CN101575244A - Organic titanium-calcium fertilizer and preparation method thereof - Google Patents
Organic titanium-calcium fertilizer and preparation method thereof Download PDFInfo
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- CN101575244A CN101575244A CNA200910022933XA CN200910022933A CN101575244A CN 101575244 A CN101575244 A CN 101575244A CN A200910022933X A CNA200910022933X A CN A200910022933XA CN 200910022933 A CN200910022933 A CN 200910022933A CN 101575244 A CN101575244 A CN 101575244A
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Abstract
The invention discloses organic titanium-calcium fertilizer and a preparation method thereof. The fertilizer takes water as solvent and respectively adds the following compositions in every liter of the solvent: 5 to 100g of organic chelated titanium, 170 to 400g of glucose, 0 to 80g of humic acid, 900 to 1,600g of calcium acetate, 70 to 230g of EDDHA chelating agent and 7 to 26g of auxiliary agent. The calcium element in the organic titanium-calcium fertilizer enters in a plant in the form of chelate complex, which ensures minimum molecular weight and is propitious for nutrients to enter in leaves and move easily in the plant; meanwhile, calcium carrying obstruction is reduced to increase calcium mobility; moreover, the organic chelated titanium and organic substance in the compositions move faster in the plant, and the nutrients can be quickly carried to the parts of the plant in demand, thereby reducing nutrient detention in cell space, quickening nutrient decomposition and release and minimizing energy and substance consumption. The organic titanium-calcium fertilizer has high calcium content, strong water dispersion of calcium solution and simple use, and is easy to be rapidly absorbed and utilized by crops.
Description
Technical field
The invention belongs to the agricultural fertilizer production field, relate to a kind of moderate-element calcareous fertilisers class chemical fertilizer, especially a kind of organic titanium-calcium fertilizer and preparation method.
Background technology
Along with agrotechnical continuous development, modern agriculture has proposed requirement higher, that upgrade to using of fertilizer.The main effect of fertilizer is to improve crop yield in the traditional agriculture, and along with modern agricultural development, very big variation has taken place in the technology and the purpose of fertilising, fertilising is not only wanted and can be increased production, and also wants to improve crop quality, saves resource, helps culture fertility, regulates Soil structure, reduces labor intensity, more important is to want to improve utilization rate of fertilizer, reduce environmental pollution, increase economic efficiency, help green agriculture and Sustainable development.
Growth and development of plant mainly depends on macroelement nitrogen, phosphorus, potassium, but also indispensable to the demand of moderate-element and trace element.
One, for the calcium constituent in the required moderate-element of plant, there is 30% soil calcium deficiency in China, and mainly in southern leaching soil, calcium contents is low, though the rich calcium profit of soil in the north is not used.Calcium constituent is vulnerable to the influence of various factors in the plant materials content, even therefore used calcareous fertilisers, crop also can not get sufficient replenishing.This be since farm crop the absorption and the transportation of general calcium constituent are obstructed, concrete reason have following some:
(1) starting material generally have calcium chloride, nitrocalcite, calcium acetate.What of foreign matter contents such as the different directly decision of raw material chlorion, thereby the security of decision use.Calcium acetate is a food raw material, and security is best, and having only U.S.'s fruit tree calcareous fertilisers to adopt calcium acetate now is raw material, and cost is higher, and all the other product great majority are calcium chloride, and small part is nitrocalcite, calcium ammonium nitrate.Wherein the outward appearance of solid nitric acid calcium is the white or the fine crystals of other colors slightly, and water absorbability is stronger, caking easily, and soluble in water, the aqueous solution reacts acid, and the solubleness temperature influence is minimum, is physiological alkaline fertilizer.It contains abundant calcium ion, but nitrocalcite belongs to nitric nitrogen, easily with the water leaching loss, especially the paddy field should not be used, and it can not use with fresh barnyard manure, compost, because the organic acid that generates in the fertilizer fermenting process, can make nitrocalcite be decomposed into nitric acid, cause the fertilizer nutrient loss.
(2) poor mobility of calcium.Calcium mobile has several primary conditions: 1. water, and moving of calcium must have the moisture pulling, and if Apple with Fruit-bagged Treatment, it not have the transpiration of fruit face substantially, can not carry out moisture to spur, so easier calcium deficiency; 2. directly enter phloem or directly be sprayed onto the fruit face on.Phloem is the unique passage that carries out the nutrient conversion between cauline leaf and the fruit, does not enter phloem, just can only directly be sprayed onto on the fruit face.The problem of having only U.S.'s fruit tree calcareous fertilisers to be difficult to move by the pure solution calcium of seminose at present directly enters phloem, realizes that the dual channel road replenishes the calcium, and this is unique.Other most calcareous fertilisers are the security that has solved calcium by chelating because they do not solve the greatest problem that this difficulty moves.
