Summary of the invention:
Technical problem to be solved by this invention is exactly to be to overcome the deficiency that the oilness of present mineral oil allotment exists, and poor characteristics of cleaning situation and a kind of manufacture method that adopts vegetables oil to make multipurpose metal working lubricant is provided.
For solving the problems of the technologies described above, the present invention has adopted following technical scheme: major ingredient and quality proportioning that this lubricant is made are as follows: vegetables oil: 100 parts; Sapn: 1-2 part; Urea: 0.2-0.7 part; Industrial spirit: 5-10 part, emulsifying agent 6-9 part; Above-mentioned raw materials after the heating emulsification reaction, through leaving standstill the cooling layering, is obtained two kinds of lubricants again.
Also be added with oxidation inhibitor, benzotriazole and water in the described lubricant composition, the quality proportioning of described composition is: 0.5 part in 0.1 part in oxidation inhibitor, 0.3 part of benzotriazole and water
Described emulsifying agent comprises: 3 parts of Fatty Alcohol(C12-C14 and C12-C18) alkylolamides, polyoxyethylene nonylphenol ether 3-6 part.
The concrete manufacturing process of the present invention is: (1), that urea, industrial spirit and water are added together stirring and dissolving is complete; (2), vegetables oil is put in the emulsion reaction pot, to add together the reactor heating by the good sapn of proportioning, oxidation inhibitor, emulsifying agent, benzotriazole again, adopt the variable-frequence governor agitator to stir, when treating that temperature rises to 75 ℃, again urea, industrial spirit and water mixture are added, be heated to together 80 ℃, open the homogenizer homogeneous, constant temperature emulsion reaction 1 hour, whole process is reacted under normal pressure; (3), the reaction finish after, material in the reactor is emitted the cooling standing demix, finally be divided into two-layer; (4), the material standing demix is divided into levels, the upper strata can directly be used as a kind of product, and lower floor adds 2-3 deionized water doubly and namely can be used as another kind of product.
Its rotating speed of variable-frequence governor agitator that above-mentioned manufacturing process adopted in (3) step is 0-2900 rev/min.
Described vegetables oil is one or more mixtures of following oil product: Oleum Gossypii semen, plam oil, peanut oil, rapeseed oil, shancangzi oil etc.
Have two kinds by the produced product of foregoing invention, its at the middle and upper levels isolated product can be used as stretching wet goods product and use, lower floor adds 2-3 deionized water doubly and namely can be used as the uses such as water-based drawing oil, water-based cutting fluid, lapping liquid.
The present invention makes simply, and can make simultaneously and process multi-purpose metal working lubricant.The main raw material that the present invention adopts is vegetables oil, carry out the emulsion reaction mode and produce by adding various emulsifying agents, to environment without any pollution.
With respect to the industrial lubricants that present mineral oil is made, the plant oil based lubricant that the present invention makes, its oilness, cooling, cleaning performance are much higher than mineral oil.This mainly is the result that vegetables oil " clever molecule " causes.This quasi-molecule is very long, and is very heavy, has bipolarity, that is: the two ends of molecule are with opposite electric charge.Two " extremely " of molecule have very strong chemical affinity to the metallic surface, and they are adsorbed on the metallic surface tightly as small magnet.The vegetables oil molecule is arranged on the metallic surface vertically, closely, equably, and the result forms thick, solid, the durable composite lubricating film of one deck on its surface.The solid composite lubricating film of this layer improved the ability of vegetables oil absorption pressure.On the contrary, the molecule of mineral oil is not to be with polarity.Their arranged evenly on the metallic surface are irregular, and the lubricant film that therefore produces is relatively weaker.Facts have proved, adopt the vegetables oil technology, to boosting productivity and improving cutter and die life has sizable superiority.In the course of processing, adopt plant oil based cooling fluid can improve smooth finish and the tolerance of dimension of finished surface, improve complete processing level, ability and boost productivity.Therefore, using plant oil based lubricant proxy mineral oil is the certainty of historical development.
