CN101410482A - Modification device for coke oven gas - Google Patents
Modification device for coke oven gas Download PDFInfo
- Publication number
- CN101410482A CN101410482A CN200780000894.2A CN200780000894A CN101410482A CN 101410482 A CN101410482 A CN 101410482A CN 200780000894 A CN200780000894 A CN 200780000894A CN 101410482 A CN101410482 A CN 101410482A
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- Prior art keywords
- coke
- oven gas
- mixing zone
- gas
- coke oven
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
- C10J3/60—Processes
- C10J3/64—Processes with decomposition of the distillation products
- C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B27/00—Arrangements for withdrawal of the distillation gases
- C10B27/06—Conduit details, e.g. valves
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1643—Conversion of synthesis gas to energy
- C10J2300/165—Conversion of synthesis gas to energy integrated with a gas turbine or gas motor
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Combustion & Propulsion (AREA)
- Industrial Gases (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Coke Industry (AREA)
Abstract
A reformer furnace that is capable of recovering the sensible heat of 700 DEG to 800 DEG C coke oven gas, and that is capable of gasifying any tar fraction and tar sludge of the coke oven gas to thereby attain efficient production of a gas fuel with low unreacted tar content. There is provided a reformer of coke oven gas from coke oven comprising a mixing zone and, connected to the downstream side thereof, a diffusion zone, wherein a coke oven gas and a reaction gas are introduced in the mixing zone, and wherein structuring is made so that the cross-section area of flow channel in diffusion zone entrance space at which the mixing zone shifts to the diffusion zone is smaller than the cross-section area of the mixing zone, and wherein the reformer internal wall at diffusion zone entrance space connected to the exit of the mixing zone exhibits a divergent angle of 5 to 10 degrees from the central axis of the diffusion zone in the direction of flow of gas mixture.
Description
Technical field
The present invention relates to the modification device of coke-oven gas.In more detail, the present invention relates to make sensible heat from high temperature coke oven coal gas that so far can not recovery of heat to reclaim to become possible the time, can make the tarry cut that contains environmental pollutants in a large number convert gas to, make the shape of the reactor that the unreacted tar content almost do not have.
Background technology
In the past, from 700～800 ℃ the coke-oven gas that coke oven comes out, spreading ammoniacal liquor was cooled to 80～100 ℃, did not therefore have the utilization of sensible heat fully.As the method for utilizing this sensible heat, open modification and the sensible heat recovery method that discloses coke-oven gas in the 2001-220584 communique the spy.In this communique, putting down in writing, make and reclaim the sensible heat that 700～800 ℃ coke-oven gas not being utilized so far because of the fault that the aggegation coking of the tarry cut that contains in the coke-oven gas causes and giving up has and become possibility, and make tarry cut or tar sludge in the coke-oven gas convert gas or charcoal to, be used to make the treatment process of the geseous fuel of cleaning.But, about the shape not record especially of modification device.
Above-mentioned spy opens the experimental result of the invention of 2001-220584 communique, be documented in as auxiliary cause, in " system iron process gas utilizes the exploitation of hydrogen manufacturing technology " achievement Report of putting down into for 16 years that corporate representative, Metal series Materials Research Development center entrusts from METI iron steel section system iron planning chamber.From the unreacted tar content that 46～47 pages the data computation of this report goes out, be 2～8% by the carbon back standard.This numerical value is that the coke-oven gas treatment capacity is 1Nm
3Value in small test device during/h, along with device maximizes, the unreacted tar content has the tendency of increase.
The flow of the coke-oven gas in the actual coke oven is compared with the standard apparatus in above-mentioned report, and per 1 is 500～600 times, and the amount of unreacted tar has the possibility that becomes more than 10% by the total carbon conversion.If it is many that unreacted tar becomes, in recovery of heat or generation gas cleaning, just become obstacle.
Summary of the invention
The invention provides a kind of modification device, this modification device is recyclable because the aggegation coking fault of the tarry cut that contains in the coke-oven gas, the sensible heat that 700～800 ℃ the coke-oven gas that is not utilized as yet and gives up has, and can make the tarry cut that makes in the coke-oven gas or tar sludge and convert the fuel that gas or charcoal, unreacted tarry cut are almost 0 cleaning to.In 35 pages of above-mentioned achievement Report book, think, because spreading area (being called Dilvar zone in this report book) is cylindrical, so the turbulent flow that (is called the dry gas top in report) in the mixing zone and generates is not eliminated in the spreading area, the tarry cut that is involved in the central part of eddy current becomes the major cause that unreacted tar generates.Therefore by reactions such as thermolysis, water vapour modification or aerifications, efficient is eliminated this unreacted tarry cut or tar sludge well or made it innoxious is important.
