CN101402269A - Viscosity-increasing precoating film of biaxial tension - Google Patents
Viscosity-increasing precoating film of biaxial tension Download PDFInfo
- Publication number
- CN101402269A CN101402269A CNA2008102248256A CN200810224825A CN101402269A CN 101402269 A CN101402269 A CN 101402269A CN A2008102248256 A CNA2008102248256 A CN A2008102248256A CN 200810224825 A CN200810224825 A CN 200810224825A CN 101402269 A CN101402269 A CN 101402269A
- Authority
- CN
- China
- Prior art keywords
- film
- ethylene
- hot melt
- melt adhesive
- eva
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010410 layer Substances 0.000 claims abstract description 87
- 229920006225 ethylene-methyl acrylate Polymers 0.000 claims abstract description 78
- 239000000463 material Substances 0.000 claims abstract description 65
- 239000004831 Hot glue Substances 0.000 claims abstract description 49
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 49
- 229920002873 Polyethylenimine Polymers 0.000 claims abstract description 42
- 229920000728 polyester Polymers 0.000 claims abstract description 25
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- 239000011248 coating agent Substances 0.000 claims description 46
- 238000000576 coating method Methods 0.000 claims description 46
- 239000011127 biaxially oriented polypropylene Substances 0.000 claims description 42
- 239000007864 aqueous solution Substances 0.000 claims description 22
- 238000003851 corona treatment Methods 0.000 claims description 21
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 15
- 239000002131 composite material Substances 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 12
- 238000005259 measurement Methods 0.000 claims description 10
- 238000007766 curtain coating Methods 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 230000005250 beta ray Effects 0.000 claims description 7
- 239000000155 melt Substances 0.000 claims description 7
- 238000003306 harvesting Methods 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 5
- 239000012943 hotmelt Substances 0.000 claims description 5
- 238000003672 processing method Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 239000012528 membrane Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 238000005096 rolling process Methods 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 abstract description 11
- 230000002457 bidirectional effect Effects 0.000 abstract description 8
- 238000012545 processing Methods 0.000 abstract description 7
- -1 polypropylene Polymers 0.000 abstract description 6
- 239000004743 Polypropylene Substances 0.000 abstract description 5
- 229920001155 polypropylene Polymers 0.000 abstract description 5
- 229920002545 silicone oil Polymers 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 22
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 238000007639 printing Methods 0.000 description 7
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000007888 film coating Substances 0.000 description 3
- 238000009501 film coating Methods 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 235000019994 cava Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000010892 electric spark Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
Images
Landscapes
- Laminated Bodies (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Abstract
The invention relates to a bidirectional stretched precoating film with increased viscosity and a processing technology thereof. The precoating film comprises a base material, a middle layer and a hot melt adhesive layer, and is characterized in that the base material is a bidirectional stretched polyester (BOPET) film or a bidirectional stretched polypropylene (BOPP) film, the middle layer is made from polyethylene imine (PEI), and the hot melt adhesive layer is a mixture consisting of ethylene-vinyl acetate (EVA) and ethylene-methyl acrylate copolymer (EMA). The bidirectional stretched precoating film with the increased viscosity is obtained by using an extruded compound production line to evenly coat and clad the middle layer and the hot melt adhesive layer on one surface of the base material in turn. Because the resin adopted by the hot melt adhesive layer of the precoating film is the mixture consisting of the ethylene-vinyl acetate (EVA) and the ethylene-methyl acrylate copolymer (EMA), the precoating film has far larger cohesive force to printed matters than the precoating film of which the hot melt adhesive is pure EVA, and can remarkably show the high cohesive force particularly to the printed matters containing silicone oil ink or the printed matters containing water-based ink.
Description
Affiliated field
The present invention relates to print the film coating technique field, particularly a kind of viscosity-increasing precoating film of biaxial tension and processing technology.
Background technology
The printed matter overlay film is the important means of post-press finishing, the final personal value of its decision print product.The coating technique of printed matter is meant with plastic sheeting and covers above the paper printing matter, the middle adhesive that uses, after the heating pressurized treatments, two kinds of materials of different nature of plastic sheeting and paper are bonded together, form paper/the mould incrustation process technology of unification.It plays protection and decorative effect to printed matter, is widely used in the packages printing field, on the Surface Machining as Front cover of book and periodical, propaganda picture album, map, advertising specialty bag, senior packing box etc.Overlay film can divide promptly films and two kinds of pre-coating films.
Be coated with membrane technology and be that the international sixties rise to coating technique behind the seal of printed matter, package.But this technology is directly used in the overlay film process and is contained benzene solvent, thereby has brought the three big drawbacks that can't overcome owing to self technology:
(1) environmental issue: because the volatilization of noxious material benzene and overflowing has caused air pollution and brought very big harm for the producer and user's health; Simultaneously, the harmful substance that residues in the overlay film has harmful effect to consumer's health.
(2) quality problems: owing to still have volatile substance benzene constantly to overflow after the overlay film processing, very easily between film and paper, form bubble, make printing product surface be vaporific, influence fineness, definition and the colour vividness of printing; Sometimes because of bonding strength is not enough, even cause cracking, fold and demoulding.In addition, the production equipment automaticity of promptly filming is low, has reduced the overlay film yield rate.
(3) safety problem: owing to contain volatile organic solvent benzene in the solution, form flammable, explosive atmosphere easily around the liquid bath, and the plastic basis material that the uses generation static that rub causes disaster hidden-trouble in operation process.Such accident number had taken place, and little then the shutdown stops production, and greatly then machine burns, and factory building caves in, casualties.
The pre-coating film film coating technique is the green technology of sustainable development.The pre-coating film film coating technique also can be referred to as environmental friendliness technology or clean technologies, has realized the protection environment, protects the health, has kept the safety in production.In pre-coating film production and the use, the volatilization that toxic gas does not take place is polluted, and therefore, effectively improves working environment, eliminates the disaster hidden-trouble that production site and product are stored; Use the pre-coating film product,, can be widely used on the packing of books and periodicals (especially student textbook), food, tobacco and wine, medicine etc. the consumer not being constituted potential threat owing to wherein do not have the hazard residue material; The process procedures such as allotment, coating and oven dry of binder have been saved simultaneously, the whole film covering process can in seconds be finished, and can not produce pollution to environment, does not have disaster hidden-trouble, do not need to clean automatic double surface gluer etc. yet, can realize high speed, efficient, high-quality overlay film; Pre-coating film has promoted the color saturation of printed matter and definition, has obviously increased its artistic effect; and printed matter played a protective role; make it water-fast, moisture resistance, fast light, prevent pollution, anti-chemical corrosion; increase the service life; improve durability, collection and the ornamental value of printed matter greatly, promoted the commercial competitiveness and the added value of product.
Common BOPP pre-coating film or common BOPET pre-coating film, because its hot melt adhesive layer is pure EVA, its cohesive force to printed matter is very little in the finished product application process, especially at printed matter that contains silicone oil printing ink or water color ink printed matter, cohesive force is littler.
Summary of the invention
The objective of the invention is: a kind of viscosity-increasing precoating film of biaxial tension and processing method are provided, produce a kind of novel pre-coating film, improve novel pre-coating film cohesive force to printed matter in the finished product application process, especially the cohesive force at printed matter that contains silicone oil printing ink or water color ink printed matter improves.
The technical scheme that the present invention is taked for its technical problem of solution is:
Viscosity-increasing precoating film of biaxial tension is characterized in that: be made up of base material, intermediate layer and hot melt adhesive layer, wherein: base material adopts Biaxially oriented polypropylene (BOPP) film or biaxial stretching polyester (BOPET) film; What the intermediate layer applied is that solid content is aqueous solution polymine (PEI) aqueous solution of 0.7%-1.2%, and coated weight is 0.01g/m
2, polymine after the drying (PEI) is evenly distributed on described film surface; Hot melt adhesive layer is the mixture that ethylene-vinyl acetate (EVA) and ethylene-methyl acrylate copolymer (EMA) constitute, VA content in the ethylene-vinyl acetate (EVA) is 15-20%, melt index is 11-20g/10min, the melt index of ethylene-methyl acrylate copolymer (EMA) is 15-20g/10min, the mixed proportion of the two: ethylene-vinyl acetate (EVA) is 50-70%, and ethylene-methyl acrylate copolymer (EMA) is 30-50%.Base material, intermediate layer and hot melt adhesive layer gross thickness are the 29-45 micron, and wherein the thickness of base material is the 9-15 micron, the thickness 20-30 micron of hot melt adhesive layer.
If base material is Biaxially oriented polypropylene (BOPP) film, its thickness is the 12-15 micron; The ethylene-vinyl acetate of hot melt adhesive layer (EVA) with the percentage by weight of ethylene-methyl acrylate copolymer (EMA) is: ethylene-vinyl acetate (EVA) is 52%, ethylene-methyl acrylate copolymer (EMA) is 48%, VA content in the ethylene-vinyl acetate (EVA) is 18%, melt index is 15g/10min, the melt index of ethylene-methyl acrylate copolymer (EMA) is 17g/10min, and the thickness of hot melt adhesive layer is 25 microns.Base material, intermediate layer and hot melt adhesive layer gross thickness are the 37-40 micron.
If base material is biaxial stretching polyester (BOPET) film, its thickness often is the 9-12 micron; The ethylene-vinyl acetate of hot melt adhesive layer (EVA) with the percentage by weight of ethylene-methyl acrylate copolymer (EMA) is: ethylene-vinyl acetate (EVA) is 61%, ethylene-methyl acrylate copolymer (EMA) is 39%, VA content in the ethylene-vinyl acetate (EVA) is 18%, and melt index is 15g/10min; The melt index of ethylene-methyl acrylate copolymer (EMA) is 17g/10min, and the thickness of hot melt adhesive layer is 25 microns.Base material, centre and hot melt adhesive layer gross thickness are the 34-37 micron.
The molecular formula of described polymine (PEI): (CH
2CH
2NH)
n, select the n value in the scope of 1000-10000 according to the mean molecule quantity of polymer.
The processing method of viscosity-increasing precoating film of biaxial tension
One, the preparation of intermediate layer materials and hot melt adhesive layer materials
The preparation of A, intermediate layer materials: with solid content is that to be deployed into solid content be 0.95% polymine (PEI) aqueous solution for 5% polymine (PEI) aqueous solution, add alcohol (analyzing pure) again, the weight ratio of 0.95% polymine (PEI) aqueous solution and alcohol is 20: 1.Stir and obtain the intermediate layer materials.
The preparation of B, hot melt adhesive layer materials: with ethylene-vinyl acetate (EVA) and ethylene-methyl acrylate copolymer (EMA) according to percentage by weight be: ethylene-vinyl acetate (EVA) is 50-70%, and ethylene-methyl acrylate copolymer (EMA) is 30-50%.Add in the homogenizer and mix about 1-5 of the time that mixes minute.
Two, unreel
With Biaxially oriented polypropylene (BOPP) film or biaxial stretching polyester (BOPET) film substrate volume, be placed on the unreeling machine and and unreel by the inflatable axle, the base material that is about to raw material and is web-like launches.
Three, corona
Because Biaxially oriented polypropylene (BOPP) film belongs to non-polar material, but its surface does not have good viscosity, and promptly its moistened surface tension force is little, so poly-interior alkene (BOPP) film of biaxial tension must pass through sided corona treatment.For itself and polymine (PEI) aqueous solution are well bonded together, need carry out the polar group that corona pre-treatment has certain activity with acquisition to its surface.Therefore, need carry out sided corona treatment to the surface (surface that combines with PEI) of preparation coating polyethylene imines (PEI) aqueous solution of Biaxially oriented polypropylene (BOPP) film, to obtain a certain amount of polar group such as carbonyl one class, represent the degree of sided corona treatment with wetting tension (dyne value), the dyne value that reaches Biaxially oriented polypropylene (BOPP) film surface is 36.
If base material is biaxial stretching polyester (BOPET) film,, can not carry out sided corona treatment because biaxial stretching polyester (BOPET) film is a polar material.
Sided corona treatment is to handle through the high-frequency and high-voltage electric spark, make the chain molecule fracture of Biaxially oriented polypropylene (BOPP) film surface, free radical that produces during the chain fracture and air corona product generation oxidation, cross-linking reaction, at Biaxially oriented polypropylene (BOPP) film surface polarization group, the segment polarity group injects film inside makes surface coarsening, thereby has increased the surface tension of film.