Two; for the required trace element of plant; as to iron; zinc; replenishing of elements such as manganese; all be to use inorganic salt form traditionally; be inorganic microelement fertilizer; as zinc sulfate; ferrous sulfate and manganous sulfate etc.; this mode has very big problem and (very easily is converted into ferric iron under field conditions (factors) and ineffective as ferrous sulfate; zinc sulfate; manganous sulfate very easily runs off); range of application is narrower; usefulness is low, is unfavorable for that crop absorbs, and because self alkali reaction and redox reaction of soil; make it oxyhydroxide that forms indissoluble etc.; reduce its biologic activity, cause soil compaction, be unfavorable for the Sustainable development of environment protection and agricultural.
Chelated microelement fertilizer (abbreviation chelate fertilizer) has appearred in modern agriculture, and it is better than inorganic microelement fertilizer, is difficult for being fixed in soil, and is soluble in water, does not dissociate again, can be utilized by plant absorbing well.Also can be solid-state with other or liquid fertilizer mix and use and chemical reaction does not take place, do not reduce the fertilizer efficiency of any fertilizer.Have only Dutch Akzo Nobel chemical company to release this product F e-EDDHA fertilizer at present, through the big area field experiment, obtained splendid effect in China, but price is very expensive, 6% Fe-EDDHA market value is 200,000/ton, has hindered the application of this product greatly.Therefore, exploitation Me-EDDHA series fertilizer becomes inevitable.Fertile and the present fertilizer that uses of EDDHA is compared, and following advantage is arranged: strong to metal ion-chelant power; Applied widely, all can use to alkaline PH310 scope in acidity; The biologic activity height, usage quantity is few; Environmental pollution is little.
Titanium elements is the new highlight that the field of plant science fertilising in recent years occurs, and is described as " fertilizer catalyzer ".Its effect is to promote plant to N, P, K and other trace elements absorbed and running forcefully, promotes activity, strengthens photosynthesis, improves the content of plant chlorophyll and fruit nutrient.But, do not utilized by plant absorbing because inorganic titanium salt character instability easily generates water-fast titanium dioxide under field conditions (factors).Therefore, occurred organic chelated titanium fertilizer in recent years, organic chelated titanium is the white solid powder, soluble in water, aqueous ph value is 6, is research and development of middle nineteen nineties in last century and the high-tech plant nutrition additive of having finished field experiment, and its main component is that titanium is (according to TiO
2Meter, 〉=15%), organic chelated machine matter (〉=33%) and ammonium nitrogen nutritive substances such as (〉=12%).Though organic chelated titanium fertilizer has above plurality of advantages, if use organic chelated titanium fertilizer merely, because it costs an arm and a leg, cost is very big, is unfavorable for the big area popularization.
Summary of the invention
The objective of the invention is to overcome the shortcoming of above-mentioned prior art, a kind of organic titanium-calcium fertilizer is provided, this organic titanium-calcium fertilizer is according to the physiological characteristic of crop and to the absorption characteristics of calcium, organic chelated titanium and the material that contains calcium ion are mixed, add organic matter, lime acetate, sugar alcohol and organic additive bioactive peptide again, further chelating forms a kind of full water-soluble Calcium of intensifiens, and very suitable fruit tree, vegetables and happiness calcium crop overcome calcium deficiency to the efficient absorption of calcium.
The objective of the invention is to solve by the following technical programs:
This organic titanium-calcium fertilizer is solvent with water, contains following component in every premium on currency:
Organic chelated titanium 5～100g, glucose 170～400g, humic acid 0～80g, lime acetate 900～1600g and EDDHA sequestrant 70～230g, auxiliary agent 7～26g;
The mass concentration of described glucose is 99%; Described auxiliary agent is one or more mixtures of plug ketone, azone, sugar alcohol or bioactive peptide; Described lime acetate is the food grade lime acetate, and described plug ketone and azone are pharmaceutical grade, and described sugar alcohol and bioactive peptide are food grade.The massfraction of the organic matter of described humic acid is 45-65%, and moisture is less than 10%, and fineness is the 80-120 order.
Further, substitute lime acetate with nitrocalcite.
