CN101376612A - Aminoacid foliar fertilizer and use thereof - Google Patents

Aminoacid foliar fertilizer and use thereof Download PDF

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CN101376612A
CN101376612A CNA2008101211860A CN200810121186A CN101376612A CN 101376612 A CN101376612 A CN 101376612A CN A2008101211860 A CNA2008101211860 A CN A2008101211860A CN 200810121186 A CN200810121186 A CN 200810121186A CN 101376612 A CN101376612 A CN 101376612A
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iron
foliar fertilizer
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rice
aminoacid
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CN101376612B (en
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吴良欢
张进
吕倩
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Zhejiang University ZJU
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Abstract

The invention provides amino acid leaf fertilizer which is composed of 20-50 percent of compound amino acids, 1-50 percent of nicotinic amide, 10-20 percent of green vitriol, 10-20 percent of urea, 5-10 percent of boric acid, 1-5 percent of ascorbic acid and 1-5 percent of surface active agent, namely polysorbate 80. The pH value is required to be 5.0-6.0. The fertilizer efficiency of the amino acid leaf fertilizer is stable, the fertilizer can obviously strengthen the iron nutrient of paddy rice seeds with different genotypes, averagely, the content of iron in winnowed paddy can be obviously increased by above 15 percent, the content of protein and amino acid in the winnowed paddy rice can be obviously increased, the nutrition and the quality of paddy rice can be enhanced all sidedly, the quality is excellent and the cost is low. Therefore, the amino acid leaf fertilizer can be applied in the highly effective biological strengthening of the iron nutrient in paddy seeds and the remarkable promotion of the nutrition and the quality of paddy rice.

Description

A kind of aminoacid foliar fertilizer and application
Technical field
The invention belongs to the foliar nutrient field, relate to a kind of foliage-spray that is used for specifically, can make the nutrition of rice grain iron obtain high efficiency bio-augmentation, the novel amino foliar nutrient that the rice nutritional quality is significantly improved.
Technical background
The nutrient imbalance problem that iron deficiency causes is present one of human main nutrient health problem that faces in the world.Iron deficiency seriously undermines human immune system's function, hinders health and grows normally.It is reported that surpass the influence that 3,000,000,000 people just are being subjected to iron, zinc nutrition shortage in the world, mainly concentrating on developing country is among the crowd of staple food with rice.In these countries, the school-ager of 40%-45% suffers from anemia, wherein makes an appointment with half owing to iron deficiency causes.The iron nutritional status of population of China allows of no optimist equally.In China especially central and west regions, because of taking in the bad problem ubiquity of human nutrition that iron level is not enough to satisfy the demand and causes in the staple food crop.
On the other hand, along with the raising of people's living standard, and the continuous increase of grain yield, agriculture production is just from being that target changes to the good quality and high output direction with single high yield.Agricultural product quality particularly nutritional quality and health quality comes into one's own day by day.But limited by economic level, China and most of people of developing country are food with vegetable food (mainly being rice, wheat, corn and vegetables) mainly, thus agricultural-food especially vegetable food be the indispensable important source of needed by human nutritive substance and benefit materials.In case when lacking iron, zinc and vitamins and other nutritious components in the product, HUMAN HEALTH will be subjected to direct influence.Therefore, the iron level of raising staple food crop and products thereof is significant to alleviation or the malnutritive problem of elimination human body iron.
Paddy rice is one of important crops in the world, and about 50% population is food with the rice, but rice is low iron, zinc nutrition food, and iron, zinc content on average only have 2mg kg in the polished rice -1With 12mg kg -1And the daily intaking amount of iron, zinc recommendation is 10-15mg and 12-15mg.Therefore, improve rice grain and be iron in the rice, zinc content to improving human body iron, zn deficiencie, it is significant to improve the human health level.