The equipment that the sided corona treatment process adopts is to be provided by U.S. Enercon company, and model is TF1006.
The sided corona treatment operating process, those skilled in the art know, and are not described in detail.
Four, apply the intermediate layer
By the silane coupling agent coating equipment, evenly apply the intermediate layer materials that one deck has configured on surface or surface of biaxial stretching polyester (BOPET) film of Biaxially oriented polypropylene (BOPP) film sided corona treatment.The quantity that applies the intermediate layer materials is 0.01g/m
2
The silane coupling agent coating equipment is provided by U.S. Black Clawson, COATER/DRYER (S.O.#C/A-1125-04).
Five, oven dry
Utilize drying plant will be coated with Biaxially oriented polypropylene (BOPP) film or the oven dry of biaxial stretching polyester (BOPET) film of polymine (PEI) aqueous solution, make polymine (PEI) be solidificated in Biaxially oriented polypropylene (BOPP) film or biaxial stretching polyester (BOPET) film surface, bake out temperature is about 85-95 ℃.The thickness in intermediate layer, oven dry back is the 0.01-0.03 micron.
The equipment that the oven dry processing procedure adopts is to be provided by U.S. Black Clawson, COATER/DRYER (S.O.#C/A-1125-04).
Six, extruding composite hot melt glue-line
Be loaded with Biaxially oriented polypropylene (BOPP) film or biaxial stretching polyester (BOPET) film of drying polymine (PEI), be sent to compound position by the deflector roll of extruding composite production line.Extruder extruding and hot melting glue-line is with expecting on Biaxially oriented polypropylene (BOPP) film or biaxial stretching polyester (BOPET) film.On the next door, compound position of extruding composite production line ozone generator is arranged.Ethylene-vinyl acetate (EVA) and ethylene-methyl acrylate copolymer (EMA) mixture (hot melt adhesive layer 3 materials) curtain coating place that the ozone that is produced by ozone generator is jetted and extruded to extruder, the concentration of ozone is 40%, power 800W, gas flow is 3.5SCXFM, and ozone makes ethylene-vinyl acetate (EVA) and ethylene-methyl acrylate copolymer (EMA) curtain coating surface produce some polar groups.The extruding of Biaxially oriented polypropylene (BOPP) film that is loaded with polymine (PEI) then and the curtain coating nip roller by extruding the compound position of composite production line combines.Extruding back forms composite membrane, after stretched again, cooling (temperature is 18 ℃), the deburring, is admitted to calibrator and detects.
During this time, the pressure of nip roller is 35PSI, and the desired temperature of extruder is respectively 130,160,190,200,220,220,220,220,220,220,220,220,220,220,220,220,220,220 ℃.
Seven, thickness measure and adjustment
Because the β ray has extremely strong penetrability and accurate measurement performance in short distance, the present invention's measurement is exactly to utilize Beta-ray this feature to measure the thickness of pre-coating film, after the measurement its result is fed back to computer, the die lip aperture at the screw speed of computer control extruder and die head position is so that obtain the pre-coating film of thickness uniformity.
The beta-ray measurement instrument is provided by U.S. NDC company, and model is 6100TC/300.
Eight, sided corona treatment
Since hot melt adhesive layer (EVA/EMA) polarity a little less than, in order to make in the product application, that is: in pre-coating film and the printed matter recombination process, have good cohesive force, need carry out the polar group that certain preliminary treatment has certain activity with acquisition to the hot melt adhesive layer surface, therefore, sided corona treatment is carried out on hot melt adhesive layer (EVA/EMA) surface, obtaining a certain amount of polar group, represent the degree of sided corona treatment to reach hot melt adhesive layer surface dyne value in the 50-54 scope with wetting tension (dyne value).
Nine, rolling
Pre-coating film harvest coiled material after utilizing winder with corona.
Ten, cut
According to client's conditions of demand, the pre-coating film of winder harvest coiled material is cut into the volume of cutting of required width of client and length.
After above-mentioned ten steps processing, obtain viscosity-increasing precoating film of biaxial tension.
Beneficial effect of the present invention: viscosity-increasing precoating film of biaxial tension of the present invention and processing technology, it is a kind of novel pre-coating film, this pre-coating film its cohesive force to printed matter in the finished product application process will be far longer than common pre-coating film, because the hot melt adhesive layer of common pre-coating film is pure EVA, especially at printed matter that contains silicone oil printing ink or water color ink printed matter, its high cohesive force more can highlight, be that common pre-coating film is incomparable, capture the unconquerable difficult problem of common pre-coating film, filled up the unapproachable market vacancy of common pre-coating film.
Description of drawings
Fig. 1 is the cross sectional representation of viscosity-increasing precoating film of biaxial tension.
Fig. 2 is in the step 6, the flowage structure schematic diagram of extruding composite hot melt glue-line 3.
Fig. 3 is in the step 6, extruding makes Biaxially oriented polypropylene (BOPP) film or biaxial stretching polyester (BOPET) film, with the schematic diagram that combines the generation novel substance between polymine (PEI) and ethylene-vinyl acetate (the EVA)/ethylene-methyl acrylate copolymer (EMA).
The specific embodiment
Embodiment 1: with width is that 1580 millimeters bidirectional stretching polypropylene film (BOPP) viscosity-increasing precoating film is an example, is elaborated.
Consult Fig. 1.Bidirectional stretching polypropylene film (BOPP) viscosity-increasing precoating film is made up of base material 1, intermediate layer 2 and hot melt adhesive layer 3.Base material 1, intermediate layer 2 are identical with the width of hot melt adhesive layer 3.
Bidirectional stretching polypropylene film (BOPP) viscosity-increasing precoating film processing method:
One, the preparation of intermediate layer 2 materials and hot melt adhesive layer 3 materials
The preparation of A, intermediate layer 2 materials: with solid content is that to be deployed into solid content in container be 0.95% polymine (PEI) aqueous solution for 5% polymine (PEI) aqueous solution, add alcohol (analyzing pure) again, the weight ratio of 0.95% polymine (PEI) aqueous solution and alcohol is 20: 1.Stirring, it is standby to obtain intermediate layer 2 materials.The mean molecule quantity of polymine (PEI) is 5000.