The inventor finds, modification device is divided into coke-oven gas and reactant gases mixed and spreading area that mixing zone that reaction is carried out to a certain degree and this gaseous mixture react and make thermolysis or aerify and carry out fully substantially, adopt the structure shrink the flow path cross sectional area between the inlet region, spreading area that moves to the spreading area from the mixing zone for the time being, make the shape orientation flow direction between this inlet region, by with specific angular spread, above-mentioned eddy current is disappeared, thereby invented this modification device.
Promptly, (1) the present invention is above-mentioned modification device for coke oven gas, the coke-oven gas modification that it will come out from coke oven, it is characterized in that, this modification device has the mixing zone and is connected the spreading area in the downstream of this mixing zone, the flow path cross sectional area structure narrower and small between the inlet region, spreading area that formation is moved to the spreading area from the mixing zone than the sectional area of mixing zone, import coke-oven gas in the mixing zone and will react with the reactant gases of this gas reaction, the gaseous mixture that produces is then sent into the spreading area, reaction is further carried out in the spreading area, and the device inwall between the inlet region of the spreading area that is connected with this mixing zone outlet constitutes 5～10 diffusion angles of spending at the flow direction of gaseous mixture and the central shaft of spreading area.
Optimal way of the present invention is as follows.
(2) modification device for coke oven gas of record in (1), wherein, reactant gases is carbon monoxide and oxygen or air, and the temperature of mixing zone becomes more than 900 ℃ and the reaction that takes place to aerify, and coal-tar middle oil cut is thermal decomposited substantially fully in the spreading area.
(3) modification device for coke oven gas of record in (1), wherein, reactant gases is oxygen or air and the water vapour more than 200 ℃, the part of coke-oven gas is burnt in the mixing zone, the temperature of mixing zone becomes more than 950 ℃, and the coke-oven gas that contains tar and tar sludge in the spreading area is aerified substantially fully.
(4) modification device for coke oven gas of record in above-mentioned (1), wherein, reactant gases is an oxygen, hydrogen and the steam more than 200 ℃, near the inlet of mixing zone, be equipped with the nozzle that is used to be blown into reactant gases, point generation oxyhydrogen flame at nozzle, the burning more than 2000 ℃ that produces generates steam and the above-mentioned mixed vapor temperature that makes of steam more than 200 ℃ reaches more than 1500 ℃, the temperature of the mixture of this steam and coke-oven gas becomes more than 950 ℃ and constitutes, aerify reaction or the reaction of water vapour modified gas take place in the spreading area, carry out aerification almost completely.At this moment, the speed that is blown into from the reactant gasess such as oxygen of nozzle for flame will often be in the position of leaving nozzle tip, preferably is defined as more than the 8m/s.This is the fusing for the nozzle tip that prevents to cause by flame with from the thermal radiation of flame.
(5) modification device for coke oven gas of in each of above-mentioned (1) to (3), putting down in writing, wherein, reactant gases is blown into the mixing zone by near the nozzle the inlet that is provided in the mixing zone, when coke oven drops into coal, in pyrogenic reaction mid-term, the coke-oven gas amount that generates in each stage when reaction finishes, if the amount of per second that will react mid-term is as 1, quantitative change when coal is dropped into becomes 2.5～3.5, the quantitative change of initial reaction stage when finishing becomes at 1.5～2.5 o'clock, cooperate the variation of coke-oven gas amount, just can make the reaction gas flow that is blown into from nozzle be altered to 1 to 3.5 times, perhaps can change the number of the nozzle of work.
(6) modification device for coke oven gas of in each of above-mentioned (1) to (5), putting down in writing, wherein, see the angles performance jeting effects that the vertical line of gas flow direction formed 30 degree～60 degree by nozzle in the gas flow direction, the reactant gases that prevents to contain the oxygen that is blown into from nozzle or air from the mixing zone adverse current to the coke oven side.
(7) modification device for coke oven gas of in each of above-mentioned (1) to (6), putting down in writing, wherein, modification device for coke oven gas has 0.5～2.5 times capacity of the maximum generating capacity of per 1 second coke-oven gas, and the volume of spreading area is equal to, or greater than the volume of mixing zone.
Description of drawings
Fig. 1 is the sketch map of outward appearance of the cold mould of expression modification device.
Fig. 2 is from representing the cold mould gas inside videograph that flows, with the identification of the gas flow rate color in the spreading area and video picture makes color identification convert the figure of black to.
Fig. 3 is the graphic representation of relation of difference of the gas flow rate of the diffusion angle of spreading area of modification device and wall and central part.
Fig. 4 represents the gas flow in the analog result that the stove about the practicability scale carries out.
Fig. 5 is the concept map of the stove of practicability scale.
Fig. 6 is the modification stove of just representing among Fig. 5, the analog result that the variation of expression nozzle number influences the gas flow of spreading area.
Fig. 7 is the concept map of expression nozzle angle.
Nomenclature:
1 inlet from coke-oven gas
2 mixing zones
3 nozzles
4 spreading areas
The outlet of 5 modified gas
Embodiment
In this manual, so-called " being thermal decomposited substantially fully " or " being aerified substantially fully " mean, preferably 90 weight % of object above, more preferably 95 weight % above, be thermal decomposited more than the preferred especially 98 weight % or aerified.
The coke-oven gas that comes out from coke oven keeps 700～800 ℃ temperature usually, is blown into above-mentioned oxygen or air in the mixing zone in coke-oven gas and mixes, and the reaction that aerifies is taking place more than 950 ℃.Perhaps in mixing above-mentioned more than 1000 ℃ or spreading area that the mixing of combustion gases district is later, utilize high-temperature steam that burning generates or the high-temperature steam that is blown into, the hydro carbons that efficient will be referred to methane and even tar well carries out the water vapour modification.Importantly, from the generating unit divided combustion or carry out the blended mixing zone of the high-temperature vapor more than 1000 ℃, the outlet to the spreading area that diffusion reaction takes place keeps 5～10 degree, is more preferably 6.5～8.5 degree, the expansions of about especially 7.5 degree.
In order to confirm the present invention, make the cold mould of transparent polyvinyl chloride system of about 1/125th sizes of practical scale size.Its shape shown in Figure 1.The leftmost mould of figure forms the shape that is installed in the entrance and exit on the cylinder.In 5 moulds, heaving of below is the mixing zone on the right, and heaving of top is the spreading area.Sectional area two interregional gas flow direction is dwindling, so gaseous mixture just enters the spreading area and further accept mixing from the mixing zone, and each gas is mixed mutually in the spreading area.The diffusion angle of spreading area is followed successively by 0 degree, 2.5 degree, 5 degree, 7.5 degree, 10 degree, 12.5 degree from the mould of Fig. 1 from a left side.Visual for the diffusion-condition that makes gas, replace coke-oven gas to use cryogenic carbon dioxide, replace being blown into oxygen and steam and use the air that contains steam fog.In order to carry out the flowing qualitatively of gas in the modification device. blended is visual, utilize the light of the wavelength 488nm (blue-greenish colour) that cylinder-prism will take place from continuous oscillation Argon ion laser (Spectra-Physics:Model 177G0-2) in visibleization zone to become the slit light of the about 2～3mm of thickness, it is used as light source.High-speed camera (Photron:FASTCAM-Net 500) is used in photography, carries out in 1/500 second with the shutter speed of 500 card/seconds of picture rate.Under this condition, the pixel count of record becomes 512 * 240, and the serial photograph between about 2.1 seconds is possible.Use this device that the flow condition of cold mould inside is carried out video photography, by the picture processing of utilizing PIV (Particle ImageVelocimetry, particle image velocimeter), the instantaneous distribution of the velocity vector that inside stream is interior is quantification clearly.Then the flow velocity in the spreading area is carried out color and discern video picture.Fig. 2 converts color identification to white black, as candy strip can recognition speed difference.In expression separately, left end is corresponding to the central shaft of the container of mould, and right-hand member is corresponding to wall of a container.
The angle of loosing as can be known is 0 when spending, and the turbulent flow that takes place in the mixing zone does not disappear, and until the spreading area outlet, the flow velocity of wall just has some slow, and the position and the central part that leave wall are essentially identical flowing.That is to say that turbulent flow does not disappear.If the diffusion angle of spreading area 2.5 degree, 5 degree, 7.5 degree, 10 degree, 12.5 degree, candy strip just occurs.In Fig. 2, obtained the height (absolute value) (with reference to the right side of Fig. 3) of the cat head direction of container center portion between the banded regions of identical flow velocity (same concentrations) and wall portion.
