CN101460526A - 担载的聚合催化剂 - Google Patents
担载的聚合催化剂 Download PDFInfo
- Publication number
- CN101460526A CN101460526A CNA2007800201687A CN200780020168A CN101460526A CN 101460526 A CN101460526 A CN 101460526A CN A2007800201687 A CNA2007800201687 A CN A2007800201687A CN 200780020168 A CN200780020168 A CN 200780020168A CN 101460526 A CN101460526 A CN 101460526A
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- compound
- catalyst component
- charged ion
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/02—Anti-static agent incorporated into the catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Description
实施例 | 催化剂 | 催化剂的量(mg) | PE的收率(g) | 活性1 | 生产率2 | 助催化剂 |
1 | A-c | 28 | 12.6 | 22584 | 426.7 | MAO |
2 | B | 29 | 37.5 | 79417 | 1292.1 | B-2 |
3 | C-c | 27 | 24.5 | 47692 | 906.4 | MAO |
4 | D | 27 | 27.5 | 62519 | 1017.2 | B-2 |
5 | E | 26 | 44.9 | 117835 | 1713.9 | B-2 |
实施例 | 催化剂 | 重量%己烯 | 支链数/千碳原子 | 重均分子量 | 多分散性(Mw/Mn) | 活化剂 |
6-c | A | 3.6 | 6.2 | 490500 | 2.07 | MAO |
7 | B | 4.7 | 8.2 | 386200 | 2.6 | B-2 |
8-c | C | 2.8 | 4.8 | 146900 | 2.6 | MAO |
9 | D | 2.9 | 4.8 | 169600 | 2.83 | B-2 |
10 | E | 2.4 | 4 | 82700 | 2.05 | B-2 |
实施例 | 催化剂 | 生产率(gPE/g催化剂) | 平均生产率 | 标准偏差 |
11 | F | 888.3 | 1051.4 | 162.4 |
12 | F | 1168.0 | ||
13 | F | 1299.0 | ||
14 | F | 973.1 | ||
15 | F | 1166.9 | ||
16 | F | 999.0 | ||
17 | F | 865.7 | ||
18 | G | 804.6 | 915.7 | 124.8 |
19 | G | 1050.7 | ||
20 | G | 891.9 | ||
21 | H | 459.0 | 459.0 | 未提供 |
Claims (11)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0610667.8A GB0610667D0 (en) | 2006-05-30 | 2006-05-30 | Supported polymerization catalysts |
GB0610667.8 | 2006-05-30 | ||
PCT/CA2007/000736 WO2007137395A1 (en) | 2006-05-30 | 2007-05-02 | Supported polymerization catalysts |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101460526A true CN101460526A (zh) | 2009-06-17 |
CN101460526B CN101460526B (zh) | 2011-07-27 |
Family
ID=36687945
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2007800201687A Expired - Fee Related CN101460526B (zh) | 2006-05-30 | 2007-05-02 | 担载的聚合催化剂 |
Country Status (6)
Country | Link |
---|---|
US (1) | US7863213B2 (zh) |
EP (1) | EP2021383A4 (zh) |
CN (1) | CN101460526B (zh) |
CA (1) | CA2587230C (zh) |
GB (1) | GB0610667D0 (zh) |
WO (1) | WO2007137395A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103380154A (zh) * | 2010-11-22 | 2013-10-30 | 阿尔比马尔公司 | 活化剂组合物、其制备及其在催化中的用途 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2734167C (en) | 2011-03-15 | 2018-03-27 | Nova Chemicals Corporation | Polyethylene film |
CA2749835C (en) * | 2011-08-23 | 2018-08-21 | Nova Chemicals Corporation | Feeding highly active phosphinimine catalysts to a gas phase reactor |
CA2798855C (en) | 2012-06-21 | 2021-01-26 | Nova Chemicals Corporation | Ethylene copolymers having reverse comonomer incorporation |
US9115233B2 (en) | 2012-06-21 | 2015-08-25 | Nova Chemicals (International) S.A. | Ethylene copolymer compositions, film and polymerization processes |
CA2800056A1 (en) | 2012-12-24 | 2014-06-24 | Nova Chemicals Corporation | Polyethylene blend compositions |
JP6185872B2 (ja) * | 2014-03-28 | 2017-08-23 | 積水化成品工業株式会社 | 高密度ポリエチレン系樹脂粒子、複合樹脂粒子、発泡粒子及び発泡成形体 |
Family Cites Families (29)
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DZ520A1 (fr) | 1982-03-24 | 2004-09-13 | Union Carbide Corp | Procédé perfectionné pour accroitre le rendement espace temps d'une réaction de polymérisation exothermique en lit fluidisé. |
ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
CA1268754A (en) | 1985-06-21 | 1990-05-08 | Howard Curtis Welborn, Jr. | Supported polymerization catalyst |
US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