The method that is used at present the nutrition of biological reinforced rice iron in the world mainly contains three kinds: plant breeding, improvement of genes and agronomic measures.Crop species by conventional breeding and Plant Biotechnology seed selection and exploitation iron, zinc nutrition heavy duty detergent and kind are one of important method of strengthening iron, zinc content in the vegetable food such as rice grain, and the research of this respect also enjoys various countries' plant breeding scholar and nutritionist's attention.But conventional breeding is consuming time expensive; Biotechnology research is the expense costliness not only, and the Biosafety problem that thereupon produces remains to be inquired into.Moreover these technology all can not in time satisfy body trace element iron, the zn deficiencie problem that needs to be resolved hurrily, and the problem that the effective iron of soil, zinc under long-term planting high ferro, the zinc kind condition are exhausted is not paid close attention yet.Now, by the farming measure, particularly fertilising method of waiting the nutrient comprehensive management technology to improve iron, zinc content in the vegetable food such as crop kernel is considered to a kind of continuable, safe and solution economy.Existing a large amount of test-results show, not only can improve crop yield by fertilising and crop nutrition content integrated management, and can significantly increase and make trace element (as iron, zinc) content in the object, improve the crop alimentary quality.
Because trace element fertilizers such as iron, zinc are cost-effective method of application easily by soil fixing by the foliar nutrient root outer spraying.The patent of this respect mainly contains composite fertilizer of multi-elements used on plant leaves and manufacturing (application number: CN89104013.7), a kind of foliar nutrient and production method (application number: CN93100095.5) thereof, preparation (the application number: CN93101656.8) of cash crop compound leaf fertilizer series, a kind of liquid plant-foliage fertilizer and preparation method thereof (application number: CN94117723.4), a kind of efficient foliage fertilizer (application number: CN97116233.6), highly effective multielement compound foliage fertilizer and production method (application number: CN200510200235.6), process for competition coordination producing (the application number: CN20051009416.7) of high concentration trace elements leaf fertilizer, a kind of plant-foliage fertilizer (application number: CN200510022755.2), liquid foliage fertilizer and production method (application number: CN200610170959.5) thereof.Existing so far composed of trace elements applied to foliage fertilizer is mainly used in rescuing of plant/crop nutritional deficiency chlorosis symptom, but not good enough or cost is too high is difficult to large scale application because of fertilizer efficiency; Aspect biological reinforced crop kernel iron, zinc content foliar nutrient, yet there are no relevant patent.Therefore, be necessary the efficient reinforcement crop kernel iron of development of new, the trace element fertilizer of zinc nutrition content,, help to correct and prevent human body iron, zinc nutrition shortcoming in order to improving crop kernel iron, zinc nutrition level.
Summary of the invention
The purpose of this invention is to provide a kind of aminoacid foliar fertilizer, (w/v) forms by following material: 20%-50% aminoacids complex, 0%-50% nicotinamide, 10%-20% iron vitriol (FeSO 47H 2O), 10%-20% urea, 5%-10% boric acid, 1%-5% xitix, 1%-5% tensio-active agent Polysorbate 80 (tween 80).
Wherein total amino acid content is at 30-40%% (w/w) in the aminoacids complex, and iron level is at 15-25% (w/w) in the iron vitriol, and the content of boron is at 15-20% (w/w) in the boric acid.
Aminoacids complex comprises L-glutamic acid (GLU), Serine (SER), arginine (ARG), proline(Pro) (PRO), Threonine (THR), aspartic acid (ASP), leucine (LEU), Isoleucine (ILE), Xie Ansuan (VAL), L-Ala (ALA), glycine (GLY), Methionin (LYS), phenylalanine (PHE), Gelucystine (CYS), Histidine (HIS), tyrosine (TYR), methionine(Met) (MET), potassium (K), calcium (Ca), magnesium (Mg), iron (Fe), zinc (Zn), copper (Cu), manganese (Mn).
Require pH5.0-6.0 in the aminoacid foliar fertilizer of the present invention.
Another object of the present invention provides this aminoacid foliar fertilizer in the nutrition of high efficiency bio-augmentation rice grain iron, and significantly promotes in the rice nutritional quality and use.
Using method of the present invention is: after diluting 100-200 times, behind rice anthesis,,, be covered with trickle water droplet but not dirty being advisable with rice leaf in line with principle repeatedly on a small quantity to the filling stage foliage-spray, spray pitch time for twice about 4-7 days, generally spray 3 times or more than.After this fertilizer sprayed, the rice leaf blade tip had the withered a little normal phenomenon that belongs to.
Aminoacid foliar fertilizer provided by the invention (Fe (II)-AA) has following advantage:
1.Fe (II)-the AA fertilizer efficiency is stable.Main component of the present invention is amino acid, ferrous ion (FeSO 47H 2O) and multiple/complex compound of urea, by potted plant and field experiment, Fe (II)-AA can significantly strengthen the nutrition of different genotype rice grain iron, and average energy makes that iron level significantly promotes more than 15% in the polished rice.
2. the rice nutritional quality promotes comprehensively.The rice that sprays Fe (II)-AA not only iron nutrition is significantly strengthened, and in the polished rice other useful in micronutrient levelss such as Ca, Mg, B, Zn, Cu, Mn etc. obvious increase is in various degree all arranged, polished rice protein and aminoacids content also have remarkable lifting.
3.Fe (II)-the AA super quality and competitive price.With blade face iron fertilizer FeSO commonly used 47H 2O compares and has avoided Fe 2+Rapid oxidation, compare low price with Fe (III)-EDTA, be convenient to produce big area and use.
Embodiment
The present invention is further described in conjunction with specific embodiments.
Embodiment 1:
Part is long-pending to be 1 liter aminoacid foliar fertilizer, with the aminoacids complexs of 400 grams, and the iron vitriol (FeSO of 100 grams 47H 2O) at normal temperatures respectively with abundant mixing behind the dissolved in distilled water, add 100 gram urea then, add 50 gram boric acid, add 10 gram xitix, use then fully to mix the back about 0.1% sulphuric acid soln or potassium hydroxide solution regulator solution pH to 5-6 and add 20-50 Polysorbate 80s (tween 80) crop surface promoting agent, get final product to 1 liter with distilled water is fixed through thorough mixing.
Embodiment 2
Part is long-pending to be 1 liter aminoacid foliar fertilizer, with the aminoacids complexs of 500 grams, and the iron vitriol (FeSO of 200 grams 47H 2O) at normal temperatures respectively with abundant mixing behind the dissolved in distilled water, add 200 gram urea then, add 100 gram boric acid, add 50 gram xitix, use then fully to mix the back about 0.1% sulphuric acid soln or potassium hydroxide solution regulator solution pH to 5-6 and add 20-50 Polysorbate 80s (tween 80) crop surface promoting agent, get final product to 1 liter with distilled water is fixed through thorough mixing.
Embodiment 3
Part is long-pending to be 1 liter aminoacid foliar fertilizer, with the aminoacids complexs of 400 grams, and the iron vitriol (FeSO of 200 grams 47H 2O) at normal temperatures respectively with abundant mixing behind the dissolved in distilled water, add 200 gram urea then, add 100 gram boric acid, add 50 gram xitix, use then fully to mix the back about 0.1% sulphuric acid soln or potassium hydroxide solution regulator solution pH to 5-6 and add 20-50 Polysorbate 80s (tween 80) crop surface promoting agent, get final product to 1 liter with distilled water is fixed through thorough mixing.
Embodiment 4
Part is long-pending to be 1 liter aminoacid foliar fertilizer, with the aminoacids complexs of 500 grams, and the iron vitriol (FeSO of 100 grams 47H 2O) at normal temperatures respectively with abundant mixing behind the dissolved in distilled water, add 100 gram urea then, add 50 gram boric acid, add 10 gram xitix, use then fully to mix the back about 0.1% sulphuric acid soln or potassium hydroxide solution regulator solution pH to 5-6 and add 20-50 Polysorbate 80s (tween 80) crop surface promoting agent, get final product to 1 liter with distilled water is fixed through thorough mixing.
Embodiment 5
Part is long-pending to be 1 liter aminoacid foliar fertilizer, with the aminoacids complexs of 300 grams, and 200 gram nicotinamides, the iron vitriol (FeSO of 100 grams 47H 2O) at normal temperatures respectively with abundant mixing behind the dissolved in distilled water, add 100 gram urea then, add 50 gram boric acid, add 10 gram xitix, use then fully to mix the back about 0.1% sulphuric acid soln or potassium hydroxide solution regulator solution pH to 5-6 and add 20-50 Polysorbate 80s (tween 80) crop surface promoting agent, get final product to 1 liter with distilled water is fixed through thorough mixing.
Embodiment 6
Part is long-pending to be 1 liter aminoacid foliar fertilizer, with the aminoacids complexs of 400 grams, and 100 gram nicotinamides, the iron vitriol (FeSO of 100 grams 47H 2O) at normal temperatures respectively with abundant mixing behind the dissolved in distilled water, add 100 gram urea then, add 50 gram boric acid, add 10 gram xitix, use then fully to mix the back about 0.1% sulphuric acid soln or potassium hydroxide solution regulator solution pH to 5-6 and add 20-50 Polysorbate 80s (tween 80) crop surface promoting agent, get final product to 1 liter with distilled water is fixed through thorough mixing.
Embodiment 7
Part is long-pending to be 1 liter aminoacid foliar fertilizer, with the aminoacids complexs of 300 grams, and 100 gram nicotinamides, the iron vitriol (FeSO of 200 grams 47H 2O) at normal temperatures respectively with abundant mixing behind the dissolved in distilled water, add 100 gram urea then, add 50 gram boric acid, add 10 gram xitix, use then fully to mix the back about 0.1% sulphuric acid soln or potassium hydroxide solution regulator solution pH to 5-6 and add 20-50 Polysorbate 80s (tween 80) crop surface promoting agent, get final product to 1 liter with distilled water is fixed through thorough mixing.
Embodiment 8
The aminoacid foliar fertilizer application process: rise at rice anthesis, get by 1 liter of the aminoacid foliar fertilizer of front embodiment configuration, convert behind the water to 100 liter at the crop foliage-spray, a mu consumption is about 50 liters.Select at 5-7 in sunny calm weather afternoon to spray, spray pitch time about 7 days, spray altogether 3 times for twice.
Embodiment 9
The aminoacid foliar fertilizer application process: rise at rice anthesis, get by 1 liter of the aminoacid foliar fertilizer of front embodiment configuration, convert behind the water to 200 liter at the crop foliage-spray, a mu consumption is about 50 liters.Select at 5-7 in sunny calm weather afternoon to spray, spray pitch time about 4 days, spray altogether 4 times for twice.
Aminoacid foliar fertilizer main component provided by the invention is amino acid, ferrous ion (FeSO 47H 2O) and multiple/complex compound of urea, contain and include potassium, calcium, magnesium, boron, zinc, copper, manganese, xitix, tensio-active agent Polysorbate 80s (tween 80) etc. are transferred pH4.0-6.0.The composition of aminoacids complex sees Table 1.
Table 1 aminoacids complex composition
Figure A200810121186D00071
Figure A200810121186D00081

Claims (6)

1. an aminoacid foliar fertilizer is characterized in that being made up of with the per-cent of w/v following material: 20%-50% aminoacids complex, 1%-50% nicotinamide, 10%-20% iron vitriol, 10%-20% urea, 5%-10% boric acid, 1%-5% xitix, 1%-5% tensio-active agent Polysorbate 80.
2. a kind of aminoacid foliar fertilizer according to claim 1, it is characterized in that: the content of total amino acid w/w is at 30-40%% in the described aminoacids complex, the content of iron w/w is at 15-25% in the described iron vitriol, and the content of boron w/w is at 15-20% in the described boric acid.
3. a kind of aminoacid foliar fertilizer according to claim 1 is characterized in that: aminoacids complex is selected L-glutamic acid, Serine, arginine, proline(Pro), Threonine, aspartic acid, leucine, Isoleucine, Xie Ansuan, L-Ala, glycine, Methionin, phenylalanine, Gelucystine, Histidine, tyrosine, methionine(Met), potassium, calcium, magnesium, iron, zinc, copper, manganese for use.
