CN101565645A - Polymeric biological liquid fuel and preparation method thereof - Google Patents
Polymeric biological liquid fuel and preparation method thereof Download PDFInfo
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- CN101565645A CN101565645A CNA2009100153311A CN200910015331A CN101565645A CN 101565645 A CN101565645 A CN 101565645A CN A2009100153311 A CNA2009100153311 A CN A2009100153311A CN 200910015331 A CN200910015331 A CN 200910015331A CN 101565645 A CN101565645 A CN 101565645A
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Abstract
The invention belongs to the technical field of energy and chemical engineering, in particular to a polymeric biological liquid fuel and a preparation method thereof. The polymeric biological liquid fuel and the preparation method thereof are characterized in that: the polymeric biological liquid fuel comprises the raw materials by weight percentage of 1 to 2 percent of alkylolamide, 0.5 to 1.5 percent of potassium hydroxide, 2 to 5 percent fatty alcohol, 60 to 80 percent of methanol, 7 to 15 percent of ethanol and 8.5 to 16.5 percent of additive; and the method comprises the steps of sequentially placing the raw materials in a reaction kettle, heating the raw materials to 35 DEG C, aerodynamically stirring the raw materials for 20 minutes, standing the raw materials at normal temperature for over 2 hours and filtering the raw materials to obtain a finished product. The polymeric biological liquid fuel and the preparation method thereof have the advantages of avoiding toxicity, harm, smoke, odor, pressure, explosion, residual liquid and three-waste discharge and having full combustion, cleanness and sanitation, energy conservation and high efficiency.
Description
(1) technical field
The invention belongs to the derived energy chemical technical field, particularly a kind of polymeric biological liquid fuel and preparation method thereof.
(2) background technology
In the today of being becoming tight worldwide energy day, because the enhancing of environmental consciousness and ordering about of economic interests, not only safety but also economic new forms of energy are being sought always by the parties concerned.In recent years, the synthol of lot of domestic and foreign constantly comes out, but so far at aspects such as pollution, safety, calorific value and economic benefits, all fails to reach desirable and practical degree, therefore is difficult to extensively be promoted.
The form that existing fuel based on fuel itself exists can be divided into gas, liquid and solid fuel; Coal gas, liquefied petroleum gas (LPG) belong to geseous fuel, and coal is solid fuel, and genus liquid fuels such as kerosene, alcohol.At family and catering industry fixed-site, coal gas or liquefied petroleum gas (LPG) become main fuel gradually because burning is clean and calorific value is high, and coal fades out greatly and day by day owing to polluting.Yet, there is carbon deposit during the kerosene burning, make the tableware blackening easily, and the alcohol volatility is big, stores dangerous relatively.Therefore, have the higher ethylene glycol of the security of selecting for use to do fuel at present, but also there is the shortcoming that makes the blackening of tableware carbon deposit in this fuel.The method that solves the fuel carbon deposit mainly is to add ignition dope, makes fuel complete.For liquid fuel, depend merely on a spot of ignition dope of adding and can't solve carbon-collecting problem.Along with the raising of living standards of the people, press for that a kind of storage is convenient, safe in utilization, the clean no carbon deposit of burning, free of contamination liquid fuel.
(3) summary of the invention
The present invention provides polymeric biological liquid fuel polymeric biological liquid fuel of a kind of noresidue and three-waste free discharge and preparation method thereof in order to remedy the deficiencies in the prior art.
The present invention is achieved through the following technical solutions:
A kind of polymeric biological liquid fuel is characterized in that: the raw material that comprises following weight percentage:
Alkylol amide 1-2%
Potassium hydroxide 0.5-1.5%
Fatty Alcohol(C12-C14 and C12-C18) 2-5%
Methyl alcohol 60-80%
Ethanol 7-15%
Ferrocene 0.5-1.5%
Hydrogen peroxide 6-10%
Toluene 2-5%.
Polymeric biological liquid fuel of the present invention is characterized in that: described ferrocene, hydrogen peroxide and toluene are additive.
The preparation method of polymeric biological liquid fuel of the present invention is characterized in that: described raw material is placed reactor successively, heat to 35 ℃, aerodynamic force stirs 20min, and normal temperature left standstill more than 2 hours, filter get final product finished product.
In the raw material that is adopted, alkylol amide is used for other polymerizable raw materials are generated biological liquid fuel of the present invention as polymerizing agent; Potassium hydroxide is used to the potential of hydrogen environment that katalysis is provided and suits of reaction as catalyzer; Fatty Alcohol(C12-C14 and C12-C18) as emulsifying agent, makes liquid form more stable emulsion as a kind of amphoterics; Methyl alcohol is as ignition dope; Ethanol is used for the sterilization and anticorrosion effect of reactive system as elimination agent.