The preparation of B, hot melt adhesive layer 3 materials: ethylene-vinyl acetate (EVA) and ethylene-methyl acrylate copolymer (EMA) are compared according to mixed weight: ethylene-vinyl acetate (EVA) is 50%, ethylene-methyl acrylate copolymer (EMA) is 50%, add in the homogenizer and mix about 3 minutes of the time that mixes.VA content in the ethylene-vinyl acetate (EVA) is 18%, and melt index is 15g/10min, and the melt index of ethylene-methyl acrylate copolymer (EMA) is 17g/10min.
Two, unreel
With width is 1600 millimeters Biaxially oriented polypropylene (BOPP) film substrate 1 volume, is placed on the unreeling machine and by the inflatable axle to unreel.The thickness of base material 1 is 15 microns.
Three, corona
Sided corona treatment is carried out on surface to preparation coating polyethylene imines (PEI) aqueous solution of Biaxially oriented polypropylene (BOPP) film, and the dyne value that reaches Biaxially oriented polypropylene (BOPP) film surface is 36.
The equipment that the sided corona treatment process adopts is to be provided by U.S. Enercon company, and model is TF1006
Four, apply intermediate layer 2
By the silane coupling agent coating equipment, evenly apply intermediate layer 2 materials that one deck has configured on the surface of Biaxially oriented polypropylene (BOPP) film sided corona treatment.The quantity that applies intermediate layer 2 materials is 0.01g/m
2
The silane coupling agent coating equipment is provided by U.S. Black Clawson, COATER/DRYER (S.O.#C/A-1125-04).
Five, oven dry
Utilize drying plant will be coated with Biaxially oriented polypropylene (BOPP) the film oven dry of polymine (PEI) aqueous solution, make polymine (PEI) be solidificated in Biaxially oriented polypropylene (BOPP) film surface, bake out temperature is 90 ℃.The thickness in intermediate layer 2, oven dry back is about 0.01 micron.
The equipment that the oven dry processing procedure adopts is to be provided by U.S. Black Clawson, COATER/DRYER (S.O.#C/A-1125-04).
Six, the composite hot melt glue-line 3
Consult Fig. 2.Be loaded with Biaxially oriented polypropylene (BOPP) film or biaxial stretching polyester (BOPET) film of drying polymine (PEI), be sent to compound position by the deflector roll of extruding equipment complex.Extruder extruding and hot melting glue-line 3 usefulness are expected on Biaxially oriented polypropylene (BOPP) film or biaxial stretching polyester (BOPET) film.On the next door, compound position of extruding equipment complex ozone generator is arranged.Ethylene-vinyl acetate (EVA) and ethylene-methyl acrylate copolymer (EMA) mixture (hot melt adhesive layer 3 materials) curtain coating place that the ozone that is produced by ozone generator is jetted and extruded to extruder.The concentration of ozone is 40%, and power 800W, gas flow are 3.5SCXFM, and ozone makes ethylene-vinyl acetate (EVA) and ethylene-methyl acrylate copolymer (EMA) curtain coating surface produce some polar groups.The extruding of Biaxially oriented polypropylene (BOPP) film that is loaded with polymine (PEI) then and the curtain coating nip roller by extruding equipment complex combines.Consult Fig. 3.After the extruding, Biaxially oriented polypropylene (BOPP) film or biaxial stretching polyester (BOPET) film, generate hydrogen bond or novel substance with combining between polymine (PEI) and ethylene-vinyl acetate (the EVA)/ethylene-methyl acrylate copolymer (EMA), then form composite membrane, after stretched again, cooling, the deburring, be admitted to calibrator and detect.25 microns of the thickness of hot melt adhesive layer 3.
During this time, the pressure of nip roller is 35PSI, and the desired temperature of extruder is respectively 130,160,190,200,220,220,220,220,220,220,220,220,220,220,220,220,220,220 ℃.
Seven, thickness measure and adjustment
Utilize the beta-ray measurement instrument to measure the thickness of pre-coating film, after the measurement its result is fed back to computer, the die lip aperture at the screw speed of computer control extruder and die head position is so that obtain the pre-coating film of thickness uniformity.Base material 1, intermediate layer 2 and hot melt adhesive layer 3 gross thickness are 40 microns.
The beta-ray measurement instrument is provided by U.S. NDC company, and model is 6100TC/300.
Eight, sided corona treatment
Sided corona treatment is carried out on hot melt adhesive layer 3 (EVA/EMA) surface, and to obtain a certain amount of polar group, reaching hot melt adhesive layer 2 surperficial dyne values is 54.
Nine, rolling
Pre-coating film harvest coiled material after utilizing winder with corona.
Ten, cut
According to client's demand, the pre-coating film of winder harvest coiled material is cut into the volume of cutting of required width of client and length.Obtain bidirectional stretching polypropylene film (BOPP) viscosity-increasing precoating film.
Both sides of the edge accumulative total is cut off 20mm, and final products will be than about the narrow 20mm of base material, in the fabric width direction, and thickness deviation≤2 micron.
Embodiment 2: with width is that 1795 millimeters biaxial stretching polyester (BOPET) viscosity-increasing precoating film is an example, describes
After the unreeling of completing steps two, directly carry out the coating intermediate layer 2 of step 4, omit the sided corona treatment process of step 3;
The ethylene-vinyl acetate of hot melt adhesive layer 3 (EVA) with the percentage by weight of ethylene-methyl acrylate copolymer (EMA) is: ethylene-vinyl acetate (EVA) is 61%, ethylene-methyl acrylate copolymer (EMA) is 39%, and the thickness of composite hot melt glue-line 3 is 25 microns.
Through extruding, stretching, cooling, the deburring system of nip roller, both sides of the edge accumulative total can be cut off 25mm after compound, and final products will be than about the narrow 25mm of base material, in the fabric width direction, and thickness deviation≤2 micron.
Pre-coating film of the present invention its cohesive force to printed matter in the finished product application process will be far longer than common pre-coating film.The row contrast table describes.
