CN100581363C - 具有增强的除草效果的除草组合物以及增强除草效果的方法 - Google Patents
具有增强的除草效果的除草组合物以及增强除草效果的方法 Download PDFInfo
- Publication number
- CN100581363C CN100581363C CN200480021593A CN200480021593A CN100581363C CN 100581363 C CN100581363 C CN 100581363C CN 200480021593 A CN200480021593 A CN 200480021593A CN 200480021593 A CN200480021593 A CN 200480021593A CN 100581363 C CN100581363 C CN 100581363C
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- CN
- China
- Prior art keywords
- yellow grand
- salt
- alkoxylated glyceride
- polyoxyethylene
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- IMEVJVISCHQJRM-UHFFFAOYSA-N triflusulfuron-methyl Chemical group COC(=O)C1=CC=CC(C)=C1S(=O)(=O)NC(=O)NC1=NC(OCC(F)(F)F)=NC(N(C)C)=N1 IMEVJVISCHQJRM-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
一种包含除草磺酰脲化合物或其盐和烷氧基化甘油酯的除草组合物。一种防治不希望的植物或抑制其生长的方法,其包括向不希望的植物或其生长区域施用除草有效量的除草组合物。一种借助烷氧基化甘油酯增强除草磺酰脲化合物或其盐的除草效果的方法。
Description
技术领域
本发明涉及一种除草效果增强的除草组合物,其含有磺酰脲化合物或其盐作为除草活性成分。
背景技术
迄今为止已经将很多种除草剂用于保护作物,而且为了例如降低除草活性成分的剂量,通常掺入能够增强除草剂除草效果的助剂。
GB专利公开第2309904号公开了一种含有二羧酸型化合物和乙氧基化和/或丙氧基化甘油三酯的混合物,且其公开了若将该混合物与除草剂混合的话,可以增强除草效果。另外,EP 0598515A公开了通过使用乙氧基化脂肪胺型表面活性剂以及植物油和/或矿物油可以改进某些特定磺酰脲化合物的除草效果。然而,这些参考文献没有公开有关使用烷氧基化甘油酯以增强除草磺酰脲化合物或其盐的除草效果的信息。
本领域常见且可市购的磺酰脲除草剂是一种具有小施用量的除草剂。然而,从环境问题或经济效率的角度考虑,需要进一步降低其施用量。另一方面,可以通过掺入助剂而降低磺酰脲除草剂的施用量。然而,若助剂本身的用量增加的话,又可能对环境或经济效率产生不利影响。因此,需要同时降低磺酰脲除草剂和助剂的施用量。
在上述情形下,本发明人针对如何显著增强磺酰脲除草剂的除草效果从而降低其施用量进行了各种研究,最终完成了本发明。
发明内容
也就是说,本发明提供了一种含有除草磺酰脲化合物或其盐和烷氧基化甘油酯的除草组合物;一种借助该类除草组合物来防治不希望的植物的方法;以及一种借助烷氧基化甘油酯来增强磺酰脲化合物或其盐的除草效果的方法。
在本发明中,借助烷氧基化甘油酯可以显著改进磺酰脲化合物或其盐的除草效果。因此,可以提供一种除草效果显著改进的除草组合物,从而可以降低磺酰脲化合物或其盐的施用量,以及提供一种显著增强该磺酰脲化合物或其盐的除草效果的方法。另外,本发明还具有如下优点:即,增加了除草效果所能防治的植物种类或延长了应用周期。
本发明的最佳实施方式
本发明的除草组合物含有除草磺酰脲化合物或其盐和烷氧基化甘油酯。另外,本发明提供了一种防治不希望的植物或抑制其生长的方法,该方法包括向不希望的植物或其生长区域施用(a)除草有效量的除草磺酰脲化合物或其盐,和(b)有效量的烷氧基化甘油酯。本发明通过例如如下方式进行:(1)借助各种添加剂配制磺酰脲化合物或其盐,该配制剂与烷氧基化甘油酯一起例如用水稀释,并将其施用至不希望的植物或其生长区域;或(2)将磺酰脲化合物或其盐和烷氧基化甘油酯与各种添加剂一起配制,该配制剂用例如水稀释或不进行稀释,并将其施用至不希望的植物或其生长区域。在本发明中,在向不希望的植物或其生长区域的施用中,优选施用至不希望的植物本身,例如叶面施用。
在本发明中,磺酰脲化合物或其盐可以与一种或多种其它除草化合物组合使用。也就是说,本发明可以通过一种通过组合使用其它除草化合物而防治不希望的植物或抑制其生长的方法进行,其包括向不希望的植物或其生长区域施用(a)除草有效量的除草磺酰脲化合物或其盐,(b)有效量的烷氧基化甘油酯,和(c)(一种或多种)除草有效量的其它除草化合物。例如该方法可以通过如下方式进行:(1)将磺酰脲化合物或其盐以及(一种或多种)其它除草化合物借助各种添加剂单独或一起配制,该配制剂与烷氧基化甘油酯一起用例如水稀释,并将其施用至不希望的植物或其生长区域;(2)将磺酰脲化合物或其盐和烷氧基化甘油酯与各种添加剂一起配制,该配制剂与单独配制的(一种或多种)其它除草化合物一起用例如水稀释,并将其施用至不希望的植物或其生长区域;(3)将磺酰脲化合物或其盐、(一种或多种)其它除草化合物以及烷氧基化甘油酯与各种添加剂一起配制,该配制剂用例如水稀释或不进行稀释,并将其施用至不希望的植物或其生长区域;或者(4)将(一种或多种)其它除草化合物与烷氧基化甘油酯与各种添加剂一起配制,该配制剂与单独配制的磺酰脲化合物或其盐一起用例如水稀释,并将其施用至不希望的植物或其生长区域。
磺酰脲化合物为具有如下部分结构的化合物:
(其中X是氢原子或烷基),且该化合物可以例如是磺氨黄隆(amidosulfuron)、四唑黄隆(azimsulfuron)、苄嘧黄隆(bensulfuron-methyl)、氯嘧黄隆(chlorimuron-ethyl)、绿黄隆(chlorsulfuron)、醚黄隆(cinosulfuron)、环丙黄隆(cyclosulfamuron)、胺苯黄隆(ethametsulfuron-methyl)、乙氧嘧黄隆(ethoxysulfuron)、啶嘧黄隆(flazasulfuron)、氟吡磺隆(flucetosulfuron)、氟啶黄隆(flupyrsulfuron)、甲酰胺黄隆(foramsulfuron)、吡氯黄隆(halosulfuron-methyl)、啶咪黄隆(imazosulfuron)、碘黄隆(iodosulfuron)、甲磺胺黄隆(mesosulfuron-methyl)、甲黄隆(metsulfuron-methyl)、烟黄隆(nicosulfuron)、环丙氧黄隆(oxasulfuron)、氟嘧黄隆(primisulfuron-methyl)、氟丙黄隆(prosulfuron)、吡嘧黄隆(pyrazosulfuron-ethyl)、玉嘧黄隆(rimsulfuron)、嘧黄隆(sulfometuron-methyl)、乙黄黄隆(sulfosulfuron)、噻黄隆(thifensulfuron-methyl)、醚苯黄隆(triasulfuron)、苯黄隆(tribenuron-methyl)、三氟啶黄隆(trifloxysulfuron)、氟胺黄隆(triflusulfuron-methyl)或三氟甲黄隆(tritosulfuron)。其中,优选啶嘧黄隆、甲酰胺黄隆、烟黄隆、玉嘧黄隆、三氟啶黄隆或三氟甲黄隆。其中,尤其优选烟黄隆。
作为该类磺酰脲化合物的盐可以提及各种类型的盐。其例如可以是与碱金属如钠或钾的盐,与碱土金属如镁或钙的盐或与胺如单甲胺、二甲胺或三乙胺的盐。
烷氧基化甘油酯用于增强磺酰脲化合物或其盐的除草效果,其例如可以是如下所示的烷氧基化甘油酯。
