CN101487188A - Spinning oil used in cellulore industry field - Google Patents
Spinning oil used in cellulore industry field Download PDFInfo
- Publication number
- CN101487188A CN101487188A CNA2009100244344A CN200910024434A CN101487188A CN 101487188 A CN101487188 A CN 101487188A CN A2009100244344 A CNA2009100244344 A CN A2009100244344A CN 200910024434 A CN200910024434 A CN 200910024434A CN 101487188 A CN101487188 A CN 101487188A
- Authority
- CN
- China
- Prior art keywords
- oil
- spinning
- sugar alcohol
- carbonic acid
- esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a spinning oil applied to the field of acetate fiber industry, comprising internal oil and external oil; the internal oil consists of 9-12 carbonate sugar alcohol anhydride esters and 9-12 alcohol lactic esters; and the external oil consists of 9-12 carbonate polyoxyethylene ethers, 9-12 of carbonate sugar alcohol anhydride ester and 9-12 alcohol lactic esters. The invention prepares the modified vegetable oil-based surfactant as cellulose acetate spinning oil which is applied to the cellulose acetate sliced acetone solution and spinning external oil, thus playing the effects of reducing the viscosity of serum, reducing resistance and anti-wearing, increasing the collection property of the tow and the subsequent anti-curling processing performance, and the like.
Description
Technical field:
The present invention relates to the spinning oil that a kind of cigarette uses with cellulose acetate tow production.
Background technology:
Use mineral oil as spinning oil in a large number in the synthetic fiber field, because of petroleum chemicals mineral oil is non-renewable resources, biodegradation is slow, is not suitable for the requirement of environmental protection and social industrial economy sustainable development.Cigarette still uses food-grade mineral oil as spinning oil (oil and outer oil in comprising) with the cellulose acetate tow industrial circle at present, with the raising of environmental requirement, is badly in need of the development and application of feature of environmental protection finish.
Summary of the invention:
Technical solution of the present invention is:
A kind of spinning oil of using at the fine industrial circle of vinegar comprises interior oil, outer oil, and it is characterized in that: interior oil is made up of following component in percentage by weight:
9～12 carbonic acid sugar alcohol acid anhydride esters 20～50%
9～12 carbon alcohol lactate 50～80%;
Outer oil is made up of following component in percentage by weight:
9～12 carbonic acid polyoxyethylene ether 20～40%
9～12 carbonic acid sugar alcohol acid anhydride esters 40～60%
9～12 carbon alcohol lactate 20～40%.
This fermentation is mixed with cigarette acetate fiber spinning oil with the modified vegetable oil based surfactants, be applied to the outer oil of celluloseacetate flake acetone soln and spinning, play slurries viscosity decreasing impedance mill and increase effects such as tow convergence and follow-up anti-curling processing characteristics.The present invention is applied to cigarette diacetate fiber industrial circle with the modified vegetable oil based surfactants, vegetable oil output is big, be the natural green resource, biological degradability is strong, catabolite is nuisanceless, by the surfactant type spinning oil of plant oil modified acquisition, have the strong characteristics of identical biological degradability.
The invention will be further described below in conjunction with embodiment.
The specific embodiment:
Embodiment 1:
A kind of spinning oil of using at the fine industrial circle of vinegar comprises interior oil, outer oil;
Interior oil is oil in the plant oil modified surfactant, is made up of following component in percentage by weight:
9～12 carbonic acid sugar alcohol acid anhydride esters 30%
9～12 carbon alcohol lactate 70%;
Outer oil is the outer oil of plant oil modified surfactant, is made up of following component in percentage by weight:
9～12 carbonic acid polyoxyethylene ether 30%
9～12 carbonic acid sugar alcohol acid anhydride esters 40%
9～12 carbon alcohol lactate 30%.
During use, oil, the outer oil of plant oil modified surfactant in the above-mentioned plant oil modified surfactant are mixed in the slurries,
Being made as of slurries of oil in containing:
Weight components is mixed, stirred 120 minutes, make cellulose diacetate acetone soln (slurries of oil in promptly containing):
68.4 parts in acetone
26.6 parts of cellulose diacetates
Oil is 0.4 part in the plant oil modified surfactant
0.4 part of titanium dioxide
4.2 parts in water
These slurries are detected shear rate and shear viscosity relation curve with senior rotation rheology system, and this slurries initial shear viscosity does not use that oil reduces by 33% in the present invention, and the slurry stream sex change improves obvious.
Contain being made as of oily slurries outward:
10 parts of 5 portions of saturated decolouring corn oils of the outer oil of plant oil modified surfactant
85 portions of bacteriostatic agents of water (hydrogen peroxide) 200PPM
Outer oil of plant oil modified surfactant and saturated decolouring corn oil high speed shear are mixed, add deionized water again, be mixed with the spinning oil aqua, by the spin finishing device cigarette is evenly oiled with Celluloseacetate cigarette filter tow, the tow convergence that obtains obviously strengthens, tow is damaging strong by coiling-resistant behind the crimping machine, and flyings are low.
Embodiment 2:
A kind of spinning oil of using at the fine industrial circle of vinegar comprises interior oil, outer oil;
Interior oil is oil in the plant oil modified surfactant, is made up of following component in percentage by weight:
9～12 carbonic acid sugar alcohol acid anhydride esters 20%
9～12 carbon alcohol lactate 80%;
Outer oil is the outer oil of plant oil modified surfactant, is made up of following component in percentage by weight:
9～12 carbonic acid polyoxyethylene ether 20%
9～12 carbonic acid sugar alcohol acid anhydride esters 60%
9～12 carbon alcohol lactate 20%.
All the other are with embodiment 1.
Embodiment 3:
A kind of spinning oil of using at the fine industrial circle of vinegar comprises interior oil, outer oil;
Interior oil is oil in the plant oil modified surfactant, is made up of following component in percentage by weight:
9～12 carbonic acid sugar alcohol acid anhydride esters 40%
9～12 carbon alcohol lactate 60%;
Outer oil is the outer oil of plant oil modified surfactant, is made up of following component in percentage by weight:
9～12 carbonic acid polyoxyethylene ether 40%
9～12 carbonic acid sugar alcohol acid anhydride esters 40%
9～12 carbon alcohol lactate 20%.
All the other are with embodiment 1.
Claims (1)
1, a kind of spinning oil of using at the fine industrial circle of vinegar comprises interior oil, outer oil, and it is characterized in that: interior oil is made up of following component in percentage by weight:
9～12 carbonic acid sugar alcohol acid anhydride esters 20～50%
9～12 carbon alcohol lactate 50～80%;
Outer oil is made up of following component in percentage by weight:
9～12 carbonic acid polyoxyethylene ether 20～40%
9～12 carbonic acid sugar alcohol acid anhydride esters 40～60%
9～12 carbon alcohol lactate 20～40%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910024434 CN101487188B (en) | 2009-02-13 | 2009-02-13 | Spinning oil used in cellulore industry field |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910024434 CN101487188B (en) | 2009-02-13 | 2009-02-13 | Spinning oil used in cellulore industry field |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101487188A true CN101487188A (en) | 2009-07-22 |
| CN101487188B CN101487188B (en) | 2010-11-10 |
Family
ID=40890240
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200910024434 Active CN101487188B (en) | 2009-02-13 | 2009-02-13 | Spinning oil used in cellulore industry field |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101487188B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108411516A (en) * | 2018-04-03 | 2018-08-17 | 湖北新阳特种纤维股份有限公司 | Acetate fiber crimps pretreatment unit, pretreatment fluid and preprocess method |
| CN109056318A (en) * | 2018-08-15 | 2018-12-21 | 江苏四新界面剂科技有限公司 | Vinegar fibre finish dedicated biomass compound emulsifying agent |
| CN111118732A (en) * | 2019-12-29 | 2020-05-08 | 山东胜伟盐碱地科技有限公司 | Non-woven fabric material for saline-alkali soil and preparation method thereof |
| CN115896982A (en) * | 2022-11-21 | 2023-04-04 | 上海丰泽源科技有限公司 | Preparation process of environment-friendly spinning oil |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050287368A1 (en) * | 2004-06-25 | 2005-12-29 | Celanese Acetate Llc | Cellulose acetate tow and method of making same |
| CN100998443A (en) * | 2006-12-29 | 2007-07-18 | 新乡化纤股份有限公司 | Viscose rayon used for cigarette, its preparing method and spinning jet therefor |
-
2009
- 2009-02-13 CN CN 200910024434 patent/CN101487188B/en active Active
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108411516A (en) * | 2018-04-03 | 2018-08-17 | 湖北新阳特种纤维股份有限公司 | Acetate fiber crimps pretreatment unit, pretreatment fluid and preprocess method |
| CN108411516B (en) * | 2018-04-03 | 2019-10-11 | 湖北新阳特种纤维股份有限公司 | Acetate fiber crimps pretreatment unit, pretreatment fluid and preprocess method |
| CN109056318A (en) * | 2018-08-15 | 2018-12-21 | 江苏四新界面剂科技有限公司 | Vinegar fibre finish dedicated biomass compound emulsifying agent |
| CN111118732A (en) * | 2019-12-29 | 2020-05-08 | 山东胜伟盐碱地科技有限公司 | Non-woven fabric material for saline-alkali soil and preparation method thereof |
| CN115896982A (en) * | 2022-11-21 | 2023-04-04 | 上海丰泽源科技有限公司 | Preparation process of environment-friendly spinning oil |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101487188B (en) | 2010-11-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Otoni et al. | The food–materials nexus: Next generation bioplastics and advanced materials from agri‐food residues | |
| JP6007081B2 (en) | Method for producing lignin degradation product | |
| Du et al. | Preparation and characterization of functional cellulose nanofibrils via formic acid hydrolysis pretreatment and the followed high-pressure homogenization | |
| TWI656250B (en) | Cellulose nanofiber and its production method, aqueous dispersion using the cellulose nanofiber, and fiber reinforced composite material | |
| CN101487188B (en) | Spinning oil used in cellulore industry field | |
| Jeong et al. | Optimization of enzymatic hydrolysis conditions for extraction of pectin from rapeseed cake (Brassica napus L.) using commercial enzymes | |
| JP6182368B2 (en) | Method for producing lignin degradation product | |
| Akin | Chemistry of plant fibres | |
| CN102229750B (en) | Modified polypropylene composite material and preparation technology thereof | |
| JP5136984B2 (en) | Method for producing sugar | |
| CN103382225B (en) | A kind of method of modifying of Cellulose nanocrystal surface esterification | |
| Mao et al. | Visual degumming process of ramie fiber using a microbial consortium RAMCD407 | |
| CN103919689A (en) | Wet tissue emulsion, wet tissue and preparation method of wet tissue | |
| CN103588886A (en) | Easily-water dispersible nanocrystalline cellulose and preparation method thereof | |
| JP2013139018A (en) | Method for manufacturing pulverized material | |
| Nlandu et al. | Flax nanofibrils production via supercritical carbon dioxide pre‐treatment and enzymatic hydrolysis | |
| JP5019421B2 (en) | Method for producing sugar | |
| JP6182369B2 (en) | Method for producing lignin degradation product | |
| Suryanto et al. | Bacterial nanocellulose from agro-industrial wastes | |
| KR101671536B1 (en) | Pulping additives for a reduction of resin from kraft pulp | |
| WO2015066507A1 (en) | Melt compounding and fractionation of lignocellulosic biomass and products produced therefrom | |
| CN103740478A (en) | Food detergent | |
| CN110305726B (en) | Multifunctional low-temperature environment-friendly durable lubricating oil | |
| CN104652159B (en) | Preparation technology of bean curd skin micro-fibrillated cellulose | |
| de Medeiros Bezerra Jácome et al. | Valorization of mangaba residue (Hancornia speciosa Gomes) for polygalacturonase production from Aspergillus niger IOC 4003 and fabrication of active chitosan films |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |