CN1012187B - Fabric with fire-proof, water proof, and fungicidal properties - Google Patents
Fabric with fire-proof, water proof, and fungicidal propertiesInfo
- Publication number
- CN1012187B CN1012187B CN 88102761 CN88102761A CN1012187B CN 1012187 B CN1012187 B CN 1012187B CN 88102761 CN88102761 CN 88102761 CN 88102761 A CN88102761 A CN 88102761A CN 1012187 B CN1012187 B CN 1012187B
- Authority
- CN
- China
- Prior art keywords
- grams per
- fabric
- per liter
- per liters
- waterproof
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a fireproof waterproof mildewproof fabric. Grey cloth is immersed, rolled, dried and baked by a fireproof waterproof mildewproof composition which is composed of 90 to 100 grams per liter of diammonium hydrogen phosphate, 40 to 50 grams per liter of ammonium biphosphate, 180 to 200 grams per liter of carbamide, 8 to 9 grams per liter of hexamethylolmelamine, 84 to 95 grams per liter of a waterproof agent (EM or AC), 15 to 20 grams per liter of polyvinyl alcohol, 15 to 20 grams per liter of antimonous oxide, 1 gram per liter of a penetrating agent (JFC) and a proper amount of water to manufacture the fireproof waterproof mildewproof fabric after desizing, scouring, bleaching and drying are carried out. The fabric has the advantages of no poison, no abnormal flavor and insensitivity for the skin, and furthermore, the fabric can be manufactured into various kinds of clothes.
Description
The present invention relates to be used to prevent fires, the fabric of waterproof and mildew-resistant.
Comprise China at present in the world, owing to the catch fire fire ratio that causes of textiles is quite big, therefore the demand to flame-retardant textile increases gradually, but some fabric is usually prevented fires again, waterproof is also wanted mildew-resistant, therefore needs multi-functional fabric make various products.Various fire retardants are also arranged in the prior art, though this fire retardant often also can waterproof or mildew-resistant, but the fabric that can reach good fire prevention, waterproof and fungicidal properties simultaneously is still few, and some fire retardant contains for example poisonous substance of hydrogen phosphide and so on, is unsuitable for using.
The object of the invention is to provide a kind of nontoxic nothing that has good fire prevention, waterproof and mildew-resistant simultaneously to smell fabric.
Study for many years through the inventor, with the grey cloth destarch, use by diammonium hydrogen phosphate 90～100 grams per liters after floating refining and oven dry, ammonium dihydrogen phosphate (ADP) 40～50 grams per liters, urea 180～200 grams per liters, hexamethylolmelamine 8～9 grams per liters, waterproofing agent (EM or AC) 84～95 grams per liters, polyvinyl alcohol 15～20 grams per liters, the fire prevention that antimonous oxide 15～20 grams per liters and bleeding agent (JFC) 1 grams per liter and suitable quantity of water are formed, waterproof and mildew-resistant composition (three anti-compositions) pad, drying is made fire prevention with baking again, waterproof and mildew-resistant fabric (protective cloth), the above object has reached fully.
Now protective cloth of the present invention is elaborated.
Grey cloth itself is because cotton yarn starching once, so grey cloth also is being with and starches, and is for making its dipping that can stand three anti-compositions, just available after the destarch.But therefore grey cloth jaundice after the destarch bleaches grey cloth with floating the refining operation again, dries in 60～80 ℃ of drying chambers subsequently, and promptly the three anti-compositions of forming with following component flood and rolling (abbreviate as and pad):
Diammonium hydrogen phosphate 90～100 grams per liters, ammonium dihydrogen phosphate (ADP) 40～50 grams per liters, urea 180～200 grams per liters, hexamethylolmelamine 8.0～8.5 grams per liters, waterproofing agent (EM or AC) 84～95 grams per liters, polyvinyl alcohol 15～20 grams per liters, antimonous oxide 15～20 grams per liters, bleeding agent (JFC) 0.5～1 grams per liter and suitable quantity of water.