Claims (7)
1, a kind of viscosity-increasing precoating film of biaxial tension is characterized in that: be made up of base material (1), intermediate layer (2) and hot melt adhesive layer (3), wherein: base material (1) adopts Biaxially oriented polypropylene (BOPP) film or biaxial stretching polyester (BOPET) film; Intermediate layer (2) is that the solid content of coating is aqueous solution polymine (PEI) aqueous solution of 0.7%-1.2%, and coated weight is 0.01g/m
2, polymine after the drying (PEI) is evenly distributed on described film surface; Hot melt adhesive layer (3) is the mixture that ethylene-vinyl acetate (EVA) and ethylene-methyl acrylate copolymer (EMA) constitute, VA content in the ethylene-vinyl acetate (EVA) is 15-20%, melt index is 11-20g/10min, the melt index of ethylene-methyl acrylate copolymer (EMA) is 15-20g/10min, the mixed proportion of the two: ethylene-vinyl acetate (EVA) is 50-70%, ethylene-methyl acrylate copolymer (EMA) is 30-50%, base material (1), intermediate layer (2) and hot melt adhesive layer (3) gross thickness are the 29-45 micron, wherein the thickness of base material (1) is the 9-15 micron, the thickness 20-30 micron of hot melt adhesive layer (3).
2, according to the described viscosity-increasing precoating film of biaxial tension of claim 1, it is characterized in that: base material (1) is Biaxially oriented polypropylene (BOPP) film, and thickness is the 12-15 micron; The ethylene-vinyl acetate (EVA) of hot melt adhesive layer (3) with the percentage by weight of ethylene-methyl acrylate copolymer (EMA) is: ethylene-vinyl acetate (EVA) is 52%, ethylene-methyl acrylate copolymer (EMA) is 48%, VA content in the ethylene-vinyl acetate (EVA) is 18%, melt index is 15g/10min, the melt index of ethylene-methyl acrylate copolymer (EMA) is 17g/10min, the thickness of hot melt adhesive layer (3) is 25 microns, and base material (1), intermediate layer (2) and hot melt adhesive layer (3) gross thickness are the 37-40 micron.
3, according to the described viscosity-increasing precoating film of biaxial tension of claim 1, it is characterized in that: base material (1) is biaxial stretching polyester (BOPET) film, and thickness often is the 9-12 micron; The ethylene-vinyl acetate (EVA) of hot melt adhesive layer (3) with the percentage by weight of ethylene-methyl acrylate copolymer (EMA) is: ethylene-vinyl acetate (EVA) is 61%, ethylene-methyl acrylate copolymer (EMA) is 39%, VA content in the ethylene-vinyl acetate (EVA) is 18%, and melt index is 15g/10min; The melt index of ethylene-methyl acrylate copolymer (EMA) is 17g/10min, and the thickness of hot melt adhesive layer (3) is 25 microns, and base material (1), intermediate layer (2) and hot melt adhesive layer (3) gross thickness are the 34-37 micron.
4, according to the described viscosity-increasing precoating film of biaxial tension of claim 1, it is characterized in that: the molecular formula of polymine (PEI): be (CH
2CH
2NH)
n, select the n value in the scope of 1000-10000 according to the mean molecule quantity of polymer.
5, according to the described viscosity-increasing precoating film of biaxial tension of claim 1, it is characterized in that: intermediate layer (2) are that the solid content of coating is polymine (PEI) aqueous solution and the crude alcohol mixture of 0.7%-1.2%, the weight ratio of 0.95% polymine (PEI) aqueous solution and alcohol is 20: 1-1.3 stirs.
6, as the processing method of claim 1,2,3,4 or 5 described viscosity-increasing precoating film of biaxial tension, it is characterized in that:
One, the preparation of intermediate layer materials and hot melt adhesive layer materials
The preparation of A, intermediate layer (2) materials: with solid content is that to be deployed into solid content be 0.95% polymine (PEI) aqueous solution for 5% polymine (PEI) aqueous solution, add alcohol (analyzing pure) again, the weight ratio of 0.95% polymine (PEI) aqueous solution and alcohol is 20: 1, stirs to obtain intermediate layer (2) materials;
The preparation of B, hot melt adhesive layer (3) materials: with ethylene-vinyl acetate (EVA) and ethylene-methyl acrylate copolymer (EMA) according to percentage by weight be: ethylene-vinyl acetate (EVA) is 50-70%, ethylene-methyl acrylate copolymer (EMA) is 30-50%, add in the homogenizer and mix about 1-5 of the time that mixes minute;
Two, unreel
With Biaxially oriented polypropylene (BOPP) film or biaxial stretching polyester (BOPET) film substrate (1) volume, be placed on the unreeling machine and and unreel by the inflatable axle;
Three, corona
Sided corona treatment is carried out on surface to preparation coating polyethylene imines (PEI) aqueous solution of Biaxially oriented polypropylene (BOPP) film, and the dyne value that reaches Biaxially oriented polypropylene (BOPP) film surface is 36;
Four, apply the intermediate layer
By the silane coupling agent coating equipment, surface or surface of biaxial stretching polyester (BOPET) film in Biaxially oriented polypropylene (BOPP) film sided corona treatment evenly apply intermediate layer (2) materials that one deck has configured, and the quantity that applies intermediate layer (2) materials is 0.01g/m
2
Five, oven dry
Utilize drying plant will be coated with Biaxially oriented polypropylene (BOPP) film or the oven dry of biaxial stretching polyester (BOPET) film of polymine (PEI) aqueous solution, make polymine (PEI) be solidificated in Biaxially oriented polypropylene (BOPP) film or biaxial stretching polyester (BOPET) film surface, bake out temperature is 85-95 ℃, and the thickness in oven dry intermediate layer, back (2) is about the 0.01-0.03 micron;
Six, composite hot melt glue-line
Be loaded with Biaxially oriented polypropylene (BOPP) film or biaxial stretching polyester (BOPET) film of drying polymine (PEI), be sent to compound position by the deflector roll of extruding composite production line, extruder extruding and hot melting glue-line (3) is with expecting on Biaxially oriented polypropylene (BOPP) film or biaxial stretching polyester (BOPET) film; On the next door, compound position of extruding composite production line ozone generator is arranged, ethylene vinyl acetate (EVA) and ethylene-methyl acrylate copolymer (EMA) mixture curtain coating place that the ozone that is produced by ozone generator is jetted and extruded to extruder, the concentration of ozone is 40%, power 800W, gas flow is 3.5SCXFM, ozone makes ethylene-vinyl acetate (EVA) and ethylene-methyl acrylate copolymer (EMA) curtain coating surface produce some polar groups, the extruding of Biaxially oriented polypropylene (BOPP) film that is loaded with polymine (PEI) then and the curtain coating nip roller by extruding the compound position of composite production line combines, form composite membrane, stretched again, cooling, after the deburring, be admitted to calibrator and detect;
The pressure of nip roller is 35PSI, and the desired temperature of extruder is respectively 130,160,190,200,220,220,220,220,220,220,220,220,220,220,220,220,220,220 ℃;
Seven, thickness measure and adjustment
Utilize the beta-ray measurement instrument to measure the thickness of pre-coating film, after the measurement its result is fed back to computer, the die lip aperture at the screw speed of computer control extruder and die head position is so that obtain the pre-coating film of thickness uniformity;
Eight, sided corona treatment
Hot melt adhesive layer (3) (EVA/EMA) is carried out sided corona treatment in the surface,, reach the surperficial dyne value of hot melt adhesive layer (2) in the 50-54 scope to obtain a certain amount of polar group;
Nine, rolling
Pre-coating film harvest coiled material after utilizing winder with corona;
Ten, cut
According to client's demand, the pre-coating film of winder harvest coiled material is cut into the volume of cutting of required width of client and length;
Obtain viscosity-increasing precoating film of biaxial tension.
