湖南古洞春茶业有限公司 | A Daye tea extract product liquid detergent and a preparing method thereof |
| CN109023948A (en) * | 2018-08-23 | 2018-12-18 | 贵州凯里经济开发区鑫田民族服饰工艺品发展有限公司 | Miao ethnic group's embroidery dress ornament and preparation method thereof |
| CN110725122A (en) * | 2019-09-03 | 2020-01-24 | 无锡德冠生物科技有限公司 | Biomass pretreatment agent and preparation method thereof |
| CN111218350A (en) * | 2020-02-12 | 2020-06-02 | 陕西科技大学 | Fulvic acid feather cleaning agent and preparation method thereof |
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Application publication date: 20100303 |