CN101037318A - 光触媒水泥木丝板及其生产方法 - Google Patents
光触媒水泥木丝板及其生产方法 Download PDFInfo
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 230000003287 optical effect Effects 0.000 title claims description 8
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 36
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 36
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 36
- 241001330002 Bambuseae Species 0.000 claims abstract description 34
- 239000011425 bamboo Substances 0.000 claims abstract description 34
- 230000001699 photocatalysis Effects 0.000 claims abstract description 13
- 239000004568 cement Substances 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 4
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 230000001681 protective effect Effects 0.000 claims abstract description 3
- 239000002023 wood Substances 0.000 claims description 38
- 210000002268 wool Anatomy 0.000 claims description 30
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 15
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 238000007493 shaping process Methods 0.000 claims description 3
- 238000003980 solgel method Methods 0.000 claims description 3
- 241000209128 Bambusa Species 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 239000003469 silicate cement Substances 0.000 claims description 2
- 229960001866 silicon dioxide Drugs 0.000 claims description 2
- 230000001954 sterilising effect Effects 0.000 abstract description 8
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 8
- 238000005034 decoration Methods 0.000 abstract description 4
- 238000004140 cleaning Methods 0.000 abstract description 3
- 238000002791 soaking Methods 0.000 abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 229910052681 coesite Inorganic materials 0.000 abstract 2
- 229910052906 cristobalite Inorganic materials 0.000 abstract 2
- 238000002955 isolation Methods 0.000 abstract 2
- 238000007146 photocatalysis Methods 0.000 abstract 2
- 229910052682 stishovite Inorganic materials 0.000 abstract 2
- 229910052905 tridymite Inorganic materials 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 238000004332 deodorization Methods 0.000 abstract 1
- 238000003825 pressing Methods 0.000 abstract 1
- 239000011941 photocatalyst Substances 0.000 description 11
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 238000005336 cracking Methods 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 230000001877 deodorizing effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
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- 230000005923 long-lasting effect Effects 0.000 description 2
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- 230000001070 adhesive effect Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 230000035922 thirst Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
- C04B2103/0076—Deodorizing agents
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
- C04B2111/2061—Materials containing photocatalysts, e.g. TiO2, for avoiding staining by air pollutants or the like
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- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/40—Porous or lightweight materials
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- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/52—Sound-insulating materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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Abstract