Behind dipping said three anti-compositions promptly in the middle of a pair roller by carrying out pressure rolling, wherein contained excessive moisture is squeezed out, in 60～80 ℃ drying chamber, dry subsequently, promptly make protective cloth after baking in that 120 ℃ bake is indoor.
So it is because added the material that can suppress the fabric combustion process that protective cloth of the present invention can be prevented fires, thereby reach fire-retardant purpose, so it is because changed the decomposable process of fabric in combustion process that combustion process is suppressed, the material that slows down decomposition rate and change to decompose produce is formed, and it is emitted do not fire, difficult combustion or the lower gas of burning degree.Diammonium hydrogen phosphate and ammonium dihydrogen phosphate (ADP) all are nonoxidizing salt, they can play the effect that changes the fabric combustion process, form melt simultaneously and be enclosed in fabric face in reaction, thereby fabric and air are completely cut off, hinder the transmission of heat, impel a fabric carbonization and polot flame not.When ammonium dihydrogen phosphate (ADP) can make fabric in impregnated in said three anti-compositions with said composition in bleeding agent (JFC) effect of etc.ing and discharge o-phenyl phenol, it makes the fabric generation expanded, and the promotion medicine fully soaks into fabric.
Phosphate itself just has the effect of fungus and mildew resistance, and phosphate is again good pesticide, so the adding of diammonium hydrogen phosphate and ammonium dihydrogen phosphate (ADP) can be prevented fires and mildew-resistant.
The consumption of diammonium hydrogen phosphate in three anti-compositions is 90 grams per liters for flimsy material, and as then can be 100 grams per liters for heavy weaves such as canvas, it is poor to measure the mildew-resistant efficient of then preventing fires less than this, if then easily make fabric tendering greater than 100 grams per liters.Ammonium dihydrogen phosphate (ADP) still is a kind of good catalyst, and addition hardens fabric less than 40 grams per liters poor effect then greater than 50 grams per liters.
As for urea, it plays three kinds of effects: (1) has good dissolving power, all help solubilization for insoluble medicament such as hexamethylolmelamine and polyvinyl alcohol; (2) urea is good hygroscopic agent, and hygroscopic capacity is 2.44%, so can promote the swelling of fiber of fabric, improves impregnability; (3) urea is baking middle decomposes, generates ammonia, and ammonia can make medicine be fixed in the fiber of fabric.The addition of urea should not be greater than 200 grams per liters, and as greater than this amount, then the finished product fabric becomes damp, and is unsuitable for dress.
Hexamethylolmelamine is as mildewproof additive, be used with waterproofing agent (EM or AC), can not add separately, the waterproofing agent addition is advisable at 84～95 grams per liters, then stable bad greater than 95 grams per liters, less than 84 grams per liters poor effect then, the addition of hexamethylolmelamine adapts with it, surpasses 9 grams per liters and then acts on not quite.
Polyvinyl alcohol is used for the medicament skinning, and then skinning is bad less than 15 grams per liters, can not use greater than 20 grams per liters then make three anti-composition knot jails.
It is better that antimonous oxide is used for adding in heavy weave such as the canvas flameproof effect, is penetrated in the fabric gap behind it and the polyvinyl alcohol gum deposit, makes heavy weave be difficult for carbonization when 800 ℃ of burnings.
The effect of bleeding agent (JFC) is to make other medicament be easy to be penetrated in the fabric, and addition 0.5～1 grams per liter is advisable, if add excessive their difficult infiltrations in the fabric that then make on the contrary.
Fabric is through drying in 60～80 ℃ of drying chambers after padding operation, bakes in that 200 ℃ bake is indoor again, promptly makes the fabric of fire prevention, waterproof and mildew-resistant.
Waterproofing agent (EM or AC) and bleeding agent (JFC) all are the general chemistry medicaments, can buy on market.
Through the tissue test of Puqi City Economic and Trade Commission, use 45 ℃ of test methods of Bunsen burner, surplus combustion is 0 second, long 10～12 millimeters of carbonization, 12 seconds burning times, the good hand touch after the fabric treating does not have toxicity, intensity allows to reduce by 15%, and anti-combustion temperature is 800～850 ℃, and the time of glowing is 0 second.
