CN104855399A - Insecticidal combination containing butene-fipronil and fluorine benzene worm amide - Google Patents
Insecticidal combination containing butene-fipronil and fluorine benzene worm amide Download PDFInfo
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- CN104855399A CN104855399A CN201510224522.4A CN201510224522A CN104855399A CN 104855399 A CN104855399 A CN 104855399A CN 201510224522 A CN201510224522 A CN 201510224522A CN 104855399 A CN104855399 A CN 104855399A
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- fipronil
- butene
- insect amide
- fluorobenzene insect
- rice
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Abstract
The invention discloses insecticidal combination containing butene-fipronil and fluorine benzene worm amide. The insecticidal combination containing butene-fipronil and fluorine benzene worm amide comprises commonly used additive, butene-fipronil and fluorine benzene worm amide, the weight part ratio of the butene-fipronil and fluorine benzene worm amide is 1: 5 to 5: 1, and the weight percentage of the ratio of total weight of the butene-fipronil and fluorine benzene worm amide in the insecticidal combination is 1-80%; the insecticidal combination is used for preventing rice-stem borer and rice leaf folder; the insecticidal combination is superior to single dosage on quickly available performance and persistent effect performance, and the dosage of pesticide is reduced, the medicine use cost is reduced, and the insecticidal combination is good for environmental protection and comprehensive control of agricultural pests.
Description
Technical field
The present invention relates to agricultural insecticide composition and application thereof, specifically a kind of Pesticidal combination that is active ingredient with butene-fipronil and fluorobenzene insect amide, is applied to water prevention chilo suppressalis and rice leaf roller.
Background technology
Butene-fipronil, English name: flufiprole, butene-fipronil is a kind of Phenylpyrazole insecticides, insecticidal spectrum is wide, to insect based on stomach poison function, have concurrently and tag and certain systemic action, its mechanism of action is the chloride metabolism hindering insect γ-aminobutyric acid to control, efficient to various pests such as the snout moth's larva of rice, snout moth's larva, vegetables lepidoptera pests.
Fluorobenzene insect amide, English name: flubendiamide, fluorobenzene insect amide belongs to Novel ortho benzenedicarboxamide insecticides, by activating ryanodine receptor calcium release passage, cause the runaway release of calcium ion of storing, insect twitches dead, all has good activity to nearly all Lepidoptera class pest, not only have excellent activity to adult and larva, and speed of action is fast, the lasting period is long.
The snout moth's larva of rice belongs to lepidoptera pest, mainly based on striped rice borer and rice leaf roller harm.In rice plant of tillering stage, harm causes the withered sheath of paddy rice, withered heart seedling to striped rice borer, causes insect bite strain and dead ears in rice earing stage harm.Rice leaf roller to be caused harm paddy rice with larva, sews leaf and becomes vertical bud, hide and wherein take food epicuticle and mesophyll, only stay white lower epidermis.Be injured seedling stage and affect paddy rice normal growth, even withered; Tillering stage was injured to the shooting stage, minimizing of tillering, and plant shortens, and breeding time postpones; After booting, particularly heading is killed to full heading time sword-like leave, and impact is blossomed and beared fruit, and Empty grain rate improves, and thousand kernel weight declines.
Different pesticide species composition carries out composite, is the common methods of preventing and treating agriculture resistant insect.The present inventor is on the basis of a large amount of indoor virulences and field medicine effect test, the compounded formula screening of butene-fipronil and fluorobenzene insect amide is conducted in-depth research, find that butene-fipronil and fluorobenzene insect amide carry out composite, in certain proportion, there is obvious synergistic function, and to the snout moth's larva of rice, there is outstanding control efficiency, after further study, the present invention is completed.
Summary of the invention
The technical problem that the present invention solves be to provide a kind of efficient, low toxicity and the lasting period long, effectively can prevent and treat crops Lepidoptera class pest, be conducive to the Pesticidal combination containing butene-fipronil and fluorobenzene insect amide of integrated pest management.