Embodiment:
Below be a specific embodiment of the present invention:
Prepare raw material according to following mass fraction proportioning,
Vegetables oil is: 100 parts;
Arlacel-80: 1 part;
Urea: 0.5 part;
Antioxidant BHT: 0.1 part;
Industrial spirit: 8 parts;
Emulsifying agent 6501 (Fatty Alcohol(C12-C14 and C12-C18) alkylolamide): 3 parts;
Emulsifying agent TX-10 (polyoxyethylene nonylphenol ether): 5 parts;
Benzo three charcoal azoles: 0.3 part,
Water: 0.5 minute.
In the above-mentioned raw materials, the molecular formula of Arlacel-80 is: C60H108O8, its chemical name: SPAN85.It can be used as emulsifying agent, solubilizing agent, suspending agent, lubricant etc. as nonionic surface active agent.
Antioxidant BHT is invented by German company, is widely used in industrial use, can prevent the acid number of lubricating oil, oil fuel or the rising of viscosity.
The molecular formula of benzo three charcoal azoles is: C6H5N3, it is mainly as water conditioner, metal antirusting agent and inhibiter.
Above-mentioned raw materials is carried out proportioning by prescription, then carry out emulsion reaction in the heating of emulsification pot, through a reaction in hour, can make required product, through leaving standstill the cooling layering, just can obtain the various metals lubricant again.Its production process and technique are as follows:
(1) prepare material by above-mentioned prescription after, wherein to be added together stirring and dissolving complete for urea, industrial spirit and water.
(2) vegetables oil is added in the emulsion reaction pot, will also add together the reactor heating by the good Arlacel-80 of proportioning, antioxidant BHT, emulsifying agent 6501, benzo three charcoal azoles, emulsifying agent TX-10 again, use
0-2900Rev/min agitator rotating speed from small to large stir, when treating that temperature rises to 75 ℃, again urea, industrial spirit and water mixture are added, be heated to together 80 ℃, open the homogenizer homogeneous, constant temperature emulsion reaction 1 hour, whole process is reacted under normal pressure.
(3) after reaction is finished, material in reactor is emitted the cooling standing demix, finally be divided into two-layer.
(4) the material standing demix is divided into levels, the upper strata can directly be used as stretching wet goods product, and lower floor adds 2-3 deionized water doubly and namely can be used as the uses such as water-based drawing oil, water-based cutting fluid, lapping liquid.
Produce different products with the form of making oil in water emulsion.
Used oil can be all vegetables oil (such as Oleum Gossypii semen, plam oil, peanut oil, rapeseed oil, shancangzi oil etc.).Or one or more vegetable oil mixts.
Manufacturing processed adds industrial spirit (alcohols), and take urea as catalyzer, this alcohols also comprises the alcohols of the simple function group such as methyl alcohol, the method for similar preparing biological diesel oil.
The main raw material that the present invention adopts is vegetables oil, carry out the emulsion reaction mode and produce by adding various emulsifying agents, to environment without any pollution.The base oil of producing is except the oil in water emulsion of the glycerin fatty acid ester formation of upper strata oiliness, and the principal reaction of lower floor is expressed as follows with molecular formula:
(fatty-acid ethyl ester)+H
2O (water)
R wherein
1, R
2, R
3Represent the fatty acid chain of identical or different carbonatoms, it can be saturated and fatty acid chain undersaturated carbonatoms, through emulsion reaction low layer water-soluble be to belong to undersaturated those fatty acid chains, the tensio-active agent that side reaction that it and part are added to and a small amount of generates has formed the water-soluble base oil of bottom.Thereby finished the transformation from the oiliness to the water-based, can satisfy metal-processing industry to the needs of lubricated, cooling, antirust and cleaning etc.
(1) the upper strata oiliness of manufacturing of the present invention and lower floor's water-based have good lubrication and cooling performance.
Plant oil based lubricant is take the product of plant as the basis.Their moiety can satisfy special processing property and require and technical requirements through refining.By the composite lubricating film layer that vegetables oil provides, its intensity is high, and lubricity is good.Therefore, the lubricity of this class cooling fluid is much higher than other mineral oil.In addition, plant oil based product has more effective and more durable lubricity than other alternative cooling fluids.Even the processing of material requirements heavy cutting, the plant oil based cooling fluid of using also need not add EP (anti-high pressure) additive.Adopt the lubricant of vegetables oil technology, its price is higher than substitute products.In order to improve its biological stability, need the more expensive composition of interpolation expense.But, to compare with alternative lubricant, its extra expense that increases can be by boosting productivity and being offset by the method for other various reduction costs.
The high lubricating property of vegetables oil is determined by the basal component of vegetables oil molecule and the chemical structure of itself.Take the cooling fluid of vegetables oil as the basis, its lubricity results from intrinsic " oiliness " of vegetables oil composition, and this specific character is the result who is directly caused by vegetables oil " clever molecule ".This quasi-molecule is very long, and is very heavy, has bipolarity, that is: the two ends of molecule are with opposite electric charge.Two " extremely " of molecule have very strong chemical affinity to the metallic surface, and they are adsorbed on the metallic surface tightly as small magnet.The vegetables oil molecule is arranged on the metallic surface vertically, closely, equably, and the result forms thick, solid, the durable composite lubricating film of one deck on its surface.The solid composite lubricating film of this layer improved the ability of vegetables oil absorption pressure.
On the contrary, the molecule of mineral oil is not to be with polarity.Their arranged evenly on the metallic surface are irregular, and the lubricant film that therefore produces is relatively weaker.The viscosity index of vegetables oil is higher, just more can guarantee the lubricating property that it is stable in operating temperature range.Along with the raising of processing temperature, the reduced viscosity speed ratio mineral oil of vegetables oil is slow.On the contrary, along with the reduction of temperature, the liquid fluidity of vegetables oil is better than mineral oil, is conducive to separate with workpiece with smear metal.And its fusing point is higher, is conducive to improve metal removal rate, reduces the formation of smog, reduces the danger of presence of fire.
The vegetables oil bulk of molecule is very even, and mineral oil bulk of molecule variation range is very large.Therefore, the physical property of mineral oil, for example its in when evaporation and the viscosity when reaching boiling point be greatly affected.The higher of vegetables oil and larger weight make it extremely low because of the loss that diffuse and evaporation causes.Because its molecular wt is higher, its sediment is limited in the less scope.Can be like this Working environment that people build a health and cleaning, airborne smog reduces in a large number, and vegetables oil can not produce any toxic side effect to environment.
Through experiment, adopt the vegetables oil technology, have sizable superiority cutter life to boosting productivity and improving.In the course of processing, adopt plant oil based cooling fluid can improve smooth finish and the tolerance of dimension of finished surface, improve complete processing level, ability and boost productivity.For example, add man-hour automobile gear is carried out drilling, adopt plant oil based cooling fluid after, can make improve 3 times the work-ing life of drill bit.In addition, when producing titanium metal and stainless steel medical treatment implantation piece, adopt the vegetables oil technology after, made output increased 10%, also make simultaneously the cutter expense reduce by 50%.Also have an example more can describe the problem: in the automotive industry Application Areas, adopt plant oil based cooling fluid after, make the screw tap of machined steel workpieces improve 15 times work-ing life.
