CN101128511B - 制备聚碳酸酯的方法 - Google Patents
制备聚碳酸酯的方法 Download PDFInfo
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- CN101128511B CN101128511B CN2005800485800A CN200580048580A CN101128511B CN 101128511 B CN101128511 B CN 101128511B CN 2005800485800 A CN2005800485800 A CN 2005800485800A CN 200580048580 A CN200580048580 A CN 200580048580A CN 101128511 B CN101128511 B CN 101128511B
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- Prior art keywords
- hydroxyphenyl
- solution
- phenol
- polycarbonate
- metered
- Prior art date
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- 239000004417 polycarbonate Substances 0.000 title claims abstract description 38
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 34
- 229930185605 Bisphenol Natural products 0.000 claims abstract description 30
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 29
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 claims abstract description 27
- -1 trimethylcyclohexyl group Chemical group 0.000 claims abstract description 24
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 13
- 239000001257 hydrogen Substances 0.000 claims abstract description 11
- 230000007062 hydrolysis Effects 0.000 claims abstract description 11
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 11
- 239000011541 reaction mixture Substances 0.000 claims abstract description 11
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims abstract description 3
- 230000008569 process Effects 0.000 claims description 11
- 125000001118 alkylidene group Chemical group 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical group CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 abstract description 7
- 150000002431 hydrogen Chemical class 0.000 abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract description 2
- 125000005587 carbonate group Chemical group 0.000 abstract description 2
- 125000006539 C12 alkyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 85
- 239000000243 solution Substances 0.000 description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 30
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 28
- 239000000203 mixture Substances 0.000 description 25
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- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 20
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- 238000005453 pelletization Methods 0.000 description 17
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 16
- 229920000642 polymer Polymers 0.000 description 15
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 12
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- 239000003513 alkali Substances 0.000 description 10
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- 150000002148 esters Chemical class 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 8
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- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
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- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
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- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 6
- 239000001294 propane Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- 238000005804 alkylation reaction Methods 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
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- HTLZVHNRZJPSMI-UHFFFAOYSA-N N-ethylpiperidine Chemical compound CCN1CCCCC1 HTLZVHNRZJPSMI-UHFFFAOYSA-N 0.000 description 4
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- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 150000001263 acyl chlorides Chemical class 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 4
- 239000006085 branching agent Substances 0.000 description 4
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 230000005501 phase interface Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000009987 spinning Methods 0.000 description 4
- 150000003512 tertiary amines Chemical class 0.000 description 4
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000029936 alkylation Effects 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
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- 238000002425 crystallisation Methods 0.000 description 3
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
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- 150000002430 hydrocarbons Chemical class 0.000 description 3
- PLVNXRJXMGRWJI-UHFFFAOYSA-N phenol;sodium Chemical compound [Na].OC1=CC=CC=C1.OC1=CC=CC=C1 PLVNXRJXMGRWJI-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
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- 229960001866 silicon dioxide Drugs 0.000 description 3
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- PAMIQIKDUOTOBW-UHFFFAOYSA-N 1-methylpiperidine Chemical compound CN1CCCCC1 PAMIQIKDUOTOBW-UHFFFAOYSA-N 0.000 description 2
- 238000005160 1H NMR spectroscopy Methods 0.000 description 2
- WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 description 2
- UMPGNGRIGSEMTC-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexyl]phenol Chemical compound C1C(C)CC(C)(C)CC1(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 UMPGNGRIGSEMTC-UHFFFAOYSA-N 0.000 description 2
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
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- 241000628997 Flos Species 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
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- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
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- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
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- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 2
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- UIAFKZKHHVMJGS-UHFFFAOYSA-N 2,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1O UIAFKZKHHVMJGS-UHFFFAOYSA-N 0.000 description 1
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- 238000010828 elution Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011552 falling film Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000033444 hydroxylation Effects 0.000 description 1
- 238000005805 hydroxylation reaction Methods 0.000 description 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 229910000064 phosphane Inorganic materials 0.000 description 1
- 150000003002 phosphanes Chemical class 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 150000003008 phosphonic acid esters Chemical class 0.000 description 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000012747 synergistic agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000000000 tetracarboxylic acids Chemical class 0.000 description 1
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/22—General preparatory processes using carbonyl halides
- C08G64/24—General preparatory processes using carbonyl halides and phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31507—Of polycarbonate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
对比试验1 | ||
双酚钠溶液(14.87wt%BPA) | kg/h | 750 |
双酚盐溶液的碱含量 | %OH | 0.12 |
溶剂,(二氯甲烷/氯苯=1∶1wt%) | kg/h | 661 |
光气 | kg/h | 58.85 |
第一氢氧化钠溶液的计量加入(32.02wt%NaOH) | kg/h | 13.98 |
第二氢氧化钠溶液的计量加入(32.02wt%NaOH) | kg/h | 48.84 |
链终止剂溶液(11.47wt%,在二氯甲烷/氯苯=1∶1中) | kg/h | 35.2 |
催化剂溶液(3.42wt%,在二氯甲烷/氯苯=1∶1wt%中) | kg/h | 17.71 |
反应温度 | ℃ | 42 |
催化剂计量加入温度 | ℃ | 44.3 |
双酚/光气的比值 | 1.22∶1 |
对比试验2 | ||
双酚钠溶液(14.93wt%BPA) | kg/h | 750 |
双酚盐溶液的碱含量 | %OH | 0.12 |
溶剂,(二氯甲烷/氯苯=1∶1wt%) | kg/h | 644 |
光气 | kg/h | 56.59 |
第一氢氧化钠溶液的计量加入(32.08wt%NaOH) | kg/h | 9.99 |
第二氢氧化钠溶液的计量加入(32.08wt%NaOH) | kg/h | 29.12 |
链终止剂溶液;(11.60wt%在二氯甲烷/氯苯=1∶1中) | kg/h | 34.0 |
催化剂溶液(2.69wt%在二氯甲烷/氯苯=1∶1wt%中) | kg/h | 32.99 |
反应温度 | ℃ | 42 |
催化剂计量加入温度 | ℃ | 41.3 |
双酚/光气的比值 | 1.16∶1 |
试验1,本发明 |
双酚钠溶液(14.88wt%BPA) | kg/h | 750 |
双酚盐溶液的碱含量 | %OH | 0.13 |
溶剂,(二氯甲烷/氧苯=1∶1wt%) | kg/h | 646 |
光气 | kg/h | 56.40 |
第一氢氧化钠溶液的计量加入(32.02wt%NaOH) | kg/h | 9.97 |
试验1,本发明 | ||
第二氢氧化钠溶液计量加入(32.02wt%NaOH) | kg/h | 29.27 |
链终止剂溶液;(11.67wt%,二氯甲烷/氯苯=1∶1) | kg/g | 34.18 |
催化剂溶液;(2.95wt%,二氯甲烷/氯苯=1∶1wt%) | kg/g | 33.01 |
反应温度 | ℃ | 35 |
催化剂计量加入温度 | ℃ | 38.4 |
双酚与光气的比值 | 1.16∶1 |
通式(2a)的氨基甲酸酯含量[ppm] | 双酚的摩尔数∶光气的摩尔数 | |
对比例1 | 1017 | 1∶1.22 |
对比例2 | 586 | 1∶1.16 |
本发明实施例1 | 48 | 1∶1.16 |
Claims (3)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200410061715 DE102004061715A1 (de) | 2004-12-22 | 2004-12-22 | Verfahren zur Herstellung von Polycarbonaten |
DE102004061715.5 | 2004-12-22 | ||
PCT/EP2005/013213 WO2006072343A1 (de) | 2004-12-22 | 2005-12-09 | Verfahren zur herstellung von polycarbonaten |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101128511A CN101128511A (zh) | 2008-02-20 |
CN101128511B true CN101128511B (zh) | 2011-07-27 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2005800485800A Expired - Fee Related CN101128511B (zh) | 2004-12-22 | 2005-12-09 | 制备聚碳酸酯的方法 |
Country Status (11)
Country | Link |
---|---|
US (1) | US7705107B2 (zh) |
EP (1) | EP1831283B1 (zh) |
JP (1) | JP2008524406A (zh) |
KR (1) | KR101243004B1 (zh) |
CN (1) | CN101128511B (zh) |
DE (1) | DE102004061715A1 (zh) |
HK (1) | HK1118068A1 (zh) |
PL (1) | PL1831283T3 (zh) |
SG (1) | SG177169A1 (zh) |
TW (1) | TW200640991A (zh) |
WO (1) | WO2006072343A1 (zh) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6974260B2 (en) * | 2003-07-30 | 2005-12-13 | Emcore Corporation | Flexible substrate for routing fibers in an optical transceiver |
DE102004061713A1 (de) * | 2004-12-22 | 2006-07-20 | Bayer Materialscience Ag | Polycarbonate mit guter Benetzbarkeit |
US20070208159A1 (en) * | 2006-03-02 | 2007-09-06 | General Electric Company | Poly(arylene ether) block copolymer compositions, methods, and articles |
DE102007022130B4 (de) | 2007-05-11 | 2015-02-19 | Bayer Intellectual Property Gmbh | Verfahren zur Herstellung von Polycarbonat nach dem Schmelzeumesterungsverfahren |
DE102007052968A1 (de) | 2007-11-07 | 2009-05-14 | Bayer Materialscience Ag | Verfahren zur Herstellung von Polycarbonat nach dem Schmelzeumesterungsverfahren |
JP5495317B2 (ja) * | 2010-04-08 | 2014-05-21 | 帝人株式会社 | カーボネート型難燃剤の製造法 |
CN102030895B (zh) * | 2010-11-05 | 2012-04-25 | 烟台万华聚氨酯股份有限公司 | 一种连续两相界面光气法制备聚碳酸酯的方法 |
JP7181006B2 (ja) * | 2018-06-01 | 2022-11-30 | 出光興産株式会社 | ポリカーボネート系樹脂及びその製造方法、並びにポリカーボネート系樹脂組成物 |
Citations (5)
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EP0263432B1 (en) * | 1986-10-10 | 1992-09-09 | General Electric Company | Method for preparing aromatic bischloroformate compositions and polycarbonates |
CN1088593A (zh) * | 1992-12-10 | 1994-06-29 | 拜尔公司 | 聚碳酸酯的制备方法 |
CN1090295A (zh) * | 1992-11-20 | 1994-08-03 | 拜尔公司 | 聚碳酸酯的制备工艺 |
CN1359895A (zh) * | 2000-12-19 | 2002-07-24 | 拜尔公司 | 生产碳酸二芳基酯的方法 |
EP1426396B1 (en) * | 2001-07-11 | 2006-09-13 | Mitsubishi Gas Chemical Company, Inc. | Process for producing polycarbonate oligomer and process for producing polycarbonate resin from the same |
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US5102696A (en) * | 1990-03-27 | 1992-04-07 | General Electric Company | Method of dispersing fluoropolymers on polycarbonate resins |
DE4118232A1 (de) * | 1991-06-04 | 1992-12-10 | Bayer Ag | Kontinuierliche herstellung von polycarbonaten |
JPH07165901A (ja) * | 1993-12-16 | 1995-06-27 | Mitsui Toatsu Chem Inc | 芳香族ポリカーボネートの製造方法 |
JPH09165442A (ja) * | 1995-10-11 | 1997-06-24 | Mitsubishi Gas Chem Co Inc | 光記録媒体用ポリカーボネート |
DE10118307A1 (de) * | 2001-04-12 | 2002-10-17 | Bayer Ag | Vefahren zur Herstellung von Polycarbonaten |
DE10300598A1 (de) * | 2003-01-10 | 2004-07-22 | Bayer Ag | Verfahren zur Herstellung von Polycarbonaten |
-
2004
- 2004-12-22 DE DE200410061715 patent/DE102004061715A1/de not_active Withdrawn
-
2005
- 2005-12-09 WO PCT/EP2005/013213 patent/WO2006072343A1/de active Application Filing
- 2005-12-09 CN CN2005800485800A patent/CN101128511B/zh not_active Expired - Fee Related
- 2005-12-09 KR KR1020077016685A patent/KR101243004B1/ko active IP Right Grant
- 2005-12-09 EP EP20050818827 patent/EP1831283B1/de active Active
- 2005-12-09 SG SG2011088879A patent/SG177169A1/en unknown
- 2005-12-09 JP JP2007547244A patent/JP2008524406A/ja active Pending
- 2005-12-09 PL PL05818827T patent/PL1831283T3/pl unknown
- 2005-12-20 US US11/312,886 patent/US7705107B2/en active Active
- 2005-12-21 TW TW094145423A patent/TW200640991A/zh unknown
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- 2008-08-13 HK HK08108981A patent/HK1118068A1/xx not_active IP Right Cessation
Patent Citations (5)
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EP0263432B1 (en) * | 1986-10-10 | 1992-09-09 | General Electric Company | Method for preparing aromatic bischloroformate compositions and polycarbonates |
CN1090295A (zh) * | 1992-11-20 | 1994-08-03 | 拜尔公司 | 聚碳酸酯的制备工艺 |
CN1088593A (zh) * | 1992-12-10 | 1994-06-29 | 拜尔公司 | 聚碳酸酯的制备方法 |
CN1359895A (zh) * | 2000-12-19 | 2002-07-24 | 拜尔公司 | 生产碳酸二芳基酯的方法 |
EP1426396B1 (en) * | 2001-07-11 | 2006-09-13 | Mitsubishi Gas Chemical Company, Inc. | Process for producing polycarbonate oligomer and process for producing polycarbonate resin from the same |
Also Published As
Publication number | Publication date |
---|---|
US20060155098A1 (en) | 2006-07-13 |
EP1831283B1 (de) | 2012-09-26 |
EP1831283A1 (de) | 2007-09-12 |
TW200640991A (en) | 2006-12-01 |
KR20070100751A (ko) | 2007-10-11 |
SG177169A1 (en) | 2012-01-30 |
CN101128511A (zh) | 2008-02-20 |
US7705107B2 (en) | 2010-04-27 |
WO2006072343A1 (de) | 2006-07-13 |
JP2008524406A (ja) | 2008-07-10 |
DE102004061715A1 (de) | 2006-07-06 |
KR101243004B1 (ko) | 2013-03-12 |
HK1118068A1 (en) | 2009-01-30 |
PL1831283T3 (pl) | 2013-02-28 |
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