CN101608058B - 一种全降解仿纸材料及其制备方法 - Google Patents
一种全降解仿纸材料及其制备方法 Download PDFInfo
- Publication number
- CN101608058B CN101608058B CN2009100893246A CN200910089324A CN101608058B CN 101608058 B CN101608058 B CN 101608058B CN 2009100893246 A CN2009100893246 A CN 2009100893246A CN 200910089324 A CN200910089324 A CN 200910089324A CN 101608058 B CN101608058 B CN 101608058B
- Authority
- CN
- China
- Prior art keywords
- weight parts
- mins
- rev
- speed
- starch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000463 material Substances 0.000 title claims abstract description 61
- 238000006731 degradation reaction Methods 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 40
- 238000001816 cooling Methods 0.000 claims abstract description 36
- 229920002472 Starch Polymers 0.000 claims abstract description 25
- 239000008107 starch Substances 0.000 claims abstract description 24
- 235000019698 starch Nutrition 0.000 claims abstract description 24
- 229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 21
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 18
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 18
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 claims abstract description 17
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 15
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 15
- 229920001610 polycaprolactone Polymers 0.000 claims abstract description 11
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 10
- 238000005469 granulation Methods 0.000 claims abstract description 9
- 230000003179 granulation Effects 0.000 claims abstract description 9
- 239000004632 polycaprolactone Substances 0.000 claims abstract description 7
- 238000001125 extrusion Methods 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims abstract 5
- 239000012752 auxiliary agent Substances 0.000 claims abstract 2
- -1 Poly(lactic acid) Polymers 0.000 claims description 43
- 239000002994 raw material Substances 0.000 claims description 23
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 21
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 20
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 235000011187 glycerol Nutrition 0.000 claims description 10
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 9
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical group CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 8
- 239000008116 calcium stearate Substances 0.000 claims description 8
- 235000013539 calcium stearate Nutrition 0.000 claims description 8
- 230000018044 dehydration Effects 0.000 claims description 8
- 238000006297 dehydration reaction Methods 0.000 claims description 8
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical group O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 8
- 239000008188 pellet Substances 0.000 claims description 8
- 238000010008 shearing Methods 0.000 claims description 8
- 239000004593 Epoxy Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 238000005096 rolling process Methods 0.000 claims description 7
- 235000012424 soybean oil Nutrition 0.000 claims description 7
- 239000003549 soybean oil Substances 0.000 claims description 7
- 239000001993 wax Substances 0.000 claims description 7
- IKEHOXWJQXIQAG-UHFFFAOYSA-N 2-tert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1 IKEHOXWJQXIQAG-UHFFFAOYSA-N 0.000 claims description 6
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 6
- 230000004927 fusion Effects 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 6
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 claims description 4
- 239000004902 Softening Agent Substances 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- 239000000314 lubricant Substances 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 239000012188 paraffin wax Substances 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 3
- 238000005266 casting Methods 0.000 claims description 3
- 235000010290 biphenyl Nutrition 0.000 claims description 2
- 239000004305 biphenyl Substances 0.000 claims description 2
- 238000007664 blowing Methods 0.000 claims description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 2
- 239000004200 microcrystalline wax Substances 0.000 claims description 2
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- 229920001592 potato starch Polymers 0.000 claims 2
- 244000017020 Ipomoea batatas Species 0.000 claims 1
- 235000002678 Ipomoea batatas Nutrition 0.000 claims 1
- 240000003183 Manihot esculenta Species 0.000 claims 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims 1
- 240000000359 Triticum dicoccon Species 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 1
- 229940100445 wheat starch Drugs 0.000 claims 1
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 238000012545 processing Methods 0.000 abstract description 2
- 239000004626 polylactic acid Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 238000010096 film blowing Methods 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 description 11