4. a kind of aminoacid foliar fertilizer according to claim 1 is characterized in that: require pH5.0-6.0 in the described aminoacid foliar fertilizer.
5. the described a kind of aminoacid foliar fertilizer of claim 1 reaches to promote in the rice nutritional quality and uses in the nutrition of biological reinforced rice grain iron.
6. the application of a kind of aminoacid foliar fertilizer according to claim 5, it is characterized in that using method is: after 100-200 times of aminoacid foliar fertilizer dilutions, behind rice anthesis to the filling stage foliage-spray, be covered with trickle water droplet but not dirty being advisable with rice leaf, spray pitch time for twice at 4-7 days, spray number of times and be 3 times or more than.
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CN103708920A (en) * 2013-12-10 2014-04-09 济南凯因生物科技有限公司 Foliar fertilizer
CN103880480A (en) * 2014-01-15 2014-06-25 华侨大学 Special amino-acid organic nutrient fertilizer for tieguanyin tea plants and preparation method thereof
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CN107445747A (en) * 2016-05-31 2017-12-08 肖范 A kind of fertilizer for preventing and treating foliar pest and preparation method thereof
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CN109053258A (en) * 2018-09-05 2018-12-21 合肥绿农肥业有限责任公司 A kind of foliar fertilizer and its application method improving crisp pears quality
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CN109704870A (en) * 2019-03-05 2019-05-03 郑州普天农业科技发展有限公司 A kind of nucleosides polypeptide amino acid multifunctional bio fertilizer and its preparation method and application
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CN102461410A (en) * 2010-11-14 2012-05-23 恩施济源药业科技开发有限公司 Selenium-enriched Angelica sinensis(oliv.) Diels production method
CN102320892A (en) * 2011-09-30 2012-01-18 浙江师范大学 The rich zinc foliage fertilizer of fruit tree
CN103708920A (en) * 2013-12-10 2014-04-09 济南凯因生物科技有限公司 Foliar fertilizer
CN103708920B (en) * 2013-12-10 2015-10-28 顾祥茂 Foliar nutrient
CN103880480A (en) * 2014-01-15 2014-06-25 华侨大学 Special amino-acid organic nutrient fertilizer for tieguanyin tea plants and preparation method thereof
CN104058859A (en) * 2014-06-25 2014-09-24 合肥路飞农业科技有限公司 Plant leaf fertilizer
CN105110968A (en) * 2015-09-16 2015-12-02 山东劲脉生物技术有限公司 Efficient foliar fertilizer and preparation method thereof
CN107445747A (en) * 2016-05-31 2017-12-08 肖范 A kind of fertilizer for preventing and treating foliar pest and preparation method thereof
CN108658654A (en) * 2017-03-28 2018-10-16 许昌学院 A kind of citrus compound foliar fertilizer special and preparation method thereof
CN109053258A (en) * 2018-09-05 2018-12-21 合肥绿农肥业有限责任公司 A kind of foliar fertilizer and its application method improving crisp pears quality
CN109320357A (en) * 2018-11-28 2019-02-12 湖南农业大学 A kind of foliar fertilizer and its preparation and method of administration promoting grape fruit coloring
CN109704870A (en) * 2019-03-05 2019-05-03 郑州普天农业科技发展有限公司 A kind of nucleosides polypeptide amino acid multifunctional bio fertilizer and its preparation method and application
CN109942329A (en) * 2019-05-06 2019-06-28 淮海工学院 A kind of Porphyra yezoensis foliar nutrition hardening agent and its application method
US20220369569A1 (en) * 2019-06-17 2022-11-24 Showa Denko K.K. Plant activator containing amino acid or salt thereof, and oligosaccharide, and use thereof
KR102124585B1 (en) * 2019-10-11 2020-06-18 엄세용 manufacturing method of fermented amino acid fertilizer and fermented amino acid fertilizer manufactured by the method
CN114667896A (en) * 2022-05-11 2022-06-28 河南省农业科学院粮食作物研究所 High-yield and high-efficiency cultivation method for zinc-rich summer corn grains

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