In the machining Application Areas, alien crop oil base cooling fluid can make the mechanical cutting performance improve comprehensively.As a technology through practical proof, since the sixties in 20th century, vegetables oil is considered to have super always.Take the lubricating fluid of vegetables oil as the basis, demonstrated the lubricating fluid that its processing characteristics is better than mineral oil and synthesizing formula greatly in the major applications field.These superiority-process-cycle shortens, changes trouble-free operation prolongation pitch time between the cutter, the quality raising-major part of workpiece should give the credit to the use of plant oil based metal working lubricant liquid and higher lubricity thereof.Adopt plant oil based cooling fluid in complete processing, productivity can improve 20%~30%, and cutting-tool's used life can improve more than 50%.Therefore, no matter be the oil in water emulsion of upper strata fatty acids glyceryl ester or the fatty acids ethanol ester of bottom, its oilness and cooling all are justifiable.
(2) upper strata of manufacturing of the present invention and bottom lubricant all have good cleaning.
The present invention crosses the emulsification of heating by the adding tensio-active agent to the vegetables oil back warp to form oil in water emulsion, thereby its surface tension descends, and the nonionogenic tenside itself that adds has hydrophilic and lipophilic group, such as 6501 (the Fatty Alcohol(C12-C14 and C12-C18) alkylolamides) that add, cleaning performance own is just good, degreasing power is strong, and is the major ingredient of preparation industrial cleaning agent.Thereby this lubricant has fabulous cleaning performance.
(3) except above-mentioned functions, also has preferably antirust function.The additive urea, 6501 (Fatty Alcohol(C12-C14 and C12-C18) alkylolamide) that joins in the vegetables oil itself is exactly good rust-preventive agent, and ferrous metal is had stronger antirust function.
(4) aftertreatment is easy, and is non-stimulated to human body skin.The protection human body, environmental safety.
According to the above-mentioned upper strata oily lubricant of producing, as metal processing drawing oil usefulness, its physicals leading indicator is as follows:
Test name |
Standard |
The result |
Outward appearance |
Brown color |
Brown color |
40 ℃ of kinematic viscosity@, mm
2/s
|
68 |
68 |
Flash-point (opening), ℃ Flash Point |
>236 |
270 |
Pour point, ℃ |
0 |
5 |
Corrosion test (steel disc, 100 ℃, 3h), |
Qualified |
Qualified |
The water-based lubricant of bottom after 20 times of dilutions, meets the GB3392/T standard-required, and its leading indicator is as follows:
According to as can be known above-mentioned, the method that this multipurpose metal working lubricant is made is very effective, at metal-processing industry superior performance is arranged.
The upper strata major advantage:
(a) good lubricant effect, suitable oil film strength prolongs die life greatly.
(b) anti-extreme pressure can be superior, prevents effectively that workpiece is not scratched, scratch, garland, draws quick-friedly, improves product processing quality.
(c) suitable viscosity has cold moving property and oilness optimal balance point, be applicable to the various material such as silieonized plate, steel plate galvanized, cold-reduced sheet, aluminium alloy punching press, stretch, roll and the processing such as prolong
(d) rustless property is outstanding, can exempt antirust processing.
(e) aftertreatment is easy, does not need degreasing, alkali cleaning, pickling, only needs clear water (or hot water) flushing to get final product, and can save process cost more than 30%.
The bottom major advantage:
(a) effectively maintain equipment (b) production efficiency improves 20%-30%
(c) the most rational processing characteristics and economic performance (d) improve more than 50% cutter life
(e) oilness stronger than mineral oil (f) starting material are vegetables oil, high-environmental
(g) minimum oil smoke and mist of oil, minimum volatility (h) has better skin adaptability
(i) has very high flash-point on the corresponding viscosity
In a word, in sum, the method for this multipurpose metal working lubricant manufacturing is truly feasible, has both protected environment, has reduced environmental pollution, has utilized again energy regeneration, has saved the energy, has advantages of that other lubricant for hardware production can not replace.
Certainly, the above only is specific examples of the present invention, be not to limit the scope of the present invention, all equivalences of doing according to the described structure of the present patent application claim, feature and principle change or modify, and all should be included in the present patent application claim.