CN101037295A - Manganese-neodymium-zinc kiln undertone purple flower glaze - Google Patents

Abstract

The invention relates to a shoal violet glaze in a manganese-neodymium-zinc kiln which is composed of composite stained oxid and residual parent glaze with a composition of material by wt.%: albite 40-60%, stalactite 5-15%, SuZhou soil 2-5%, steatite 3-8%, zinc oxide 5-10%, strontium carbonate 5-10%, titania 1-10%, manganese oxide 1-10%, and neodymia 1-10%. The invention is a typical rare-earth staining glaze which is produced by raw material and baked in a temperature of 1190-1210 DEG C. The process arranges proper stained oxid and mates a parent glaze prompting to color development and the process is same to the common ceramic colour glaze and meets the requirement of ceramic articles of daily use so as to be suitable for producing in a large scale.

Description

Manganese-neodymium-zinc kiln undertone purple flower glaze

Technical field

The present invention relates to a kind of manganese-neodymium-zinc kiln undertone purple flower glaze, belong to the ceramic technology field.

Background technology

Along with the fierceness day by day of market competition, also be incorporated in the domestic ceramic product gradually as the high-grade fancy glaze of decorating of ceramics.

China's rare earth resources is abundant, and the Ceramic glaze color and luster that the adding rare earths material makes is pure vivid, the glossiness height; corrosion stability is strong, but the tinting strength of rare earth element is relatively poor, and decorative effect is poor; the kind of exploitation is also fewer at present, and manufacture difficulty is also bigger, is difficult for forming large-scale production.

Summary of the invention

The object of the present invention is to provide a kind of manganese-neodymium-zinc kiln undertone purple flower glaze, constant product quality, good decorating effect prepares easyly, is fit to scale operation.

Manganese-neodymium-zinc kiln undertone purple flower glaze of the present invention, the composite coloration oxide compound of being made up of 2～20% weight percent and the parent glaze of surplus are formed, and wherein the glaze formula of parent glaze is:

In the composite coloration oxide compound that 2～20% weight percent are formed, MnO ₂1～10% and Nd ₂O ₃1～10%.

SiO in the glaze formula of parent glaze ₂/ Al ₂O ₃=6～10, can obtain the transparent preferably effect that sets off.

The percentage composition of manganese-neodymium-zinc kiln undertone purple flower glaze ingredients by weight is:

Albite 40～60%, quartz 10～30%, Stalactitum 5～15%, Suzhou soil 2～5%, talcum 3～8%, zinc oxide 5～10%, Strontium carbonate powder 5～10%, titanium oxide 1～10%, manganese oxide 1～10% and Neodymium trioxide 1～10%.

Manganese neodymium zinc transmutation lilac fancy glaze of the present invention is the painted fancy glaze of a kind of typical rare earth, and product appearance elegance, meaning are deep, and good decorating effect has been catered to the urbanite and returned Piao and return psychological needs true, gentle easiness, is subjected to liking of consumers in general deeply.

The present invention adopts raw meal proportioning enamel frit makeing by arranging in pairs or groups rational coloring oxide and be equipped with the parent glaze that promotes color development, and oxidizing atmosphere is burnt till, 1190～1210 ℃ of firing temperatures, production technique is identical with conventional ceramic color glaze, and is easy and simple to handle, meet the requirement of domestic ceramic product, be fit to scale operation.

Embodiment

The invention will be further described below in conjunction with implementing.

Test raw materials used composition and see Table 1.

Table 1, the raw materials used chemical weight percentage composition table of test

Remarks: other not mentioned person is a technical pure chemical industry raw material.

Embodiment 1

Manganese-neodymium-zinc kiln undertone purple flower glaze parent glaze glaze formula of the present invention is as follows:

Manganese-neodymium-zinc kiln undertone purple flower glaze ingredients by weight of the present invention percentage composition sees Table 2.

Table 2, manganese-neodymium-zinc kiln undertone purple flower glaze ingredients by weight percentage composition table

Raw material	The coloring oxide component		The parent glaze component
											Manganese oxide	Neodymium trioxide	Zinc oxide	Titanium oxide	Albite	Quartzy	Stalactitum	Suzhou soil	Strontium carbonate powder	Talcum
	Content	5％	4％	7％	2％	45％	14％	10％	3％	6％											4％

The same with common preparation method of colored glaze, get final product in a conventional manner.

Ball milling: material: ballstone: water=1: 2: 0.8;

Fineness: 250 mesh sieves tail over less than 0.07%;

Burn till after the glazing: tunnel furnace, oxidizing atmosphere, firing temperature: 1200 ℃.

Product glaze after burning till, color are to be mingled with fine and closely woven white point in plain implicit pansy, the purple, and abundant gradation sense is arranged, and be fine and smooth soft, elegant and tasteful.

