CN101460238B - Method and device for the production and/or conditioning of powdered material - Google Patents

Method and device for the production and/or conditioning of powdered material Download PDF

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Publication number
CN101460238B
CN101460238B CN2007800205283A CN200780020528A CN101460238B CN 101460238 B CN101460238 B CN 101460238B CN 2007800205283 A CN2007800205283 A CN 2007800205283A CN 200780020528 A CN200780020528 A CN 200780020528A CN 101460238 B CN101460238 B CN 101460238B
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Prior art keywords
jet chamber
jetted layers
built
flow
dust separator
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CN2007800205283A
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CN101460238A (en
Inventor
K·林普勒
M·雅各布
F·奥林多夫
B·万德
R·伯贝尔
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Glatt Ingenieurtechnik GmbH
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Glatt Ingenieurtechnik GmbH
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2/00Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
    • B01J2/16Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by suspending the powder material in a gas, e.g. in fluidised beds or as a falling curtain
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C19/00Other disintegrating devices or methods
    • B02C19/06Jet mills
    • B02C19/068Jet mills of the fluidised-bed type

Abstract

A method and a device for producing and/or conditioning powdered material. The inventive method is characterized in that the material is treated in several stages in a spouted bed comprising inert particles, wherein the powdered material that is preprocessed in a first spouted bed of a first jet chamber (6) and is separated from the larger material particles in an integrated dust collector is fed to a superimposed second spouted bed of a second jet chamber (8) as a material-gas flow along with the gas flow discharged from the first spouted bed in order to be further reduced in size and be conditioned. After separating the fine particles from the larger material particles in a dust collector that is integrated into the second stage, the fine particles are discharged from the two-stage spouted bed treatment along with the gas flow as a powdered material having very small particle diameters. The separated larger material particles are once again fed to the second spouted bed of the second jet chamber.; The device includes a spouted bed apparatus in which a jet chamber encompassing an integrated dust collector as well as a second superimposed jet chamber encompassing another integrated dust collector are disposed.

