CN101157036A - 一种轻度碱化烃类水蒸汽转化催化剂及其制备方法 - Google Patents
一种轻度碱化烃类水蒸汽转化催化剂及其制备方法 Download PDFInfo
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- CN101157036A CN101157036A CNA2007100504874A CN200710050487A CN101157036A CN 101157036 A CN101157036 A CN 101157036A CN A2007100504874 A CNA2007100504874 A CN A2007100504874A CN 200710050487 A CN200710050487 A CN 200710050487A CN 101157036 A CN101157036 A CN 101157036A
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- catalyst
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- 239000003054 catalyst Substances 0.000 title claims abstract description 89
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 35
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 44
- 238000006243 chemical reaction Methods 0.000 title claims description 34
- 238000000034 method Methods 0.000 title description 11
- 229910000480 nickel oxide Inorganic materials 0.000 claims abstract description 18
- 239000002131 composite material Substances 0.000 claims abstract description 16
- 238000002360 preparation method Methods 0.000 claims abstract description 15
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 27
- 229910052700 potassium Inorganic materials 0.000 claims description 18
- 239000011591 potassium Substances 0.000 claims description 18
- -1 potassium aluminates Chemical class 0.000 claims description 18
- 239000004568 cement Substances 0.000 claims description 16
- 239000011265 semifinished product Substances 0.000 claims description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 14
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 claims description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 13
- 238000000354 decomposition reaction Methods 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 13
- 239000000047 product Substances 0.000 claims description 13
- 238000005303 weighing Methods 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 12
- 238000001354 calcination Methods 0.000 claims description 11
- 238000007598 dipping method Methods 0.000 claims description 11
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims description 11
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 238000005520 cutting process Methods 0.000 claims description 8
- 239000000470 constituent Substances 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 206010013786 Dry skin Diseases 0.000 claims description 5
- 239000000314 lubricant Substances 0.000 claims description 5
- 238000005245 sintering Methods 0.000 claims description 5
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 5
- 230000003197 catalytic effect Effects 0.000 abstract description 3
- 238000000629 steam reforming Methods 0.000 abstract description 3
- 230000003113 alkalizing effect Effects 0.000 abstract 2
- 239000002638 heterogeneous catalyst Substances 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 description 12
- 239000007789 gas Substances 0.000 description 11
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 239000003610 charcoal Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 229940072033 potash Drugs 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 239000007868 Raney catalyst Substances 0.000 description 1
- 229910000564 Raney nickel Inorganic materials 0.000 description 1
- 230000003044 adaptive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000010523 cascade reaction Methods 0.000 description 1
- 238000007233 catalytic pyrolysis Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
Landscapes
- Catalysts (AREA)
Abstract
Description
项目 | Al2O3 | NiO | CaO | SiO2 | Fe2O3 | K2O | Na2O | TiO2 |
份比 | 64 | 18 | 14.5 | 0.1 | 0.1 | 2.5 | 0.3 | 0.5 |
项目 | Al2O3 | NiO | CaO | SiO2 | Fe2O3 | K2O | Na2O | TiO2 |
份比 | 60 | 25 | 9.0 | 0.2 | 0.1 | 5.0 | 0.5 | 0.1 |
项目 | Al2O3 | NiO | CaO | SiO2 | Fe2O3 | K2O | Na2O | TiO2 |
份比 | 70 | 10 | 18 | 0.1 | 0.2 | 1 | 0.2 | 2 |
项目 | 对比催化剂 | 本发明催化剂 | |||
ICI25-4 | G90B | 实施例1 | 实施例2 | 实施例3 | |
干转化气中CH4(Vol%) | 42.85 | 45.56 | 41.35 | 42.11 | 41.74 |
干转化气中C2以上烃类g/m3 | 12.97 | 3.31 | 1.93 | 1.14 | 2.31 |
卸下催化剂状况 | 无碳 | 有碳 | 无碳 | 无碳 | 无碳 |
项目 | 干转化气中CH4组成(Vol%) | |
对比催化剂 | ICI65-2 | 80.55 |
G90B | 92.37 | |
本发明催化剂 | 实施例1 | 72.83 |
实施例2 | 74.59 | |
实施例3 | 73.23 |
Claims (8)
Priority Applications (1)
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CNB2007100504874A CN100463716C (zh) | 2007-11-13 | 2007-11-13 | 一种轻度碱化烃类水蒸汽转化催化剂及其制备方法 |
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CNB2007100504874A CN100463716C (zh) | 2007-11-13 | 2007-11-13 | 一种轻度碱化烃类水蒸汽转化催化剂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN101157036A true CN101157036A (zh) | 2008-04-09 |
CN100463716C CN100463716C (zh) | 2009-02-25 |
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CNB2007100504874A Expired - Fee Related CN100463716C (zh) | 2007-11-13 | 2007-11-13 | 一种轻度碱化烃类水蒸汽转化催化剂及其制备方法 |
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CN (1) | CN100463716C (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102091631A (zh) * | 2010-12-29 | 2011-06-15 | 公主岭国家农业科技园区三剂化工厂 | 煤制天然气催化剂及其制造方法 |
CN105457640A (zh) * | 2015-11-17 | 2016-04-06 | 西南化工研究设计院有限公司 | 一种改进的新型烃类水蒸汽转化催化剂 |
CN111097447A (zh) * | 2018-10-29 | 2020-05-05 | 中国石油天然气股份有限公司 | 一种甲烷低温催化裂解制氢催化剂及其制备方法、甲烷低温催化裂解制氢的方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1051251C (zh) * | 1993-03-25 | 2000-04-12 | 中国石油化工总公司 | 烃类水蒸汽转化下段催化剂及制法 |
-
2007
- 2007-11-13 CN CNB2007100504874A patent/CN100463716C/zh not_active Expired - Fee Related
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102091631A (zh) * | 2010-12-29 | 2011-06-15 | 公主岭国家农业科技园区三剂化工厂 | 煤制天然气催化剂及其制造方法 |
CN105457640A (zh) * | 2015-11-17 | 2016-04-06 | 西南化工研究设计院有限公司 | 一种改进的新型烃类水蒸汽转化催化剂 |
CN111097447A (zh) * | 2018-10-29 | 2020-05-05 | 中国石油天然气股份有限公司 | 一种甲烷低温催化裂解制氢催化剂及其制备方法、甲烷低温催化裂解制氢的方法 |
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CN100463716C (zh) | 2009-02-25 |
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Owner name: SOUTHWEST RESEARCH + DESIGN INSTITUTE OF CHEMICAL Free format text: FORMER NAME: SOUTHWEST RESEARCH + DESIGN INSTITUTE OF CHEMICAL INDUSTRY |
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Address after: No. 5 high tech Zone Gaopeng road in Chengdu city of Sichuan Province in 610041 Patentee after: SOUTHWEST RESEARCH & DESIGN INSTITUTE OF CHEMICAL INDUSTRY Patentee after: Shanghai Shidongkou Gas Making Co.,Ltd. Address before: No. 5 high tech Zone Gaopeng road in Chengdu city of Sichuan Province in 610041 Patentee before: THE SOUTHWEST RESEARCH & DESIGN INSTITUTE OF CHEMICAL INDUSTRY Patentee before: Shanghai Shidongkou Gas Making Co.,Ltd. |
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Effective date of registration: 20200117 Address after: 611430 No.777, Xinghua 10th Road, dengshuang Town, Xinjin County, Chengdu City, Sichuan Province (Industrial Park) Co-patentee after: Shanghai Shidongkou Gas Making Co.,Ltd. Patentee after: HAO HUA (CHENGDU) TECHNOLOGY Co.,Ltd. Address before: No. 5 high tech Zone Gaopeng road in Chengdu city of Sichuan Province in 610041 Co-patentee before: Shanghai Shidongkou Gas Making Co.,Ltd. Patentee before: SOUTHWEST RESEARCH & DESIGN INSTITUTE OF CHEMICAL INDUSTRY |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
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Granted publication date: 20090225 |