一种光触媒水泥木丝板生产方法,将刨切成的竹木丝与水泥及水混匀,压成竹木丝板,再用浸泡或喷涂的方法披覆SiO2溶凝胶,干燥成膜后再用TiO2光触媒纳米溶凝胶浸泡或喷涂带有SiO2保护膜的竹木丝板,干燥后即成。本板可广泛应用于教学楼、居室、会议厅、戏剧院、音乐厅、播音室等建筑物的装潢,具有轻质、高强度、隔音、隔热、杀菌、消毒、防霉、除臭、净化空气、自洁防污、与空气接触的表面积大、木丝不易裂化破坏等优点。
Description
技术领域
本发明涉及一种用无机胶粘剂、竹木丝、光触媒浸喷剂为主要原料的具有杀菌、消毒、分解有害污染物、隔音、隔热功能的人造板及其生产方法。
背景技术
纳米级TiO2光触媒以其长效的杀菌、抑菌、除霉、除臭、净化空气、自洁防污性能,尤其是对经装潢的人居室内的游离甲醛、游离苯酚的分解净化,解决了长期来人们渴望得到解决的问题,因此,近年倍受世人关注,应用领域不断拓宽,技术创新层出不穷。经检索查新,在竹、木板体上结合TiO2光触媒浸喷剂直接覆于板体表面,无法克服光触媒在光反应中对有机板材的快速裂化破坏,影响板材的使用寿命;二是作为浸喷光触媒的基材的板体多为平面体,与空气接触的表面积小,光触媒的效能发挥欠充分,如CN2574897Y公开的“光触媒热固性树脂装饰板”,便是一例。
发明内容
针对现有技术的上述不足,本发明的目的是提供一种用竹、木丝制作的,使板体与空气接触的表面积更大的,TiO2光触媒不直接与板体接触,从而降低裂化破坏,提高使用寿命的,且具有杀菌、消毒、防霉、除臭、净化空气、隔音、隔热性能的光触媒水泥木丝板及其生产方法。
本发明采用的技术方案是:光触媒水泥木丝板生产方法包括如下步骤:
(1)用溶胶凝胶法制成二氧化硅溶凝胶备用;
(2)市售TiO2光触媒纳米溶凝胶备用;
(3)竹木丝板的制作:切丝机从单板中切得木丝或用刨丝机从竹、木材中刨得竹木丝,或从竹段中劈得竹丝,用硅酸盐水泥或镁水泥等,按灰木丝为0.5-3∶1的比例,加水拌均匀后,控制压力0.01-1MPa压成木丝板,整形后备用;
(4)将木丝板浸或喷上SiO2溶凝胶,干燥成膜后再浸或喷上TiO2光触媒纳米凝胶,干燥后即成。
所述的光触媒水泥木丝板生产方法制成的板,是由竹丝或木丝、水泥、SiO2溶凝胶、TiO2光触媒纳米溶凝胶组成,众竹或木丝上下纵横交错、杂乱重叠,叠合成网状结构,竹木丝条或板体表面由里及外为SiO2溶凝胶保护膜层、TiO2光触媒纳米溶凝胶层。
本发明的有益效果是:用竹木丝压成的板材,呈网状结构,因而省木材、轻质、高强度、隔音、隔热,在光触媒与木丝之间夹有SiO2保护膜,降低了光触媒在光反应时对木丝的裂化破坏,不影响竹木丝的使用寿命,并具有长效的杀菌、消毒、防霉、除臭、净化空气、自洁防污性能,尤其是分解净化室内装潢造成的游离甲醛、游离苯酚的性能,解决了人们长期渴望解决的问题。
具体实施方式
本发明下面结合实施例作进一步详述:SiO2溶凝胶采用溶胶凝胶方法制备,这是同行业普通技术人员熟知的,不细述。TiO2光触媒纳米溶凝胶可向北京求流环保技术科技有限公司求购;木、竹丝板的制作需经下列工序:原竹原木的预处理、刨丝或制成单板切丝、水泥木丝及水的配比、混合搅拌、铺装成型、压制、养护调湿、整形即成木(竹)丝板。
将木竹丝板先在SiO2溶凝胶池中浸泡30S,沥干后晾干或烘干成膜,披覆在竹木丝条或竹木丝板的表面上,晾干或烘干成膜,再在TiO2光触媒纳米溶凝胶池浸泡30S,或在板表面喷涂TiO2光触媒纳米溶凝胶,干后即成。
本光触媒水泥木丝板可广泛应用于教室、居室、会议厅、剧院、医院、音乐厅、转播室、机舱、车厢等建筑物和交通工具的装潢。
木丝、竹丝长60-500mm、厚0.2-1.5mm、宽0.3-4.0mm。
本申请材料中的SiO2溶凝胶、TiO2溶凝胶以无色透明的优选,文中凡提到木丝的,都包括竹丝,反之亦然;因本竹、木丝板是与无机的水泥搅匀压制的,竹木丝外包覆有水泥层而有所遮挡,光触媒对竹木丝的裂化破坏相应较轻,也可不采用SiO2保护膜层,直接一次性浸喷在竹木丝上,但相对而言,这应属改劣方案。
Claims (2)
1、一种光触媒水泥木丝板生产方法,其特征是包括如下步骤:
(1)用溶胶凝胶法制成二氧化硅溶凝胶备用;
(2)市售TiO2光触媒纳米溶凝胶备用;
(3)竹木丝板的制作:切丝机从单板中切得木丝或用刨丝机从竹、木材中刨得竹木丝,或从竹段中劈得竹丝,用硅酸盐水泥或镁水泥等,按灰木比为0.5-3∶1的比例,加水拌均匀后,控制压力0.01-1MPa压成木丝板,整形后备用;
(4)将木丝板浸或喷上SiO2溶凝胶,干燥成膜后再浸或喷上TiO2光触媒纳米溶凝胶,干燥后即成。
2、如权利要求1所述的光触媒水泥木丝板生产方法制成的板,其特征是由竹丝或木丝、水泥、SiO2溶凝胶、TiO2光触媒纳米溶凝胶组成,众竹或木丝上下纵横交错、或杂乱重叠,叠合成网状结构,竹木丝条或板体表面由里及外为SiO2溶凝胶保护膜层、TiO2光触媒纳米溶凝胶层。
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102518275A (zh) * | 2011-12-20 | 2012-06-27 | 南京倍立达实业有限公司 | 纳米自洁纤维增强水泥制品及其生产方法 |
CN103608533A (zh) * | 2011-07-05 | 2014-02-26 | 瓦林格光催化股份有限公司 | 涂覆的木制品以及制备涂覆的木制品的方法 |
CN104788057A (zh) * | 2014-01-18 | 2015-07-22 | 上海腾音实业有限公司 | 一种竹丝水泥板及其制备方法 |
CN107311671A (zh) * | 2017-06-30 | 2017-11-03 | 长兴泓矿炉料有限公司 | 一种抗氧化碳化硅系耐火材料及其制备方法 |
CN107382364A (zh) * | 2017-06-30 | 2017-11-24 | 长兴泓矿炉料有限公司 | 一种轻量低损耗碳化硅系耐火材料及其制备方法 |
-
2007
- 2007-03-22 CN CNA200710067738XA patent/CN101037318A/zh active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103608533A (zh) * | 2011-07-05 | 2014-02-26 | 瓦林格光催化股份有限公司 | 涂覆的木制品以及制备涂覆的木制品的方法 |
CN103608533B (zh) * | 2011-07-05 | 2017-03-22 | 瓦林格光催化股份有限公司 | 涂覆的木制品以及制备涂覆的木制品的方法 |
CN102518275A (zh) * | 2011-12-20 | 2012-06-27 | 南京倍立达实业有限公司 | 纳米自洁纤维增强水泥制品及其生产方法 |
CN104788057A (zh) * | 2014-01-18 | 2015-07-22 | 上海腾音实业有限公司 | 一种竹丝水泥板及其制备方法 |
CN107311671A (zh) * | 2017-06-30 | 2017-11-03 | 长兴泓矿炉料有限公司 | 一种抗氧化碳化硅系耐火材料及其制备方法 |
CN107382364A (zh) * | 2017-06-30 | 2017-11-24 | 长兴泓矿炉料有限公司 | 一种轻量低损耗碳化硅系耐火材料及其制备方法 |
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