Description

Be used to make and/or the method and apparatus of conditioning of powdered material
Technical field
The present invention relates to a kind ofly be used to make and/or the method for conditioning of powdered material and the equipment that sets with it.
Background technology
The known shape material that in a fluidised material layer, makes powder is wherein imported an air-flow, to keep the material layer of fluidisation.What several kinds were used for moving the fluidised material layer below known here can be so as to making the basic mode of graininess or dusty material.
1. spray dryer
In the spray dryer that is for example known by Patent data DD 285724A5, in the high temperature gas flow that contains material, spray the liquid that contains solid.In air-flow, form material granule through drying, they have hollow ball shape or its fragment.The material granule that forms has bigger granularity, has poor emulsifiability more mostly.Spray dryer by prior art is very big with therefore expensive equipment, requires big repacking space and big energy requirement.These spray dryers are not suitable for making very little solid particle.The heat treatment that in spray dryer, can not add to the particle of making.
2. be with the fluid unit of inert bed
The fluid unit of for example being known by Patent data US 6187238 that has inert bed (Inertbetten) has a ventilative fluid bed bottom surface.Gas through from following input forms a fluidised material layer through the fluid bed bottom surface, also has corresponding inert body (Inertkoerper) in its inside.Yet can not make the very thin particle below about 100 μ m with them; Because the pulse that acts on the inert particle (Inertpartikel) only is decided by that inert particle is in the existence layer of fluid bed; That is the only main vertical upper and lower reciprocating motion between eddy current point and output point, therefore do not satisfy by evaporating/requirement of the solid particle that aerosolizable liquid manufacturing is thin.Solid in being included in adding liquid wherein can not carry out other heat treatments in the fluid bed stage the lip-deep drying of inert body.
3. be with the atomizing scrubbing tower of fluid bed
For example by the known atomizing scrubbing tower of Patent data DD 272576A3, they in its lower end with a fluidisation bed operating.Here fluid bed can be used or without inert body work.Here can carry out subsequent heat treatment or mechanical treatment through the corresponding abrasion of the particle that falls from the atomizing scrubbing tower conditionally.Its shortcoming is that the mixing of different air-flows takes place when subsequent heat treatment.When this combination, also limited fine grain manufacturing for above-mentioned reasons.
4. jetted layers device
In the inert bed jetted layers stage; Be applied to pulse on the inert particle significantly greater than with in the fluid bed of identical inert body; Because in inlet zone endoparticle speed significantly greater than the output speed of (for example big 10 times) particle, and since the typical structure of spraying equipment however particle do not exported.By Patent data DD 225630A1, DD 224233A1, DE 10303836B4 become known for the making powder jetted layers device of shape material.Wherein import high velocity air from the below to the jetted layers device for the jetted layers that produces a vertical rotation.The liquid that contains solid for example through single, double or many materials jetting device from the below, top or side spray into the jet chamber like this, makes the wetting as far as possible all the time inert particle of liquid surface, that is do not exist and overflow.The liquid that contains solid, for example mud also can pass through suitable transport, for example screw rod and/or slurry dispenser, for example the wheel of rotation is transported on the inert bed of motion.Employing is positioned at shot-peening steel ball, Ceramic Balls or the Teflon particle of suitable particle size, shape, surface nature and the density of jetted layers as inert particle.Liquid is evaporated through high temperature gas flow, thereby forms on the one hand dry material granule and dry material on inert particle.Material granule is ground through the inert particle by rolling shape beam motion with dry solid, discharges from the jet chamber with the form (for example<50 μ m) of dust.Dust is separated at the different solid separators (cyclone separator, filter) of the identical or different type of the single or plural serial stage that is arranged in the outside as product usually.Series multiple through at jetted layers device dust separator at the back can obtain the power of the more and more littler dust-like product-basis of particle size in inert bed-jetted layers stage.Shortcoming is that desirable little granularity can only be given birth to the volume production that can ignore little.The series connection consumes energy of dust separator is therefore very expensive in addition.
Summary of the invention
The objective of the invention is; Create a kind of be used for having in the jetted layers of inert particle one make and/or the method for conditioning of powdered material and the equipment that sets with it, wherein in a continuous device channels economical with produce quite in large quantities and/or preliminary treatment has the very fine powder of the drying of small particle diameters.
Realize through method and apparatus of the present invention by this purpose of the present invention.
Be used to use equipment according to the invention to comprise to make in the jetted layers of inert bed particle and/or the method for conditioning of powdered material by of the present invention one; Wherein produce granular size to be reached and in a separator, isolate final products through the material granule and the grinding of inert bed particle of in jetted layers, moving each other; It is characterized by: in a two-stage or multistage material processed; In first jetted layers of one first jet chamber, be transferred second jetted layers that is arranged in above it to as material-air-flow in second jet chamber by pretreated and dusty material that separates with thicker material granule and the air-flow that from first jetted layers, flows out in built-in first dust separator; So that further pulverize and preliminary treatment; And in built-in second dust separator, separate the dusty material output from the jetted layers of two-stage is handled of back and air-flow, and thicker material granule is transferred second jetted layers to second jet chamber again as particle with target size with thicker material granule.
The characteristic of the inventive method is, has one that material divided at least two stages handled in the jetted layers of inert particle.Wherein flow to second jetted layers that is positioned at above it as material-air-flow, so that further pulverize and preliminary treatment by preliminary treatment in one first jetted layers and dusty material that in a built-in dust separator, separates and the air-flow that from first jetted layers, flows out with thicker material granule.Fine grained is with after thicker material granule separates in the dust separator that is built in the second stage, fine grained as dusty material with unusual small particle diameters with air-flow output from two-stage or multistage jetted layers are handled.Isolated thicker material granule is flowed to the jetted layers of second jet chamber again.
Preferably; Roughly flow to first air-flow or material-air-flow first jet chamber and flow to second jet chamber to second material-air-flow and to the such deflection of jetted layers device lateral wall direction in the center, make produce one along first jet chamber and second jet chamber flowing of the axial rolling shape that on lateral wall, makes progress.
Preferably, the thicker material granule that in first dust separator, separates is transferred first jetted layers to first jet chamber again.
Preferably, with liquid or contain the liquid of solid, import first jet chamber and/or second jet chamber through a jetting device.
Preferably, first jetted layers of first jet chamber and second jetted layers of second jet chamber indirectly and adjustable ground be heated by means of high frequency electric so that material is heat-treated.
Preferably, the liquid of importing first jet chamber and/or second jet chamber comprises the salt that is dissolved in the liquid.
Preferably, inert bed particle and/or the coating of inert bed particle of second jetted layers that is positioned at first jetted layers and second jet chamber of first jet chamber is made up of the material of the enough high frequency electric heating of a kind of ability.
Preferably, the Powdered drying material of output is transferred to a terminal separator from the two-stage jetted layers is handled, so that isolate the final products with re-set target size.
By the equipment that is used for by means of a jetted layers device manufacturing and/or conditioning of powdered material of the present invention; This jetted layers device comprises a jet chamber; This jet chamber has along the outward-dipping sidewall of flow direction of the air-flow of input from the below; And the upper area of this jet chamber is made disengagement chamber; It is characterized by: second jet chamber that has built-in second dust separator that is positioned at above it is set in first jet chamber that has built-in first dust separator at the back, and they constitute the jetted layers device jointly.
Equipment of the present invention comprises a jetted layers device, in its inside one second jet chamber with another built-in dust separator in the above, first jet chamber and with a built-in dust separator is set.
Preferably, first jet chamber and second jet chamber in lower area, have one roughly be arranged on the center the hole, this hole feeds the passage towards sidewall direction in both sides.
Preferably, being arranged on first jet chamber and first dust separator above second jet chamber and second dust separator is that a kind of zigzag pneumatic separator perhaps is made up of a cross section expansion section.
Preferably, above the hole of first jet chamber and second jet chamber, be provided with one be designed to wedge shape built-in fitting, the lower wall of this built-in fitting constitutes a sidewall of passage respectively.
Preferably, the jetted layers device has a monosymmetric rectangular cross section.
Preferably, an adjustable heater that is used for to material heat treatment is set in constituting hollow built-in fitting.
Preferably, the sidewall of the built-in fitting of wedge shape has profile straight line or aduncate, and wherein each sidewall of built-in fitting and the angle between the bottom surface are between 45 ° to 60 °.
Preferably, in first jet chamber and/or second jet chamber, be provided for liquid or contain the jetting device of the liquid of solid.
Preferably, second dust separator has higher separative efficiency than first dust separator.
Preferably, the jetted layers device connects a separator at the back.
Through heating and/or cooling device being set and/or importing liquid or contain the liquid of solid, heat treatment that material to be made can additionally be stipulated and preliminary treatment are like polymerization, curing or coating.
The advantage of the inventive method and equipment is, in a continuous device channels, makes the consistent meticulous dust-like product with very little particle diameter with mode efficiently.Material when needed to be made in addition can heat treatment mildly (preliminary treatment) in jetted layers, so that realize thus having known performance but powder with novel product form.
Another advantage is only in an equipment, have the very manufacturing of the dusty material of small particle diameters, external heat transfer device, mill or the sieve that therefore no longer need add.Only need efficient blower or its combination of compression common on the market or suction operation, to overcome the initial pressure loss in the jetted layers, so that can be used on the known degree much little that stressor layer loss works in running status.
Description of drawings
Specify the present invention by means of an embodiment below.In attached figure, represent:
The cutaway view of Fig. 1 jetted layers device of the present invention,
The thin portion cutaway view of Fig. 2 jetted layers device,
The cutaway view of Fig. 3 built-in fitting form of implementation in the jetted layers device,
The specific embodiment
Expression one jetted layers device 1 of the present invention in Fig. 1, it especially has a monosymmetric rectangular cross section.But can consider that also jetted layers device 1 is designed with a figure cross section.Jetted layers device 1 comprises that one first jet chamber 6 and a built-in dust separator 7 and are positioned at second jet chamber 8 and a built-in dust separator 9 of its top.In jet chamber 6 and/or jet chamber 8, be provided for liquid or contain the liquid of solid such as the jetting device 10 of suspension, solution, liquation or mud.Connect a unshowned separator that is used for the consistent target size product of final separation in jetted layers device 1 back.
The dust separator 7 or 9 that is arranged on jet chamber 6 or 8 tops for example is a kind of zigzag pneumatic separator (Sichter).Dust separator 7 and 9 also can be made up of a cross section expansion section of jetted layers device 1 outer wall.Dust separator 9 has higher separation rate than dust separator 7, makes the material of only hoping particle size to some extent just be discharged from from jetted layers device 1 through dust separator 9.