The curve representation of Fig. 3 is usually an above-mentioned height in two situations of amount and its 2 times of amounts in the coke-oven gas amount.In 7.5 degree, highly minimum, along with angle becomes big than 7.5 degree or diminishes, highly change greatly.The difference that is central part flow velocity and wall flow velocity increases, and produces eddy current.If make the gas flow multiplication, it is more remarkable that this tendency just becomes.Therefore, do not lack in order to have eddy current, turbulent flow in the spreading area, the diffusion angle is 5～10 degree preferably, near 7.5 degree, for example are 7～9 degree more preferably.
Then, carried out being thought of as the device simulation of practical scale (device that in cold mould experiment, uses 125 times).At the concept map of the left side of Fig. 5 indication device, and be illustrated in the principal dimension of the device that uses in the simulation on the right of Fig. 5.Numeral 1 expression among the figure is from the outlet of the coke-oven gas of coke oven, and 2 represent mixing zones, and 3 expressions are used to be blown into the nozzle of reactant gases, 4 expression spreading areas, 5 expression modified gas outlets.In Fig. 5, the spread angle metric is decided to be 7.5 degree.Use is shown among Fig. 4 with the example of the analog result of the factors such as coefficient of frictional resistance of the mobile relevant wall that obtains in the parsing of cold mould experiment.White deceive deep or light corresponding to the speed of below figure, representing.But, below nozzle tip and above outlet, fastest, in the expression of the look moon, be red, Ruo Baihei represents just incorrect, therefore should locate to omit as blank in Fig. 4.Identical with cold mould experimental result, the elimination of the turbulent flow in the spreading area of the diffusion angles that keep 7.5 degree is the most effective, then obtain with 5～10 degree are effective results.
Then, about setting the modification device (Fig. 5) of the spreading area that keeps 7.5 diffusions of spending, when being used to be blown into the number of nozzle of oxygenant such as oxygen or air and steam or high-temperature steam more than 1000 ℃ or combustion gases in variation, implement the simulation how the diffusive mixing state changes.Therefore make from the flow of each nozzle mutually the samely, change being blown into gas flow according to the nozzle number.
Ecbatic in Fig. 6.Line with " variation of same central position flow velocity " in the presentation graphs represents that the speed of central shaft is in the central position of specific value.Similarly, represent that with the line of expression " variation of same wall flow velocity " speed of wall is in the wall position of specific value.Can confirm along with the nozzle number becomes many, it is big that " poor " of stipulating in Fig. 3 becomes bit by bit, even but it is many to be blown into the gas stream quantitative change, the big disorder of gas stream does not take place yet, the effect that the disorder that modification device shown in Figure 5 takes place in the mixing zone disappears is big and irrelevant with the nozzle number.
Fig. 7 is the concept map of the angle of expression nozzle.For easy understanding, two nozzles of relative position are shown.The 1st, be in the inlet of coke-oven gas of the below of mixing zone, at the angle configurations nozzle 3 of this inlet with α.Is 30 degree～60 degree in the read fortune of gas flow direction for the angle [alpha] of the vertical line of gas flow direction, particularly preferably is 40～50 degree.Bring into play jeting effect whereby, can prevent to come self-contained oxygen or air nozzle be blown into gas from the mixing zone adverse current to the coke oven side.
Below explanation is according to 3 kinds of modes of the modification processing method of coke-oven gas of the present invention.
1. 2 be blown into carbon monoxide and oxygen or air in the mixing zone from nozzle 3, the pyritous combustion gases are taken place, with the temperature of coke-oven gas be more than 900 ℃, preferred make more than 950 ℃ approaching about 30% the tarry cut that contains in the coke-oven gas in the spreading area 4 almost by complete pyrolysated method.In more detail, from the coke-oven gas importing mixing zone 2 of coke oven 1 with 700～800 ℃.The pyritous combustion gases of carbon monoxide and oxygen or air take place to be blown into from several nozzles 3 at this, with the temperature of coke-oven gas be more than 900 ℃, the preferred tarry cut thermolysis that makes more than 950 ℃ near about 30%.At this moment, also can make and only be blown into oxygen or air, make the part burning of coke-oven gas, gas temperature is reached more than 900 ℃ from nozzle 3.Because promoting thermolysis more than 900 ℃,, finishes in coke-oven gas pyrolysis so being admitted to spreading area 4, the ratio of unreacted tar part can be suppressed at below 5% of total carbon.