7, the processing method of viscosity-increasing precoating film of biaxial tension as claimed in claim 6 is characterized in that: the unit type that step 3 is used is TF1006; The equipment that step 4 and step 5 are used is (COATER/DRYER) S.O.#C/A-1125-04; The beta-ray measurement instrument model that step 7 is used is 6100TC/300.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200810224825 CN101402269B (en) | 2008-10-22 | 2008-10-22 | Viscosity-increasing precoating film of biaxial tension |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200810224825 CN101402269B (en) | 2008-10-22 | 2008-10-22 | Viscosity-increasing precoating film of biaxial tension |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101402269A true CN101402269A (en) | 2009-04-08 |
| CN101402269B CN101402269B (en) | 2013-05-01 |
Family
ID=40536493
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200810224825 Active CN101402269B (en) | 2008-10-22 | 2008-10-22 | Viscosity-increasing precoating film of biaxial tension |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101402269B (en) |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101992579A (en) * | 2010-08-31 | 2011-03-30 | 东莞市爱克斯曼机械有限公司 | Hot-melt adhesive non-woven fabric based adhesion processing equipment |
| CN102380215A (en) * | 2011-11-17 | 2012-03-21 | 金冠(龙海)塑料包装有限公司 | Magic color balloon and preparation method thereof |
| CN102732174A (en) * | 2012-06-26 | 2012-10-17 | 北京康得新复合材料股份有限公司 | Pre-coating film and preparation method for the same |
| CN102757738A (en) * | 2012-07-04 | 2012-10-31 | 北京康得新复合材料股份有限公司 | Biaxially-oriented tackified precoating film and production method thereof |
| CN102757740A (en) * | 2012-07-04 | 2012-10-31 | 北京康得新复合材料股份有限公司 | Two-way stretch digital pre-coating film and preparation method thereof |
| CN103146318A (en) * | 2013-03-19 | 2013-06-12 | 安徽国风塑业股份有限公司 | Pre-coating film for paper-plastic lamination and preparation method thereof |
| CN103342970A (en) * | 2013-07-12 | 2013-10-09 | 浙江顺福印业有限公司 | High-efficiency environment-friendly pre-coated film processing technology |
| CN103350550A (en) * | 2013-07-30 | 2013-10-16 | 浙江顺福印业有限公司 | Processing process for waterproof pre-coating film |
| WO2014005538A1 (en) * | 2012-07-04 | 2014-01-09 | 北京康得新复合材料股份有限公司 | Universal precoating film |
| CN103539957A (en) * | 2013-10-18 | 2014-01-29 | 莱芜中天绝缘材料有限公司 | Treatment method of polyimide film |
| CN103834103A (en) * | 2014-03-04 | 2014-06-04 | 芜湖市艾德森自动化设备有限公司 | Self-healing capacity modified isotatic polypropylene capacitor metalized film and preparation method thereof |
| CN103911085A (en) * | 2013-04-09 | 2014-07-09 | 北京康得新复合材料股份有限公司 | Biaxially oriented polyester matte precoat and preparation method thereof |
| CN104290422A (en) * | 2014-09-19 | 2015-01-21 | 安徽国风塑业股份有限公司 | Polyester composite film applied to extrusion coating type packaging bags and preparation method of polyester composite film |
| CN106189902A (en) * | 2016-07-14 | 2016-12-07 | 安徽东瑞塑业有限责任公司 | A kind of production method of the pre-coating film containing primary coat operation |
| CN107011819A (en) * | 2017-03-15 | 2017-08-04 | 方俸君 | A kind of pre-coating film |
| CN107128051A (en) * | 2017-06-21 | 2017-09-05 | 深圳市三上高分子环保新材料股份有限公司 | Pre-coating film and its manufacture method and device systems with pile effects |
| CN109628011A (en) * | 2018-12-26 | 2019-04-16 | 惠州艺都文化用品有限公司 | Heat mounting film for printed matter |
| CN110861375A (en) * | 2019-11-16 | 2020-03-06 | 湖北劲佳包装有限公司 | Preparation method of laminated composite non-woven fabric |
| CN111171756A (en) * | 2019-10-16 | 2020-05-19 | 宁波盈瑞聚合科技有限公司 | Antistatic precoating film and production method thereof |
| CN111171755A (en) * | 2019-10-16 | 2020-05-19 | 宁波盈瑞聚合科技有限公司 | Biaxial stretching tackifying pre-coating film and production method thereof |
| CN111690330A (en) * | 2020-05-07 | 2020-09-22 | 安徽国风塑业股份有限公司 | Primer-free double-sided adhesive layer polypropylene pre-coating film and preparation method thereof |
| CN113415056A (en) * | 2021-06-30 | 2021-09-21 | 福建技术师范学院 | Flexible gloss type environment-friendly hot-melt direct-coating film and preparation method thereof |
| CN114262572A (en) * | 2021-12-31 | 2022-04-01 | 厦门印驰包装有限公司 | Super-viscous hot-coating pre-coating film and preparation method thereof |
| CN114456726A (en) * | 2021-12-28 | 2022-05-10 | 安徽国风塑业股份有限公司 | BOPP digital pre-coating film for low-temperature embossing and preparation method thereof |
| CN114989737A (en) * | 2022-07-22 | 2022-09-02 | 苏州昆岭薄膜工业有限公司 | Printable high-viscosity aluminized pre-coating film for packaging and preparation method thereof |
| CN115505155A (en) * | 2022-09-27 | 2022-12-23 | 惠州艺都文化用品有限公司 | Plate film and preparation method thereof |
| CN116656266A (en) * | 2023-05-16 | 2023-08-29 | 广东德冠薄膜新材料股份有限公司 | Biaxially oriented precoating film, and preparation method and application thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4784708A (en) * | 1986-06-11 | 1988-11-15 | Waldorf Corporation | Bonding method of employing gluability enhancement composition |
