CN101244843A - 从氧化钇稳定氧化锆固熔体废物中回收氧化锆及氧化钇的方法 - Google Patents
从氧化钇稳定氧化锆固熔体废物中回收氧化锆及氧化钇的方法 Download PDFInfo
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- CN101244843A CN101244843A CNA2008100735017A CN200810073501A CN101244843A CN 101244843 A CN101244843 A CN 101244843A CN A2008100735017 A CNA2008100735017 A CN A2008100735017A CN 200810073501 A CN200810073501 A CN 200810073501A CN 101244843 A CN101244843 A CN 101244843A
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- zirconium
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- 238000000034 method Methods 0.000 title claims abstract description 27
- 239000002699 waste material Substances 0.000 title claims abstract description 15
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 title claims description 26
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 title claims description 6
- 229910001928 zirconium oxide Inorganic materials 0.000 title claims description 6
- 239000007787 solid Substances 0.000 title description 4
- 238000004064 recycling Methods 0.000 title description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 38
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 23
- 239000012452 mother liquor Substances 0.000 claims abstract description 20
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 20
- 239000006104 solid solution Substances 0.000 claims abstract description 18
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000843 powder Substances 0.000 claims abstract description 13
- 238000001354 calcination Methods 0.000 claims abstract description 12
- 239000000243 solution Substances 0.000 claims abstract description 12
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims abstract description 11
- 235000011130 ammonium sulphate Nutrition 0.000 claims abstract description 11
- IVORCBKUUYGUOL-UHFFFAOYSA-N 1-ethynyl-2,4-dimethoxybenzene Chemical compound COC1=CC=C(C#C)C(OC)=C1 IVORCBKUUYGUOL-UHFFFAOYSA-N 0.000 claims abstract description 10
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 claims abstract description 10
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 claims abstract description 9
- IBSDADOZMZEYKD-UHFFFAOYSA-H oxalate;yttrium(3+) Chemical compound [Y+3].[Y+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O IBSDADOZMZEYKD-UHFFFAOYSA-H 0.000 claims abstract description 7
- 150000003839 salts Chemical class 0.000 claims abstract description 7
- 238000002386 leaching Methods 0.000 claims abstract description 6
- 239000006227 byproduct Substances 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims description 25
- 239000013078 crystal Substances 0.000 claims description 18
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 15
- 239000000047 product Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- 239000002671 adjuvant Substances 0.000 claims description 8
- 230000020477 pH reduction Effects 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- DEXZEPDUSNRVTN-UHFFFAOYSA-K yttrium(3+);trihydroxide Chemical compound [OH-].[OH-].[OH-].[Y+3] DEXZEPDUSNRVTN-UHFFFAOYSA-K 0.000 claims description 6
- GNKHOVDJZALMGA-UHFFFAOYSA-N [Y].[Zr] Chemical compound [Y].[Zr] GNKHOVDJZALMGA-UHFFFAOYSA-N 0.000 claims description 5
- 239000012141 concentrate Substances 0.000 claims description 5
- 238000001556 precipitation Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000002425 crystallisation Methods 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 239000002910 solid waste Substances 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 230000008020 evaporation Effects 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- 239000012065 filter cake Substances 0.000 claims description 3
- 238000006386 neutralization reaction Methods 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 230000008025 crystallization Effects 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 238000000746 purification Methods 0.000 claims description 2
- -1 yttrium ion Chemical class 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract description 2
- 230000001376 precipitating effect Effects 0.000 abstract 4
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 abstract 3
- 230000003472 neutralizing effect Effects 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 9
- 229910052742 iron Inorganic materials 0.000 description 9
- 238000011084 recovery Methods 0.000 description 9
- 239000010987 cubic zirconia Substances 0.000 description 5
- 229910052761 rare earth metal Inorganic materials 0.000 description 4
- 150000002910 rare earth metals Chemical class 0.000 description 4
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000010437 gem Substances 0.000 description 3
- 229910001751 gemstone Inorganic materials 0.000 description 3
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- 229910052845 zircon Inorganic materials 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 241001062472 Stokellia anisodon Species 0.000 description 1
- 229910006501 ZrSiO Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
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- 229910052802 copper Inorganic materials 0.000 description 1
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- 238000005260 corrosion Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- KAQHZJVQFBJKCK-UHFFFAOYSA-L potassium pyrosulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OS([O-])(=O)=O KAQHZJVQFBJKCK-UHFFFAOYSA-L 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
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- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
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CN2008100735017A CN101244843B (zh) | 2008-03-18 | 2008-03-18 | 从氧化钇稳定氧化锆固熔体废物中回收氧化锆及氧化钇的方法 |
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CN2008100735017A CN101244843B (zh) | 2008-03-18 | 2008-03-18 | 从氧化钇稳定氧化锆固熔体废物中回收氧化锆及氧化钇的方法 |
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Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102531588A (zh) * | 2012-03-03 | 2012-07-04 | 赣州虔东稀土集团股份有限公司 | 回收氧化锆陶瓷磨削加工废料制备氧化锆陶瓷的方法 |
CN102583491A (zh) * | 2012-02-15 | 2012-07-18 | 淄博市周村磊宝耐火材料有限公司 | 从宝石废料和/或陶瓷废料中制取高纯氧化钇的方法 |
CN102583532A (zh) * | 2011-06-15 | 2012-07-18 | 淄博市周村磊宝耐火材料有限公司 | 从锆刚玉废砖中提纯制取高纯氧化锆的方法 |
CN102826601A (zh) * | 2011-06-15 | 2012-12-19 | 淄博市周村磊宝耐火材料有限公司 | 从脱硅锆中提纯制取高纯氧化锆的方法 |
CN103253702A (zh) * | 2012-02-15 | 2013-08-21 | 淄博市周村磊宝耐火材料有限公司 | 从锆废砖中提纯制取高纯氧化锆的方法 |
CN103253700A (zh) * | 2012-02-15 | 2013-08-21 | 淄博市周村磊宝耐火材料有限公司 | 从锆英砂中提纯制取高纯氧化锆的方法 |
CN103253701A (zh) * | 2012-02-15 | 2013-08-21 | 淄博市周村磊宝耐火材料有限公司 | 从斜锆石中提纯制取高纯氧化锆的方法 |
CN103539203A (zh) * | 2013-11-04 | 2014-01-29 | 李树昌 | 从含锆固体废物中制取二氧化锆的方法 |
CN103553128A (zh) * | 2013-10-21 | 2014-02-05 | 江西赛瓷材料有限公司 | 氧化钪稳定氧化锆烧结体中氧化钪、氧化锆的回收方法 |
CN104185606A (zh) * | 2011-12-07 | 2014-12-03 | 齐龙工业陶瓷公司 | 使稀土和氧化锆材料再循环的方法 |
CN104651619A (zh) * | 2015-03-17 | 2015-05-27 | 湖南东方钪业股份有限公司 | 含有钪及稀土稳定的氧化锆陶瓷废料中分离回收钪的方法 |
CN105036739A (zh) * | 2015-08-31 | 2015-11-11 | 山东磊宝锆业科技股份有限公司 | 用钇稳定氧化锆固体废料制备锆钇和锆铝复合粉体的方法 |
CN105140504A (zh) * | 2015-08-11 | 2015-12-09 | 东北大学 | 一种利用提钒弃渣制备锂电池电极材料的方法 |
CN105369393A (zh) * | 2014-08-12 | 2016-03-02 | 山东宏瑞超高温纤维科技有限公司 | 一种氧化锆陶瓷纤维的制备方法 |
CN107377867A (zh) * | 2017-08-22 | 2017-11-24 | 汉川市石金科技有限公司 | 一种铸钢涂料及其制备方法 |
CN108002441A (zh) * | 2017-12-20 | 2018-05-08 | 山东磊宝锆业科技股份有限公司 | 从脱硅锆中提纯制取高纯四水硫酸锆的方法 |
CN108083332A (zh) * | 2017-12-25 | 2018-05-29 | 山东磊宝锆业科技股份有限公司 | 一种用固体废锆制备氧化锆的方法 |
CN108083333A (zh) * | 2017-12-25 | 2018-05-29 | 山东磊宝锆业科技股份有限公司 | 一种利用固体废锆制备锆铝复合粉体的方法 |
CN112110726A (zh) * | 2020-09-24 | 2020-12-22 | 郑州方铭高温陶瓷新材料有限公司 | 废旧炉衬的钇稳定氧化锆砖的回收利用分离方法 |
-
2008
- 2008-03-18 CN CN2008100735017A patent/CN101244843B/zh active Active
Cited By (24)
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CN102583532A (zh) * | 2011-06-15 | 2012-07-18 | 淄博市周村磊宝耐火材料有限公司 | 从锆刚玉废砖中提纯制取高纯氧化锆的方法 |
CN102826601A (zh) * | 2011-06-15 | 2012-12-19 | 淄博市周村磊宝耐火材料有限公司 | 从脱硅锆中提纯制取高纯氧化锆的方法 |
CN104185606A (zh) * | 2011-12-07 | 2014-12-03 | 齐龙工业陶瓷公司 | 使稀土和氧化锆材料再循环的方法 |
CN102583491A (zh) * | 2012-02-15 | 2012-07-18 | 淄博市周村磊宝耐火材料有限公司 | 从宝石废料和/或陶瓷废料中制取高纯氧化钇的方法 |
CN103253702A (zh) * | 2012-02-15 | 2013-08-21 | 淄博市周村磊宝耐火材料有限公司 | 从锆废砖中提纯制取高纯氧化锆的方法 |
CN103253700A (zh) * | 2012-02-15 | 2013-08-21 | 淄博市周村磊宝耐火材料有限公司 | 从锆英砂中提纯制取高纯氧化锆的方法 |
CN103253701A (zh) * | 2012-02-15 | 2013-08-21 | 淄博市周村磊宝耐火材料有限公司 | 从斜锆石中提纯制取高纯氧化锆的方法 |
CN103253702B (zh) * | 2012-02-15 | 2016-01-27 | 山东磊宝锆业科技股份有限公司 | 从锆废砖中提纯制取高纯氧化锆的方法 |
CN102531588A (zh) * | 2012-03-03 | 2012-07-04 | 赣州虔东稀土集团股份有限公司 | 回收氧化锆陶瓷磨削加工废料制备氧化锆陶瓷的方法 |
CN103553128B (zh) * | 2013-10-21 | 2015-09-30 | 湖北工业大学 | 氧化钪稳定氧化锆烧结体中氧化钪、氧化锆的回收方法 |
CN103553128A (zh) * | 2013-10-21 | 2014-02-05 | 江西赛瓷材料有限公司 | 氧化钪稳定氧化锆烧结体中氧化钪、氧化锆的回收方法 |
CN103539203B (zh) * | 2013-11-04 | 2014-11-05 | 李树昌 | 从含锆固体废物中制取二氧化锆的方法 |
CN103539203A (zh) * | 2013-11-04 | 2014-01-29 | 李树昌 | 从含锆固体废物中制取二氧化锆的方法 |
CN105369393A (zh) * | 2014-08-12 | 2016-03-02 | 山东宏瑞超高温纤维科技有限公司 | 一种氧化锆陶瓷纤维的制备方法 |
CN104651619A (zh) * | 2015-03-17 | 2015-05-27 | 湖南东方钪业股份有限公司 | 含有钪及稀土稳定的氧化锆陶瓷废料中分离回收钪的方法 |
CN105140504B (zh) * | 2015-08-11 | 2018-02-02 | 东北大学 | 一种利用提钒弃渣制备锂电池电极材料的方法 |
CN105140504A (zh) * | 2015-08-11 | 2015-12-09 | 东北大学 | 一种利用提钒弃渣制备锂电池电极材料的方法 |
CN105036739A (zh) * | 2015-08-31 | 2015-11-11 | 山东磊宝锆业科技股份有限公司 | 用钇稳定氧化锆固体废料制备锆钇和锆铝复合粉体的方法 |
CN107377867A (zh) * | 2017-08-22 | 2017-11-24 | 汉川市石金科技有限公司 | 一种铸钢涂料及其制备方法 |
CN107377867B (zh) * | 2017-08-22 | 2019-10-18 | 汉川市石金科技有限公司 | 一种铸钢涂料及其制备方法 |
CN108002441A (zh) * | 2017-12-20 | 2018-05-08 | 山东磊宝锆业科技股份有限公司 | 从脱硅锆中提纯制取高纯四水硫酸锆的方法 |
CN108083332A (zh) * | 2017-12-25 | 2018-05-29 | 山东磊宝锆业科技股份有限公司 | 一种用固体废锆制备氧化锆的方法 |
CN108083333A (zh) * | 2017-12-25 | 2018-05-29 | 山东磊宝锆业科技股份有限公司 | 一种利用固体废锆制备锆铝复合粉体的方法 |
CN112110726A (zh) * | 2020-09-24 | 2020-12-22 | 郑州方铭高温陶瓷新材料有限公司 | 废旧炉衬的钇稳定氧化锆砖的回收利用分离方法 |
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