The preparation method of this organic titanium-calcium fertilizer, carry out according to following steps:
1), organic chelated titanium and glucose added to stir in the entry is uniform solution according to the proportioning of each component of claim 1;
2) above-mentioned solution is added in the reactor, stirs, lime acetate is slowly added in the reactor according to proportioning, it is fully dissolved after, according to proportioning the EDDHA sequestrant is added in the reactor again, the back that stirs is with temperature heating 1～2h of 40-65 ℃;
3) react completely after, according to proportioning, slowly add humic acid and auxiliary agent at normal temperatures, stir, with 80-100 purpose strainer filtering, the filtrate that obtains is organic titanium-calcium fertilizer.
Organic titanium-calcium fertilizer of the present invention has the following advantages:
(1) good water solubility, advantages of good calcium supplying effect: superpower water-soluble, easily absorbed and utilize by crop.Adopt chelating technology and high-efficient penetrant, effectively solve calcium and in plant materials, transport and absorb a difficult problem slowly.Can prevent and treat illness that the crop calcium deficiency causes, increase output, improve quality, prolong the fruit freshness date of guaranteeing the quality, improve and store.
(2) absorb high efficiency: organic titanium calcium contents height is absorbed, improves the calcareous fertilisers utilization ratio easilier after spraying than common calcareous fertilisers by crop.
(3) easy to use: this organic titanium-calcium fertilizer is a liquid fertilizer, water dispersible is good, stable chemical performance, good with other farmingization products and little fertile intermiscibility, being mixed property is good, is neutral after organic titanium-calcium fertilizer and the water dissolution, can mix use with other most agricultural chemicals and liquid fertilizer, save farming season greatly, convenient and swift.
(4) safe in utilization: organic titanium-calcium fertilizer is chloride and objectionable impurities not, does not injure the crop cauline leaf; Do not have corrodibility, can not produce blade face calcination or root and burn withered phenomenon, safe and effective.
(5) disease-resistant sterilization, drought resisting are freeze proof, improve the plant immunization function, reduce disease and take place.
(6) select materials superior, nontoxic, environment-friendly and green, and the anticorrosion anti-ulcer of going mouldy are the storage transportation.
(7) impayable nutrition efficient absorbs and the advantage of transportation because the organic titanium-calcium fertilizer product has, even under the lower situation of working concentration, very high nutrition absorption efficient also can satisfy the demand of crop fully, and its effect of increasing production far surpasses like product and high density foliage fertilizer product.
Embodiment
Embodiment 1
Organic titanium-calcium fertilizer among this embodiment is a solvent with water, adds following component in every premium on currency respectively:
Organic chelated titanium 5g; Glucose 170g;
Humic acid 40g; Lime acetate 900g;
EDDHA sequestrant 70g; Plug ketone 7g;
Above glucose sugar employing mass concentration is 99% edible glucose Icing Sugar; Lime acetate is the food grade lime acetate; Plug ketone is pharmaceutical grade; Requiring the massfraction of the organic matter of humic acid is 45-65%, and moisture is less than 10%, and fineness is the 80-120 order.
Preparation method among this embodiment is specific as follows:
1), at first organic chelated titanium and glucose are added to stir in the entry and be uniform solution according to the proportioning of each component;
2) above-mentioned solution is added in the reactor, stirs, lime acetate is slowly added in the reactor according to proportioning, it is fully dissolved after, according to proportioning the EDDHA sequestrant is added in the reactor again, the back that stirs is with 40 ℃ temperature heating 2h;
3) react completely after, according to proportioning, slowly add at normal temperatures humic acid and the plug ketone, stir, with 80 purpose strainer filterings, the filtrate that obtains is organic titanium-calcium fertilizer.
Embodiment 2
Organic titanium-calcium fertilizer among this embodiment is a solvent with water, adds following component in every premium on currency respectively:
Organic chelated titanium 10g; Glucose: 200g;
Humic acid 20g; Lime acetate: 1000g;
EDDHA sequestrant 100g; Plug ketone: 10g;
Above glucose sugar employing mass concentration is 99% edible glucose Icing Sugar; Lime acetate is the food grade lime acetate; Plug ketone is pharmaceutical grade; Requiring the massfraction of the organic matter of humic acid is 45-65%, and moisture is less than 10%, and fineness is the 80-120 order.
Preparation method among this embodiment is specific as follows:
1), at first organic chelated titanium and glucose are added to stir in the entry and be uniform solution according to the proportioning of each component;
2) above-mentioned solution is added in the reactor, stirs, lime acetate is slowly added in the reactor according to proportioning, it is fully dissolved after, according to proportioning the EDDHA sequestrant is added in the reactor again, the back that stirs is with 45 ℃ temperature heating 1.5h;
3) react completely after, according to proportioning, slowly add at normal temperatures humic acid and the plug ketone, stir, with 100 purpose strainer filterings, the filtrate that obtains is organic titanium-calcium fertilizer.
Embodiment 3
Organic titanium-calcium fertilizer among this embodiment is a solvent with water, adds following component in every premium on currency respectively:
Organic chelated titanium 50g; Glucose: 250g;
Humic acid 30g; Lime acetate: 1300g;
EDDHA sequestrant 200g; Plug ketone: 20g;
Above glucose sugar employing mass concentration is 99% edible glucose Icing Sugar; Lime acetate is the food grade lime acetate; Plug ketone is pharmaceutical grade; Requiring the massfraction of the organic matter of humic acid is 45-65%, and moisture is less than 10%, and fineness is the 80-120 order.
Preparation method among this embodiment is specific as follows:
1), at first organic chelated titanium and glucose are added to stir in the entry and be uniform solution according to the proportioning of each component;
2) above-mentioned solution is added in the reactor, stirs, lime acetate is slowly added in the reactor according to proportioning, it is fully dissolved after, according to proportioning the EDDHA sequestrant is added in the reactor again, the back that stirs is with 65 ℃ temperature heating 1h;
3) react completely after, according to proportioning, slowly add at normal temperatures humic acid and the plug ketone, stir, with 80 purpose strainer filterings, the filtrate that obtains is organic titanium-calcium fertilizer.
Embodiment 4
Organic titanium-calcium fertilizer among this embodiment is a solvent with water, adds following component in every premium on currency respectively:
Organic chelated titanium 60g; Glucose: 300g;
Lime acetate: 1600g; EDDHA sequestrant 230g;
Plug ketone: 26g;
Above glucose sugar employing mass concentration is 99% edible glucose Icing Sugar; Lime acetate is the food grade lime acetate; Plug ketone is pharmaceutical grade.
Preparation method among this embodiment is specific as follows:
1), at first organic chelated titanium and glucose are added to stir in the entry and be uniform solution according to the proportioning of each component;
2) above-mentioned solution is added in the reactor, stirs, lime acetate is slowly added in the reactor according to proportioning, it is fully dissolved after, according to proportioning the EDDHA sequestrant is added in the reactor again, the back that stirs is with 65 ℃ temperature heating 1.5h;
3) react completely after, according to proportioning, slowly add plug ketone at normal temperatures, stir, with 80 purpose strainer filterings, the filtrate that obtains is organic titanium-calcium fertilizer.
Embodiment 5
Organic titanium-calcium fertilizer among this embodiment is a solvent with water, adds following component in every premium on currency respectively:
Organic chelated titanium 70g; Glucose: 350g;
Humic acid 10g; Nitrocalcite: 1400g;
EDDHA sequestrant 100g; Azone: 7g;
Above glucose sugar employing mass concentration is 99% edible glucose Icing Sugar; Azone is a pharmaceutical grade; Requiring the massfraction of the organic matter of humic acid is 45-65%, and moisture is less than 10%, and fineness is the 80-120 order.
Preparation method among this embodiment is specific as follows:
1), at first organic chelated titanium and glucose are added to stir in the entry and be uniform solution according to the proportioning of each component;
2) above-mentioned solution is added in the reactor, stirs, nitrocalcite is slowly added in the reactor according to proportioning, it is fully dissolved after, according to proportioning the EDDHA sequestrant is added in the reactor again, the back that stirs is with 55 ℃ temperature heating 2h;
3) react completely after, according to proportioning, slowly add humic acid and azone at normal temperatures, stir, with 100 purpose strainer filterings, the filtrate that obtains is organic titanium-calcium fertilizer.
Embodiment 6
Organic titanium-calcium fertilizer among this embodiment is a solvent with distilled water, adds following component in every liter of solvent respectively:
Organic chelated titanium 80g; Glucose: 400g;
Humic acid 50g; Nitrocalcite: 1300g;
EDDHA sequestrant 120g; Azone: 26g;
Above glucose sugar employing mass concentration is 99% edible glucose Icing Sugar; Azone is a pharmaceutical grade; Requiring the massfraction of the organic matter of humic acid is 45-65%, and moisture is less than 10%, and fineness is the 80-120 order.
Preparation method among this embodiment is specific as follows:
1), at first organic chelated titanium and glucose are added to stir in the entry and be uniform solution according to the proportioning of each component;
2) above-mentioned solution is added in the reactor, stirs, nitrocalcite is slowly added in the reactor according to proportioning, it is fully dissolved after, according to proportioning the EDDHA sequestrant is added in the reactor again, the back that stirs is with 40 ℃ temperature heating 2h;
3) react completely after, according to proportioning, slowly add humic acid and azone at normal temperatures, stir, with 100 purpose strainer filterings, the filtrate that obtains is organic titanium-calcium fertilizer.
Embodiment 7
Organic titanium-calcium fertilizer among this embodiment is a solvent with water, adds following component in every premium on currency respectively:
Organic chelated titanium 90g; Glucose: 180g;
Humic acid 60g; Nitrocalcite: 1500g;
EDDHA sequestrant 220g; Azone: 7g;
Above glucose sugar employing mass concentration is 99% edible glucose Icing Sugar; Azone is a pharmaceutical grade; Requiring the massfraction of the organic matter of humic acid is 45-65%, and moisture is less than 10%, and fineness is the 80-120 order.
Preparation method among this embodiment is specific as follows:
1), at first organic chelated titanium and glucose are added to stir in the entry and be uniform solution according to the proportioning of each component;
2) above-mentioned solution is added in the reactor, stirs, nitrocalcite is slowly added in the reactor according to proportioning, it is fully dissolved after, according to proportioning the EDDHA sequestrant is added in the reactor again, the back that stirs is with 65 ℃ temperature heating 1.5h;
3) react completely after, according to proportioning, slowly add humic acid and azone at normal temperatures, stir, with 80 purpose strainer filterings, the filtrate that obtains is organic titanium-calcium fertilizer.
Embodiment 8
Organic titanium-calcium fertilizer among this embodiment is a solvent with water, adds following component in every premium on currency respectively:
Organic chelated titanium 100g; Glucose: 260g;
Humic acid 70g; Nitrocalcite: 1600g;
EDDHA sequestrant 210g; Azone: 26g
Above glucose sugar employing mass concentration is 99% edible glucose Icing Sugar; Azone is a pharmaceutical grade; Requiring the massfraction of the organic matter of humic acid is 45-65%, and moisture is less than 10%, and fineness is the 80-120 order.
Preparation method among this embodiment is specific as follows:
1), at first organic chelated titanium and glucose are added to stir in the entry and be uniform solution according to the proportioning of each component;
2) above-mentioned solution is added in the reactor, stirs, nitrocalcite is slowly added in the reactor according to proportioning, it is fully dissolved after, according to proportioning the EDDHA sequestrant is added in the reactor again, the back that stirs is with 50 ℃ temperature heating 2h;
3) react completely after, according to proportioning, slowly add humic acid and azone at normal temperatures, stir, with 100 purpose strainer filterings, the filtrate that obtains is organic titanium-calcium fertilizer.
Embodiment 9
Organic titanium-calcium fertilizer among this embodiment is a solvent with water, adds following component in every premium on currency respectively:
Organic chelated titanium 8g; Glucose: 250g;
Humic acid 20g; Lime acetate: 1200g;
EDDHA sequestrant 130g; Sugar alcohol: 10g;
Above glucose sugar employing mass concentration is 99% edible glucose Icing Sugar; Requiring the massfraction of the organic matter of humic acid is 45-65%, and moisture is less than 10%, and fineness is the 80-120 order; Lime acetate is selected the food grade lime acetate for use; Sugar alcohol is a food grade.
Preparation method among this embodiment is specific as follows:
1), at first organic chelated titanium and glucose are added to stir in the entry and be uniform solution according to the proportioning of each component;
2) above-mentioned solution is added in the reactor, stirs, lime acetate is slowly added in the reactor according to proportioning, it is fully dissolved after, according to proportioning the EDDHA sequestrant is added in the reactor again, the back that stirs is with 55 ℃ temperature heating 1h;
3) react completely after, according to proportioning, slowly add humic acid and sugar alcohol at normal temperatures, stir, with 100 purpose strainer filterings, the filtrate that obtains is organic titanium-calcium fertilizer.
