CN101092538B - 脂肪族防水透湿合成革涂饰树脂及其预聚制造方法 - Google Patents
脂肪族防水透湿合成革涂饰树脂及其预聚制造方法 Download PDFInfo
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- CN101092538B CN101092538B CN2006100880806A CN200610088080A CN101092538B CN 101092538 B CN101092538 B CN 101092538B CN 2006100880806 A CN2006100880806 A CN 2006100880806A CN 200610088080 A CN200610088080 A CN 200610088080A CN 101092538 B CN101092538 B CN 101092538B
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- toluene
- chainextender
- catalyzer
- paint
- synthetic leather
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- 239000011347 resin Substances 0.000 title claims abstract description 21
- 229920005989 resin Polymers 0.000 title claims abstract description 21
- 125000001931 aliphatic group Chemical group 0.000 title claims abstract description 17
- 239000002649 leather substitute Substances 0.000 title claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 238000006116 polymerization reaction Methods 0.000 title description 3
- 239000004970 Chain extender Substances 0.000 claims abstract description 25
- 238000006243 chemical reaction Methods 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 111
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 32
- -1 polydimethylsiloxane Polymers 0.000 claims description 31
- 239000011259 mixed solution Substances 0.000 claims description 20
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 claims description 17
- 239000003973 paint Substances 0.000 claims description 17
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 16
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 16
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 claims description 16
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 16
- 150000002148 esters Chemical class 0.000 claims description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 14
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 13
- 239000004922 lacquer Substances 0.000 claims description 13
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 13
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 12
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 12
- 239000013256 coordination polymer Substances 0.000 claims description 12
- 229920000570 polyether Polymers 0.000 claims description 12
- 238000010792 warming Methods 0.000 claims description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 9
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 239000012895 dilution Substances 0.000 claims description 8
- 238000010790 dilution Methods 0.000 claims description 8
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 7
- 229910052797 bismuth Inorganic materials 0.000 claims description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 4
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 229920000909 polytetrahydrofuran Polymers 0.000 claims description 3
- 229920000151 polyglycol Polymers 0.000 claims description 2
- 239000010695 polyglycol Substances 0.000 claims description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims 2
- BJZYYSAMLOBSDY-QMMMGPOBSA-N (2s)-2-butoxybutan-1-ol Chemical compound CCCCO[C@@H](CC)CO BJZYYSAMLOBSDY-QMMMGPOBSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 229920001223 polyethylene glycol Polymers 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 9
- 230000008961 swelling Effects 0.000 abstract description 3
- 238000010559 graft polymerization reaction Methods 0.000 abstract description 2
- 239000012948 isocyanate Substances 0.000 abstract description 2
- 150000002513 isocyanates Chemical class 0.000 abstract description 2
- 229920000728 polyester Polymers 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 150000002009 diols Chemical class 0.000 abstract 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 4
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 4
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 4
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 3
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 235000019439 ethyl acetate Nutrition 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- KXBFLNPZHXDQLV-UHFFFAOYSA-N [cyclohexyl(diisocyanato)methyl]cyclohexane Chemical compound C1CCCCC1C(N=C=O)(N=C=O)C1CCCCC1 KXBFLNPZHXDQLV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Landscapes
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2006100880806A CN101092538B (zh) | 2006-06-23 | 2006-06-23 | 脂肪族防水透湿合成革涂饰树脂及其预聚制造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN2006100880806A CN101092538B (zh) | 2006-06-23 | 2006-06-23 | 脂肪族防水透湿合成革涂饰树脂及其预聚制造方法 |
Publications (2)
Publication Number | Publication Date |
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CN101092538A CN101092538A (zh) | 2007-12-26 |
CN101092538B true CN101092538B (zh) | 2010-11-10 |
Family
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Family Applications (1)
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CN2006100880806A Expired - Fee Related CN101092538B (zh) | 2006-06-23 | 2006-06-23 | 脂肪族防水透湿合成革涂饰树脂及其预聚制造方法 |
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CN (1) | CN101092538B (zh) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101613451B (zh) * | 2009-08-05 | 2011-04-06 | 辽宁恒星精细化工(集团)有限公司 | 高含量水性聚氨酯乳液及制备方法 |
CN101781516B (zh) * | 2010-02-04 | 2012-09-05 | 河北华腾万富达精细化工有限责任公司 | 一种软包装挤出复合用底涂剂及其应用 |
CN101812229B (zh) * | 2010-04-02 | 2012-06-20 | 宜兴市新光科技有限公司 | 隔热减震防护膜及其制造方法 |
CN102993400A (zh) * | 2012-11-28 | 2013-03-27 | 浙江华峰合成树脂有限公司 | 透湿防水型不黄变鞋革用聚氨酯树脂及制备方法 |
CN103172821B (zh) * | 2013-03-20 | 2014-12-31 | 嘉兴学院 | 一种低膨润高透湿聚氨酯树脂制备方法 |
CN104975521B (zh) * | 2015-07-06 | 2016-11-30 | 辽宁恒星精细化工有限公司 | 尼龙面料用水性聚氨酯胶浆乳液及制备方法 |
CN111019080A (zh) * | 2019-12-26 | 2020-04-17 | 江苏宝泽高分子材料股份有限公司 | 一种无溶剂型服装革用聚氨酯树脂及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1032174A (zh) * | 1987-09-25 | 1989-04-05 | 山东大学 | 聚氨酯聚硅氧烷线型嵌段共聚物的制备及应用 |
CN1276030A (zh) * | 1997-09-18 | 2000-12-06 | 美国3M公司 | 包含封端异氰酸酯增量剂的氟化物组合物和用它处理纤维基材的方法 |
-
2006
- 2006-06-23 CN CN2006100880806A patent/CN101092538B/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1032174A (zh) * | 1987-09-25 | 1989-04-05 | 山东大学 | 聚氨酯聚硅氧烷线型嵌段共聚物的制备及应用 |
CN1276030A (zh) * | 1997-09-18 | 2000-12-06 | 美国3M公司 | 包含封端异氰酸酯增量剂的氟化物组合物和用它处理纤维基材的方法 |
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ASS | Succession or assignment of patent right |
Owner name: YIXING XINGUANG SYNTHETIC LEATHER CO., LTD. Free format text: FORMER OWNER: YIXING XINGUANG CHEMICAL CO., LTD. Effective date: 20110318 |
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Effective date of registration: 20110318 Address after: 214205 No. 158 Nanyue Road, ring garden, Yixing, Jiangsu Patentee after: Yixing Xinguang Synthetic Leather Co., Ltd. Address before: 214205 No. 158 Nanyue Road, ring garden, Yixing, Jiangsu Patentee before: Xinguang Chemical Plant |
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Owner name: YIXING YUANFENG CABLE CO., LTD. Free format text: FORMER OWNER: YIXING XINGUANG SYNTHETIC LEATHER CO., LTD. Effective date: 20130129 |
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Free format text: CORRECT: ADDRESS; FROM: 214205 WUXI, JIANGSU PROVINCE TO: 214251 WUXI, JIANGSU PROVINCE |
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Effective date of registration: 20130129 Address after: 214251 C District, Yixing, Jiangsu Patentee after: Yixing Yuanfeng Cable Co., Ltd. Address before: 214205 No. 158 Nanyue Road, ring garden, Yixing, Jiangsu Patentee before: Yixing Xinguang Synthetic Leather Co., Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20101110 Termination date: 20160623 |
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CF01 | Termination of patent right due to non-payment of annual fee |