2. be blown into oxygen or air and the steam of temperature more than 200 ℃ in mixing zone 2 from nozzle 3, mix fully, make the part burning of coke-oven gas, with temperature in the stove be more than 950 ℃, the preferred method that the coke-oven gas that contains tar or tar sludge is almost completely aerified in spreading area 4.In more detail, from the coke-oven gas importing mixing zone 2 of coke oven 1 with 700～800 ℃.At this, being blown into oxygen or air and steam from several nozzles 3 mixes fully, make the part burning of coke-oven gas, with temperature in the stove be more than 950 ℃, the preferred coke-oven gas ideal gasization that contains tar or tar sludge that makes more than 1000 ℃, the ratio of unreacted tar part can be suppressed at below 5% of total carbon.
3. 2 be blown into oxygen and hydrogen and steam in the mixing zone from nozzle 3, oxyhydrogen flame is produced, the vapor temperature that generates is defined as more than 1500 ℃, be blown into mixing zone 2, the temperature of mixing zone 2 is reached more than 950 ℃, preferably reach more than 1000 ℃, 4 make aerify reaction or water vapour modified gas reaction end in the spreading area, make it the method for aerification almost completely.In more detail, from the coke-oven gas importing mixing zone 2 of coke oven 1 with 700～800 ℃.At this, from several nozzles 3 be blown into oxygen or and hydrogen and steam, make combustion of hydrogen, be that steam more than 1500 ℃ is blown into mixing zone 2 as vapor temperature.For more than 950 ℃, preferably in reaction or the water vapour modification of promote aerifying more than 1000 ℃, coke-oven gas 2 is sent into spreading area 4 from the mixing zone, finishes reaction, the ratio of unreacted tar part can be suppressed at below 5% of total carbon.
The invention effect
According to the present invention, coke-stove gas is accepted the conversion process of thermal decomposition or aerification, steam modified gas, has not almost had to cause the tarry distillate of environmental pollution, therefore obtains clean fuel gas, the every 1Nm of this fuel gas3Has the calorie more than 3350 kilocalories. This fuel gas is rich in hydrogen, and if steam The modified-reaction combination just becomes the good hydrogen supply source of efficient. All goods in 3 kinds of above-mentioned modes In, because the unreacted tar content is pressed carbon and converted, lack to below 5%, so gas cleaning is easy, Can be as the clean air of cheapness. Even therefore goods gas also is possible as the gas turbine fuel utilization .
Claims (7)
1. modification device for coke oven gas, modification device for the coke-oven gas modification that will come out from coke oven, it is characterized in that, modification device has the mixing zone and is connected the spreading area in the downstream of this mixing zone, flow path cross sectional area between the inlet region, spreading area that formation is moved to the spreading area from the mixing zone is than the narrow and small structure of the sectional area of mixing zone, import coke-oven gas in the mixing zone and will react with the reactant gases of this gas reaction, the gaseous mixture that generates is then sent into the spreading area, further react in the spreading area, and the device inwall between the inlet region of the spreading area that is connected with this mixing zone outlet, form 5～10 diffusion angles of spending at the flow direction of gaseous mixture and the central shaft of spreading area.
2. modification device for coke oven gas according to claim 1, wherein, reactant gases is carbon monoxide and oxygen or air, and the temperature of mixing zone becomes generation aerification reaction more than 900 ℃, and tarry cut is thermal decomposited substantially fully in the spreading area.
3. modification device for coke oven gas according to claim 1, wherein, reactant gases is oxygen or air and the water vapour more than 200 ℃, make the part burning of coke-oven gas in the mixing zone, the temperature of mixing zone becomes more than 950 ℃, and the coke-oven gas that contains tar and tar sludge in the spreading area is aerified substantially fully.
4. modification device for coke oven gas according to claim 1, wherein, reactant gases is an oxygen, hydrogen and the water vapour more than 200 ℃, near the inlet of mixing zone, possesses the nozzle that is used to be blown into reactant gases, point generation oxyhydrogen flame at nozzle, the burning more than 2000 ℃ that produces generates steam and above-mentioned vapor mixing more than 200 ℃, vapor temperature is reached more than 1500 ℃, the temperature of the mixture of this steam and coke-oven gas becomes more than 950 ℃ and constitutes, aerify reaction or the reaction of water vapour modified gas take place in the spreading area, aerify substantially completely.
5. according to claim 1, the described modification device for coke oven gas of arbitrary claim in 2 and 3, wherein, reactant gases is blown into the mixing zone by the nozzle that is equipped with near the inlet of mixing zone, when coke oven drops into coal, in pyrogenic reaction mid-term, the coke-oven gas amount that generates in each stage when reaction finishes, if with the amount of per second in reaction mid-term as 1, quantitative change when coal is dropped into becomes 2.5～3.5, the quantitative change of initial reaction stage when finishing becomes at 1.5～2.5 o'clock, cooperate the variation of this coke-oven gas amount, just can make the reaction gas flow that is blown into from nozzle be altered to 1 to 3.5 times, perhaps can change the number of the nozzle of work.
6. according to the described modification device for coke oven gas of arbitrary claim in the claim 1～5, wherein, see the angles performance jeting effects that the vertical line of gas flow direction formed 30 degree～60 degree by nozzle in the gas flow direction, the reactant gases that prevents to contain the oxygen that is blown into from nozzle or air from the mixing zone adverse current to the coke oven side.
7. according to the described modification device for coke oven gas of arbitrary claim in the claim 1～6, wherein, modification device for coke oven gas has 0.5～2.5 times capacity of the maximum generating capacity of per 1 second coke-oven gas, and the volume of spreading area is equal to, or greater than the volume of mixing zone.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2007/058461 WO2008129676A1 (en) | 2007-04-18 | 2007-04-18 | Reformer for coke oven gas |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101410482A true CN101410482A (en) | 2009-04-15 |
Family
ID=39875223
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200780000894.2A Pending CN101410482A (en) | 2007-04-18 | 2007-04-18 | Modification device for coke oven gas |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP5001355B2 (en) |
| CN (1) | CN101410482A (en) |
| WO (1) | WO2008129676A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103958649A (en) * | 2011-04-06 | 2014-07-30 | 伊内奥斯生物股份公司 | Apparatus and methods for tar removal from syngas |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011057869A (en) * | 2009-09-10 | 2011-03-24 | Babcock Hitachi Kk | Reforming furnace |
| JP5901734B2 (en) * | 2014-12-09 | 2016-04-13 | 三菱日立パワーシステムズ株式会社 | Reforming furnace |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5349001A (en) * | 1976-10-15 | 1978-05-04 | Nippon Steel Corp | Modification of thermal decomposition gases rich in tars and dusts |
| DE2733785A1 (en) * | 1977-07-27 | 1979-02-08 | Didier Eng | PROCESS FOR PROCESSING COOKING GAS |
| US4168956A (en) * | 1977-08-18 | 1979-09-25 | Combustion Engineering, Inc. | Method of operating a coal gasifier |
| JPS57117591A (en) * | 1981-01-12 | 1982-07-22 | Sumitomo Metal Ind Ltd | Heat recovery from coke oven by-product gas |
| JPH0631347B2 (en) * | 1985-03-26 | 1994-04-27 | 三菱重工業株式会社 | Coal gasifier |
| DE19951191C2 (en) * | 1999-10-22 | 2001-08-23 | Thyssen Krupp Encoke Gmbh | Method and device for discharging hot raw gases which are formed when coking in the furnace chambers of a coke oven battery |
| JP2001220584A (en) * | 2000-02-10 | 2001-08-14 | Yukuo Katayama | Modification of coke oven gas and process for recovering sensible heat |
| JP2003082355A (en) * | 2001-09-14 | 2003-03-19 | Sumitomo Metal Ind Ltd | Coke oven and its operation method |
| JP3748431B2 (en) * | 2002-12-04 | 2006-02-22 | 日本碍子株式会社 | Gas reforming furnace and its deposit removal method |
-
2007
- 2007-04-18 CN CN200780000894.2A patent/CN101410482A/en active Pending
- 2007-04-18 WO PCT/JP2007/058461 patent/WO2008129676A1/en active Application Filing
- 2007-04-18 JP JP2009510709A patent/JP5001355B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103958649A (en) * | 2011-04-06 | 2014-07-30 | 伊内奥斯生物股份公司 | Apparatus and methods for tar removal from syngas |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5001355B2 (en) | 2012-08-15 |
| WO2008129676A1 (en) | 2008-10-30 |
| JPWO2008129676A1 (en) | 2010-07-22 |
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Application publication date: 20090415 |