Embodiment 2

Manganese-neodymium-zinc kiln undertone purple flower glaze parent glaze glaze formula of the present invention is as follows:

Manganese-neodymium-zinc kiln undertone purple flower glaze ingredients by weight of the present invention percentage composition sees Table 3.

Table 3, neodymium-zinc kiln undertone purple flower glaze ingredients by weight percentage composition table

Raw material	The coloring oxide component		The parent glaze component
											Manganese oxide	Neodymium trioxide	Zinc oxide	Titanium oxide	Albite	Quartzy	Stalactitum	Suzhou soil	Strontium carbonate powder	Talcum
	Content	8％	6％	5％	3％	41％	14％	9％	4％	5％											5％

Making method is with embodiment 1,1210 ℃ of firing temperatures.

Product after burning till, color is deep strong than embodiment's 1, is mingled with fine and closely woven ivory white white point.

Embodiment 3

Manganese-neodymium-zinc kiln undertone purple flower glaze parent glaze glaze formula of the present invention is as follows:

Manganese-neodymium-zinc kiln undertone purple flower glaze ingredients by weight of the present invention percentage composition sees Table 4.

Table 4, manganese-neodymium-zinc kiln undertone purple flower glaze ingredients by weight percentage composition table

Raw material	The coloring oxide component		The parent glaze component
											Manganese oxide	Neodymium trioxide	Zinc oxide	Titanium oxide	Albite	Quartzy	Stalactitum	Suzhou soil	Strontium carbonate powder	Talcum
	Content	9％	5％	5％	2％	51％	10％	6％	3％	5％											4％

Making method is with embodiment 1,1190 ℃ of firing temperatures.

Product after burning till, color are to be mingled with fine and closely woven white point in the red-purple.

Embodiment 4

Manganese-neodymium-zinc kiln undertone purple flower glaze ingredients by weight of the present invention percentage composition sees the following form

Raw material	The coloring oxide component		The parent glaze component
											Manganese oxide	Neodymium trioxide	Zinc oxide	Titanium oxide	Albite	Quartzy	Stalactitum	Suzhou soil	Strontium carbonate powder	Talcum
	Content	6％	7％	7％	3％	46％	14％	5％	3％	6％											3％

Making method is with embodiment 1,1210 ℃ of firing temperatures.

Embodiment 5

Manganese-neodymium-zinc kiln undertone purple flower glaze ingredients by weight of the present invention percentage composition sees the following form

Raw material	The coloring oxide component		The parent glaze component
											Manganese oxide	Neodymium trioxide	Zinc oxide	Titanium oxide	Albite	Quartzy	Stalactitum	Suzhou soil	Strontium carbonate powder	Talcum
	Content	3％	6％	5％	3％	51％	8％	7％	4％	8％											5％

Making method is with embodiment 1,1200 ℃ of firing temperatures.

Embodiment 6

Manganese-neodymium-zinc kiln undertone purple flower glaze ingredients by weight of the present invention percentage composition sees the following form

Raw material	The coloring oxide component		The parent glaze component
											Manganese oxide	Neodymium trioxide	Zinc oxide	Titanium oxide	Albite	Quartzy	Stalactitum	Suzhou soil	Strontium carbonate powder	Talcum
	Content	10％	6％	5％	2％	42％	14％	9％	2％	5％											5％

Making method is with embodiment 1,1210 ℃ of firing temperatures.

Claims (3)

1, a kind of manganese-neodymium-zinc kiln undertone purple flower glaze is characterized in that the composite coloration oxide compound be made up of 2～20% weight percent and the parent glaze of surplus form, and wherein the glaze formula of parent glaze is:

$\left.\begin{array}{cc}0.20~0.38& {\mathrm{Na}}_{2}O\\ \mathrm{0,15}~0.88& \mathrm{CaO}\\ 0.10~0.30& \mathrm{ZnO}\\ 0.05~0.10& \mathrm{MgO}\\ 0.05~0.15& \mathrm{SrO}\end{array}\right\}0.22~0.32{\mathrm{Al}}_2{O}_3\left\{\begin{array}{c}2.10~3.22{\mathrm{SiO}}_2\\ 0.05~0.30\mathrm{Ti}{O}_2\end{array}\right.$

In the composite coloration oxide compound that 2～20% weight percent are formed, MnO ₂1～10% and Nd ₂O ₃1～10%.

2, manganese-neodymium-zinc kiln undertone purple flower glaze according to claim 1 is characterized in that SiO in the glaze formula of parent glaze ₂/ Al ₂O ₃=6～10.

3,, it is characterized in that the ingredients by weight percentage composition is according to claims 1 or 2 described manganese-neodymium-zinc kiln undertone purple flower glazes:

Albite 40～60%, quartz 10～30%, Stalactitum 5～15%, Suzhou soil 2～5%, talcum 3～8%, zinc oxide 5～10%, Strontium carbonate powder 5～10%, titanium oxide 1～10%, manganese oxide 1～10% and Neodymium trioxide 1～10%.