CN101403051B - 从锗蒸馏废酸中回收铟的方法 - Google Patents
从锗蒸馏废酸中回收铟的方法 Download PDFInfo
- Publication number
- CN101403051B CN101403051B CN200810022968A CN200810022968A CN101403051B CN 101403051 B CN101403051 B CN 101403051B CN 200810022968 A CN200810022968 A CN 200810022968A CN 200810022968 A CN200810022968 A CN 200810022968A CN 101403051 B CN101403051 B CN 101403051B
- Authority
- CN
- China
- Prior art keywords
- indium
- acid
- distillation waste
- washing
- sulfuric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052738 indium Inorganic materials 0.000 title claims abstract description 104
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 title claims abstract description 104
- 239000002253 acid Substances 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims abstract description 35
- 229910052732 germanium Inorganic materials 0.000 title claims abstract description 22
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 238000004821 distillation Methods 0.000 title claims description 27
- 239000002699 waste material Substances 0.000 title claims description 27
- 238000004064 recycling Methods 0.000 title description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 64
- 238000000605 extraction Methods 0.000 claims abstract description 44
- 238000005406 washing Methods 0.000 claims abstract description 27
- 238000002386 leaching Methods 0.000 claims abstract description 20
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 38
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 239000007788 liquid Substances 0.000 claims description 27
- 239000012141 concentrate Substances 0.000 claims description 23
- 150000002978 peroxides Chemical class 0.000 claims description 16
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 16
- 239000002002 slurry Substances 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 10
- 239000003513 alkali Substances 0.000 claims description 8
- 239000004317 sodium nitrate Substances 0.000 claims description 8
- 229940001516 sodium nitrate Drugs 0.000 claims description 8
- 235000010344 sodium nitrate Nutrition 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 239000006228 supernatant Substances 0.000 claims description 7
- 239000004568 cement Substances 0.000 claims description 6
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 5
- 238000010521 absorption reaction Methods 0.000 claims description 5
- 238000001704 evaporation Methods 0.000 claims description 5
- 230000008020 evaporation Effects 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 2
- 239000002585 base Substances 0.000 claims description 2
- 230000002045 lasting effect Effects 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 230000003113 alkalizing effect Effects 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 abstract description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 12
- 238000011084 recovery Methods 0.000 abstract description 10
- 238000005266 casting Methods 0.000 abstract description 5
- 230000004927 fusion Effects 0.000 abstract description 2
- 238000005272 metallurgy Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000002893 slag Substances 0.000 description 12
- 239000004411 aluminium Substances 0.000 description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 10
- 229910052718 tin Inorganic materials 0.000 description 10
- 239000011135 tin Substances 0.000 description 10
- 239000012535 impurity Substances 0.000 description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 8
- 229910052787 antimony Inorganic materials 0.000 description 8
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 8
- 239000010703 silicon Substances 0.000 description 8
- 229910052710 silicon Inorganic materials 0.000 description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 239000011133 lead Substances 0.000 description 7
- 239000012074 organic phase Substances 0.000 description 7
- 229910052725 zinc Inorganic materials 0.000 description 7
- 239000011701 zinc Substances 0.000 description 7
- 238000006073 displacement reaction Methods 0.000 description 6
- 239000003350 kerosene Substances 0.000 description 6
- 238000012797 qualification Methods 0.000 description 6
- 229910052785 arsenic Inorganic materials 0.000 description 5
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 5
- 229910052797 bismuth Inorganic materials 0.000 description 5
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 4
- 239000000284 extract Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000002912 waste gas Substances 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910003437 indium oxide Inorganic materials 0.000 description 2
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003500 flue dust Substances 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- PSCMQHVBLHHWTO-UHFFFAOYSA-K indium(iii) chloride Chemical compound Cl[In](Cl)Cl PSCMQHVBLHHWTO-UHFFFAOYSA-K 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- -1 lead Chemical compound 0.000 description 1