For solving the problem, the technical solution adopted in the present invention is: a kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide, comprise usual auxiliaries, butene-fipronil and fluorobenzene insect amide, the ratio of weight and number of butene-fipronil and fluorobenzene insect amide is 1:5-5:1, and butene-fipronil and the percentage by weight of fluorobenzene insect amide weight summation in Pesticidal combination are 1%-80%.
Preferably, butene-fipronil and the percentage by weight of fluorobenzene insect amide weight summation in Pesticidal combination are 10-60%.
Described Pesticidal combination according to well known to a person skilled in the art method, can be mixed with the application forms of the applicable agricultural uses such as suspending agent, water dispersible granules, aqueous emulsion, microemulsion, wetting powder.
Described Pesticidal combination is also containing the usual auxiliaries of preparation needed for pesticidal preparations, usual auxiliaries is the mixing of one or more in solvent, emulsifier, wetting agent, stabilizing agent, dispersant, thickener, pH adjusting agent, defoamer, antifreezing agent, packing agent etc., be known substance, various auxiliary agents conventional in pesticidal preparations, can change to some extent according to different situations, be not particularly limited.
The application of described Pesticidal combination, for preventing and treating crop pests, main water prevention chilo suppressalis and rice leaf roller.
Pesticidal combination provided by the invention, usually adopts the method for spraying to use, also can adopt other operation techniques agriculturally applied as required.
Compared with prior art, the invention has the advantages that:
1, butene-fipronil and fluorobenzene insect amide is composite has beyond thought synergistic function, is used alone the control efficiency that improve insect and germ than single dose;
2, butene-fipronil and the fluorobenzene insect amide mechanism of action different, mixed can delay insect and the drug-fast generation of germ;
3, butene-fipronil and fluorobenzene insect amide two kinds of active ingredients composite, decrease Pesticide use amount, reduce use cost and alleviate pollution to environment.
Embodiment
In order to understand essence of the present invention better, below in conjunction with embodiment, content of the present invention is described further, but can not be considered as limitation of the present invention, content mentioned in embodiment is not limitation of the invention, material prescription is selected to suit measures to local conditions and on result without substantial impact.In these embodiments, unless otherwise indicated, all percentage is all weight percentage.
Example of formulations 1: described Pesticidal combination is suspending agent, and each component percentages is respectively:
Concrete operation step is: first mixed by other auxiliary agent, and in clipper, shear-mixed is even, then adds active ingredient, in ball crusher, grinds 2-3h, make a diameter all at below 5mm, can obtain Pesticidal combination aqueous suspension formulations of the present invention.
Example of formulations 2: described Pesticidal combination is aqueous emulsion, and each component percentages is respectively:
Concrete operation step is: first active ingredient, solvent, emulsifier are mixed, and dissolves and becomes uniform oil phase.Again part water and other auxiliary agents are mixed, dissolve and become uniform aqueous phase.Then oil phase is added aqueous phase while high-speed stirred in a kettle., slowly add water to and reach phase inversion point, carry out high speed shear afterwards, and add remaining water, shear about 30min, Pesticidal combination aqueous emulsion preparation of the present invention can be obtained.
Example of formulations 3: described Pesticidal combination is microemulsion, and each component percentages is respectively:
Concrete operation step is: active ingredient solvent and cosolvent are dissolved completely, and then adds other auxiliary agent, mixes, finally adds water, after fully stirring, can obtain Pesticidal combination microemulsion formulation of the present invention.
Example of formulations 4: described Pesticidal combination is wetting powder, and each component percentages is respectively:
Concrete operation step is: active ingredient, other auxiliary agent and filler are mixed, fully stir in stirred tank, mixes, can obtain Pesticidal combination wettable powder formulation of the present invention after airslide disintegrating mill is pulverized.
Example of formulations 5: described Pesticidal combination is water dispersible granules, and each component percentages is respectively:
Concrete operation step is: active ingredient, other auxiliary agent and filler are mixed, pulverize with micro jet, add after mediating after carrying out granulation, drying, screening in fluidized-bed granulation dryer, Pesticidal combination water-dispersible grain agent formulation of the present invention can be obtained.