Jet chamber 6 and 8 in lower area, have one roughly be arranged on the center hole 2.Hole 2 feeds the passage 16 of sidewall 3 directions on one day in both sides.Here sidewall 3 is outward-dipping with respect to plumb line, makes linear or is equipped with inside bending.Above the hole of jet chamber 6 and 8, be provided with one be designed to wedge shape built-in fitting (Einbauteil) 5.A sidewall of the corresponding formation passage 16 of the lower wall of built-in fitting 5 wherein.Built-in fitting 5 formations that are positioned at jet chamber 6 and 8 are hollow, wherein in constituting hollow built-in fitting 5, an adjustable heater 11 are set, and for example the high-frequency heating element is used for material is heat-treated.Each sidewall of the built-in fitting 5 of wedge shape has a profile linear or aduncate, and each sidewall of built-in fitting 5 and the included angle A between the bottom surface are between about 45 ° to 60 ° here.
Expression built-in fitting 5 corresponding forms of implementation in Fig. 3.
In Fig. 3 a and 3c the outer wall of built-in fitting 5 make straight, wherein in Fig. 3 c outer wall than in Fig. 3 a, pulling out highly.Fig. 3 b representes the outer wall with an aduncate profile.Outer wall crooked in Fig. 3 d pulls out higherly.Outer wall crooked in Fig. 3 e pulls out so not highly, and it imitates the outer wall of inclination.
Roughly give the jet chamber 6 input air-flow or material air-flows 12 according to method of the present invention at the center; Give jet chamber's 8 input materials-air-flow 15; And to the such deflection of jetted layers device 1 lateral wall, 3 directions, thereby obtain one along jet chamber 6 and 8 axial rolling shapes, on lateral wall 3 towards flow 13.Find, the inert bed that rolling shape ground moves upward along the lateral wall 3 that tilts when this injection guiding grind effect than much bigger when the injection guiding from outside to inside.In jet chamber 6 and 8, form a jetted layers 4 through air-flow, it is by material granule, inert body with by forming attached to the material granule wet and that do on the inert body.13 make material granule and inert body upwards get rid of apace and come back to gas input port according to the direction of arrow 14 through flowing of making progress along the madial wall of built-in fitting 5 inclinations along the lateral wall 3 that tilts; And upwards get rid of again, thereby form the rolling form that inert particle flows.Sometimes can demonstrate rapid reciprocating stratum granulosum through rolling.This particle circulation is carried out very fastly and is steady.
Can give the jetted layers 4 input liquid in jet chamber 6 and/or the jet chamber 8 or contain the liquid of solid through jetting device 10, like suspension, solution, liquation or mud.
Above jet chamber 6, carry out material separation, preventing from the jet chamber 6 the too big dust granules of first jetted layers, 4 outputs, and they are imported in first jetted layers 4 again downwards through dust separator 7.The size of dust separator 7 is definite like this, make it not only can let desired dimensions powder particle but also the dust granules with bigger slightly sizes is passed through, but no longer include too big particle.Too big dust granules falls into the jetted layers 4 of jet chamber 6 again, and continues there to pulverize and upwards output again.
Import the jet chamber 8 that be positioned at its top with air-flow as material-air-flow 15 through the material granule of dust separator 7.In jet chamber 8, rebulid a jetted layers 4, but its adapts to the condition changed.Jetted layers 4 is equipped with such inert body, and they have the for example less and/or lighter inert body with rough surface under the similar situation of layer quality.In the rolling shape jetted layers 4 of jet chamber 8, also too big particle continues to be pulverized, and the dust granules that has target size then and passes the dust separator 9 that is arranged on 8 tops, jet chamber together, and it is designed to only also let the particle of target size pass through.Still too big dust granules falls to get back in the jet chamber 8 from dust separator 9, and continues to grind forr a short time.
In jet chamber 6 and 8, mainly infinitely carry out the device interior precise dose and regulate, also be used for material hot treatment sometimes through the common heating generator with 30kHz-300MHz frequency range 11 according to the present invention.Heater 11 is arranged in the built-in fitting 5.Material and inert body on its lateral wall with material closely and little speed to lower slider; Make exist here on the one hand through from built-in fitting 5 by of the heat conduction of the wooden partition surface of eddy-current heating to the inert particle of the wet coating that is not dielectrically heated, but especially by heating generator 11 induction ground directly to the heat conducting particularly advantageous condition of the inert particle of the coating that wets.
If the enough ohm conductive capabilities of wet product-wet dust, the liquid that sprays into or the mud that feeds-on the inert body surface, have; Thereby can in electric field, promote heating through ionic conduction, are particularly advantageous conditions for adopting thermatron 11 so.If for example in the solid of water-wet, comprise the salt of dissolving, just conductive capability is enough high so.Because conductive capability itself depends on water capacity in this solid, wet zone is stronger than dry zone heating, and this caters to the solution of being asked a question very much.That is to say; The soft rising of this heating generator 11 temperature or both acted on reposefully sometimes on the sidewall of built-in fitting 5 of wet coating; Especially act on again on strenuous exercise and the fully mixed jetted layers, if inert body by a kind of be suitable for that material that high frequency conducts heat is formed and with wet more or less, treat the milled solid grain coating.So just, guarantee to coating or not coating inert body and thus to pending product fast, effectively and accurate heat transmit.
In order in low temperature range, to adjust temperature, can replace heating generator from the 2nd grade of 8 jetted layers through constituting hollow built-in fitting 5 direct direct cooled gas or cooling fluids.
In addition, can carry refrigerating gas for second level jetted layers 8 through a gas inlet pipe 17 from same purpose.
The pictorial symbolization table
1 jetted layers device, 10 jetting devices
2 holes, 11 heaters
3 sidewalls, 12 air-flows
4 jetted layers 13 flowing up
5 built-in fittings, 14 directions of arrow
6 jet chambers, 15 materials-air-flow
7 dust separators, 16 passages
8 jet chambers, 17 refrigerating gas input pipes
9 dust separator A angles