- ZBJWWKFMHOAPNS-UHFFFAOYSA-N loretin Chemical compound C1=CN=C2C(O)=C(I)C=C(S(O)(=O)=O)C2=C1 ZBJWWKFMHOAPNS-UHFFFAOYSA-N 0.000 description 1
- 229950010248 loretin Drugs 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 235000021110 pickles Nutrition 0.000 description 1
- 238000011027 product recovery Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200810022968A CN101403051B (zh) | 2008-07-04 | 2008-07-04 | 从锗蒸馏废酸中回收铟的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200810022968A CN101403051B (zh) | 2008-07-04 | 2008-07-04 | 从锗蒸馏废酸中回收铟的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101403051A CN101403051A (zh) | 2009-04-08 |
CN101403051B true CN101403051B (zh) | 2012-09-26 |
Family
ID=40537209
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200810022968A Active CN101403051B (zh) | 2008-07-04 | 2008-07-04 | 从锗蒸馏废酸中回收铟的方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101403051B (zh) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104451205B (zh) * | 2013-09-12 | 2017-01-25 | 汉能新材料科技有限公司 | 一种高效除铁的铟提取方法 |
CN104561557A (zh) * | 2014-12-11 | 2015-04-29 | 济源豫金靶材科技有限公司 | 一种铟碱煮渣的处理工艺及其装置 |
CN107557596A (zh) * | 2016-07-01 | 2018-01-09 | 吕芳贤 | 由酸蚀刻废液中回收铟和锡元素的方法 |
CN106756126A (zh) * | 2016-11-22 | 2017-05-31 | 云南临沧鑫圆锗业股份有限公司 | 一种从低浓度含锗废液中回收锗的工艺方法 |
CN106676579B (zh) * | 2017-01-05 | 2018-10-23 | 京东方科技集团股份有限公司 | 处理氧化锡铟刻蚀废液的方法 |
CN113969354A (zh) * | 2021-10-09 | 2022-01-25 | 六盘水中联工贸实业有限公司 | 一种从锌冶炼烟灰中回收铟、锌方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101186976A (zh) * | 2006-09-28 | 2008-05-28 | 同和金属矿业有限公司 | 从含铟物质中回收铟的方法 |
-
2008
- 2008-07-04 CN CN200810022968A patent/CN101403051B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101186976A (zh) * | 2006-09-28 | 2008-05-28 | 同和金属矿业有限公司 | 从含铟物质中回收铟的方法 |
Also Published As
Publication number | Publication date |
---|---|
CN101403051A (zh) | 2009-04-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101265524B (zh) | 一种从石煤中提取v2o5的方法 | |
CN102212697B (zh) | 钨渣处理方法 | |
CN101760651B (zh) | 一种石煤酸浸提钒工艺 | |
CN101403051B (zh) | 从锗蒸馏废酸中回收铟的方法 | |
CN103290224B (zh) | 钨渣中有价金属的回收工艺 | |
CN101899582A (zh) | 由钒渣提取五氧化二钒的方法 | |
CN110004294B (zh) | 白钨矿碱分解渣的处理方法 | |
WO2008101396A1 (fr) | Procédé de prétraitement d'un solvant d'extraction organique, produit prétraité et son utilisation | |
CN102925686B (zh) | 一种从含钒、铬的溶液中选择性分离和提取钒与铬的方法 | |
CN102557153B (zh) | 一种从硫酸镍溶液中去除钙镁杂质的方法 | |
CN100535139C (zh) | 酸浸-硫化沉淀联合工艺回收ito废料中铟锡的方法 | |
CN106086439A (zh) | 一种从锌冶炼渣中回收锌、钴的方法 | |
CN108026609A (zh) | 含钪浓缩物的生产和从中进一步提取高纯度氧化钪 | |
CA1083358A (en) | Process for the recovery and purification of germanium from zinc ores | |
CN103789560A (zh) | 一种从石煤酸浸液中提钒的方法 | |
CN102392144A (zh) | 一种从锗精矿中回收铟锗的工艺方法 | |
CN102876899A (zh) | 一种从沉钒废水中有效分离和提取钒与铬的方法 | |
WO2004099079A1 (en) | A method for producing an electrolytic solution containing vanadium | |
CN104291362B (zh) | 一种利用含钾、氯离子的固废物生产碳酸钾的方法 | |
CN101319277A (zh) | 从锗蒸馏废酸中回收铟的碱化方法 | |
CN101403047A (zh) | 从锗蒸馏废酸中回收铟的还原调酸方法 | |
CN113186399A (zh) | 一种提取钽和铌的方法 | |
CN101403048A (zh) | 从锗蒸馏废酸中回收铟的硫酸浸出方法 | |
CN102676808B (zh) | 一种从钒渣分解液中分离钒铬的方法 | |
CN106746402B (zh) | 处理除砷污泥的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: YANGZHOU NINGDA NOBLE METAL Co.,Ltd. Assignor: Fan Hongjie Contract record no.: 2010320001097 Denomination of invention: Method for recycling indium from germanium distillation waste acid License type: Exclusive License Open date: 20090408 Record date: 20100826 |
|
ASS | Succession or assignment of patent right |
Owner name: HU'NAN QIU ZEYOU PATENT STRATEGIC PLANNING CO., LT Free format text: FORMER OWNER: QIU ZEYOU Effective date: 20101029 |
|
C41 | Transfer of patent application or patent right or utility model | ||
COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 410011 28/F, SHUNTIANCHENG, NO.59, SECTION 2 OF FURONG MIDDLE ROAD, CHANGSHA CITY, HU'NAN PROVINCE TO: 410205 JUXING INDUSTRY BASE, NO.8, LUJING ROAD, CHANGSHA HIGH-TECH. DEVELOPMENT ZONE, YUELU DISTRICT, CHANGSHA CITY, HU'NAN PROVINCE |
|
TA01 | Transfer of patent application right |
Effective date of registration: 20101104 Address after: 225231 No. 1, industrial concentration area, Yiling Town, Jiangdu City, Jiangsu Province Applicant after: YANGZHOU NINGDA NOBLE METAL Co.,Ltd. Address before: 225231 No. 1, industrial concentration area, Yiling Town, Jiangdu City, Jiangsu Province Applicant before: Fan Hongjie |
|
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP03 | Change of name, title or address | ||
CP03 | Change of name, title or address |
Address after: 225000 Industrial Park, Yiling Town, Jiangdu District, Yangzhou City, Jiangsu Province Patentee after: Jiangsu Ningda environmental protection Co.,Ltd. Address before: 225231 No. 1, industrial concentration area, Yiling Town, Jiangdu City, Jiangsu Province Patentee before: YANGZHOU NINGDA NOBLE METAL Co.,Ltd. |
|
DD01 | Delivery of document by public notice | ||
DD01 | Delivery of document by public notice |
Addressee: Li Xiaomeng Document name: Notice of Qualified Procedures |