CA1304746C (en) | 1987-08-31 | 1992-07-07 | The Dow Chemical Company | Preparation of polyhydrocarbylaluminoxanes |
NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
DE551277T1 (de) | 1990-06-22 | 1996-10-10 | Exxon Chemical Patents Inc., Linden, N.J. | Aluminiumfreie monocyclopentadienyl-metallocenkatalysatoren für olefinpolymerisation. |
JP2849492B2 (ja) | 1991-05-31 | 1999-01-20 | シャープ株式会社 | 投影型液晶表示装置 |
US5240894A (en) | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
ES2125458T3 (es) | 1993-05-13 | 1999-03-01 | Exxon Chemical Patents Inc | Copolimeros de etileno que tienen una distribucion de la composicion estrecha, su produccion y uso. |
ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
NZ268270A (en) | 1993-06-24 | 1997-10-24 | Dow Chemical Co | Titanium (ii)- or zirconium (ii)- containing complexes and addition polymerisation catalysts therefrom (m is ti or zr) |
ES2160634T3 (es) | 1993-09-17 | 2001-11-16 | Exxonmobil Chem Patents Inc | Sistemas catalizadores de polimerizacion, su produccion y uso. |
CA2193410C (en) | 1994-06-24 | 2005-06-07 | George Allen Vaughn | Polymerization catalyst systems, their production and use |
US5616664A (en) | 1994-08-02 | 1997-04-01 | The Dow Chemical Company | Polymerization process with biscyclopentadienyl diene complex containing catalysts |
WO1996004318A1 (en) | 1994-08-05 | 1996-02-15 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
KR100427159B1 (ko) | 1995-07-06 | 2004-06-16 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 예비중합되고지지된메탈로센촉매계의제조방법 |
US5783512A (en) | 1996-12-18 | 1998-07-21 | The Dow Chemical Company | Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same |
CA2210131C (en) * | 1997-07-09 | 2005-08-02 | Douglas W. Stephan | Supported phosphinimine-cp catalysts |
CA2254841C (en) * | 1998-11-26 | 2007-02-06 | Nova Chemicals Ltd. | Nitrogen substituted phosphinimine ligand |
US6340771B1 (en) * | 1999-12-22 | 2002-01-22 | Nova Chemicals (International) S. A. | “Sweet” MAO |
GB0017547D0 (en) | 2000-07-17 | 2000-09-06 | Bp Chem Int Ltd | Supported polymerisation catalysts |
TWI300782B (en) * | 2002-08-29 | 2008-09-11 | Ineos Europe Ltd | Supported polymerisation catalysts |
JP5086637B2 (ja) * | 2003-07-09 | 2012-11-28 | ランクセス エラストマーズ ビー.ブイ. | エチレン、α−オレフィン、およびビニルノルボルネンのモノマー単位を含むポリマーの製造方法 |
GB0329348D0 (en) * | 2003-12-18 | 2004-01-21 | Bp Chem Int Ltd | Polymerisation process |
GB0425443D0 (en) * | 2004-11-18 | 2004-12-22 | Bp Chem Int Ltd | Supported polymerisation catalysts |
US7323523B2 (en) * | 2004-12-07 | 2008-01-29 | Nova Chemicals (International) S.A. | Adjusting polymer characteristics through process control |
US7531602B2 (en) * | 2005-10-05 | 2009-05-12 | Nova Chemicals (International) S.A. | Polymer blends |
-
2006
- 2006-05-30 GB GBGB0610667.8A patent/GB0610667D0/en not_active Ceased
-
2007
- 2007-05-02 WO PCT/CA2007/000736 patent/WO2007137395A1/en active Application Filing
- 2007-05-02 CN CN2007800201687A patent/CN101460526B/zh not_active Expired - Fee Related
- 2007-05-02 CA CA2587230A patent/CA2587230C/en active Active
- 2007-05-02 EP EP07719661.6A patent/EP2021383A4/en not_active Withdrawn
- 2007-05-07 US US11/800,773 patent/US7863213B2/en active Active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103380154A (zh) * | 2010-11-22 | 2013-10-30 | 阿尔比马尔公司 | 活化剂组合物、其制备及其在催化中的用途 |
Also Published As
Publication number | Publication date |
---|---|
CA2587230C (en) | 2016-02-09 |
US7863213B2 (en) | 2011-01-04 |
EP2021383A4 (en) | 2014-01-01 |
CN101460526B (zh) | 2011-07-27 |
WO2007137395A1 (en) | 2007-12-06 |
GB0610667D0 (en) | 2006-07-05 |
EP2021383A1 (en) | 2009-02-11 |
CA2587230A1 (en) | 2007-11-30 |
US20080045406A1 (en) | 2008-02-21 |
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