Claims (18)

1. be used for equipment by means of a jetted layers device manufacturing and/or conditioning of powdered material; This jetted layers device comprises a jet chamber; This jet chamber has along the outward-dipping sidewall of flow direction of the air-flow of input from the below; And the upper area of this jet chamber is made disengagement chamber; It is characterized by: be provided with in the back, first jet chamber (6) that has built-in first dust separator (7) one be positioned at its top second jet chamber (8) that has built-in second dust separator (9), they constitute jetted layers device (1) jointly.
2. by the described equipment of claim 1, it is characterized by: first jet chamber (6) and second jet chamber (8) in lower area, have one roughly be arranged on the center the hole, this hole in both sides feeding towards the passage (16) of sidewall (3) direction.
3. by the described equipment of claim 1, it is characterized by: first dust separator (7) and second dust separator (9) that are arranged on above first jet chamber (6) and second jet chamber (8) are a kind of zigzag pneumatic separators or are made up of a cross section expansion section.
4. by the described equipment of claim 2, it is characterized by: be provided with in the top in the hole of first jet chamber (6) and second jet chamber (8) one be designed to wedge shape built-in fitting (5), the lower wall of this built-in fitting constitutes a sidewall of passage (16) respectively.
5. by the described equipment of claim 1, it is characterized by: jetted layers device (1) has a monosymmetric rectangular cross section.
6. by the described equipment of claim 4, it is characterized by: an adjustable heater (11) that is used for to material heat treatment is set in constituting hollow built-in fitting (5).
7. by the described equipment of claim 4, it is characterized by: the sidewall of the built-in fitting of wedge shape (5) has profile straight line or aduncate, and wherein each sidewall of built-in fitting (5) and the angle (A) between the bottom surface are between 45 ° to 60 °.
8. by the described equipment of claim 1, it is characterized by: in first jet chamber (6) and/or second jet chamber (8), be provided for liquid or contain the jetting device (10) of the liquid of solid.
9. by the described equipment of claim 1, it is characterized by: second dust separator (9) has higher separative efficiency than first dust separator (7).
10. by the described equipment of claim 1, it is characterized by: jetted layers device (1) back connects a separator.
11. be used for using and comprise one like each described equipment of claim 1 to 10 and to make in the jetted layers of inert bed particle and/or the method for conditioning of powdered material; Wherein produce granular size to be reached and in a separator, isolate final products through the material granule and the grinding of inert bed particle of in jetted layers, moving each other; It is characterized by: in a two-stage or multistage material processed; In first jetted layers of one first jet chamber (6) by pretreated with in built-in first dust separator (7), be transferred second jetted layers that is arranged in its top to as material-air-flow (15) in second jet chamber (8) with thicker material granule dusty material that separates and the air-flow that from first jetted layers, flows out; So that further pulverize and preliminary treatment; And in built-in second dust separator (9), separate the dusty material output from the jetted layers of two-stage is handled of back and air-flow, and thicker material granule is transferred second jetted layers to second jet chamber (8) again as particle with target size with thicker material granule.
12. by the described method of claim 11; It is characterized by: roughly flow to first air-flow or material-air-flow (12) first jet chamber (6) and flow to second jet chamber (8) to second material-air-flow (15) and to the such deflection of jetted layers device (1) lateral wall (3) direction in the center, make produce one axial in mobile (13) that lateral wall (3) is gone up rolling shape upwards along first jet chamber (6) and second jet chamber (8).
13. by the described method of claim 11, it is characterized by: the thicker material granule that in first dust separator (7), separates is transferred first jetted layers to first jet chamber (6) again.
14. by the described method of claim 11, it is characterized by: with liquid or contain the liquid of solid, import first jet chamber (6) and/or second jet chamber (8) through a jetting device (10).
15. by the described method of claim 11, it is characterized by: second jetted layers of first jetted layers of first jet chamber (6) and second jet chamber (8) indirectly and adjustable ground be heated by means of high frequency electric so that material is heat-treated.
16. by the described method of claim 14, it is characterized by: the liquid of importing first jet chamber (6) and/or second jet chamber (8) comprises the salt that is dissolved in the liquid.
17. by the described method of claim 11, it is characterized by: inert bed particle and/or the coating of inert bed particle of second jetted layers that is positioned at first jetted layers and second jet chamber (8) of first jet chamber (6) is made up of the material that the enough high frequency electrics of a kind of ability heat.
18. by the described method of claim 11, it is characterized by: the Powdered drying material of output is transferred to a terminal separator from the two-stage jetted layers is handled, so that isolate the final products with re-set target size.
CN2007800205283A 2006-11-22 2007-09-01 Method and device for the production and/or conditioning of powdered material Expired - Fee Related CN101460238B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102006054930.9 2006-11-22
DE102006054930A DE102006054930A1 (en) 2006-11-22 2006-11-22 Method and device for producing and / or conditioning powdered material
PCT/EP2007/007647 WO2008061579A2 (en) 2006-11-22 2007-09-01 Method and device for the production and/or conditioning of powdered material

