CN101495683B - 具有高的热定形性的聚氨酯弹性纤维 - Google Patents

具有高的热定形性的聚氨酯弹性纤维 Download PDF

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Publication number: CN101495683B
Authority: CN; China
Prior art keywords: chain extender; polyurethane; prepolymer; diisocyanate; fabric
Prior art date: 2006-07-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

CN2007800277099A

Other languages

English (en)

Chinese (zh)

Other versions

CN101495683A (zh

Inventor

姜渊秀

徐升渊

晋中成

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Xiaoxing Tianxi (zhu)

Original Assignee

Hyosung Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2006-07-31

Filing date

2007-07-31

Publication date

2011-09-14

2007-07-31 Application filed by Hyosung Corp filed Critical Hyosung Corp

2009-07-29 Publication of CN101495683A publication Critical patent/CN101495683A/zh

2011-09-14 Application granted granted Critical

2011-09-14 Publication of CN101495683B publication Critical patent/CN101495683B/zh

Status Active legal-status Critical Current

2027-07-31 Anticipated expiration legal-status Critical

Links

229920002635 polyurethane Polymers 0.000 title claims abstract description 44
239000004814 polyurethane Substances 0.000 title claims abstract description 44
210000004177 elastic tissue Anatomy 0.000 title 1
239000004744 fabric Substances 0.000 claims abstract description 42
239000004970 Chain extender Substances 0.000 claims abstract description 17
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims abstract description 7
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims abstract description 6
VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 claims abstract description 6
KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 claims abstract description 6
AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 claims abstract description 5
239000005700 Putrescine Substances 0.000 claims abstract description 3
GHWVXCQZPNWFRO-UHFFFAOYSA-N butane-2,3-diamine Chemical compound CC(N)C(C)N GHWVXCQZPNWFRO-UHFFFAOYSA-N 0.000 claims abstract description 3
238000009998 heat setting Methods 0.000 claims description 30
238000000034 method Methods 0.000 claims description 27
-1 polytetramethylene Polymers 0.000 claims description 18
238000002360 preparation method Methods 0.000 claims description 11
238000006243 chemical reaction Methods 0.000 claims description 10
239000012948 isocyanate Substances 0.000 claims description 10
150000002513 isocyanates Chemical class 0.000 claims description 7
235000010290 biphenyl Nutrition 0.000 claims description 5
239000004305 biphenyl Substances 0.000 claims description 5
125000006267 biphenyl group Chemical group 0.000 claims description 5
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
239000000463 material Substances 0.000 claims description 5
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 5
239000003960 organic solvent Substances 0.000 claims description 4
150000005846 sugar alcohols Polymers 0.000 claims description 4
239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 2
239000005058 Isophorone diisocyanate Substances 0.000 claims description 2
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 2
RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 2
NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 2
229920001451 polypropylene glycol Polymers 0.000 claims description 2
238000004519 manufacturing process Methods 0.000 abstract description 6
XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 abstract description 5
VKIRRGRTJUUZHS-UHFFFAOYSA-N cyclohexane-1,4-diamine Chemical compound NC1CCC(N)CC1 VKIRRGRTJUUZHS-UHFFFAOYSA-N 0.000 abstract 1
230000000052 comparative effect Effects 0.000 description 15
229920001778 nylon Polymers 0.000 description 11
239000004677 Nylon Substances 0.000 description 10
239000000835 fiber Substances 0.000 description 9
229920001730 Moisture cure polyurethane Polymers 0.000 description 8
238000009940 knitting Methods 0.000 description 7
230000008542 thermal sensitivity Effects 0.000 description 7
238000002788 crimping Methods 0.000 description 6
WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 description 6
229920006306 polyurethane fiber Polymers 0.000 description 6
238000005096 rolling process Methods 0.000 description 6
230000015556 catabolic process Effects 0.000 description 5
238000006731 degradation reaction Methods 0.000 description 5
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
239000000654 additive Substances 0.000 description 4
230000000996 additive effect Effects 0.000 description 4
150000004985 diamines Chemical group 0.000 description 4
HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 4
229920002955 Art silk Polymers 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
239000004743 Polypropylene Substances 0.000 description 3
229920002334 Spandex Polymers 0.000 description 3
208000012886 Vertigo Diseases 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
239000012299 nitrogen atmosphere Substances 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
229920001155 polypropylene Polymers 0.000 description 3
229920002215 polytrimethylene terephthalate Polymers 0.000 description 3
239000004759 spandex Substances 0.000 description 3
238000009987 spinning Methods 0.000 description 3
238000003756 stirring Methods 0.000 description 3
210000002268 wool Anatomy 0.000 description 3
IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
125000005442 diisocyanate group Chemical group 0.000 description 2
238000000578 dry spinning Methods 0.000 description 2
238000011156 evaluation Methods 0.000 description 2
239000000203 mixture Substances 0.000 description 2
239000004408 titanium dioxide Substances 0.000 description 2
ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
239000012964 benzotriazole Substances 0.000 description 1
XEVRDFDBXJMZFG-UHFFFAOYSA-N carbonyl dihydrazine Chemical compound NNC(=O)NN XEVRDFDBXJMZFG-UHFFFAOYSA-N 0.000 description 1
239000000969 carrier Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
125000004427 diamine group Chemical group 0.000 description 1
150000002009 diols Chemical group 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
229920003226 polyurethane urea Polymers 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
238000002166 wet spinning Methods 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/70—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyurethanes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/061—Load-responsive characteristics elastic
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S528/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S528/906—Fiber or elastomer prepared from an isocyanate reactant

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Knitting Of Fabric (AREA)
Artificial Filaments (AREA)

CN2007800277099A 2006-07-31 2007-07-31 具有高的热定形性的聚氨酯弹性纤维 Active CN101495683B (zh)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
KR1020060071869A KR100711644B1 (ko)	2006-07-31	2006-07-31	열세트성이 향상된 폴리우레탄 탄성사
KR10-2006-0071869		2006-07-31
KR1020060071869		2006-07-31
PCT/KR2007/003689 WO2008016255A1 (en)	2006-07-31	2007-07-31	A polyurethane elastic fiber with high heat settable property

Publications (2)

Publication Number	Publication Date
CN101495683A CN101495683A (zh)	2009-07-29
CN101495683B true CN101495683B (zh)	2011-09-14

Family

ID=38182389

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CN2007800277099A Active CN101495683B (zh)	2006-07-31	2007-07-31	具有高的热定形性的聚氨酯弹性纤维

Country Status (3)

Country	Link
KR (1)	KR100711644B1 (ko)
CN (1)	CN101495683B (ko)
WO (1)	WO2008016255A1 (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
MX2011003995A (es) *	2008-10-17	2011-05-10	Invista Tech Sarl	Elastano fusible bicomponente.
CN103255500B (zh) *	2013-05-30	2015-03-25	浙江华峰氨纶股份有限公司	一种适合低温定形的聚氨酯弹性纤维的制备方法
CN103498209B (zh) *	2013-10-21	2015-10-28	浙江华峰氨纶股份有限公司	具有耐高温和耐碱聚氨酯弹性纤维的制备方法
CN105506777A (zh) *	2016-01-26	2016-04-20	浙江华峰氨纶股份有限公司	一种易粘合聚氨酯弹性纤维及其制备方法
CN107663670B8 (zh) *	2017-08-16	2019-10-15	东华大学	一种聚氨酯弹性纤维及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN1176967A (zh) *	1996-07-24	1998-03-25	晓星T＆C株式会社	制备改性聚氨酯纤维聚合物的方法
CN1344337A (zh) *	1999-03-19	2002-04-10	旭化成株式会社	聚氨酯脲弹性纤维及其生产方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5000899A (en) *	1988-05-26	1991-03-19	E. I. Du Pont De Nemours And Company	Spandex fiber with copolymer soft segment
AUPP991799A0 (en)	1999-04-23	1999-05-20	Cardiac Crc Nominees Pty Limited	Siloxane-containing polyurethane-urea compositions
TW589421B (en) *	2000-04-26	2004-06-01	Du Pont	Spandex with high heat-set efficiency
US6984708B2 (en) *	2002-10-04	2006-01-10	Invista North America S.A.R.L.	Spandex of a particular composition and process for making same

2006
- 2006-07-31 KR KR1020060071869A patent/KR100711644B1/ko active IP Right Grant
2007
- 2007-07-31 CN CN2007800277099A patent/CN101495683B/zh active Active
- 2007-07-31 WO PCT/KR2007/003689 patent/WO2008016255A1/en active Application Filing

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN1176967A (zh) *	1996-07-24	1998-03-25	晓星T＆C株式会社	制备改性聚氨酯纤维聚合物的方法
CN1344337A (zh) *	1999-03-19	2002-04-10	旭化成株式会社	聚氨酯脲弹性纤维及其生产方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JP平2-19511A 1990.01.23 *

Also Published As

Publication number	Publication date
KR100711644B1 (ko)	2007-04-25
WO2008016255A1 (en)	2008-02-07
CN101495683A (zh)	2009-07-29

Legal Events

Date	Code	Title	Description
2009-07-29	C06	Publication
2009-07-29	PB01	Publication
2009-09-23	C10	Entry into substantive examination
2009-09-23	SE01	Entry into force of request for substantive examination
2011-09-14	C14	Grant of patent or utility model
2011-09-14	GR01	Patent grant
2018-12-21	TR01	Transfer of patent right	Effective date of registration: 20181203 Address after: Seoul, South Kerean Patentee after: Xiaoxing Tianxi (Zhu) Address before: Seoul, South Korea Patentee before: Hyosung Corp.
2018-12-21	TR01	Transfer of patent right

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