| US6294264B1 (en) * | 1999-03-30 | 2001-09-25 | Cryovac, Inc. | Oriented cook-in film with good interply adhesion |
| DE10311125A1 (en) * | 2002-03-30 | 2003-11-27 | Henkel Kgaa | Multilayer film, useful for the production of flexible packaging, is coated with first hot-sealing adhesive containing cellulose nitrate and acrylic polymers and is sealable against layer based on polyvinyl compound |
-
2008
- 2008-10-22 CN CN 200810224825 patent/CN101402269B/en active Active
Cited By (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101992579B (en) * | 2010-08-31 | 2013-04-10 | 东莞市爱克斯曼机械有限公司 | Hot-melt adhesive non-woven fabric based adhesion processing equipment |
| CN101992579A (en) * | 2010-08-31 | 2011-03-30 | 东莞市爱克斯曼机械有限公司 | Hot-melt adhesive non-woven fabric based adhesion processing equipment |
| CN102380215A (en) * | 2011-11-17 | 2012-03-21 | 金冠(龙海)塑料包装有限公司 | Magic color balloon and preparation method thereof |
| CN102732174A (en) * | 2012-06-26 | 2012-10-17 | 北京康得新复合材料股份有限公司 | Pre-coating film and preparation method for the same |
| WO2014000631A1 (en) * | 2012-06-26 | 2014-01-03 | 北京康得新复合材料股份有限公司 | Precoating film and preparation method thereof |
| WO2014005537A1 (en) * | 2012-07-04 | 2014-01-09 | 北京康得新复合材料股份有限公司 | Biaxially-oriented tackifying precoated film and manufacturing method therefor |
| WO2014005538A1 (en) * | 2012-07-04 | 2014-01-09 | 北京康得新复合材料股份有限公司 | Universal precoating film |
| CN102757738A (en) * | 2012-07-04 | 2012-10-31 | 北京康得新复合材料股份有限公司 | Biaxially-oriented tackified precoating film and production method thereof |
| CN102757738B (en) * | 2012-07-04 | 2014-08-13 | 北京康得新复合材料股份有限公司 | Biaxially-oriented tackified precoating film and production method thereof |
| CN102757740A (en) * | 2012-07-04 | 2012-10-31 | 北京康得新复合材料股份有限公司 | Two-way stretch digital pre-coating film and preparation method thereof |
| WO2014005533A1 (en) * | 2012-07-04 | 2014-01-09 | 北京康得新复合材料股份有限公司 | Biaxially-oriented digitally-precoated film and manufacturing method therefor |
| CN103146318A (en) * | 2013-03-19 | 2013-06-12 | 安徽国风塑业股份有限公司 | Pre-coating film for paper-plastic lamination and preparation method thereof |
| CN103911085A (en) * | 2013-04-09 | 2014-07-09 | 北京康得新复合材料股份有限公司 | Biaxially oriented polyester matte precoat and preparation method thereof |
| WO2014166339A1 (en) * | 2013-04-09 | 2014-10-16 | 北京康得新复合材料股份有限公司 | Biaxially-oriented polyester matte laminating film and manufacturing method therefor |
| CN103342970A (en) * | 2013-07-12 | 2013-10-09 | 浙江顺福印业有限公司 | High-efficiency environment-friendly pre-coated film processing technology |
| CN103350550B (en) * | 2013-07-30 | 2016-03-09 | 浙江顺福印业有限公司 | A kind of waterproof pre-coating film processing technology |
| CN103350550A (en) * | 2013-07-30 | 2013-10-16 | 浙江顺福印业有限公司 | Processing process for waterproof pre-coating film |
| CN103539957A (en) * | 2013-10-18 | 2014-01-29 | 莱芜中天绝缘材料有限公司 | Treatment method of polyimide film |
| CN103834103A (en) * | 2014-03-04 | 2014-06-04 | 芜湖市艾德森自动化设备有限公司 | Self-healing capacity modified isotatic polypropylene capacitor metalized film and preparation method thereof |
| CN103834103B (en) * | 2014-03-04 | 2016-02-17 | 芜湖市艾德森自动化设备有限公司 | Capacitor metalized film of a kind of self-healing ability modification isotatic polypropylene and preparation method thereof |
| CN104290422A (en) * | 2014-09-19 | 2015-01-21 | 安徽国风塑业股份有限公司 | Polyester composite film applied to extrusion coating type packaging bags and preparation method of polyester composite film |
| CN106189902A (en) * | 2016-07-14 | 2016-12-07 | 安徽东瑞塑业有限责任公司 | A kind of production method of the pre-coating film containing primary coat operation |
| CN107011819A (en) * | 2017-03-15 | 2017-08-04 | 方俸君 | A kind of pre-coating film |
| CN107128051A (en) * | 2017-06-21 | 2017-09-05 | 深圳市三上高分子环保新材料股份有限公司 | Pre-coating film and its manufacture method and device systems with pile effects |
| CN109628011A (en) * | 2018-12-26 | 2019-04-16 | 惠州艺都文化用品有限公司 | Heat mounting film for printed matter |
| CN111171756A (en) * | 2019-10-16 | 2020-05-19 | 宁波盈瑞聚合科技有限公司 | Antistatic precoating film and production method thereof |
| CN111171755A (en) * | 2019-10-16 | 2020-05-19 | 宁波盈瑞聚合科技有限公司 | Biaxial stretching tackifying pre-coating film and production method thereof |
| CN110861375A (en) * | 2019-11-16 | 2020-03-06 | 湖北劲佳包装有限公司 | Preparation method of laminated composite non-woven fabric |
| CN111690330A (en) * | 2020-05-07 | 2020-09-22 | 安徽国风塑业股份有限公司 | Primer-free double-sided adhesive layer polypropylene pre-coating film and preparation method thereof |
| CN113415056A (en) * | 2021-06-30 | 2021-09-21 | 福建技术师范学院 | Flexible gloss type environment-friendly hot-melt direct-coating film and preparation method thereof |
| CN114456726A (en) * | 2021-12-28 | 2022-05-10 | 安徽国风塑业股份有限公司 | BOPP digital pre-coating film for low-temperature embossing and preparation method thereof |
| CN114262572A (en) * | 2021-12-31 | 2022-04-01 | 厦门印驰包装有限公司 | Super-viscous hot-coating pre-coating film and preparation method thereof |