Embodiment 10
Organic titanium-calcium fertilizer among this embodiment is a solvent with water, adds following component in every premium on currency respectively:
Organic chelated titanium 20g; Glucose: 240g;
Humic acid 10g; Lime acetate: 1000g;
EDDHA sequestrant 100g; Sugar alcohol: 26g;
Above glucose sugar employing mass concentration is 99% edible glucose Icing Sugar; Requiring the massfraction of the organic matter of humic acid is 45-65%, and moisture is less than 10%, and fineness is the 80-120 order; Lime acetate is selected the food grade lime acetate for use; Sugar alcohol is a food grade.
Preparation method among this embodiment is specific as follows:
1), at first organic chelated titanium and glucose are added to stir in the entry and be uniform solution according to the proportioning of each component;
2) above-mentioned solution is added in the reactor, stirs, lime acetate is slowly added in the reactor according to proportioning, it is fully dissolved after, according to proportioning the EDDHA sequestrant is added in the reactor again, the back that stirs is with 65 ℃ temperature heating 1h;
3) react completely after, according to proportioning, slowly add humic acid and sugar alcohol at normal temperatures, stir, with 80 purpose strainer filterings, the filtrate that obtains is organic titanium-calcium fertilizer.
Embodiment 11
Organic titanium-calcium fertilizer among this embodiment is a solvent with distilled water, adds following component in every liter of solvent respectively:
Organic chelated titanium 45g; Glucose: 200g;
Humic acid 60g; Lime acetate: 1100g;
EDDHA sequestrant 120g; Bioactive peptide: 20g;
Above glucose sugar employing mass concentration is 99% edible glucose Icing Sugar; Requiring the massfraction of the organic matter of humic acid is 45-65%, and moisture is less than 10%, and fineness is the 80-120 order; Lime acetate is selected the food grade lime acetate for use; Bioactive peptide is a food grade.
Preparation method among this embodiment is specific as follows:
1), at first organic chelated titanium and glucose are added to stir in the entry and be uniform solution according to the proportioning of each component;
2) above-mentioned solution is added in the reactor, stirs, lime acetate is slowly added in the reactor according to proportioning, it is fully dissolved after, according to proportioning the EDDHA sequestrant is added in the reactor again, the back that stirs is with 65 ℃ temperature heating 1h;
3) react completely after, according to proportioning, slowly add humic acid and bioactive peptide at normal temperatures, stir, with 100 purpose strainer filterings, the filtrate that obtains is organic titanium-calcium fertilizer.
Embodiment 12
Organic titanium-calcium fertilizer among this embodiment is a solvent with water, adds following component in every premium on currency respectively:
Organic chelated titanium 65g; Glucose: 220g;
Humic acid 40g; Lime acetate: 1300g;
EDDHA sequestrant 140g; Plug ketone 10g+ azone 10g;
Above glucose sugar employing mass concentration is 99% edible glucose Icing Sugar; Requiring the massfraction of the organic matter of humic acid is 45-65%, and moisture is less than 10%, and fineness is the 80-120 order; Lime acetate is selected the food grade lime acetate for use; Plug ketone and azone are pharmaceutical grade.
Preparation method among this embodiment is specific as follows:
1), at first organic chelated titanium and glucose are added to stir in the entry and be uniform solution according to the proportioning of each component;
2) above-mentioned solution is added in the reactor, stirs, lime acetate is slowly added in the reactor according to proportioning, it is fully dissolved after, according to proportioning the EDDHA sequestrant is added in the reactor again, the back that stirs is with 55 ℃ temperature heating 2h;
3) react completely after, according to proportioning, slowly add humic acid, plug ketone and azone at normal temperatures, stir, with 80 purpose strainer filterings, the filtrate that obtains is organic titanium-calcium fertilizer.
Embodiment 13
Organic titanium-calcium fertilizer among this embodiment is a solvent with water, adds following component in every premium on currency respectively:
Organic chelated titanium 86g; Glucose: 200g;
Humic acid 65g; Nitrocalcite: 1000g;
EDDHA sequestrant 115g; Sugar alcohol 7g+ bioactive peptide 12g;
Above glucose sugar employing mass concentration is 99% edible glucose Icing Sugar; Requiring the massfraction of the organic matter of humic acid is 45-65%, and moisture is less than 10%, and fineness is the 80-120 order; Nitrocalcite is selected technical grade nitrocalcite for use; Sugar alcohol and bioactive peptide are food grade.
Preparation method among this embodiment is specific as follows:
1), at first organic chelated titanium and glucose are added to stir in the entry and be uniform solution according to the proportioning of each component;
2) above-mentioned solution is added in the reactor, stirs, nitrocalcite is slowly added in the reactor according to proportioning, it is fully dissolved after, according to proportioning the EDDHA sequestrant is added in the reactor again, the back that stirs is with 65 ℃ temperature heating 1.5h;
3) react completely after, according to proportioning, slowly add humic acid, sugar alcohol and bioactive peptide at normal temperatures, stir, with 100 purpose strainer filterings, the filtrate that obtains is organic titanium-calcium fertilizer.
More than among each embodiment used organic chelated titanium can directly buy from the market, we also can directly prepare, the preparation method of described organic chelated titanium is: is mixing in 1: 2 with butyl (tetra) titanate and methyl ethyl diketone with the mole proportioning, and with 40-60 ℃ of low-grade fever chelating formation chelating liquid, be 95% ethylene glycol again with analytically pure glacial acetic acid and massfraction with mol ratio be to mix at 1: 1 to form mixture, treat then after the chelating liquid cooling but mixture and the chelating liquid mass ratio with 1: 1 is mixed, stirring obtains faint yellow limpid liquid, is dried to solid with 80 ℃ and promptly obtains organic chelated titanium.
Aspect the bioactive peptide making, can make full use of the higher waste materials of protein content such as milk, agricultural byproducts and handle, enzymolysis ferments, extracts, adds other organic raw material huge legendary turtles to close, and makes finished product, reduces the product cost of earning a livelihood greatly.
In each component of organic titanium-calcium fertilizer of the present invention, lime acetate is a calcium of organic acid, high efficiency nutritious calcium-enriched dose of a kind of ionic, absorption rate is 79%, and it is 98% that rate is stayed in storage, has no side effect, if retrofit synthesised food level is for human body, long-term effect of supplemented calcium very.Soluble in water, the aqueous solution is neutral, in foodstuffs industry, use as sequestrant, mold inhibitor, stablizer, buffer reagent and sweetener always, we are at first after using on the agricultural, first calcium contents improves rapidly, break the highest at present 220 gram/l content, and improved organic content and the nutrient of crop, make calcium be able to fully absorb supply plant calcium deficiency phenomenon.To preventing that fruit from going mouldy, storage endurance, improve fruit color, increase the hardness of fruit, change quality, fruit aromatic flavour etc. plays active effect.
Titanium is a kind of transition metal, by the metal of the unique permission implant into body of WHO (WHO).Titanium is one of teleorganic element, and the inner complex of titanium is one of most important method of whole world increases in grain production, and plant is one of important factor that influences its growth to the absorption of titanium.
Bioactive peptide this use effect very good in many-sides such as food, medicine, feeds, can be used as additive, immunomodulator, antioxidant, natural antiseptic agent, nutritious physiological regulatory action, reduce drug dose, anti-oxidant, regulate immunity of organism, antiviral, sterilization, bacteriostatic action.Bioactive peptide has good absorptivity, its assimilated efficiency is all higher than amino acid and protein, and unique physiological regulation function is arranged, activity is very high, often very little amount just can play very big effect to the human body beneficial, and the biologist is called the biologically active substance of good reputations such as the favorite of human health " 21st century ", " angel of happy mystery ", " soul of life ", " the most promising heath food ".
It is intravital that calcium constituent in the organic titanium-calcium fertilizer of the present invention is that the form with inner complex enters plant, molecular weight is minimum, this helps nutrient and enters blade interior, easily in the plant body, move, can alleviate the obstruction of calcium transportation, strengthen the movability of calcium, organic chelated titanium in the composition and organic matter (glucose) are very fast in intravital infiltration of plant and translational speed in conjunction with the back, can rest branch rapidly and be transported to crop demand position, especially the phloem more product organ that distributes, reduce the delay of nutrient in cell spaces, be easy to decompose the release nutrient, the energy and the material of consumption are minimum.Calcium contents height in the organic titanium-calcium fertilizer of the present invention, calcium liquid water dispersible is strong, is easily utilized by the crop rapid absorption, and it is easy and simple to handle, provide well for the crop calcium deficiency and replenish, and remedied the deficiency of solid calcium, its energy sweetening of the soil acidity, the pH value is adjusted to 6～7 slightly acidic soil less than 5.5 acid soil, reduce soil to phosphorus fixation, regulate the supply of soil, improve the soil microorganisms living condition trace element, strengthen the ventilating permeable of soil, thereby improve the fertilizer-preserving ability of soil.Not only directly supply with the essential calcium of crop, and can improve nitrogen, the phosphorus of crop, the nutritional condition of potassium three elements, and can improve saline soil.Humic acid in the organic titanium-calcium fertilizer composition and organism mass-energy are effectively improved the ventilating permeable of soil.
The present invention through in Shanxi, Shaanxi, repeatedly spot testing of Hunan, proof can be increased production more than 10% than other similar liquid fertilizers again, and the plantibody of using this fertilizer strengthens, immunizing power improves, increased functionality, disease reduces, and the anti-transportation of the anti-storage of fruit can not be used in storage period with objectionable impuritiess such as sanitass.The content of the effective ingredient of the organic titanium-calcium fertilizer of this invention, function all have international advanced, leading domestic status, and be leading in world's liquid fertilizer ranks.
Claims (5)
1. organic titanium-calcium fertilizer, it is characterized in that, with water is solvent, contains following component in every premium on currency: organic chelated titanium 5～100g, glucose 170～400g, humic acid 0～80g, lime acetate 900～1600g, EDDHA sequestrant 70～230g and auxiliary agent 7～26g;
The mass concentration of described glucose is 99%; Described auxiliary agent is one or more mixtures of plug ketone, azone, sugar alcohol or bioactive peptide.
2. organic titanium-calcium fertilizer according to claim 1 is characterized in that, described lime acetate is the food grade lime acetate, and described plug ketone and azone are pharmaceutical grade, and described sugar alcohol and bioactive peptide are food grade.
3. organic titanium-calcium fertilizer according to claim 1 is characterized in that, substitutes lime acetate with nitrocalcite.
4. organic titanium-calcium fertilizer according to claim 1 is characterized in that, the massfraction of the organic matter of described humic acid is 45-65%, and moisture is less than 10%, and fineness is the 80-120 order.
5. the preparation method of the described organic titanium-calcium fertilizer of claim 1 is characterized in that, carries out according to following steps:
1), organic chelated titanium and glucose added to stir in the entry is uniform solution according to the proportioning of each component of claim 1;
2) above-mentioned solution is added in the reactor, stirs, lime acetate is slowly added in the reactor according to proportioning, it is fully dissolved after, according to proportioning the EDDHA sequestrant is added in the reactor again, the back that stirs is with temperature heating 1～2h of 40-65 ℃;
3) react completely after, according to proportioning, slowly add humic acid and auxiliary agent at normal temperatures, stir, with 80-100 purpose strainer filtering, the filtrate that obtains is organic titanium-calcium fertilizer.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102584485A (en) * | 2011-01-06 | 2012-07-18 | 徐伟 | Organic titanium calcium fertilizer and preparation method thereof |
| CN103819280A (en) * | 2014-03-20 | 2014-05-28 | 上海永通化工有限公司 | High-concentration liquid calcium fertilizer and preparation method thereof |
| CN105272599A (en) * | 2015-10-26 | 2016-01-27 | 淮阴师范学院 | Ca fertilizer for leaf surface |
| CN107586170A (en) * | 2017-10-25 | 2018-01-16 | 河北农业大学 | Leaf vegetable nutrient and application thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1064035C (en) * | 1996-09-17 | 2001-04-04 | 裴圣镐 | Multi-element and composite tiltanium trace element fertilizer |
| CN1257054A (en) * | 1999-12-28 | 2000-06-21 | 张玉梅 | Titanium-containing chelate plant nutrient liquid |
| CN100341824C (en) * | 2003-04-01 | 2007-10-10 | 栾雁 | Animal and plant high effect ecological nutritive liquid and its preparation method |
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2009
- 2009-06-12 CN CN200910022933A patent/CN101575244B/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102584485A (en) * | 2011-01-06 | 2012-07-18 | 徐伟 | Organic titanium calcium fertilizer and preparation method thereof |
| CN103819280A (en) * | 2014-03-20 | 2014-05-28 | 上海永通化工有限公司 | High-concentration liquid calcium fertilizer and preparation method thereof |
| CN103819280B (en) * | 2014-03-20 | 2015-12-02 | 上海永通化工有限公司 | A kind of high concentration liquid calcareous fertilisers and preparation method thereof |
| CN105272599A (en) * | 2015-10-26 | 2016-01-27 | 淮阴师范学院 | Ca fertilizer for leaf surface |
| CN107586170A (en) * | 2017-10-25 | 2018-01-16 | 河北农业大学 | Leaf vegetable nutrient and application thereof |
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| CN101575244B (en) | 2012-10-17 |
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