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CN101460238B true CN101460238B (en) 2012-04-25

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US (1) US7823810B2 (en)
EP (1) EP2056957B1 (en)
JP (1) JP5086365B2 (en)
CN (1) CN101460238B (en)
AT (1) ATE501784T1 (en)
DE (2) DE102006054930A1 (en)
DK (1) DK2056957T3 (en)
ES (1) ES2362943T3 (en)
PL (1) PL2056957T3 (en)
PT (1) PT2056957E (en)
RU (1) RU2444685C2 (en)
WO (1) WO2008061579A2 (en)

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ES2362943T3 (en) 2011-07-15
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DK2056957T3 (en) 2011-07-04
ATE501784T1 (en) 2011-04-15
US20090134250A1 (en) 2009-05-28
RU2444685C2 (en) 2012-03-10
JP2010510054A (en) 2010-04-02
WO2008061579A2 (en) 2008-05-29
RU2008148012A (en) 2010-07-10
EP2056957B1 (en) 2011-03-16
PL2056957T3 (en) 2011-07-29
DE102006054930A1 (en) 2008-05-29
DE502007006740D1 (en) 2011-04-28
PT2056957E (en) 2011-06-01
US7823810B2 (en) 2010-11-02
CN101460238A (en) 2009-06-17
EP2056957A2 (en) 2009-05-13

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