- 239000004033 plastic Substances 0.000 description 11
- 230000015556 catabolic process Effects 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000013410 fast food Nutrition 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012092 media component Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- NQHJWFYVHSKTLX-UHFFFAOYSA-N phosphoric acid;toluene Chemical compound OP(O)(O)=O.CC1=CC=CC=C1 NQHJWFYVHSKTLX-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009100893246A CN101608058B (zh) | 2009-07-16 | 2009-07-16 | 一种全降解仿纸材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009100893246A CN101608058B (zh) | 2009-07-16 | 2009-07-16 | 一种全降解仿纸材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101608058A CN101608058A (zh) | 2009-12-23 |
CN101608058B true CN101608058B (zh) | 2010-08-25 |
Family
ID=41481970
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2009100893246A Expired - Fee Related CN101608058B (zh) | 2009-07-16 | 2009-07-16 | 一种全降解仿纸材料及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101608058B (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101851353A (zh) * | 2010-04-28 | 2010-10-06 | 广西师范学院 | 植物纤维增强阻燃热塑性淀粉基复合材料及其制备方法 |
CN104861600A (zh) * | 2015-05-13 | 2015-08-26 | 常州龙骏天纯环保科技有限公司 | 一种聚乳酸可降解复合材料及其制备方法 |
CN109467752A (zh) * | 2018-10-27 | 2019-03-15 | 林毅平 | 一种淀粉/木质素全降解仿纸材料及其制备方法 |
CN111438910A (zh) * | 2019-01-16 | 2020-07-24 | 纪腾萦 | 环保吸管及其制造方法 |
CN110013625B (zh) * | 2019-04-22 | 2020-10-30 | 安徽字母表工业设计有限公司 | 空投式消防水囊 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1992019680A1 (en) * | 1991-05-03 | 1992-11-12 | Novamont S.P.A. | Biodegradable polymeric compositions based on starch and thermoplastic polymers |
JP2000109665A (ja) * | 1998-10-02 | 2000-04-18 | Nippon Shokuhin Kako Co Ltd | 有機物質含有生分解性組成物の製造方法 |
US7037959B1 (en) * | 1999-04-12 | 2006-05-02 | The United States Of America As Represented By The Secretary Of The Agriculture | Biodegradable polymer compositions methods for making same and articles therefrom |
CN1785641A (zh) * | 2005-12-15 | 2006-06-14 | 闫万琪 | 一种共混生物降解材料的生产工艺 |
CN101157792A (zh) * | 2007-09-20 | 2008-04-09 | 浙江海正生物材料股份有限公司 | 一种可完全生物降解的聚乳酸复合材料及其制备方法 |
CN101235156A (zh) * | 2007-11-16 | 2008-08-06 | 江苏科技大学 | 一种聚乳酸/热塑性淀粉挤出吹塑薄膜及其生产方法与应用 |
-
2009
- 2009-07-16 CN CN2009100893246A patent/CN101608058B/zh not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1992019680A1 (en) * | 1991-05-03 | 1992-11-12 | Novamont S.P.A. | Biodegradable polymeric compositions based on starch and thermoplastic polymers |
JP2000109665A (ja) * | 1998-10-02 | 2000-04-18 | Nippon Shokuhin Kako Co Ltd | 有機物質含有生分解性組成物の製造方法 |
US7037959B1 (en) * | 1999-04-12 | 2006-05-02 | The United States Of America As Represented By The Secretary Of The Agriculture | Biodegradable polymer compositions methods for making same and articles therefrom |
CN1785641A (zh) * | 2005-12-15 | 2006-06-14 | 闫万琪 | 一种共混生物降解材料的生产工艺 |
CN101157792A (zh) * | 2007-09-20 | 2008-04-09 | 浙江海正生物材料股份有限公司 | 一种可完全生物降解的聚乳酸复合材料及其制备方法 |
CN101235156A (zh) * | 2007-11-16 | 2008-08-06 | 江苏科技大学 | 一种聚乳酸/热塑性淀粉挤出吹塑薄膜及其生产方法与应用 |
Also Published As
Publication number | Publication date |
---|---|
CN101608058A (zh) | 2009-12-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103160012B (zh) | 一种隔氧且可降解的塑料薄膜 | |
CN101781467B (zh) | 生物质合成塑料制品及其制备方法 | |
CN100572433C (zh) | 一种可完全生物降解塑料树脂及其薄膜类制品的生产方法 | |
TWI443140B (zh) | 聚丁二酸丁二酯(pbs)及改質聚丁二酸丁二酯(mpbs)製成之熱成形物件 | |
CN102277005B (zh) | 一种高填充的全生物降解包装材料 | |
CN103044716B (zh) | 生物降解材料及其制备方法 | |
CN101805499A (zh) | 一种全降解热塑复合材料及其片材 | |
CN101608058B (zh) | 一种全降解仿纸材料及其制备方法 | |
CN101649072B (zh) | 一种全降解生物材料及其薄膜制品 | |
CN102875853A (zh) | 一种可降解塑料及其制备方法 | |
CN101993558A (zh) | 用淀粉纤维废塑料生产薄膜 | |
CN108329529A (zh) | 一种完全生物降解共聚挤出片材原料及制品生产工艺 | |
CN101792591A (zh) | 一种全生物降解塑料薄膜及其制备方法 | |
CN102120870A (zh) | 一种可降解塑料及其生产方法 | |
CN110343397A (zh) | 一种竹粉全生物降解材料及其制备方法 | |
CN101717537B (zh) | 一种聚烯烃薄膜及其制造方法 | |
CN110819085A (zh) | 一种高韧性全生物降解塑料袋及其制备方法 | |
KR20220121242A (ko) | 생분해성 및 퇴비성 조성물 | |
CN111138811A (zh) | 一种全生物降解塑料包装材料及其制备方法 | |
CN103205045A (zh) | 一种隔氧且可降解塑料薄膜的制备方法 | |
JP2023511750A (ja) | 土質植物質の堆肥化可能な生分解性の基材、及び、その製造方法 | |
CN112574541A (zh) | 可生物堆肥降解材料、可生物堆肥降解管材及其制备方法和应用 | |
CN114031914A (zh) | 一种生物基吸塑材料及其制备方法 | |
CN100509945C (zh) | 生物降解塑料及其制备方法 | |
WO2023220007A1 (en) | Sustainable foam |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Free format text: FORMER OWNER: SUN APIN ZHANG XUEGUANG Effective date: 20120718 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20120718 Address after: 100061 Beijing city Chongwen district south street leading international building No. 3 room 1203 Patentee after: Ren Wei Address before: 100061 Beijing city Chongwen district south street leading international building No. 3 room 1203 Co-patentee before: Sun Apin Patentee before: Ren Wei Co-patentee before: Zhang Xueguang |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100825 Termination date: 20180716 |
|
CF01 | Termination of patent right due to non-payment of annual fee |