In above formulation, auxiliary agent is selected from the following stated:
Solvent can be trimethylbenzene, durene, methyl naphthalene, methyl oleate, fatty acid methyl ester, loose base oil, soybean oil, biodiesel, 2-butyl acetate, dimethyl carbonate, diesel oil, white oil, machine oil, etc. in one or more.
Emulsifier can be calcium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether, triphenoethyl benzene phenol polyoxyethylene polyoxypropylene block polymer, dibenzyl xenyl APEO, phenethyl phenol polyethenoxy ether, castor oil polyoxyethylene ether, phenethyl fluosite APEO, phenethyl phenol polyoxyethylene polyoxypropylene ether, alkylaryl polyoxyethylene polyoxypropylene ether, phenethyl phenol formaldehyde resin APEO, Sorbitan fatty acid ester, sorbitan fatty acid ester APEO, natural fatty alcohol and ethylene oxide adduct, fatty acid and ethylene oxide condensate, one or more in polyoxyethylene fatty acid ester etc.
Wetting agent can be one or more in sodium butylnaphthalenesulfonate, lauryl sodium sulfate, aliphatic alcohol polyethenoxy (6-7) ether, aerosol-OT salt, Morwet EFW, alkylnaphthalene sulfonate etc.
Disintegrant can be one or more in sodium bicarbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, ammonium sulfate, bentonite etc.
Dispersant can be the formaldehyde condensation products of methyl naphthalene sulfonic acid sodium, sodium lignin sulfonate, calcium lignosulfonate, to methoxyl group fatty acyl anilinesulfonic acid, desugar one or more in the sodium lignin sulfonate of classification, naphthalene sulfonic acid condensate sodium salt, alkyl naphthalene sulfonic acid condensation polymer sodium salt, alkylphenol polyoxyethylene formaldehyde condensation products sulfuric acid etc.
Thickener can be one or more in xanthans, aluminium-magnesium silicate, bentonite, white carbon etc.
PH adjusting agent can be one or more in ammonium hydroxide, potassium hydroxide, sodium hydroxide, hydrochloric acid, acetic acid, citric acid, phosphoric acid etc.
Stabilizing agent can be one or more in epoxidized soybean oil, epoxychloropropane, butylated hydroxy anisole, dibutyl hydroxy toluene, n-propyl gallate, ditert-butylhydro quinone etc.
Defoamer can be one or more in silicone compound, methyl alcohol, silicone oil etc.
Antifreezing agent can be one or more in glycerine, ethylene glycol, propane diols, sorbierite, polyethylene glycol etc.
Carrier can be one or more in kaolin, diatomite, bentonite, white carbon, precipitated calcium carbonate, attapulgite, clay, talcum powder, quartz sand, starch, APG etc.
Assays Example 1: butene-fipronil and fluorobenzene insect amide are to the indoor joint toxicity measuring test of the snout moth's larva of rice.
Test medicine adopts the former medicine of 96% butene-fipronil and the former medicine of 96% fluorobenzene insect amide.
Snout moth's larva system picks up from Zhong Kai district, Huizhou Shi Zhen village snout moth's larva and serious paddy field occurs.
With reference to the rice-stem dipping method of the accurate NY/T1154.11-2008 of raw mark, choose two leaf one core rice seedling 15 strains, after supplying to flood 30 seconds in reagent liquid, taking-up is dried naturally, root insulation is encased with wet absorbent cotton, outsourcing preservative film, is placed in glass (Φ 200 × 30mm), and every concentration repeats for 4 times.Then with snout moth's larva 3 nymph in age of writing brush access ether light anesthesia, often pipe 20 ± 2, the white gauze of the mouth of pipe is tightened.Be disposed, be placed in observation ward.Check examination worm death condition after 72h, line item of going forward side by side, the dead criterion of examination worm counts death for contacting examination with writing brush gently worm being reactionless.