| CN114989737A (en) * | 2022-07-22 | 2022-09-02 | 苏州昆岭薄膜工业有限公司 | Printable high-viscosity aluminized pre-coating film for packaging and preparation method thereof |
| CN114989737B (en) * | 2022-07-22 | 2024-03-08 | 苏州昆岭薄膜工业有限公司 | Printable high-viscosity aluminized precoated film for packaging and preparation method thereof |
| CN115505155A (en) * | 2022-09-27 | 2022-12-23 | 惠州艺都文化用品有限公司 | Plate film and preparation method thereof |
| CN115505155B (en) * | 2022-09-27 | 2023-03-10 | 惠州艺都文化用品有限公司 | Plate film and preparation method thereof |
| CN116656266A (en) * | 2023-05-16 | 2023-08-29 | 广东德冠薄膜新材料股份有限公司 | Biaxially oriented precoating film, and preparation method and application thereof |
| CN116656266B (en) * | 2023-05-16 | 2023-11-14 | 广东德冠薄膜新材料股份有限公司 | Biaxially oriented precoating film, and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101402269B (en) | 2013-05-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101402269B (en) | Viscosity-increasing precoating film of biaxial tension | |
| CN101396892B (en) | Metallization biaxial stretching polyester (BOPET) pre-coating film using chemical treatment | |
| CN103911085A (en) | Biaxially oriented polyester matte precoat and preparation method thereof | |
| CN102757740B (en) | Two-way stretch digital pre-coating film and preparation method thereof | |
| KR102136002B1 (en) | Packing film using environment-friendly ink and method of manufacturing the same | |
| CN103336321B (en) | Polypropylene type optical protective film | |
| US20160229156A1 (en) | Matte thermal laminating film and preparing method thereof | |
| CN204174147U (en) | Anti-scratching flat top pre-coating film | |
| CN103342970A (en) | High-efficiency environment-friendly pre-coated film processing technology | |
| CN105882094B (en) | Solar panels high-temperature-resistant ultraviolet-resistant self-adhesive film | |
| CN202965391U (en) | No-primer lamination film and biaxially oriented polypropylene film of no-primer lamination film | |
| US9550930B2 (en) | Thermal lamination adhesive coatings for use on substrates | |
| CN108407342A (en) | Preparation method of environment-friendly potato chip packaging film | |
| CN108441129B (en) | Rubber-coated medical instrument packaging material capable of being stably and cleanly peeled and preparation method thereof | |
| EP3149079A1 (en) | Primer coatings for use on substrates | |
| CN114536919B (en) | Polypropylene thermal composite material and preparation method and application thereof | |
| CN103350550B (en) | A kind of waterproof pre-coating film processing technology | |
| CN103865418B (en) | A kind of without rainbow line chemical treatment biaxial tension polyester precoating film and preparation method thereof | |
| CN108136751A (en) | Cosmetic sheet | |
| CN203890281U (en) | Biaxially oriented polyester semi-gloss pre-coating film | |
| CN206646058U (en) | Outer spreading type Antistatic type pre-coating film | |
| CN201217285Y (en) | Biaxial tension polypropylene precoating film | |
| CN102229786B (en) | Environmentally-friendly lamination film | |
| CN115450065A (en) | Biodegradable alcohol-resistant water-based plastic replacement oil and preparation method thereof | |
| CN201217288Y (en) | Biaxial tension polyester precoating film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: JIANGSU KANGDEXIN COMPOSITE MATERIAL CO., LTD. Free format text: FORMER NAME: BEIJING KANGDE XIN COMPOSITE MATERIAL CO., LTD. |
|
| CP03 | Change of name, title or address |
Address after: Jiangsu environmental protection new material Industrial Park Road on the north side of Hong Kong, Hong Chen Hua Road West Patentee after: Jiangsu kangdexin composite materials Limited by Share Ltd. Address before: 102200, 26, Zhenxing Road, Changping science and Technology Park, Beijing Patentee before: BEIJING KANGDE XIN COMPOSITE MATERIAL Co.,Ltd. |
|
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: Jiangsu environmental protection new material Industrial Park Road on the north side of Hong Kong, Hong Chen Hua Road West Patentee after: Kang Kang composite material group Limited by Share Ltd. Address before: Jiangsu environmental protection new material Industrial Park Road on the north side of Hong Kong, Hong Chen Hua Road West Patentee before: Jiangsu kangdexin composite materials Limited by Share Ltd. |
|
| PP01 | Preservation of patent right |
Effective date of registration: 20190118 Granted publication date: 20130501 |
|
| PP01 | Preservation of patent right | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20220118 Granted publication date: 20130501 |
|
| PD01 | Discharge of preservation of patent | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20220118 Granted publication date: 20130501 |
|
| PP01 | Preservation of patent right | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20230407 Granted publication date: 20130501 |
|
| PD01 | Discharge of preservation of patent |