The use of additive mainly is in order to improve firing a little of polymeric biological liquid fuel of the present invention, and makes the fuel of generation be used for substituting the fuel oil of different labels with overregulating the amount that adds additive.
Because raw materials such as methyl alcohol and ethanol can discharge a large amount of heat in polymerization process, when fuel fabrication, be in this way under the normal temperature, reactive system need not heat substantially just can reach 35 ℃, generally need heat a little when reactive system envrionment temperature of living in is very low.
It mainly is in order to make each feed composition reach mixing, therefore not need to adopt than aerodynamic force and stir more fierce mechanical stirring that aerodynamic force stirs.
The present invention can prepare the fuel of different purposes according to weight proportions different between each raw material, be mainly used in and substitute civilian conventional fuel, as coal gas, liquefied petroleum gas (LPG), gasoline and diesel oil, therefore, can be used as the fuel of the fuel of cooking in the kitchen, boiler heat supplying and car combustion engine fuel etc.
The main physical and chemical of polymeric biological liquid fuel of the present invention is:
(1) flash-point: 50 ℃;
(2) burning-point: 65 ℃;
(3) fusing point :-90 ℃
(4) spontaneous ignition temperature: 480 ℃;
Temperature when (5) burning: 800 ℃;
(6) calorific value 7000-8000kcal/kg (1kcal=4186.8J);
(7) the per kilogram burning is more than 4 hours;
(8) pH value: 〉=6.5-7.0.
This product is a domestic fuel, meets the relevant regulations of " People's Republic of China's renewable resources method ".
The present invention is nontoxic, smoke-free and tasteless, and it is no quick-fried not have pressure, no raffinate, three-waste free discharge, sufficient combustion, sanitation and hygiene, efficient energy-saving.Compare with gasoline, diesel oil, coal gas, liquefied petroleum gas (LPG), price reduces 1/3-1/2, and burning makes CO (carbon monoxide converter) emission reduce more than 1/2, and production technique is simple, and raw material is easily purchased, and stores normal temperature and pressure, belong to high-quality low-cost, environmental protection, reproducible clean energy.
(4) embodiment
Embodiment 1:
Each raw material is placed reactor successively by following part by weight:
Alkylol amide 2%, potassium hydroxide 1%, Fatty Alcohol(C12-C14 and C12-C18) 3%, methyl alcohol 72%, ethanol 10%, additive 12% (wherein, ferrocene 1%, toluene 2%, hydrogen peroxide 9%).
Raw material in the reactor is heated to 35 ℃, and aerodynamic force stirs 20min, and normal temperature left standstill more than 2 hours, and filtration can obtain the kitchen special fuel of replacement liquid gasification.
According to the kitchen special fuel of the described method preparation of present embodiment 1 and the use correlation data of liquefied gas:
| Sequence number | The contrast project | Liquefied gas cooker (simple eye) | This fuel kitchen range |
| 1 | Fuel consumption | 0.30-0.35kg/ hour | 0.30-0.35kg/ hour |
| 2 | 4kg water is boiled | Time spent 10-12 minute | Time spent 10-12 minute |
| 3 | Fuel value | The 6000-7000 calorie/hour | The 6000-7000 calorie/hour |
| 4 | Fuel price | 5-6 unit/kg | 2-3 unit/kg |
| 5 | The fuel moon consumption | About 15kg | About 15kg |
| 6 | Container pressure | Special cylinder pressure 1-1.2mpa | Common vessel, no pressure |
| 7 | The raffinate degree | Raffinate is arranged | No raffinate |
| 8 | Security situation | Catching fire is difficult for putting out, and the high pressure storage is easily explosion caused, reveals to be liquid, is difficult for being found | Water goes out once watering when catching fire, and the normal pressure storage is difficult for explosion caused, reveals to be liquid, easily finds |
Embodiment 2:
Each raw material is placed reactor successively by following part by weight:
Alkylol amide 1%, potassium hydroxide 0.5%, Fatty Alcohol(C12-C14 and C12-C18) 2%, methyl alcohol 80%, ethanol 8%, additive 8.5% (wherein, ferrocene 0.5%, toluene 2%, hydrogen peroxide 6%).
Raw material in the reactor is heated to 35 ℃, and aerodynamic force stirs 20min, and normal temperature left standstill more than 2 hours, and filtration can obtain polymeric biological liquid fuel.
Embodiment 3:
Each raw material is placed reactor successively by following part by weight:
Alkylol amide 2%, potassium hydroxide 1.5%, Fatty Alcohol(C12-C14 and C12-C18) 5%, methyl alcohol 60%, ethanol 15%, additive 16.5% (wherein, ferrocene 1.5%, toluene 5%, hydrogen peroxide 10%).
Raw material in the reactor is heated to 35 ℃, and aerodynamic force stirs 20min, and normal temperature left standstill more than 2 hours, and filtration can obtain substituting polymeric biological liquid fuel.
Claims (3)
1. polymeric biological liquid fuel is characterized in that: the raw material that comprises following weight percentage:
Alkylol amide 1-2%
Potassium hydroxide 0.5-1.5%
Fatty Alcohol(C12-C14 and C12-C18) 2-5%
Methyl alcohol 60-80%
Ethanol 7-15%
Ferrocene 0.5-1.5%
Hydrogen peroxide 6-10%
Toluene 2-5%.
2. polymeric biological liquid fuel according to claim 1 is characterized in that: described ferrocene, hydrogen peroxide and toluene are additive.
3. the preparation method of polymeric biological liquid fuel according to claim 1 is characterized in that: described raw material is placed reactor successively, heat to 35 ℃, aerodynamic force stirs 20min, and normal temperature left standstill more than 2 hours, filter get final product finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN200910015331A CN101565645B (en) | 2009-05-21 | 2009-05-21 | Polymeric biological liquid fuel and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910015331A CN101565645B (en) | 2009-05-21 | 2009-05-21 | Polymeric biological liquid fuel and preparation method thereof |
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| Publication Number | Publication Date |
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| CN101565645A true CN101565645A (en) | 2009-10-28 |
| CN101565645B CN101565645B (en) | 2012-10-17 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN200910015331A Expired - Fee Related CN101565645B (en) | 2009-05-21 | 2009-05-21 | Polymeric biological liquid fuel and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102154039A (en) * | 2011-03-16 | 2011-08-17 | 平煤蓝天化工股份有限公司 | High-clear alcohol-based fuel oil |
| CN102504887A (en) * | 2011-11-02 | 2012-06-20 | 平凉市中力新能源科技研究院 | Special methanol compound fuel for cooking range |
| CN103897749A (en) * | 2014-03-25 | 2014-07-02 | 桂林市淦隆环保科技有限公司 | Alcohol-based fuel with advantages of combustion completeness and high heat efficiency and preparation method thereof |
| CN105713685A (en) * | 2014-08-11 | 2016-06-29 | 雷菊花 | Industrial safe low-carbon alcohol-based fuel core agent |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU7682396A (en) * | 1995-11-15 | 1997-06-05 | American Technologies Group, Inc. | A combustion enhancing fuel additive comprising microscopic water structures |
| CN100339463C (en) * | 2005-09-20 | 2007-09-26 | 张志坤 | Mathanol regenerating liquid fuel |
| CN101177633A (en) * | 2007-12-04 | 2008-05-14 | 刘均涛 | Vehicle high(middle) ratio low-carbon alcohol gasoline |
| CN101182426A (en) * | 2007-12-28 | 2008-05-21 | 刘均涛 | Vehicle high-ratio methanol diesel oil |
-
2009
- 2009-05-21 CN CN200910015331A patent/CN101565645B/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102154039A (en) * | 2011-03-16 | 2011-08-17 | 平煤蓝天化工股份有限公司 | High-clear alcohol-based fuel oil |
| CN102154039B (en) * | 2011-03-16 | 2013-12-25 | 中国平煤神马集团蓝天化工股份有限公司 | High-clear alcohol-based fuel oil |
| CN102504887A (en) * | 2011-11-02 | 2012-06-20 | 平凉市中力新能源科技研究院 | Special methanol compound fuel for cooking range |
| CN103897749A (en) * | 2014-03-25 | 2014-07-02 | 桂林市淦隆环保科技有限公司 | Alcohol-based fuel with advantages of combustion completeness and high heat efficiency and preparation method thereof |
| CN103897749B (en) * | 2014-03-25 | 2016-03-09 | 桂林市淦隆环保科技有限公司 | Alcohol-group fuel that a kind of complete thermo-efficiency that burns is high and preparation method thereof |
| CN105713685A (en) * | 2014-08-11 | 2016-06-29 | 雷菊花 | Industrial safe low-carbon alcohol-based fuel core agent |
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| CN101565645B (en) | 2012-10-17 |
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Granted publication date: 20121017 Termination date: 20130521 |