Statistical analysis is carried out, by calculating the LC of each medicament with DPS statistical analysis software
50evaluate the insecticidal activity of each medicament, and calculate the co-toxicity coefficient (CTC value) of mixture according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC
50/ reagent agent LC
50) × 100.
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture A percentage composition+B medicament toxicity index × mixture in the percentage composition of B.
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] × 100.
According to the NY/T11547.7-2006 insecticide combination effect criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80 < co-toxicity coefficient (CTC) < 120 show as summation action.
As can be seen from Table 1 and Table 2, butene-fipronil and fluorobenzene insect amide composite in the scope of 1:5 ~ 5:1 time, co-toxicity coefficient (CTC) is all greater than 120, all shows synergistic function to rice-stem borer and rice leaf roller.Visible butene-fipronil and fluorobenzene insect amide is composite has reasonability and feasibility.
Table 1, butene-fipronil and fluorobenzene insect amide are to the indoor joint toxicity measuring result of striped rice borer
Table 2, butene-fipronil and fluorobenzene insect amide are to the indoor joint toxicity measuring result of rice leaf roller
Assays Example 2: butene-fipronil and the composite field control effectiveness test to the snout moth's larva of rice of fluorobenzene insect amide.
Striped rice borer test site is positioned at Huizhou paddy field.In striped rice borer harm Sheng phase dispenser, adopt spray-on process.Adopt 5% butene-fipronil missible oil, 10% fluorobenzene insect amide suspending agent medicament in contrast, 7 chemicals treatment are established in test altogether, and each process repeats for 3 times.The withered heart rate of cornerwise five somes investigation paddy rice in district is managed throughout, often some investigation 30 strain paddy rice before dispenser.Within after dispenser 3 days, 7 days, 14 days, respectively investigate a control efficiency, record withered heart rate, calculate control efficiency, result of the test is as shown in table 3.
The result of the test of table 3, butene-fipronil and fluorobenzene insect amide mixture water prevention chilo suppressalis
All to use apparently higher than the butene-fipronil missible oil single dose same period 5% preventive effect of striped rice borer after butene-fipronil and fluorobenzene insect amide composite 3d, 7d, 14d as can be seen from Table 3 and 10% fluorobenzene insect amide suspending agent single dose uses, the preventive effect to striped rice borer can be improved compared with illustrating that butene-fipronil and fluorobenzene insect amide are composite and being used alone with two kinds of single doses, after medicine, 14d preventive effect still reaches more than 80% simultaneously, illustrate to have good lasting effect, duration of test does not find that this compound drug produces poisoning to paddy rice.
Rice leaf roller test site is positioned at Huizhou paddy field.In rice leaf roller harm Sheng phase dispenser, adopt spray-on process.Adopt 5% butene-fipronil missible oil, 10% fluorobenzene insect amide suspending agent medicament in contrast, 7 chemicals treatment are established in test altogether, and each process repeats for 3 times.Cornerwise five somes investigation in district rice leaf roll rate is managed throughout, often some investigation 30 strain paddy rice before dispenser.Within after dispenser 3 days, 7 days, 14 days, respectively investigate a control efficiency, record leaf roll rate, calculate control efficiency, result of the test is as shown in table 4.
Table 4, butene-fipronil and fluorobenzene insect amide mixture prevent and treat the result of the test of paddy rice rice leaf roller
All to use apparently higher than the butene-fipronil EC single dose same period 5% preventive effect of rice leaf roller after butene-fipronil and fluorobenzene insect amide composite 3d, 7d, 14d as can be seen from Table 4 and 10% fluorobenzene insect amide SC single dose uses, the preventive effect to rice leaf roller can be improved compared with illustrating that butene-fipronil and fluorobenzene insect amide are composite and being used alone with two kinds of single doses, after medicine, 14d preventive effect still reaches more than 80% simultaneously, illustrate to have good lasting effect, duration of test does not find that this compound drug produces poisoning to paddy rice.