In waterproof test, soak into running water flushing, nothing.
In fungus-proof test, in the season of 18～20 ℃ of Puqi Cities, common fabric and protective cloth finished product be packaged in deposited in the warehouse three months, not send out mashed after opening bag through the common cloth mildew of three anti-compositions-treated, protective cloth of the present invention is then in good health.
Fire prevention of the present invention, waterproof and mildew-resistant fabric have fire prevention, waterproof, the multiple function of mildew-resistant, particularly nontoxic free from extraneous odour, skin is insensitive to it, therefore except that military, in civilian, also account for critical positions, can do fire-entry suit, for the Work Clothes of smelting, casting, forging, welding worker, tent, yurt, mailbag etc. are used cloth, and be respond well.In addition, the present invention's fire prevention, waterproof and mildew-resistant composition can also be used for eider down chemical fibre, carpet, also can play fire prevention, waterproof and mildew-proof function.
Claims (1)
1, fire prevention, waterproof and mildew-resistant fabric, it is characterized in that, used fire prevention, waterproof and mildew-resistant composition are by diammonium hydrogen phosphate 90～100 grams per liters, ammonium dihydrogen phosphate (ADP) 40～50 grams per liters, urea 180～200 grams per liters, hexamethylolmelamine 8～9 grams per liters, waterproofing agent (EM or AC) 84～95 grams per liters, polyvinyl alcohol 15～20 grams per liters, antimonous oxide 15～20 grams per liters and bleeding agent (JFC) 1 grams per liter, and surplus is that water is formed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88102761 CN1012187B (en) | 1988-05-13 | 1988-05-13 | Fabric with fire-proof, water proof, and fungicidal properties |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88102761 CN1012187B (en) | 1988-05-13 | 1988-05-13 | Fabric with fire-proof, water proof, and fungicidal properties |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1037556A CN1037556A (en) | 1989-11-29 |
| CN1012187B true CN1012187B (en) | 1991-03-27 |
Family
ID=4832293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 88102761 Expired CN1012187B (en) | 1988-05-13 | 1988-05-13 | Fabric with fire-proof, water proof, and fungicidal properties |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1012187B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR0117202A (en) * | 2001-12-19 | 2004-12-14 | 3M Innovative Properties Co | Aqueous composition, method for treating a fibrous substrate and fibrous substrate |
| CN102162188A (en) * | 2011-01-10 | 2011-08-24 | 郑州大学 | Method for finishing flame retardant cotton fabric |
| CN102851960A (en) * | 2012-09-20 | 2013-01-02 | 昆山市周市斐煌服饰厂 | Production method of fireproof mould-proof fabric |
| CN102851764A (en) * | 2012-09-20 | 2013-01-02 | 昆山市周市斐煌服饰厂 | Weaving method of fireproof and mildewproof fabric |
| CN103696240A (en) * | 2013-11-29 | 2014-04-02 | 顾德华 | Flame-retardant finishing method of cotton packaging material |
| CN103790005A (en) * | 2013-11-30 | 2014-05-14 | 常熟市亚欧进出口贸易有限公司 | Method for producing fireproof mildew-proof shell fabric |
| CN104499268A (en) * | 2014-12-23 | 2015-04-08 | 常熟市中宏针织厂 | Linen fabric finishing process |
| CN105297445A (en) * | 2015-12-07 | 2016-02-03 | 常熟市华谊织造有限公司 | After-finishing process of real silk fabric |
| CN109842845B (en) * | 2017-11-29 | 2021-01-08 | 大原博 | Method for manufacturing loudspeaker vibrating piece by using desized original cloth |
-
1988
- 1988-05-13 CN CN 88102761 patent/CN1012187B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CN1037556A (en) | 1989-11-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C13 | Decision | ||
| GR02 | Examined patent application | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 410007 No. 58, Shaoshan Road, Hunan, Changsha Applicant after: Changsha printing and dyeing mill Address before: No. 25 Chengbei Road, Hubei, Puqi Applicant before: Chen Shengcai |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: CHEN SHENGCAI TO: CHANGSHA PRINTING FACTORY |
|
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |