CN101538441B - 改性的氨基烤漆反相乳液、其制备方法以及使用该乳液制备烤漆涂层的方法 - Google Patents
改性的氨基烤漆反相乳液、其制备方法以及使用该乳液制备烤漆涂层的方法 Download PDFInfo
- Publication number
- CN101538441B CN101538441B CN2009100028006A CN200910002800A CN101538441B CN 101538441 B CN101538441 B CN 101538441B CN 2009100028006 A CN2009100028006 A CN 2009100028006A CN 200910002800 A CN200910002800 A CN 200910002800A CN 101538441 B CN101538441 B CN 101538441B
- Authority
- CN
- China
- Prior art keywords
- baking vanish
- emulsion
- reversed
- emulsifying agent
- amino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 221
- 239000002966 varnish Substances 0.000 title claims abstract description 80
- 238000002360 preparation method Methods 0.000 title claims abstract description 44
- 238000000576 coating method Methods 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 30
- 239000011248 coating agent Substances 0.000 title claims description 37
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 title abstract 6
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 158
- 239000000203 mixture Substances 0.000 claims abstract description 48
- 229920001214 Polysorbate 60 Polymers 0.000 claims abstract description 43
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000001593 sorbitan monooleate Substances 0.000 claims abstract description 21
- 235000011069 sorbitan monooleate Nutrition 0.000 claims abstract description 21
- 229940035049 sorbitan monooleate Drugs 0.000 claims abstract description 21
- -1 formaldehyde, benzene compounds Chemical class 0.000 claims abstract description 10
- 229920000053 polysorbate 80 Polymers 0.000 claims abstract description 5
- 239000012071 phase Substances 0.000 claims description 118
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 93
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 84
- 150000001875 compounds Chemical class 0.000 claims description 77
- 125000003368 amide group Chemical group 0.000 claims description 55
- 239000008346 aqueous phase Substances 0.000 claims description 52
- 238000012986 modification Methods 0.000 claims description 43
- 230000004048 modification Effects 0.000 claims description 43
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical group CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 22
- 150000003839 salts Chemical class 0.000 claims description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 14
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical group CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 12
- 239000011159 matrix material Substances 0.000 claims description 11
- 239000004065 semiconductor Substances 0.000 claims description 11
- 239000004408 titanium dioxide Substances 0.000 claims description 11
- 238000005507 spraying Methods 0.000 claims description 10
- 238000005516 engineering process Methods 0.000 claims description 9
- 238000013019 agitation Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 239000003973 paint Substances 0.000 claims description 7
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 229920000178 Acrylic resin Polymers 0.000 claims description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 4
- 229920000877 Melamine resin Polymers 0.000 claims description 4
- 239000004640 Melamine resin Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 239000001530 fumaric acid Substances 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical group OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- 229910052732 germanium Inorganic materials 0.000 claims description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 239000010955 niobium Substances 0.000 claims description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229910052712 strontium Inorganic materials 0.000 claims description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 23
- 239000002131 composite material Substances 0.000 abstract description 14
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 abstract description 9
- 239000000126 substance Substances 0.000 abstract description 9
- 230000000593 degrading effect Effects 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 100
- 229910010413 TiO 2 Inorganic materials 0.000 description 31
- 238000003756 stirring Methods 0.000 description 21
- 230000015556 catabolic process Effects 0.000 description 19
- 238000006731 degradation reaction Methods 0.000 description 19
- 239000007921 spray Substances 0.000 description 18
- 229910000831 Steel Inorganic materials 0.000 description 16
- 239000010959 steel Substances 0.000 description 16
- 230000000694 effects Effects 0.000 description 14
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000012074 organic phase Substances 0.000 description 8
- 238000005303 weighing Methods 0.000 description 8
- 230000005540 biological transmission Effects 0.000 description 7
- 239000003153 chemical reaction reagent Substances 0.000 description 7
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 230000001699 photocatalysis Effects 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000001132 ultrasonic dispersion Methods 0.000 description 6
- 239000013543 active substance Substances 0.000 description 5
- 230000032683 aging Effects 0.000 description 5
- 239000002609 medium Substances 0.000 description 5
- 239000002105 nanoparticle Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 235000019634 flavors Nutrition 0.000 description 4
- 239000008098 formaldehyde solution Substances 0.000 description 4
- TZMFJUDUGYTVRY-UHFFFAOYSA-N pentane-2,3-dione Chemical compound CCC(=O)C(C)=O TZMFJUDUGYTVRY-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 229930040373 Paraformaldehyde Natural products 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920003180 amino resin Polymers 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- 230000008033 biological extinction Effects 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002086 nanomaterial Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229920002866 paraformaldehyde Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 2
- MPDGHEJMBKOTSU-YKLVYJNSSA-N 18beta-glycyrrhetic acid Chemical compound C([C@H]1C2=CC(=O)[C@H]34)[C@@](C)(C(O)=O)CC[C@]1(C)CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@H](O)C1(C)C MPDGHEJMBKOTSU-YKLVYJNSSA-N 0.000 description 2
- NTDQQZYCCIDJRK-UHFFFAOYSA-N 4-octylphenol Chemical compound CCCCCCCCC1=CC=C(O)C=C1 NTDQQZYCCIDJRK-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 150000001555 benzenes Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical group COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 230000003381 solubilizing effect Effects 0.000 description 2
- 238000002798 spectrophotometry method Methods 0.000 description 2
- 229940099259 vaseline Drugs 0.000 description 2
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 240000005373 Panax quinquefolius Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 241001464837 Viridiplantae Species 0.000 description 1
- OZZOVSQSDIWNIP-UHFFFAOYSA-N acetic acid;azane Chemical compound [NH4+].[NH4+].CC([O-])=O.CC([O-])=O OZZOVSQSDIWNIP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- LBJNMUFDOHXDFG-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu].[Cu] LBJNMUFDOHXDFG-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000007590 electrostatic spraying Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- KDRHKDNXHXANOQ-UHFFFAOYSA-N formaldehyde pentane-2,3-dione Chemical compound C(C)C(=O)C(=O)C.C=O KDRHKDNXHXANOQ-UHFFFAOYSA-N 0.000 description 1
- HQVFCQRVQFYGRJ-UHFFFAOYSA-N formic acid;hydrate Chemical compound O.OC=O HQVFCQRVQFYGRJ-UHFFFAOYSA-N 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 238000002525 ultrasonication Methods 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
Images
Landscapes
- Catalysts (AREA)
- Paints Or Removers (AREA)
Abstract
Description
量(重量份) | 百分含量(%) | |
热固性丙烯酸树脂(9360) | 225.5 | 72.64 |
丙二醇甲醚醋酸酯(PMA) | 12 | 3.87 |
二甲苯 | 5 | 1.61 |
601A(三木的环氧树脂) | 9 | 2.90 |
丁醚化氨基树脂5860(正丁醇醚化三聚氰胺树脂) | 58.35 | 18.79 |
415(迪高的流平剂) | 0.6 | 0.19 |
310.45 | 100.00 |
Claims (18)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009100028006A CN101538441B (zh) | 2009-01-24 | 2009-01-24 | 改性的氨基烤漆反相乳液、其制备方法以及使用该乳液制备烤漆涂层的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009100028006A CN101538441B (zh) | 2009-01-24 | 2009-01-24 | 改性的氨基烤漆反相乳液、其制备方法以及使用该乳液制备烤漆涂层的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101538441A CN101538441A (zh) | 2009-09-23 |
CN101538441B true CN101538441B (zh) | 2011-05-04 |
Family
ID=41121835
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2009100028006A Expired - Fee Related CN101538441B (zh) | 2009-01-24 | 2009-01-24 | 改性的氨基烤漆反相乳液、其制备方法以及使用该乳液制备烤漆涂层的方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101538441B (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103396714B (zh) * | 2013-07-05 | 2015-10-14 | 丹阳市佳美化工有限公司 | 真空电镀专用清漆 |
CN105693104A (zh) * | 2015-09-06 | 2016-06-22 | 广州叶子环保科技有限公司 | 纳米二氧化钛在陶瓷、玻璃及家具上的使用方法 |
CN107141984A (zh) * | 2017-06-30 | 2017-09-08 | 四川锦泓佳建筑装饰工程有限公司 | 一种除甲醛涂料 |
CN111072996A (zh) * | 2019-12-09 | 2020-04-28 | 兴业皮革科技股份有限公司 | 聚氨酯微粉的乳化方法、聚氨酯微粉乳液、皮革补伤剂及其应用 |
CN112973437B (zh) * | 2021-02-20 | 2022-08-26 | 武汉绿知行环保科技有限公司 | 一种空气净化装置用甲醛去除母粒及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1448214A (zh) * | 2002-03-29 | 2003-10-15 | 徐瑞芬 | 纳米二氧化钛光催化剂、其制备方法及其应用 |
EP1397441B1 (de) * | 2001-06-01 | 2005-07-27 | BASF Coatings AG | Pigmentierte pulverlacksuspensionen (pigmentierte pulverslurries), verfahren zu ihrer herstellung und ihre verwendung |
CN1814629A (zh) * | 2005-02-05 | 2006-08-09 | 广州宏昌胶粘带厂 | 含无机纳米粒子的核-壳无机-有机复合压敏胶乳液及其制备方法和应用 |
US20070009453A1 (en) * | 2005-07-11 | 2007-01-11 | L'oreal | Photoprotective compositions comprising an aqueous phase and a low melting point apolar wax |
CN101220228A (zh) * | 2007-04-26 | 2008-07-16 | 天津兆阳纳米科技有限公司 | 一种超声波制备稳定的纳米级水性颜料分散液的方法 |
-
2009
- 2009-01-24 CN CN2009100028006A patent/CN101538441B/zh not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1397441B1 (de) * | 2001-06-01 | 2005-07-27 | BASF Coatings AG | Pigmentierte pulverlacksuspensionen (pigmentierte pulverslurries), verfahren zu ihrer herstellung und ihre verwendung |
CN1448214A (zh) * | 2002-03-29 | 2003-10-15 | 徐瑞芬 | 纳米二氧化钛光催化剂、其制备方法及其应用 |
CN1814629A (zh) * | 2005-02-05 | 2006-08-09 | 广州宏昌胶粘带厂 | 含无机纳米粒子的核-壳无机-有机复合压敏胶乳液及其制备方法和应用 |
US20070009453A1 (en) * | 2005-07-11 | 2007-01-11 | L'oreal | Photoprotective compositions comprising an aqueous phase and a low melting point apolar wax |
CN101220228A (zh) * | 2007-04-26 | 2008-07-16 | 天津兆阳纳米科技有限公司 | 一种超声波制备稳定的纳米级水性颜料分散液的方法 |
Non-Patent Citations (1)
Title |
---|
JP特开2004-269582A 2004.09.30 |
Also Published As
Publication number | Publication date |
---|---|
CN101538441A (zh) | 2009-09-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101538441B (zh) | 改性的氨基烤漆反相乳液、其制备方法以及使用该乳液制备烤漆涂层的方法 | |
CN105400239B (zh) | 一种超疏水改性二氧化硅的制备方法 | |
CN104497765A (zh) | 一种除甲醛的内墙乳胶漆及其制备方法 | |
CN1730581A (zh) | 纳米银抗菌水性木器漆及其制备方法 | |
AU2014237704B2 (en) | Superhydrophilic coating composition | |
CN107418331A (zh) | 变色涂料及其制备方法 | |
JP5295621B2 (ja) | 殺菌性充填剤組成物 | |
KR100951918B1 (ko) | 토목건축용 마감재도료의 제조방법 | |
US9539557B2 (en) | Treated inorganic pigments having improved dispersability and use thereof in coating compositions | |
CN106833204A (zh) | 一种室内用除甲醛抗菌环保水漆及其制备方法 | |
JPH02292201A (ja) | 抗菌性シリカゲルおよび抗菌性樹脂 | |
CN113122030A (zh) | 一种硅藻土改性无机水性涂料及其制备方法 | |
CN110982354A (zh) | 一种建筑用抗菌防霉内墙涂料及其制备方法和应用 | |
CN109370347A (zh) | 一种负离子仿花岗岩漆及其制备方法 | |
CN108102489A (zh) | 一种水性环保涂料及其制备方法 | |
EP1953197A1 (en) | Hydrophobic Metal and Metal Oxide Particles with Unique Optical Properties | |
CN104862973B (zh) | 织物用紫外屏蔽涂层材料及制备方法 | |
CN103627280B (zh) | 一种单组分水性户外清面漆 | |
CN107418254B (zh) | 一种疏水性固体粉末分散材料及其应用 | |
KR20050118756A (ko) | 수용성 광촉매 도료 조성물 및 그 제조방법 | |
CN114680106B (zh) | 抗菌液及其制备方法和应用、抗菌制品 | |
CN108822693A (zh) | 一种抗菌疏水涂层的制备方法 | |
CN111100274B (zh) | 一种抗菌纳米银树脂的制备方法及含有该树脂的不粘涂料 | |
EP3515992B1 (en) | Method for manufacturing bismuth based pigment having an improved alkaline resistance by encapsulating said pigment with a chelating agent | |
CN114752273A (zh) | 抗菌液及其制备方法和应用、抗菌制品 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Free format text: FORMER OWNER: XU RUIFEN Owner name: JIANGSU KAOPULE NEW MATERIAL INC. Free format text: FORMER OWNER: CHANGZHOU XINGANG GAOLI CHEMICAL CO., LTD. Effective date: 20101130 |
|
C41 | Transfer of patent application or patent right or utility model | ||
COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 213315 NO.36, WEISHANHU ROAD, XIXIASHU TOWN, XINBEI DISTRICT, CHANGZHOU CITY, JIANGSU PROVINCE TO: 213135 NO.36, WEISHANHU ROAD, XIXIASHU TOWN, XINBEI DISTRICT, CHANGZHOU CITY, JIANGSU PROVINCE |
|
TA01 | Transfer of patent application right |
Effective date of registration: 20101130 Address after: 213135 No. 36, Weishan Lake Road, Xixia villa town, Xinbei District, Jiangsu, Changzhou Applicant after: Jiangsu Kaopule New Materials Co., Ltd. Address before: 213315 No. 36, Weishan Lake Road, Xixia villa town, Xinbei District, Jiangsu, Changzhou Applicant before: Changzhou Xingang Gaoli Chemical Co., Ltd. Co-applicant before: Xu Ruifen |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: JIANGSU KAOPULE NEW MATERIAL CO., LTD. Free format text: FORMER NAME: JIANGSU KAOPULE NEW MATERIAL INC. |
|
CP01 | Change in the name or title of a patent holder |
Address after: 213135 No. 36, Weishan Lake Road, Xixia villa town, Xinbei District, Jiangsu, Changzhou Patentee after: JIANGSU KAOPULE NEW MATERIAL CO., LTD. Address before: 213135 No. 36, Weishan Lake Road, Xixia villa town, Xinbei District, Jiangsu, Changzhou Patentee before: Jiangsu Kaopule New Materials Co., Ltd. |
|
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110504 Termination date: 20200124 |