Assays Example 3: snout moth's larva is tested the pesticide resistance indoor measurement of butene-fipronil fluorobenzene insect amide.
Worm source gathers from Huizhou.The concentration that test medicine adopts is the 50%-90% lethal dose of the snout moth's larva of rice, butene-fipronil, the former medicine of fluorobenzene insect amide is mixed with the test medicine needed for test.Test adopts cane infusion process, consistent with the method for above-mentioned toxicity test.Reject dead examination worm after 72 hours, the examination worm stayed continues at indoor feeding, so repeatedly processes 20 generations examination worm.If the liquid only containing auxiliary agent is treated to blank.Measure each medicament tries worm half lethal concentration LC to 1st generation, the 5th generation, the 10th generation and the 20th generation
50, by contrast each treatment agent to 1st generation, the 5th generation, the 10th generation and the 20th generation examination worm LC
50evaluate examination worm to change the pesticide resistance of reagent agent.
Can find out according to table 5, table 6, in butene-fipronil and fluorobenzene insect amide complex preparation process 20 generation, try the pesticide resistance that the pesticide resistance of worm population to this complex preparation is starkly lower than butene-fipronil and the generation of fluorobenzene insect amide single dose process 20 generation examination worm after trying worm.This test shows, butene-fipronil and fluorobenzene insect amide is composite can effectively delay the snout moth's larva of rice and develop immunity to drugs.
Table 5, butene-fipronil and fluorobenzene insect amide are composite to the drug-fast determination test result of striped rice borer
Note: above table medium multiple represents that corresponding algebraically striped rice borer is to the pesticide resistance of each medicament.
Table 6, butene-fipronil and fluorobenzene insect amide are composite to the drug-fast determination test result of rice leaf roller
Note: above table medium multiple represents that corresponding algebraically rice leaf roller is to the pesticide resistance of each medicament.
In sum, the present invention adopts two kinds of active components to be the complex composition of butene-fipronil and fluorobenzene insect amide, compared with existing unitary agent, not only there is obvious synergistic effect, also have good insecticidal effect, the lasting period is long, to Crop securify, the generation of pest resistance to insecticide can be slowed down, be worth applying in agricultural production.
Claims (4)
1. one kind contains the Pesticidal combination of butene-fipronil and fluorobenzene insect amide, comprise usual auxiliaries, butene-fipronil and fluorobenzene insect amide, it is characterized in that: the ratio of weight and number of butene-fipronil and fluorobenzene insect amide is 1:5-5:1, butene-fipronil and the percentage by weight of fluorobenzene insect amide weight summation in Pesticidal combination are 1%-80%.
2. a kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide according to claim 1, is characterized in that: its formulation is the one in suspending agent, water dispersible granules, aqueous emulsion, microemulsion, wetting powder.
3. an a kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide according to claim 1 is preventing and treating the application in crop pests.
4. a kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide according to claim 3, is characterized in that: described insect is rice-stem borer, rice leaf roller.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107372546A (en) * | 2017-06-30 | 2017-11-24 | 江苏省绿盾植保农药实验有限公司 | A kind of rice seed treating agent containing bromine cyanogen insect amide and butene-fipronil and its application |
| CN113197208A (en) * | 2021-05-11 | 2021-08-03 | 安徽丰乐农化有限责任公司 | Insecticidal composition containing flubendiamide and acetoprole and application thereof |
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2015
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| EP1006107A2 (en) * | 1998-11-30 | 2000-06-07 | Nihon Nohyaku Co., Ltd. | Phthalamide derivatives, or salt thereof agrohorticultural insecticide, and method for using the same |
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Cited By (2)
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| CN107372546A (en) * | 2017-06-30 | 2017-11-24 | 江苏省绿盾植保农药实验有限公司 | A kind of rice seed treating agent containing bromine cyanogen insect amide and butene-fipronil and its application |
| CN113197208A (en) * | 2021-05-11 | 2021-08-03 | 安徽丰乐农化有限责任公司 | Insecticidal composition containing flubendiamide and acetoprole and application thereof |
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