CN101580618B - 一种制备聚乙烯醇薄膜的方法 - Google Patents
一种制备聚乙烯醇薄膜的方法 Download PDFInfo
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- CN101580618B CN101580618B CN2009100335911A CN200910033591A CN101580618B CN 101580618 B CN101580618 B CN 101580618B CN 2009100335911 A CN2009100335911 A CN 2009100335911A CN 200910033591 A CN200910033591 A CN 200910033591A CN 101580618 B CN101580618 B CN 101580618B
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- film
- pva
- pvoh
- polyvinyl alcohol
- gel
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- 239000004372 Polyvinyl alcohol Substances 0.000 title claims abstract description 39
- 229920002451 polyvinyl alcohol Polymers 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title description 4
- 238000000034 method Methods 0.000 claims abstract description 31
- 239000002904 solvent Substances 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 108010025899 gelatin film Proteins 0.000 claims abstract description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- 229910000831 Steel Inorganic materials 0.000 claims description 7
- 239000010959 steel Substances 0.000 claims description 7
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 6
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical group CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 6
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 6
- 239000004902 Softening Agent Substances 0.000 claims description 5
- 239000013530 defoamer Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000012745 toughening agent Substances 0.000 claims description 5
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 4
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical group COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical group CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 238000013019 agitation Methods 0.000 claims description 4
- 229910021538 borax Inorganic materials 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- -1 polyethylene Polymers 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 239000004328 sodium tetraborate Substances 0.000 claims description 4
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 4
- 239000004327 boric acid Substances 0.000 claims description 3
- 125000005619 boric acid group Chemical group 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 3
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 claims description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 2
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 claims description 2
- 229960001826 dimethylphthalate Drugs 0.000 claims description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 2
- 238000010792 warming Methods 0.000 claims description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims 22
- 238000004519 manufacturing process Methods 0.000 abstract description 11
- 238000005265 energy consumption Methods 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract 2
- 239000004014 plasticizer Substances 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000006184 cosolvent Substances 0.000 abstract 1
- 238000007602 hot air drying Methods 0.000 abstract 1
- 238000012423 maintenance Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 206010039424 Salivary hypersecretion Diseases 0.000 description 2
- 229920002978 Vinylon Polymers 0.000 description 2
- 238000006136 alcoholysis reaction Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 230000036314 physical performance Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 208000026451 salivation Diseases 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
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- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Description
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Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2009100335911A CN101580618B (zh) | 2009-06-24 | 2009-06-24 | 一种制备聚乙烯醇薄膜的方法 |
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CN2009100335911A CN101580618B (zh) | 2009-06-24 | 2009-06-24 | 一种制备聚乙烯醇薄膜的方法 |
Publications (2)
Publication Number | Publication Date |
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CN101580618A CN101580618A (zh) | 2009-11-18 |
CN101580618B true CN101580618B (zh) | 2010-12-08 |
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CN2009100335911A Active CN101580618B (zh) | 2009-06-24 | 2009-06-24 | 一种制备聚乙烯醇薄膜的方法 |
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Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102068923B (zh) * | 2010-12-31 | 2013-07-31 | 河北诺恩水净化设备有限公司 | 一种聚偏氟乙烯中空纤维膜的制造方法 |
CN102286183B (zh) * | 2011-06-17 | 2013-09-11 | 包头市恒瑞新材料科技有限公司 | 可塑性pva树脂及其制备方法 |
CN102838769B (zh) * | 2012-09-28 | 2014-05-14 | 上海海洋大学 | 一种吸湿包装薄膜的制备方法 |
CN104403298B (zh) * | 2014-11-24 | 2016-06-29 | 西北农林科技大学 | 一种可生物降解复合薄膜及其制备方法 |
CN104403245B (zh) * | 2014-12-12 | 2016-08-17 | 云南云天化股份有限公司 | 一种具有优良染色性能的聚乙烯醇系聚合物薄膜及其制造方法 |
CN105287360A (zh) * | 2015-11-13 | 2016-02-03 | 邢月军 | 具有消炎抗菌功效的医用凝胶 |
CN105504615B (zh) * | 2015-12-25 | 2018-03-02 | 佛山市博维环保材料有限公司 | 一种耐候性优良的快速冷水溶刺绣底衬膜及其制备方法 |
CN105418949B (zh) * | 2016-01-11 | 2018-04-03 | 云南云天化股份有限公司 | 一种聚乙烯醇薄膜的制备方法 |
CN105713215A (zh) * | 2016-04-27 | 2016-06-29 | 安徽皖维高新材料股份有限公司 | 一种聚乙烯醇薄膜的生产方法 |
CN106167897A (zh) * | 2016-08-28 | 2016-11-30 | 青岛费米新材料科技有限公司 | 一种可水解的聚合物的金属表面成膜方法 |
CN107141674B (zh) * | 2017-05-24 | 2020-05-22 | 浙江理工大学 | 一种聚乙烯醇和磷酸类化合物共混薄膜及其制备方法 |
CN107686620A (zh) * | 2017-09-16 | 2018-02-13 | 常州富思通管道有限公司 | 一种聚乙烯醇薄膜 |
CN107718185A (zh) * | 2017-10-30 | 2018-02-23 | 南宁科天水性科技有限责任公司 | 一种实木复合地板用无醛胶膜纸、实木复合地板用胶合板及其压贴工艺 |
CN109180976A (zh) * | 2018-09-07 | 2019-01-11 | 重庆云天化瀚恩新材料开发有限公司 | 一种偏光片用聚乙烯醇薄膜的制造方法 |
CN111057336B (zh) * | 2019-12-30 | 2023-02-03 | 武汉轻工大学 | 一种食品用复合膜及其制备方法 |
CN111391531B (zh) * | 2020-03-19 | 2021-07-23 | 湖南工业大学 | 一种数码喷墨打印水转印膜的制备方法、水转印膜及水转印方法 |
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- 2009-06-24 CN CN2009100335911A patent/CN101580618B/zh active Active
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Address after: Yang Xiang Zhen Huang Jia Cun 214200 Jiangsu city of Yixing province Yixing Gaotuo polymer material Co Ltd Patentee after: Wuxi high extension new material Limited by Share Ltd Address before: Yang Xiang Zhen Huang Jia Cun 214200 Jiangsu city of Yixing province Yixing Gaotuo polymer material Co Ltd Patentee before: Yixing Goto Macromolecule Materials Co., Ltd. |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Polyvinyl alcohol film and preparation method thereof Effective date of registration: 20170718 Granted publication date: 20101208 Pledgee: Jiangsu Yixing rural commercial bank Limited by Share Ltd Yang Xiang sub branch Pledgor: Wuxi high extension new material Limited by Share Ltd Registration number: 2017990000648 |
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Date of cancellation: 20200616 Granted publication date: 20101208 Pledgee: Jiangsu Yixing rural commercial bank Limited by Share Ltd. Yang Xiang sub branch Pledgor: WUXI GOTO NEW MATERIAL Co.,Ltd. Registration number: 2017990000648 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Polyvinyl alcohol film and preparation method thereof Effective date of registration: 20200616 Granted publication date: 20101208 Pledgee: Jiangsu Yixing rural commercial bank Limited by Share Ltd. Yang Xiang sub branch Pledgor: WUXI GOTO NEW MATERIAL Co.,Ltd. Registration number: Y2020990000624 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |