CN101475417B - Biological mineral compound fertilizer and production method thereof - Google Patents

Biological mineral compound fertilizer and production method thereof Download PDF

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CN101475417B
CN101475417B CN 200910073705 CN200910073705A CN101475417B CN 101475417 B CN101475417 B CN 101475417B CN 200910073705 CN200910073705 CN 200910073705 CN 200910073705 A CN200910073705 A CN 200910073705A CN 101475417 B CN101475417 B CN 101475417B
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potassium
compound fertilizer
weight percent
bacillus
fertilizer
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CN101475417A (en
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牧耀贵
何文鹤
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Shanxi Green Biotechnology Industry Co ltd
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Abstract

The invention relates to a biomineral compound fertilizer, which comprises the following effective ingredients: 15 to 20 weight percent of organic substances, 5.8 to 10.3 weight percent of potassium oxide, 2 to 2.95 weight percent of microelements such as iron and copper, 1.5 to 2 weight percent of medium elements such as calcium, magnesium and sulfur, 1 to 5 weight percent of urea, 3 to 5 weight percent of phosphorus and potassium decomposing bacteria, and the balance being water and impurities, wherein the pH value of the fertilizer is between 6.5 and 7. The biomineral compound fertilizer contains the effective ingredients required by various crops, and has most nutritive compositions required for crop growth. The phosphorus and potassium decomposing bacteria in the biomineral compound fertilizer can also decompose insoluble phosphorus and potassium elements in soil, and are favorable for crop absorption. Moreover, the biomineral compound fertilizer promotes material exchange and beneficial cycle of a cropland biosphere 'soil-plant-animal-microorganism'.

Description

Biological mineral compound fertilizer and working method thereof
Technical field
The present invention relates to a kind of agricultural fertilizer, be specially a kind of compound fertilizer that is used to plant meticulous farm crop that contains microbial bacteria.
Background technology
Fertilizer is the grain of farm crop, and nitrogen, phosphorus, potassium three elements are the indispensable nutritive substances of all growth and development of plants.People have invented chemical fertilizer for this reason, but long-term a large amount of use of chemical fertilizer, particularly the excessive use of nitrogenous fertilizer causes the hardening soil, soil and water environment pollution, a series of worldwide problems of degradation under the crops quality.For this reason, many restrictions have been made to the use of chemical fertilizer on agricultural in the world.Country that has even the use of forbidding chemical fertilizer.Chemical fertilizer mainly is can residual various salt, acid group and heavy metal etc. in the decomposition course after it gets into soil to the infringement of environment.
In the farm crop production process, maximum with nitrogen element amount of application.And phosphorus, potassium element are comparatively rare, especially rare with potassium element, and use the last resolvent vitriol of potassium sulfate fertilizers can form pollution usually to soil.Chinese patent 2005101172665 discloses a kind of " biological multi element phosphorus potassium ferbilizer ", and it adopts potassium-bearing shale after pulverizing, adding the P and K decomposing bacterium, to ferment, and this bio-feritlizer has been avoided the pollution defective of chemical fertilizer.Deficiency is a complete nonnitrogenous element in the fertilizer, is not enough and in plant growing process, rely on the nitrogen element in the soil fully, therefore also must impose nitrogenous fertilizer, increases labor capacity.The secondth, effective potassium content is not enough, can not satisfy the needs of meticulous farm crop.
Summary of the invention
The invention provides a kind of working method of biological mineral compound fertilizer, it is single to have solved existing bio-feritlizer effective constituent, the deficiency that the compound manure production cost is high.
A kind of working method of biological mineral compound fertilizer is characterized in that comprising the steps:
1. screen potassium oxide content greater than 8% potassium-bearing shale and be crushed to the 200-300 order;
2. mix stirring by weight the potassium-bearing shale powder 70-80% that gets above-mentioned pulverizing with humic acids 20-30%;
3. add P and K decomposing bacterium and enzymatic microorganism in the said mixture, adding total amount is the 4-8% of mixture total weight, and the back that stirs keeps 28-33 ℃ of temperature, and humidity is more than 60%, and the adjustment pH value fermented 10-15 days to 6.5-7; Said P and K decomposing bacterial content is 50-100 hundred million strain/grams; Described P and K decomposing bacterium is bacillus megaterium (Bacillus megairius debary); Bacillusmusilaginosiengineering (Bacillus mucilaginosus) and/or subtilis (Bacillus subtilis);
4. in the gained tunning, add the urea of the 2. said mixture total weight amount of step 1-5% and stir.
The working method of described a kind of biological mineral compound fertilizer is characterized in that adding during step 4. the vitriolate of tartar of mixture total weight amount 1-5% and the fused(calcium magnesium)phosphate of 2-7%.
The working method of a kind of biological mineral compound fertilizer of the present invention contains the necessary nutritive element of ten multiple kinds of crops, can satisfy the required big portion nutritive element of crop growth.P and K decomposing bacterium wherein can also be decomposed mineral elements such as insoluble phosphorus, potassium in the soil, helps the crop absorption utilization.Thereby promote the exchange of substance and the biopurification function in biosphere, farmland " soil-plant-animal-mikrobe ", thereby reach the effect of optimizing the environment.Therefore can improve crops quality and output effectively.Big area test statistics data presentation, field crop raising the output 15%.Melon and fruit, vegetables are increased production more than 30%.And the fruit type of melon and fruit is neat, beautiful in colour, sugar degree is high, and mouthfeel is good, anti-storage.Biological mineral compound fertilizer of the present invention is a base manure type fertilizer, disposablely uses as base manure, does not need to impose phosphorus, potash fertilizer again.Only need the nitrogen critical porion to impose the purpose that nitrogenous fertilizer just can obtain increasing both production and income in right amount crop.The polynary disposition of this fertilizer has the advantage and the strong point of chemical fertilizer, bio-feritlizer concurrently, according to the regulation of " green food fertilizer usage criteria ", uses this fertilizer, can make most dry crops become A level green food.Fertiliser prodn cost of the present invention is low, has only about 1/3rd of existing composite fertilizer cost.
Embodiment
Embodiment 1 chooses potassium-bearing shale, detects potassium oxide content 8.1%, gets 160 kilograms and is crushed to 300 orders, and careless carbon (humic acids) is crushed to 250 orders for 40 kilograms, the two mixing and stirring.Add 2.5 kilograms of dried bacterium of bacillus megaterium Bacillus megairius debary and 3 kilograms of dried bacterium of bacillusmusilaginosiengineering Bacillus mucilaginosus and 2.5 kilograms of enzymatic microorganism; And adding an amount of warm water stirring, the bacterial content of above-mentioned two kinds of dried bacterium is 50-100 hundred million strain/grams.Adjustment pH value 6.5-7, envrionment temperature keeps 28-33 ℃, and humidity was fermented 12 days more than 60%, added urea and vitriolate of tartar then and stirred for each 5 kilograms.Obtain 250 kilograms of biological mineral compound fertilizers.Wherein active constituent content is organic 15 %; Potassium oxide 10.1 %; Trace element such as zinc, iron, copper amounts to 2.03 %; Moderate-elements such as calcium, magnesium, sulphur amount to 2.11 %; Urea 5 %; P and K decomposing bacterium 3 %.All the other are impurity and water, and impurity mainly is silicon-dioxide, robust fibre.
Embodiment 2 chooses potassium-bearing shale, detects potassium oxide content 8.3%, gets 320 tons and be crushed to 250 orders, and humic acids is crushed to 200 orders for 80 tons, the two mixing and stirring.Add 8 tons of dried bacterium of bacillus megaterium Bacillus megairius debary, bacterial content 8,000,000,000 strain/grams.10 tons of dried bacterium of gel-shaped bacillus mucilaginosus and 4 tons of enzymatic microorganism, bacterial content are 10,000,000,000 strain/grams.And add an amount of warm water and stir.Adjustment pH value 6.5-7, envrionment temperature keeps 28-33 ℃, and humidity 70% was fermented 15 days, added 5 tons in urea then, and 7 tons of vitriolate of tartar also stir.Obtain 500 tons of biological mineral compound fertilizers.Wherein the effective constituent weight percentage is organic 18 %; Potassium oxide 9.8 %; Trace element such as zinc, iron, copper amounts to 2.44 %; Moderate-elements such as calcium, magnesium, sulphur amount to 1.63 %; Urea 5 %; P and K decomposing bacterium 4.4 %; Surplus is water and impurity, and impurity comprises silicon-dioxide and robust fibre etc.
Embodiment 3 chooses 70 tons of potassium-bearing shales, detects potassium oxide content 8%, is crushed to 250 orders, and humic acids is crushed to 200 orders for 30 tons, the two mixing and stirring.Add 2.5 tons of dried bacterium of bacillus megaterium Bacillus megairius debary, bacterial content 8,000,000,000 strain/grams.3 tons of dried bacterium of subtilis Bacillus subtilis and 2 tons of enzymatic microorganism, bacterial content are 10,000,000,000 strain/grams.And add an amount of warm water and stir.Adjustment pH value 6.5-7, envrionment temperature keeps 28-33 ℃, and humidity 75% was fermented 13 days, added 3 tons in urea then, and 3.5 tons of vitriolate of tartar also stir.Obtain 150 tons of biological mineral compound fertilizers.Detecting the effective constituent weight percentage is organic 20.8 %; Potassium oxide 5.9 %; Trace element such as zinc, iron, copper amounts to 2.84 %; Moderate-elements such as calcium, magnesium, sulphur amount to 1.70 %; Urea 2.0 %; P and K decomposing bacterium 5.0 %; Surplus is water and impurity, and impurity comprises silicon-dioxide and robust fibre etc.
Embodiment 4 chooses 300 tons of potassium-bearing shales, detects potassium oxide content 8.3%, is crushed to 250 orders, and humic acids is crushed to 200 orders for 100 tons, the two mixing and stirring.Add 12 tons of dried bacterium of bacillus megaterium Bacillus megairius debary, bacterial content 8,000,000,000 strain/grams.10 tons of dried bacterium of gel-shaped bacillus mucilaginosus, 5 tons of subtilis Bacillus subtilis and 7 tons of enzymatic microorganism, bacterial content is 10,000,000,000 strain/grams.And add an amount of warm water and stir.Adjustment pH value 6.5-7, envrionment temperature keeps 28-33 ℃, and humidity 70% was fermented 14 days, added 2.5 tons in urea then and stirred.Obtain 250 tons of biological mineral compound fertilizers.Wherein the effective constituent weight percentage is organic 16 %; Potassium oxide 6.6 %; Trace element such as zinc, iron, copper amounts to 2.15 %; Moderate-elements such as calcium, magnesium, sulphur amount to 1.50 %; Urea 1 %; P and K decomposing bacterium 6.8 %; Surplus is water and impurity, and impurity comprises silicon-dioxide and robust fibre etc.
The bacillus megaterium of selecting for use in the embodiment of the invention, bacillusmusilaginosiengineering, subtilis and enzymatic microorganism all adopt the commercially available prod.
In the above-mentioned production process, the adjustment pH value adopts yellow soda ash or Hydrogen chloride.
Above-mentioned potassium-bearing shale is taken from the Jinzhong City, Shanxi Province, and its major ingredient and weight percentage are following:
K?7.84-9.17%?; P 0.05-0.1%?; SiO2?65-75%?;
Zn?0.1-0.2%?;?Fe?1-2%?;?Cu?0.0005-0.005%?;?Mn?0.0001-0.001%?;
Mo?0.001-0.040%?;?B?0.001-0.01%?; Se?0.001-0.01%?;
S?0.01-0.1%?; Na?0.1-1%?;
The field test instance:
1 years corn field test results in part village, Chen Kan township, Yuci, Shanxi Province of instance, the contrast raising the output result who uses this bio-feritlizer is that 96.5 kilograms of/mu mus increase income rate 14.3%.
The tomato test-results that instance was improved literature and pressed down in the Yuci, Shanxi in 2 years, comparison increases income rate 25%. for 404 kilograms/mu according to the field raising the output
Dongyang town, instance three late sowing wheats Yuci in October, 2006 fits date of seeding about September 20 this test site winter wheat; Promptly belong to the late sowing phase after getting into October. general through strengthening application rate; Obtain high yield by enlarging colony; So the late sowing sowing quantity is at 30-35 kilogram/mu. for testing the effect of this fertilizer; Application rate reduces to 15 kilograms/mu. execute 50 kilograms/mu of this bio-feritlizers, experimental field before stubble for soybean. do not use other fertilizer and nitrogenous fertilizer. jointing stage of turning green next year is executed 40 kilograms/mu in urea. winter irrigation, period of seedling establishment, full-bloom stage and filling stage respectively pour water once.
Test-results such as following table:
Figure BDA0000211040911

Claims (2)

1. the working method of a biological mineral compound fertilizer is characterized in that comprising the steps:
1. screen potassium oxide content greater than 8% potassium-bearing shale and be crushed to the 200-300 order;
2. mix stirring by weight the potassium-bearing shale powder 70-80% that gets above-mentioned pulverizing with humic acids 20-30%;
3. add P and K decomposing bacterium and enzymatic microorganism in the said mixture, adding total amount is the 4-8% of mixture total weight, and the back that stirs keeps 28-33 ℃ of temperature, and humidity is more than 60%, and the adjustment pH value fermented 10-15 days to 6.5-7; Said P and K decomposing bacterial content is 50-100 hundred million strain/grams; Described P and K decomposing bacterium is bacillus megaterium (Bacillus megairius debary); Bacillusmusilaginosiengineering (Bacillus mucilaginosus) and/or subtilis (Bacillus subtilis);
4. in the gained tunning, add the urea of the 2. said mixture total weight amount of step 1-5% and stir.
2. according to the working method of the described a kind of biological mineral compound fertilizer of claim 1, it is characterized in that adding during step 4. the vitriolate of tartar of mixture total weight amount 1-5% and the fused(calcium magnesium)phosphate of 2-7%.
CN 200910073705 2009-01-20 2009-01-20 Biological mineral compound fertilizer and production method thereof Expired - Fee Related CN101475417B (en)

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CN101967070B (en) * 2010-07-23 2013-01-02 中化重庆涪陵化工有限公司 Sulfur, zinc, manganese and boron-containing phosphate ammoniate fertilizer and production method thereof
CN102060605A (en) * 2010-11-16 2011-05-18 张晓明 Biologic mineral compound fertilizer
CN102167639A (en) * 2011-01-10 2011-08-31 艾应伟 Microbial fertilizer special for slope artificial soil
CN102351596B (en) * 2011-07-06 2013-11-20 山东宝源生物有限公司 Pakchoi organic composite fertilizer
CN103030471B (en) * 2013-01-21 2014-11-05 四川华讯资产经营管理有限公司 Nano microorganism organic and inorganic compound fertilizer and production method thereof
CN103755474B (en) * 2014-01-13 2015-05-13 花庆渝 Organic-inorganic compound fertilizer
CN104130050B (en) * 2014-07-01 2018-02-09 山西绿图生物科技有限公司 Multielement composite microbe fertilizer and its production method
CN104355813A (en) * 2014-10-29 2015-02-18 贵州省化工研究院 Method for producing organic-inorganic compound fertilizer through potassium-bearing shale
CN104478586A (en) * 2014-12-10 2015-04-01 山东大学 Selenium-rich microbial preparation prepared by fermentation of animal serum and preparation method of selenium-rich microbial preparation
CN106045614A (en) * 2016-05-26 2016-10-26 内蒙古科技大学 Method for preparing multiple species inoculant by using microorganism decomposing slates
CN108129243A (en) * 2018-03-16 2018-06-08 常国占 A kind of mineral element biological compound fertilizer
CN115537208A (en) * 2022-09-30 2022-12-30 武汉工程大学 Method for preparing soil conditioner by utilizing phosphorus potassium tailings and waste biomass

Citations (4)

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Publication number Priority date Publication date Assignee Title
BR9903634A (en) * 1999-08-17 2001-04-24 Luiz Antonio Do Nascimento Lou Production of organic phosphate compound, through the activity of the bioprocessor
CN1699294A (en) * 2005-05-29 2005-11-23 崔克昌 Method for producing fermented potash fertilizer by bacterium enzymatic treatment of potassium-containing rock and preparing organic-inorganic compound mixed fertilizers
CN1785934A (en) * 2005-11-02 2006-06-14 刘计川 Biological multi element phosphorus potassium ferbilizer
CN101177361A (en) * 2007-11-16 2008-05-14 湖南豫园生物工程有限公司 Highly effective microbe fertilizer formulation and method for making same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9903634A (en) * 1999-08-17 2001-04-24 Luiz Antonio Do Nascimento Lou Production of organic phosphate compound, through the activity of the bioprocessor
CN1699294A (en) * 2005-05-29 2005-11-23 崔克昌 Method for producing fermented potash fertilizer by bacterium enzymatic treatment of potassium-containing rock and preparing organic-inorganic compound mixed fertilizers
CN1785934A (en) * 2005-11-02 2006-06-14 刘计川 Biological multi element phosphorus potassium ferbilizer
CN101177361A (en) * 2007-11-16 2008-05-14 湖南豫园生物工程有限公司 Highly effective microbe fertilizer formulation and method for making same

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