作为烷氧基化甘油酯,存在甘油单酯、甘油二酯和甘油三酯,本发明包括了所有形式。
烷氧基化甘油酯在甘油酯的任意位置具有一个或多个氧化烯部分。该类氧化烯部分可以是例如氧化乙烯、氧化丙烯、其共聚物或其嵌段共聚物。氧化烯的平均总摩尔量为1-200摩尔,优选2-150摩尔,更优选10-100摩尔。
烷氧基化甘油酯的甘油酯部分例如可以是甘油或其衍生物与脂肪酸基团或其衍生物键合的脂肪酸酯,或甘油或其衍生物与磷酸基团或其衍生物键合的磷酸甘油酯。特别优选甘油或其衍生物与脂肪酸基团或其衍生物键合的脂肪酸酯。
上述甘油或其衍生物可以是例如下式(I)所表示的化合物:
(其中R是氢原子或C1-6烷基,n是0-6的整数。)
上述脂肪酸基团可以是饱和或不饱和的,且可以是直链或支化的,其碳数可以为4-24,优选10-20。该脂肪酸例如可以是饱和脂肪酸如丁酸、正己酸、辛酸、正癸酸、月桂酸、肉豆蔻酸、棕榈酸、硬脂酸、异硬脂酸或花生酸,或不饱和脂肪酸如棕榈油酸、油酸、亚油酸、亚麻酸、monocticacid、花生四烯酸或二十二碳六烯酸。其中,优选例如棕榈酸、硬脂酸、异硬脂酸或油酸。
上述脂肪酸基团可以是环状的且可以在该环状基团中含有一个或多个杂原子,或者其中亚甲基部分可以转化成氧代或硫代。其具体实例可以提及焦谷氨酸基团。另外,该脂肪酸基团可以在任意位置上被羟基取代。其具体实例可以提及蓖麻油酸基团。
另外,烷氧基化甘油酯可以在脂肪酸基团的末端(位于与甘油键合位相反的一侧)具有氧化烯,并且在该氧化烯的末端还可以进一步键合脂肪酸基团。
上述磷酸甘油酯可以是例如磷脂酰胆碱、磷脂酰乙醇胺、磷脂酰丝氨酸、磷脂酰肌醇、磷脂酰甘油或双磷脂酰甘油。
作为烷氧基化甘油酯的具体实例,例如可以提及如下物质。
聚氧乙烯氢化蓖麻油(商品名:EMANON CH-25、EMANON CH-80,EMALEX HC-5、EMALEX HC-100,Sorpol HC-10、Sorpol HC-20、SorpolHC-40、Sorpol HC-50、Sorpol HC-80、Sorpol HC-100、Sorpol HC-150,PEGNOL HC-30,NIKKOL HCO-5、NIKKOL HCO-10、NIKKOLHCO-20、NIKKOL HCO-30、NIKKOL HCO-40、NIKKOL HCO-50、NIKKOL HCO-60、NIKKOL HCO-80、NIKKO HCO-100等)
聚氧乙烯甘油基单硬脂酸酯(商品名:EMALEX GM-5、EMALEXGM-40等)
聚氧乙烯蓖麻油(商品名:EMALEX C-20、EMALEX C-50等)
聚氧乙烯甘油基三异硬脂酸酯(商品名:EMALEX GWIS-303、EMALEX GWIS-340、EMALEX GWIS-360、EMALEX GWIS-340EX等)
聚氧乙烯甘油基单异硬脂酸酯(商品名:EMALEX GWIS-103、EMALEX GWIS-115、EMALEX GWIS-125、EMALEX GWIS-160、EMALEX GWIS-160EX等)
聚氧乙烯甘油基三硬脂酸酯(商品名:EMALEX GWS-303、EMALEXGWS-320等)
聚氧乙烯甘油基二硬脂酸酯(商品名:EMALEX GWS-204等)
聚氧乙烯甘油基三油酸酯(商品名:EMALEX GWO-303、EMALEXGWO-360等)
聚氧乙烯氢化蓖麻油单异硬脂酸酯(商品名:EMALEX RWIS-105、EMALEX RWIS-158、EMALEX RWIS-150EX等)
聚氧乙烯氢化蓖麻油三异硬脂酸酯(商品名:EMALEX RWIS-305、EMALEX RWIS-360、EMALEX RWIS-360EX等)
聚氧乙烯氢化蓖麻油单月桂酸酯(商品名:EMALEX RWL-120、EMALEX RWL-160等)
聚氧乙烯1,1,1-三羟甲基丙烷三硬脂酸酯(商品名:EMALEX TPS-303、EMALEX TPS-310等)
聚氧乙烯1,1,1-三羟甲基丙烷三肉豆蔻酸酯(商品名:EMALEXTPM-303、EMALEX TPM-330等)
聚氧乙烯1,1,1-三羟甲基丙烷二硬脂酸酯(商品名:EMALEX TPS-203、EMALEX TPS-205等)
聚氧乙烯1,1,1-三羟甲基丙烷三异硬脂酸酯(商品名:EMALEXTPIS-303、EMALEX TPIS-350等)
聚氧乙烯氢化蓖麻油焦谷氨酸异硬脂酸酯(商品名:PYROTERCPI-30、PYROTER CPI-60等)
聚氧乙烯甘油基焦谷氨酸异硬脂酸酯(商品名:PYROTER GPI-25等)
在由上述商品名所表示的烷氧基化甘油酯中,EMANONS由KaoCorporation生产,EMALEX和PYROTER由Nihon Emulsion Co.,Ltd.生产,Sorpol和PEGNOL由TOHO Chemical Industry Co.,Ltd.生产,NIKKOLS由NIKKO CHEMICALS CO.,LTD生产。
在上述烷氧基化甘油酯中,优选例如聚氧乙烯氢化蓖麻油、聚氧乙烯甘油基三异硬脂酸酯、聚氧乙烯甘油基单异硬脂酸酯、聚氧乙烯1,1,1-三羟甲基丙烷三异硬脂酸酯、聚氧乙烯氢化蓖麻油焦谷氨酸异硬脂酸酯或聚氧乙烯甘油基焦谷氨酸异硬脂酸酯。
作为可以与磺酰脲化合物或其盐组合施用的(一种或多种)其它除草化合物,可以提及例如以下(1)-(10)的化合物(通用名包括其用于ISO中的名称)。在该类化合物具有盐、烷基酯或各种结构异构体如旋光异构体的情况下,即使未明确提及,上述形式当然包括在内。
(1)据信通过干扰植物的激素活性而具有除草效果的除草剂,例如苯氧基类如2,4-滴(2,4-D)、2,4-滴丙酸(2,4-DP)、2甲4氯(MCPA)、2甲4氯丁酸(MCPB)、2甲4氯丙酸(MCPP)或萘丙胺(naproanilide),芳族羧酸类如草芽平(2,3,6-TBA)、麦草畏(dicamba)、敌草腈(dichlobenil)、毒莠定(picloram)、定草酯(triclopyr)或二氯皮考啉酸(clopyralid),以及其它除草剂如草除灵(benazolin)、二氯喹啉酸(quinclorac)、喹草酸(quinmerac)、二氟吡隆(diflufenzopyr)和噻氟啶草(thiazopyr)。
(2)据信通过抑制植物的光合作用而具有除草效果的除草剂,例如脲类如绿麦隆(chlorotoluron)、敌草隆(diuron)、伏草隆(fluometuron)、利谷隆(linuron)、异丙隆(isoproturon)、色满隆(metobenzuron)或丁唑隆(tebuthiuron),三嗪类如西玛津(simazine)、莠去津(atrazine)、阿特拉通(atratone)、西草净(simetryn)、扑草净(prometryn)、戊草净(dimethametryn)、六嗪同(hexazinone)、赛克津(metribuzin)、特丁津(terbuthylazine)、草净津(cyanazine)、莠灭净(ametryn)、cybutryne、丙氧丙胺津(triaziflam)或扑灭津(propazine),尿嘧啶类如除草定(bromacil)、环草定(lenacil)或特草定(terbacil),酰替苯胺类如敌稗(propanil)或环草胺(cypromid),氨基甲酸酯类如灭草灵(swep)、异苯敌草(desmedipham)或苯敌草(phenmedipham),羟基苯甲腈类如溴苯腈(bromoxynil)、溴苯腈辛酸酯(bromoxynil-octanoate)或碘苯腈(ioxynil),以及其它除草剂如哒草止(pyridate)、灭草松(bentazon)和氨唑草酮(amicarbazone)。
(3)季铵盐类,例如百草枯(paraquat)或敌草快(diquat),据信该类除草剂在植物体中通过使本身转化为游离基而形成活性氧。
(4)据信通过抑制植物的叶绿素生物合成以及在植物体中异常地聚集光敏化过氧化物物质而具有除草效果的除草剂,例如二苯基醚类如除草醚(nitrofen)、氯硝醚(chlomethoxyfen)、治草醚(bifenox)、氟锁草醚(acifluorfen-sodium)、氟黄胺草醚(fomesafen)、氟硝草醚(oxyfluorfen)、乳氟禾草灵(lactofen)或氯氟草醚乙酯(ethoxyfen-ethyl),环亚胺类如姆克616(chlorphthalim)、氟噁嗪酮(flumioxazin)、酰亚胺苯氧乙酸戊酯(flumiclorac-pentyl)或达草氟(fluthiacet-methyl),以及其它除草剂如炔丙噁唑草(oxadiargyl)、恶草灵(oxadiazon)、磺胺草唑(sulfentrazone)、氟酮唑草(carfentrazone-ethyl)、噻二唑胺(thidiazimin)、戊噁唑草(pentoxazone)、唑啶炔草(azafenidin)、氟唑草酯(pyraflufen-ethyl)、双苯嘧草酮(benzfendizone)、氟丙嘧草酯(butafenacil)、色满隆(metobenzuron)、吲哚酮草酯(cinidon-ethyl)、胺草唑(flupoxam)、异丙吡草酯(fluazolate)、氟唑草胺(profluazol)和pyrachlonil。
(5)据信通过抑制植物的色素形成如类胡萝卜素而具有其特征为增白活性的除草效果的除草剂,例如哒嗪酮类如达草灭(norflurazon)或氟哒草(metflurazon),吡唑类如吡唑特(pyrazolate)、苄草唑(pyrazoxyfen)或吡草酮(benzofenap),以及其它除草剂如杀草强(amitrol)、氟草同(fluridone)、呋草酮(flurtamone)、吡氟草胺(diflufenican)、去草酮(methoxyphenone)、异恶草酮(clomazone)、磺草酮(sulcotrione)、硝磺酮(mesotrione)、异噁氟草(isoxaflutole)、苯敌快(difenzoquat)、isoxachlortole、benzobicyclone、picolinofen和氟丁酰草胺(beflubutamid)。
(6)据信特异针对禾本科植物具有强除草效果的除草剂,例如芳氧基苯氧基丙酸类如禾草灵(diclofop-methyl)、麦草伏M(flamprop-M-methyl)、pyriphenop-sodium、吡氟禾草灵(fluazifop-butyl)、吡氟氯禾灵(haloxyfop-methyl)、喹禾灵(quizalofop-ethyl)、氰氟草酯(cyhalofop-butyl)或噁唑禾草灵(fenoxaprop-ethyl),以及环己二酮类如枯杀述(alloxydim-sodium)、烯草酮(clethodim)、稀禾啶(sethoxydim)、肟草酮(tralkoxydim)、丁氧环酮(butroxydim)、醌肟草(tepraloxydim)、caloxydim或环苯草酮(clefoxydim)。
(7)据信通过抑制植物的氨基酸生物合成而具有除草效果的除草剂,例如***并嘧啶磺胺类如氟唑啶草(flumetsulam)、唑草磺胺(metosulam)、唑嘧磺胺(diclosulam)、唑嘧磺胺盐(cloransulam-methyl)、双氟磺草胺(florasulam)、metosulfam或五氟磺草胺(penoxsulam),咪唑啉酮类如灭草烟(imazapyr)、咪草烟(imazethapyr)、灭草喹(imazaquin)、咪草啶酸(imazamox)、咪烟唑草(imazameth)、咪草酯(imazamethabenz)或甲基咪唑烟酸(imazapic),嘧啶基水杨酸类如嘧硫苯甲酸钠(pyrithiobac-sodium)、双嘧苯甲酸钠(bispyribac-sodium)、肟啶草(pyriminobac-methyl)、嘧苯草肟(pyribenzoxim)或环酯草醚(pyriftalid),磺酰基氨基羰基***啉酮类如氟酮黄隆(flucarbazone)或丙苯黄隆(procarbazone-sodium),以及其它除草剂如草甘膦铵盐(glyphosate-ammonium)、草甘膦异丙胺盐(glyphosate-isopropylamine)、草铵膦(glufosinate-ammonium)和双丙氨酰膦(bialaphos)。
(8)据信通过抑制植物细胞有丝***而具有除草效果的除草剂,例如二硝基苯胺类如氟乐灵(trifluralin)、黄草消(oryzalin)、磺乐灵(nitralin)、胺硝草(pendimethalin)或丁氟消草(ethalfluralin),有机磷类如甲基胺草磷(amiprofos-methyl)、草胺磷(butamifos)、莎稗磷(anilofos)或哌草磷(piperophos),苯基氨基甲酸酯类如氯苯胺灵(chlorpropham)或燕麦灵(barban),枯基胺类如香草隆(daimuron)、苄草隆(cumyluron)或溴丁酰草胺(bromobutide),以及其它除草剂如黄草灵(asulam)、氟硫草定(dithiopyr)和噻氟啶草(thiazopyr)。
(9)据信通过抑制植物的蛋白质生物合成或脂质生物合成而具有除草效果的除草剂,例如硫代氨基甲酸酯类如扑草灭(EPTC)、苏达灭(butylate)、草达灭(molinate)、哌草丹(dimepiperate)、异丙吡草酯(fluazolate)、禾草畏(esprocarb)、杀草丹(thiobencarb)、稗草畏(pyributicarb)或野麦畏(trialate),氯代乙酰胺类如甲草胺(alachlor)、丁草胺(butachlor)、丙草胺(pretilachlor)、异丙甲草胺(metolachlor)、S-异丙甲草胺(S-metolachlor)、噻醚草胺(thenylchlor)、烯草胺(pethoxamid)、噻吩草胺(dimethenamid)、乙草胺(acetochlor)或扑草胺(propachlor),以及其它除草剂如乙苯酰草(etobenzanid)、苯噻草胺(mefenacet)、氟噻草胺(flufenacet)、灭草环(tridiphane)、唑草胺(cafenstrole)、四唑草胺(fentrazamide)、氯噁嗪草(oxaziclomefone)和茚草酮(indanofan)。
(10)据信通过寄生于植物上而具有除草效果的除草剂,例如野油菜黄单胞菌(Xanthomonas campestris)、Epicoccosurus nematosurus、Exserohilum monoseras和Drechsrela monoceras。
在本发明中,若需要更显著地增强磺酰脲化合物或其盐的除草效果、扩大除草效果所能有效对抗的植物类型或延长施用周期,可以使用助剂。
作为该类助剂,可以提及例如螯合剂、含氮肥料或阳离子表面活性剂。其中,优选螯合剂或含氮肥料。当施用助剂时,若需要的话,可以适当地组合使用其中的两种或更多种。
螯合剂的具体实例包括氨基多羧酸和脂族羧酸。氨基多羧酸可以是例如乙二胺四乙酸(EDTA)、亚氨基二乙酸(IDA)、氨三乙酸(NTA)、乙二醇双(2-氨基乙基醚)-N,N,N′,N′-四乙酸(EGTA)、二亚乙基三胺-N,N,N′N″,N″-五乙酸(DTPA)、环己烷二胺四乙酸(CDTA)或其盐。另外,脂族羧酸可以是例如柠檬酸、苹果酸、草酸、乳酸、葡糖酸、庚糖酸或其盐。若需要的话,可以适当地组合使用其中的两种或更多种。
含氮肥料的具体实例包括铵盐,例如硫酸铵、氯化铵、亚磷酸铵和磷酸铵;硝酸盐例如硝酸铵、硝酸钾和硝酸钙。若需要的话,可以适当地组合使用其中的两种或更多种。
阳离子表面活性剂的具体实例包括叔胺,例如烷氧基化脂肪酸胺、叔胺的盐和季铵盐。若需要的话,可以适当地组合使用其中的两种或更多种。
作为上述氨基多羧酸或脂族羧酸的盐,可以提及各种盐。例如,与碱金属如钠或钾形成的盐、与碱土金属如镁或钙形成的盐或与胺如单甲胺、二甲胺或三乙胺形成的盐。
在本发明中,磺酰脲化合物或其盐与烷氧基化甘油酯的混合比例不能一概而论,因为这可以根据磺酰脲化合物或烷氧基化甘油酯的类型、配方、气候条件、需要防治的植物的类型或大小等进行适当改变。然而,以重量比计,其例如可以在16∶1-1∶6000范围内,更优选8∶1-1∶1000,进一步优选2∶1-1∶600,仍进一步优选1∶2-1∶50。
若在本发明中使用助剂的话,其混合比例也不能一概而论,因为这可以根据磺酰脲化合物的类型、烷氧基化甘油酯的类型、助剂的类型、配方、气候条件、需要防治的植物的类型和大小等进行适当改变。然而,以重量比计,烷氧基化甘油酯与助剂的混合比例例如可以在4000∶1-1∶5范围内,优选500∶1-2∶1。
另外,若该混合比例是具体针对各种实际应用模型的话,可以提及如下情形。(1)在借助各种添加剂配制磺酰脲化合物或其盐,然后与烷氧基化甘油酯一起用例如水稀释并施用至不希望的植物或其生长区域的情况下,所配制的磺酰脲化合物或其盐和烷氧基化甘油酯用10-3000升/公顷,优选50-2000升/公顷、更优选100-1000升/公顷的水稀释,基于稀释的液体,以0.005-4重量%,优选0.01-2重量%、更优选0.02-0.5重量%的量加入烷氧基化甘油酯。(2)在将磺酰脲化合物或其盐和烷氧基化甘油酯与各种添加剂一起配制,然后用例如水稀释或不进行稀释,施用至不希望的植物或其生长区域的情况下,可以将磺酰脲化合物或其盐和烷氧基化甘油酯进行混合以使其比例落入上述重量比范围内。(3)在组合使用一种或多种其它除草化合物与磺酰脲化合物或其盐的情况下,可以按照上述情形(1)或(2)中的混合比例进行操作。(4)在另外还使用助剂,并以与上述相同的方式将其用水稀释的情况下,基于稀释的液体,在上述各情形(1)、(2)和(3)中,加入的助剂量可以为0.0001-0.05重量%,优选0.001-0.01重量%。
在本发明中,(1)在其中磺酰脲化合物或其盐和(一种或多种)其它除草化合物借助各种添加剂单独或一起配制的情况下,(2)在其中磺酰脲化合物或其盐和烷氧基化甘油酯与各种添加剂一起配制的情况下,(3)在其中磺酰脲化合物或其盐、(一种或多种)其它除草化合物和烷氧基化甘油酯与各种添加剂一起配制的情况下,或(4)在其中磺酰脲化合物或其盐、(一种或多种)其它除草化合物、烷氧基化甘油酯和助剂与各种添加剂一起配制的情况下,它们可以配制成各种配制剂。例如,可以提及各种配制剂如可湿性粉剂、水分散性颗粒剂、基于水的悬浮剂、基于油的悬浮剂、凝胶配制剂、乳油、水溶性颗粒剂、乳剂、微乳剂、悬浮乳剂、复合型乳剂(multipleemulsion)。本发明中使用的各种添加剂可以是该技术领域常用的任何添加剂,可以提及例如表面活性剂、载体、溶剂、植物油、矿物油、抗沉降剂、增稠剂、防沫剂、防冻剂、抗氧化剂、吸油剂、胶凝剂、填料、分散体稳定剂、降低植物毒性剂、防霉剂(anti-mold agent)、粘合剂、稳定剂、崩解剂、防腐剂以及无机铵盐。可提及如下物质作为上述各种添加剂的具体实例。另外,该类配制剂可以按照该技术领域常用的方法制备。
表面活性剂包括例如阴离子表面活性剂,如脂肪酸的盐、苯甲酸盐、磺基琥珀酸烷基酯、磺基琥珀酸二烷基酯、聚羧酸酯、烷基硫酸酯的盐、烷基硫酸盐、烷基芳基硫酸盐、烷基二甘醇醚硫酸盐、醇硫酸酯的盐、烷基磺酸盐、烷基芳基磺酸盐、芳基磺酸盐、木素磺酸盐、烷基二苯基醚二磺酸盐、聚苯乙烯磺酸盐、烷基磷酸酯的盐、烷基芳基磷酸盐、苯乙烯基芳基磷酸盐、聚氧乙烯烷基醚硫酸酯的盐、聚氧乙烯烷基芳基醚硫酸盐、聚氧乙烯苯乙烯基芳基醚硫酸盐、聚氧乙烯苯乙烯基芳基醚硫酸铵、聚氧乙烯烷基芳基醚硫酸酯的盐、聚氧乙烯烷基醚磷酸盐、聚氧乙烯烷基芳基磷酸酯的盐、聚氧乙烯苯乙烯基芳基醚磷酸酯或其盐、萘磺酸酯与甲醛水溶液的缩合物的盐以及烷基萘硫酸酯与甲醛水溶液的缩合物的盐;非离子表面活性剂例如失水山梨糖醇脂肪酸酯、甘油脂肪酸酯、脂肪酸甘油多酯、脂肪酸醇聚二醇醚、炔属二醇、炔属醇、氧化烯嵌段聚合物、聚氧乙烯烷基醚、聚氧乙烯烷基芳基醚、聚氧乙烯苯乙烯基芳基醚、聚氧乙烯二醇烷基醚、聚氧乙烯脂肪酸酯、聚氧乙烯失水山梨糖醇脂肪酸酯、聚氧乙烯甘油脂肪酸酯、聚氧乙烯氢化蓖麻油以及聚氧丙烯脂肪酸酯;和阳离子表面活性剂如烷氧基化脂肪酰胺。若需要的话,可以适当地组合使用其中的两种或更多种。
载体或填料可以是例如硅藻土、熟石灰、碳酸钙、滑石、白碳黑、高岭土、膨润土、高岭土和绢云母的混合物、粘土、碳酸钠、碳酸氢钠、芒硝、沸石、淀粉、氯化钠、磷酸铵、硫酸铵、氯化铵、糖、尿素、乳糖或葡萄糖。若需要的话,可以适当地组合使用其中的两种或更多种。
溶剂可以是例如水、溶剂石脑油、石蜡、二噁烷、丙酮、异佛尔酮、甲基异丁基酮、氯苯、环己烷、二甲亚砜、二甲基甲酰胺、N-甲基-2-吡咯烷酮、醇、乙酸、丁酸、乙酸异丙酯、乙酸丁酯、苯、烷基苯或烷基萘。若需要的话,可以适当地组合使用其中的两种或更多种。
植物油可以是例如橄榄油、爪哇木棉油、蓖麻油、番木瓜油、山茶油、椰子油、芝麻油、玉米油、米糠油、花生油、棉籽油、大豆油、油菜籽油、亚麻子油、桐油、向日葵油、红花油,或由上述各种油衍生的脂肪酸或该类脂肪酸的烷基酯。矿物油可以是例如脂族烃,如液体石蜡或石蜡类石油,或芳族烃如烷基苯或烷基萘。若需要的话,可以适当地组合使用其中的两种或更多种。上述脂肪酸可以是例如C12-22饱和或不饱和脂肪酸,例如月桂酸、棕榈酸、硬脂酸、油酸、亚油酸、亚油酸、芥酸或巴西烯酸,及其烷基酯如C1-18直链或支链烷基酯,例如甲酯、丁酯、异丁酯或油酯。
抗沉降剂可以是例如硅石、有机膨润土(膨润土-烷基氨基配合物)、膨润土、白碳黑或硅酸铝镁。若需要的话,可以适当地组合使用其中的两种或更多种。
增稠剂可以是例如杂多糖如黄原胶或瓜耳胶,水溶性聚合物如聚乙烯醇,羧甲基纤维素的钠盐或藻酸钠,膨润土或白碳黑。若需要的话,可以适当地组合使用其中的两种或更多种。
防沫剂可以是例如聚二甲基硅氧烷或炔属醇。若需要的话,可以适当地组合使用其中的两种或更多种。
防冻剂可以是例如乙二醇、丙二醇、甘油或尿素。若需要的话,可以适当地组合使用其中的两种或更多种。
吸油剂可以是例如二氧化硅、水解淀粉、高岭土、粘土、滑石、硅藻土、硅藻土/石灰的合成产品、石棉、高岭石和绢云母的混合物、硅酸钙、碳酸钙、碳酸硅酸钙、酸性粘土、碳黑、石墨、珍珠岩加工产品、氧化铝、二氧化钛、碱性碳酸镁、硅酸铝镁、硅石-氧化铝填料或水合硅酸镁。若需要的话,可以适当地组合使用其中的两种或更多种。
胶凝剂可以是例如硅石、有机绿坡缕石、粘土、氢化蓖麻油、高级脂肪酸酯、高级醇、二烷基磺基琥珀酸酯的盐、苯甲酸盐、烷基硫酸盐、聚丙烯酸聚合物或聚丙烯酸共聚物与水的混合物或12-羟基硬脂酸。若需要的话,可以适当地组合使用其中的两种或更多种。
粘合剂可以是例如木素磺酸、黄原胶、羧甲基纤维素或淀粉。若需要的话,可以适当地组合使用其中的两种或更多种。
稳定剂可以是例如尿素。
崩解剂可以是例如羧甲基纤维素的钙盐、无机盐例如硫酸铵、氯化钾或氯化镁、以及上述表面活性剂中显示出崩解活性的物质,例如月桂基硫酸钠、十二烷基苯磺酸钠或聚丙烯酸铵。若需要的话,可以适当地组合使用其中的两种或更多种。
防腐剂可以是例如甲醛水溶液、对氯间二甲苯酚或1,2-苯并异噻唑-3-酮。若需要的话,可以适当地组合使用其中的两种或更多种。
在上述各种配制剂中,各组分的混合比例不能一概而论,因为它们可以适当地根据混合组分的类型、配方或施用地点而变化。然而可以例如通过如下方式制备配制剂,即以0.1-95重量份,优选2-85重量份的比例掺入磺酰脲化合物或其盐,其余则以5-99.9重量份,优选15-98重量份的比例掺入各种添加剂。此外,在根据需要以0.1-94.9重量份,优选5-60重量份的比例掺入烷氧基化甘油酯的情况下,在根据需要以0.1-94.9重量份,优选0.5-75重量份的比例掺入(一种或多种)其它除草化合物的情况下,或在根据需要以0.1-94.9重量份,优选0.2-60重量份的比例掺入助剂的情况下,通过掺入剩余量(使总量为100重量份)的各种添加剂而制得配制剂。下面对某些配制剂中各组分的混合比例进行示例性说明,但是应当理解绝不以任何方式使本发明限制于这些具体配制剂。
在可湿性粉剂情况下,可按如下所述制备配制剂,即掺入比例为0.1-95重量份,优选5-85重量份的磺酰脲化合物或其盐,混入比例为0.5-40重量份,优选5-30重量份的表面活性剂,其余部分则混入比例为4.5-99.4重量份,优选10-90重量份的载体或填料。此外,在根据需要掺入比例为0.1-94.9重量份,优选10-60重量份的烷氧基化甘油酯的情况下,在根据需要掺入比例为0.1-94.9重量份,优选0.5-75重量份的(一种或多种)其它除草化合物的情况下,在根据需要掺入比例为0.1-94.9重量份,优选0.2-60重量份的助剂的情况下,或在根据需要掺入比例为1-90重量份,优选1-50重量份的吸油剂的情况下,通过掺入剩余量(使总量为100重量份)的载体或填料而制备配制剂。
在水分散性颗粒剂情况下,可按如下所述制备配制剂,即掺入比例为0.1-95重量份,优选5-85重量份的磺酰脲化合物或其盐和比例为0.5-40重量份,优选5-30重量份的表面活性剂,其余部分则混入比例为4.5-99.4重量份,优选10-90重量份的载体或填料。此外,在根据需要掺入比例为0.1-94.9重量份,优选10-60重量份的烷氧基化甘油酯的情况下,在根据需要掺入比例为0.1-94.9重量份,优选0.5-75重量份的(一种或多种)其它除草化合物的情况下,在根据需要掺入比例为0.1-94.9重量份,优选0.2-60重量份的助剂的情况下,在根据需要掺入比例为0.1-10重量份,优选0.5-5重量份的粘合剂的情况下,在根据需要掺入比例为0.1-40重量份,优选0.5-20重量份的崩解剂的情况下,或在根据需要掺入比例为1-90重量份,优选1-50重量份的吸油剂的情况下,通过掺入剩余量(使总量为100重量份)的载体或填料而制备配制剂。
在基于水的悬浮剂情况下,可按如下所述制备配制剂,即掺入比例为0.1-60重量份,优选2-50重量份的磺酰脲化合物或其盐和比例为0.5-20重量份,优选1-15重量份的表面活性剂,其余部分则掺入比例为25-99.4重量份,优选30-97重量份的水。此外,在根据需要掺入比例为0.1-60重量份,优选5-40重量份的烷氧基化甘油酯的情况下,在根据需要掺入比例为0.1-60重量份,优选0.5-30重量份的(一种或多种)其它除草化合物的情况下,在根据需要掺入比例为0.1-60重量份,优选0.2-40重量份的助剂的情况下,在根据需要掺入比例为0.05-3重量份,优选0.1-1重量份的防沫剂的情况下,在根据需要掺入比例为0.5-10重量份,优选2-10重量份的防冻剂的情况下,在根据需要掺入比例为0.1-5重量份,优选0.5-3重量份的抗沉降剂的情况下,在根据需要掺入比例为0.1-5重量份,优选0.1-2重量份的增稠剂的情况下,或在根据需要掺入比例为0.01-1重量份,优选0.05-0.2重量份的防腐剂的情况下,通过掺入剩余量(使总量为100重量份)的水而制备配制剂。
在基于油的悬浮剂情况下,可按如下所述制备配制剂,即掺入比例为0.1-40重量份,优选2-35重量份的磺酰脲化合物或其盐和比例为1-30重量份,优选1-25重量份的表面活性剂,其余部分则掺入比例为10-98.9重量份,优选20-97重量份的植物油或矿物油。此外,在根据需要掺入比例为0.1-80重量份,优选5-60重量份的烷氧基化甘油酯的情况下,在根据需要掺入比例为0.1-40重量份,优选0.5-30重量份的(一种或多种)其它除草化合物的情况下,在根据需要掺入比例为0.1-40重量份,优选0.2-35重量份的助剂的情况下,在根据需要掺入比例为0.1-5重量份,优选0.5-3重量份的抗沉降剂的情况下,或在根据需要掺入比例为0.1-20重量份,优选1-10重量份的防腐剂的情况下,通过掺入剩余量(使总量为100重量份)的植物油或矿物油而制备配制剂。
在凝胶配制剂情况下,可按如下所述制备配制剂,即掺入比例为0.1-40重量份,优选2-30重量份的磺酰脲化合物或其盐,比例为1-30重量份,优选1-15重量份的表面活性剂和比例为0.1-50重量份,优选5-40重量份的胶凝剂,其余部分则掺入比例为10-98.8重量份,优选20-92重量份的植物油或矿物油。此外,在根据需要掺入比例为0.1-60重量份,优选5-25重量份的烷氧基化甘油酯的情况下,在根据需要掺入比例为0.1-30重量份,优选0.5-20重量份的(一种或多种)其它除草化合物的情况下,在根据需要掺入比例为0.1-40重量份,优选0.2-30重量份的助剂的情况下,或在根据需要掺入比例为0.1-3重量份,优选0.5-2重量份的抗沉降剂的情况下,通过掺入剩余量(使总量为100重量份)的植物油或矿物油而制备配制剂。
通过向不希望的植物或其生长区域施药,例如通过叶面施药,本发明的除草组合物能够防治宽范围的杂草或抑制它们的生长,所述杂草包括例如莎草科(Cyperaceae)如碎米莎草(Cyperus iria L.)或香附子(Cyperusrotundus L.),禾本科(gramineae)如稗(Echinochloa crus-galli L.)、马唐(Digitaria sanguinalis L.)、狗尾草(Setaria viridis L.)、牛筋草(Eleusineindica L.)、野燕麦(Avena fatua L.)、石茅高粱(Sorghum halepense L.)或偃麦草草(Agropyron repens L.),以及阔叶杂草例如苘麻(Abutilontheophrasti MEDIC.)、圆叶牵牛(Ipomoea purpurea L.)、藜(Chenopodiumalbum L.)、刺黄花稔(Sida spinosa L.)、马齿苋(Portulaca oleracea L.)、西风古(Amaranthus retroflexus L.)、钝叶决明(Cassia obtusifolia L.)、龙葵(Solanum nigrum L.)、酸模叶蓼(Polygonum lapathifolium L.)、繁缕(Stellaria media L.)、欧州苍耳(Xanthium strumarium L.)、碎米荠(Cardamine flexuosa WITH.)、宝盖草(Lamium amplexicaule L.)或铁苋菜(Acalypha austalis L.)。因此,其应用范围不仅在于作物田地,而且还扩展到农田如果园或桑园,以及非农业区域如森林、农路、运动场、工厂厂区和草坪。磺酰脲化合物或其盐可以1-500g/公顷,优选2-250g/公顷的量施用。特别地,含有烟黄隆或其盐和烷氧基化甘油酯的除草组合物能够防治有害杂草或抑制其生长,同时不会对玉米产生植物毒性,因此其非常适合用于玉米田地。烟黄隆可以2-400g/公顷,优选5-200g/公顷的量施用。另外,其还可以与其它农用化学品、肥料、植物毒性降低剂等组合或混合使用,预期将具有更好的活性或效果。
下面对本发明的某些优选实施方案进行示例性说明。然而,本发明绝不受限于此。
(1)上述除草组合物,其包含a)除草有效量的磺酰脲化合物或其盐和b)增强除草活性的有效量的烷氧基化甘油酯。
(2)上述除草组合物,其包含a)磺酰脲化合物或其盐、b)增强除草活性的有效量的烷氧基化甘油酯和c)增强除草活性的有效量的助剂。
(3)上述除草组合物,其特征在于将磺酰脲化合物或其盐和烷氧基化甘油酯与添加剂一起配制。
(4)上述除草组合物,其特征在于将磺酰脲化合物或其盐、烷氧基化甘油酯和助剂与添加剂一起配制。
(5)上述除草组合物,其特征在于其包含磺酰脲化合物或其盐和烷氧基化甘油酯,其形式为可施用至不希望的植物或其生长区域的水稀释性液体。
(6)上述除草组合物,其特征在于其包含磺酰脲化合物或其盐、烷氧基化甘油酯和助剂,其形式为可施用至不希望的植物或其生长区域的水稀释性液体。
(7)上述除草组合物,其还含有除草有效量的(一种或多种)其它除草化合物。
(8)上述除草组合物,其特征在于磺酰脲化合物或其盐的除草效果通过烷氧基化甘油酯而增强。
(9)上述除草组合物,其特征在于磺酰脲化合物或其盐的除草效果通过烷氧基化甘油酯和助剂而增强。
(10)上述除草组合物,其特征在于包含磺酰脲化合物或其盐以及(一种或多种)其它除草化合物的除草组合物的除草效果通过烷氧基化甘油酯而增强。
(11)上述除草组合物,其特征在于包含磺酰脲化合物或其盐以及(一种或多种)其它除草化合物的除草组合物的除草效果通过烷氧基化甘油酯和助剂而增强。
(12)上述防治不希望的植物或抑制其生长的方法,其包括向不希望的植物或其生长区域施用a)除草有效量的磺酰脲化合物或其盐、和b)增强除草活性的有效量的烷氧基化甘油酯。
(13)上述防治不希望的植物或抑制其生长的方法,其包括向不希望的植物或其生长区域施用a)除草有效量的磺酰脲化合物或其盐、b)增强除草活性的有效量的烷氧基化甘油酯和c)增强除草活性的有效量的助剂。
(14)上述防治不希望的植物或抑制其生长的方法,其包括借助各种添加剂配制磺酰脲化合物或其盐,与烷氧基化甘油酯一起用水稀释,并施用至不希望的植物或其生长区域。
(15)上述防治不希望的植物或抑制其生长的方法,其包括借助各种添加剂配制磺酰脲化合物或其盐,与烷氧基化甘油酯和助剂一起用水稀释,并施用至不希望的植物或其生长区域。
(16)上述防治不希望的植物或抑制其生长的方法,其包括将磺酰脲化合物或其盐和烷氧基化甘油酯与各种添加剂一起配制,用水稀释,并施用至不希望的植物或其生长区域。
(17)上述防治不希望的植物或抑制其生长的方法,其包括将磺酰脲化合物或其盐、烷氧基化甘油酯和助剂与各种添加剂一起配制,用水稀释,并施用至不希望的植物或其生长区域。
(18)上述防治不希望的植物或抑制其生长的方法,其特征在于对不希望的植物应用叶面施药。
(19)上述防治不希望的植物或抑制其生长的方法,其中还含有除草有效量的(一种或多种)其它除草化合物。
(20)上述增强磺酰脲化合物或其盐的除草效果的方法,其借助增强除草活性的有效量的烷氧基化甘油酯。
(21)上述增强磺酰脲化合物或其盐的除草效果的方法,其借助增强除草活性的有效量的烷氧基化甘油酯以及增强除草活性的有效量的助剂。
(22)上述增强含有磺酰脲化合物或其盐和(一种或多种)其它除草化合物的除草组合物的除草效果的方法,其借助增强除草活性的有效量的烷氧基化甘油酯以及增强除草活性的有效量的助剂。
实施例
实施例1
(1)烟黄隆(纯度:93.6%):81.78重量份
(2)烷基萘磺酸钠与甲醛水溶液缩合物(商品名:Supragil MNS/90,由Rhodia Nicca,Ltd.生产):5重量份
(3)十二烷基苯磺酸钠(商品名:Neogen Powder,由DAI-ICHIKOGYO SEIYAKU CO.,LTD.生产):13.22重量份
将上述组分均匀混合,向其中加入水,随后捏合,然后挤出造粒,干燥并调节尺寸得到水分散性颗粒剂。将该水分散性颗粒剂与烷氧基化甘油酯一起用水稀释,然后施用。
实施例2
[1]
(1)十二烷基苯磺酸钠(商品名:Sorpol 5060,由TOHO ChemicalIndustry Co.,Ltd.生产):2重量份
(2)聚氧乙烯壬基苯基醚硫酸盐(商品名:Sorpol 5073,由TOHOChemical Industry Co.,Ltd.生产):3重量份
(3)聚氧乙烯十二烷基苯基醚(商品名:Noigen EA-33,由DAI-ICHIKOGYO SEIYAKU CO.,Ltd.生产):1重量份
(4)粘土(商品名:hydrated clay,由TODOROKI SANGYO CO.,Ltd.生产):78重量份
(5)白碳黑(商品名:Carplex#80,由Shionogi&Co.,Ltd.生产):16重量份
将上述组分混合,得到共混物[A]。
[2]
(1)甲酰胺黄隆(纯度:99.6%):10重量份
(2)共混物[A]:90重量份
将上述组分混合,得到可湿性粉剂。该可湿性粉剂与烷氧基化甘油酯一起用水稀释,然后施用。
实施例3
(1)三氟甲黄隆(纯度:至少98%):10重量份
(2)上述实施例2中得到的共混物[A]:90重量份
将上述组分混合,得到可湿性粉剂。该可湿性粉剂与烷氧基化甘油酯一起用水稀释,然后施用。
实施例4
(1)烟黄隆(纯度:94.3%):10.7重量份
(2)聚羧酸酯(商品名:Geropon T/36,由Rhodia Nicca,Ltd.生产):3重量份
(3)Supragil MNS/90(商品名):4.3重量份
(4)烷基萘磺酸钠(商品名:Supragil WP,由Rhodia Nicca,Ltd.生产):2重量份
(5)Carplex#80(商品名):33.3重量份
(6)聚氧乙烯氢化蓖麻油(商品名:EMANON CH-25,由KaoCorporation生产):46.7重量份
将EMANON CH-25吸附于Carplex#80上,然后向其中混入其它组分,得到可湿性粉剂。
实施例5
(1)烟黄隆(纯度:94.3%):10.7重量份
(2)Supragil MNS/90(商品名):5重量份
(3)Neogen Powder(商品名):14.3重量份
(4)Carplex#80(商品名):35重量份
(5)聚氧乙烯氢化蓖麻油(商品名:EMANON CH-80,由KaoCorporation生产):35重量份
将熔融的EMANON CH-80吸附于Carplex#80上,然后向其中混入其它组分。向其中加入水,随后捏合,然后挤出造粒,干燥并调节尺寸,得到水分散性颗粒剂。
实施例6
(1)烟黄隆(纯度:94.3%):10.7重量份
(2)Supragil MNS/90(商品名):5重量份
(3)Neogen Powder(商品名):12.3重量份
(4)木素磺酸钠(商品名:New Kalgen WG-4,由TAKEMOTO OIL&FAT CO.,Ltd.生产):2重量份
(5)Carplex#80(商品名):35重量份
(6)聚氧乙烯氢化蓖麻油焦谷氨酸异硬脂酸酯(商品名:PYROTERCPI-60,由Nihon Emulsion Co.,Ltd.生产):35重量份
将熔融的PYROTER CPI-60吸附于Carplex#80上,然后向其中混入其它组分。向其中加入水,随后捏合,然后挤出造粒,干燥并调节尺寸,得到水分散性颗粒剂。
实施例7
(1)烟黄隆(纯度:94.3%):10.7重量份
(2)Supragil MNS/90(商品名):5重量份
(3)十二烷基苯磺酸钙(商品名:Rhodacal 70,由Rhodia Nicca,Ltd.生产):4重量份
(4)膨润土(商品名:KUNIGELV1,由Kunimine Industries Co.,Ltd.生产):10.3重量份
(5)Carplex#80(商品名):35重量份
(6)聚氧乙烯甘油基三异硬脂酸酯(商品名:EMALEX GWIS-360,由Nihon Emulsion Co.,Ltd.生产):35重量份
将熔融的EMALEX GWIS-360吸附于Carplex#80上,然后向其中混入其它组分。向其中加入水,随后捏合,然后挤出造粒,干燥并调节尺寸,得到水分散性颗粒剂。
实施例8
(1)烟黄隆(纯度:93.4%):5.35重量份
(2)聚氧乙烯三苯乙烯基苯基醚磷酸酯(商品名:Soprophor 3D33,由Rhodia Nicca,Ltd.生产):5重量份
(3)聚二甲基硅氧烷(商品名:Rhodorsil antifoam 432,由RhodiaNicca,Ltd.生产):0.1重量份
(4)丙二醇:5重量份
(5)水:54.55重量份
(6)EMANON CH-25(商品名):30重量份
将上述组分混合,通过湿磨机湿研磨5分钟,得到基于水的悬浮剂。
实施例9
(1)烟黄隆(纯度:93.4%):32.11重量份
(2)Soprophor 3D33(商品名):5重量份
(3)Rhodorsil antifoam 432(商品名):0.1重量份
(4)丙二醇:5重量份
(5)水:37.79重量份
(6)EMANON CH-25(商品名):20重量份
将上述组分混合,通过湿磨机湿研磨5分钟,得到基于水的悬浮剂。
实施例10
(1)烟黄隆(纯度:93.4%):4.93重量份
(2)聚氧乙烯氢化蓖麻油和磺基琥珀酸二辛酯的混合物:10.46重量份
(3)膨润土-烷基氨基配合物(商品名:New D Orben,由SHIRAISHIKOGYO KAISHA,Ltd.生产):1.05重量份
(4)玉米油:62.64重量份
(5)EMANON CH-25(商品名):20.92重量份
将上述组分混合,通过湿磨机湿研磨15分钟,得到基于油的悬浮剂。
实施例11
(1)烟黄隆(纯度:93.4%):7.38重量份
(2)聚氧乙烯氢化蓖麻油和磺基琥珀酸二辛酯的混合物:10.46重量份
(3)New D Orben(商品名):1.05重量份
(4)玉米油:49.73重量份
(5)EMANON CH-25(商品名):31.38重量份
将上述组分混合,通过湿磨机湿研磨15分钟,得到基于油的悬浮剂。
实施例12
(1)烟黄隆(纯度:93.4%):4.93重量份
(2)聚氧乙烯氢化蓖麻油和磺基琥珀酸二辛酯的混合物:10.46重量份
(3)New D Orben(商品名):0.53重量份
(4)尿素:2.09重量份
(4)玉米油:61.07重量份
(5)EMANON CH-25(商品名):20.92重量份
上述组分混合后,通过湿磨机湿法研磨15分钟得到基于油的悬浮剂。
实施例13
(1)烟黄隆(纯度:93.4%):11.7重量份
(2)聚氧乙烯氢化蓖麻油和烷基芳基磺酸酯的混合物:10重量份
(3)芳族烃溶剂(商品名:Solvesso 150,EXXON CHEMICAL生产):28.3重量份
(4)EMANON CH-25(商品名):50重量份
将上述组分混合,通过湿磨机湿研磨10分钟,得到基于油的悬浮剂。
实施例14
(1)烟黄隆(纯度:93.4%):11.7重量份
(2)聚氧乙烯氢化蓖麻油和烷基芳基磺酸酯的混合物:10重量份
(3)尿素:3重量份
(4)Solvesso 150(商品名):25.3重量份
(5)EMANON CH-25(商品名):50重量份
将上述组分混合,通过湿磨机湿研磨10分钟,得到基于油的悬浮剂。
实施例15
[1]
(1)烟黄隆(纯度:93.4%):4.93重量份
(2)聚氧乙烯氢化蓖麻油和磺基琥珀酸二辛酯的混合物:10.46重量份
(3)New D Orben(商品名):1.05重量份
(4)玉米油:62.64重量份
(5)EMANON CH-25(商品名):20.92重量份
将上述组分混合,通过湿磨机湿研磨15分钟,得到共混物[B]。
[2]
(1)磺基琥珀酸二辛酯钠和苯甲酸钠的混合物(商品名:New KalgenEX-70,由TAKEMOTO OIL&FAT CO.,Ltd.生产):50重量份
(2)玉米油:50重量份
将上述组分在180℃下混合30分钟,然后放置冷却,得到共混物[C]。
[3]
(1)共混物[B]:50重量份
(2)共混物[C]:50重量份
上述组分在80℃下混合5分钟,然后放置冷却,得到凝胶配制剂。
实施例16
(1)烟黄隆(纯度:93.4%):7.38重量份
(2)聚氧乙烯氢化蓖麻油和磺基琥珀酸二辛酯的混合物:10.46重量份
(3)尿素:3.14重量份
(4)玉米油:52.87重量份
(5)EMANON CH-25(商品名):26.15重量份
将上述组分混合,通过湿磨机湿研磨10分钟,得到基于油的悬浮剂。
实施例17
(1)烟黄隆(纯度:93.4%):7.38重量份
(2)聚氧乙烯氰化蓖麻油和磺基琥珀酸二辛酯的混合物:10.46重量份
(3)尿素:3.14重量份
(4)玉米油:47.64重量份
(5)EMANON CH-25(商品名):31.38重量份
将上述组分混合,通过湿磨机湿研磨10分钟,得到基于油的悬浮剂。
实施例18
(1)烟黄隆(纯度:93.4%):8.56重量份
(2)Geropon T/36(商品名):3重量份
(3)Supragil WP(商品名):2重量份
(4)烷基萘磺酸钠与甲醛水溶液缩合物(商品名:Supragil MNS/25,由Rhodia Nicca,Ltd.):5重量份
(5)粘土(商品名:MS clay,由Fubasamiclay Co.,Ltd.生产):9.44重量份
(6)EMANON CH-25(商品名):40重量份
(7)Carplex#80(商品名):32重量份
将熔融的EMANON CH-25吸附于Carplex#80上,然后向其中混入其它组分,得到可湿性粉剂。
实施例19
(1)烟黄隆(纯度:93.4%):8.56重量份
(2)Geropon T/36(商品名):3重量份
(3)Supragil WP(商品名):2重量份
(4)Supragil MNS/25(商品名):5重量份
(5)MS Clay(商品名):9.44重量份
(6)EMANON CH-80(商品名):40重量份
(7)Carplex#80(商品名):32重量份
将熔融的EMANON CH-25吸附于Carplex#80上,然后向其中混入其它组分,得到可湿性粉剂。
测试实施例1
将马唐种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当马唐长至3叶阶段时,将按照实施例1配制的规定量(20g a.i./公顷)的含有烟黄隆作为活性成分的水分散性颗粒剂用水稀释至相当于300升/公顷,以0.05重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。另外,为了进行对比,使用乙氧基化动物脂肪胺类助剂(商品名:Frigate,由ISK Biosciences Europe S.A.生产)替代烷氧基化甘油酯,以相同方式进行叶面施药。
在施用除草剂后的第21天,通过肉眼观察马唐的生长(生长抑制比(%)=0:未处理区至100:完全杀灭),从而得到如表1所示的结果。
如下结果由表1显而易见。市售助剂Frigate增强了烟黄隆的除草效果。然而,烷氧基化甘油酯甚至在相同浓度下更加显著地增强了烟黄隆的除草效果。
表1
测试实施例2
将龙葵种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当龙葵长至2.2叶阶段时,将按照实施例1配制的规定量(20g a.i./公顷)的含有烟黄隆作为活性成分的水分散性颗粒剂用水稀释至相当于300升/公顷,以0.1重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。另外,为了进行对比,使用聚氧乙烯失水山梨糖醇单月桂酸酯类助剂(相当于市售的助剂Tween 20,由NACALAI TESQUE生产)替代烷氧基化甘油酯,以相同方式进行叶面施药。
在施用除草剂后的第21天,按照与前面测试实施例1相同的方式观察龙葵的生长,从而得到如表2所示的结果。
如下结果由表2显而易见。市售助剂聚氧乙烯失水山梨糖醇单月桂酸酯增强了烟黄隆的除草效果。然而,烷氧基化甘油酯甚至在相同浓度下更加显著地增强了烟黄隆的除草效果。
表2
测试实施例3
将西风古种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当西风古长至3.6叶阶段时,将按照前面实施例1配制的规定量(5g a.i./公顷)的含有烟黄隆作为活性成分的水分散性颗粒剂用水稀释至相当于300升/公顷,以0.025重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。另外,为了进行对比,使用烷基芳基聚二醇醚类助剂(商品名:Citowett,由BASF France生产)替代烷氧基化甘油酯,以相同方式进行叶面施药。
在施用除草剂后的第21天,按照与测试实施例1相同的方式观察西风古的生长,从而得到如表3所示的结果。
如下结果由表3显而易见。市售助剂Citowett增强了烟黄隆的除草效果。然而,烷氧基化甘油酯甚至在相同浓度下更加显著地增强了烟黄隆的除草效果。
表3
测试实施例4
将马唐种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当马唐长至3叶阶段时,将规定量(15g a.i./公顷)的含有啶嘧黄隆作为活性成分的水分散性颗粒剂(商品名:KATANA,由Ishihara SangyoKaisha,Ltd.生产)用水稀释至相当于300升/公顷,以0.025重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。另外,为了进行对比,使用Citowett(与测试实施例3相同)替代烷氧基化甘油酯,以相同方式进行叶面施药。
在施用除草剂后的第21天,按照与前面测试实施例1相同的方式观察马唐的生长,从而得到如表4所示的结果。
如下结果由表4显而易见。市售助剂Citowett增强了啶嘧黄隆的除草效果。然而,烷氧基化甘油酯甚至在相同浓度下更加显著地增强了啶嘧黄隆的除草效果。
表4
测试实施例5
将马唐种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当马唐长至3叶阶段时,将规定量(15g a.i./公顷)的含有三氟啶黄隆作为活性成分的水分散性颗粒剂(商品名:Envoke,由Syngenta生产)用水稀释至相当于300升/公顷,以0.025重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。另外,为了进行对比,使用Citowett(与测试实施例3相同)替代烷氧基化甘油酯,以相同方式进行叶面施药。
在施用除草剂后的第21天,按照与前面测试实施例1相同的方式观察马唐的生长,从而得到如表5所示的结果。
如下结果由表5显而易见。市售助剂Citowett增强了三氟啶黄隆的除草效果。然而,烷氧基化甘油酯甚至在相同浓度下更加显著地增强了三氟啶黄隆的除草效果。
表5
测试实施例6
将马唐种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当马唐长至3叶阶段时,将按照前面实施例2配制的含有甲酰胺黄隆作为活性成分的规定量(20g a.i./公顷)的可湿性粉剂用水稀释至相当于300升/公顷,以0.05重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。另外,为了进行对比,使用Citowett(与测试实施例3相同)替代烷氧基化甘油酯,以相同方式进行叶面施药。
在施用除草剂后的第21天,按照与前面测试实施例1相同的方式观察马唐的生长,从而得到如表6所示的结果。
如下结果由表6显而易见。市售助剂Citowett增强了甲酰胺黄隆的除草效果。然而,烷氧基化甘油酯甚至在相同浓度下更加显著地增强了甲酰胺黄隆的除草效果。
表6
测试实施例7
将苘麻种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当苘麻长至3叶阶段时,将按照前面实施例3配制的含有三氟甲黄隆作为活性成分的规定量(20 g a.i./公顷)的可湿性粉剂用水稀释至相当于300升/公顷,以0.05重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。
在施用除草剂后的第21天,按照与前面测试实施例1相同的方式观察苘麻的生长,从而得到如表7所示的结果。
如下结果由表7显而易见。烷氧基化甘油酯以与前述测试实施例相同的方式显著增强了三氟甲黄隆的除草效果。
表7
测试实施例8
将马唐种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当马唐长至3叶阶段时,将含有玉嘧黄隆作为活性成分的规定量(5ga.i./公顷)的水分散性颗粒剂(商品名:TITUS,由Du Pont生产)用水稀释至相当于300升/公顷,以0.05重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。另外,为了进行对比,使用Citowett(与测试实施例3相同)替代烷氧基化甘油酯,以相同方式进行叶面施药。
在施用除草剂后的第21天,按照与前面测试实施例1相同的方式观察马唐的生长,从而得到如表8所示的结果。
如下结果由表8显而易见。市售助剂Citowett增强了玉嘧黄隆的除草效果。然而,烷氧基化甘油酯甚至在相同浓度下更加显著地增强了玉嘧黄隆的除草效果。
表8
测试实施例9
将马唐种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当马唐长至3.3叶阶段时,将按照前面实施例1配制的含有烟黄隆作为活性成分的规定量(35ga.i./公顷)的水分散性颗粒剂用水稀释至相当于300升/公顷,以0.01重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。另外,为了进行对比,使用Frigate(与测试实施例1相同)替代烷氧基化甘油酯,以相同方式进行叶面施药。
在施用除草剂后的第22天,按照与前面测试实施例1相同的方式观察马唐的生长,从而得到如表9所示的结果。
如下结果由表9显而易见。市售助剂Frigate增强了烟黄隆的除草效果。然而,烷氧基化甘油酯甚至在相同浓度下更加显著地增强了烟黄隆的除草效果。
表9
测试实施例10
将马唐种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当马唐长至3.3叶阶段时,将按照前面实施例1配制的含有烟黄隆作为活性成分的规定量(30ga.i./公顷)的水分散性颗粒剂用水稀释至相当于300升/公顷,以0.01重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。另外,为了进行对比,使用Citowett(与测试实施例3相同)替代烷氧基化甘油酯,以相同方式进行叶面施药。
在施用除草剂后的第22天,按照与前面测试实施例1相同的方式观察马唐的生长,从而得到如表10所示的结果。
如下结果由表10显而易见。市售助剂Citowett没有增强烟黄隆的除草效果。然而,烷氧基化甘油酯甚至在相同浓度下更加显著地增强了烟黄隆的除草效果。
表10
测试实施例11
将马唐种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当马唐长至3.3叶阶段时,将按照前面实施例1配制的含有烟黄隆作为活性成分的规定量(30ga.i./公顷)的水分散性颗粒剂用水稀释至相当于300升/公顷,以0.02重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。另外,为了进行对比,使用Citowett(与测试实施例3相同)替代烷氧基化甘油酯,以相同方式进行叶面施药。
在施用除草剂后的第22天,按照与前面测试实施例1相同的方式观察马唐的生长,从而得到如表11所示的结果。
如下结果由表11显而易见。市售助剂Citowett没有增强烟黄隆的除草效果。然而,烷氧基化甘油酯甚至在相同浓度下更加显著地增强了烟黄隆的除草效果。
表11
测试实施例12
将稗种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当稗长至2叶阶段时,将按照前面实施例1配制的含有烟黄隆作为活性成分的规定量(1.5ga.i./公顷)的水分散性颗粒剂用水稀释至相当于300升/公顷,以0.3重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。另外,为了进行对比,使用Citowett(与测试实施例3相同)替代烷氧基化甘油酯,以相同方式进行叶面施药。
在施用除草剂后的第22天,按照与前面测试实施例1相同的方式观察稗的生长,从而得到如表12所示的结果。
如下结果由表12显而易见。市售助剂Citowett增强了烟黄隆的除草效果。然而,烷氧基化甘油酯甚至在相同浓度下更加显著地增强了烟黄隆的除草效果。
表12
测试实施例13
将稗种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当稗长至2叶阶段时,将按照前面实施例1配制的含有烟黄隆作为活性成分的规定量(1.5ga.i./公顷)的水分散性颗粒剂用水稀释至相当于300升/公顷,以0.2重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。另外,为了进行对比,使用Citowett(与测试实施例3相同)替代烷氧基化甘油酯,以相同方式进行叶面施药。
在施用除草剂后的第22天,按照与前面测试实施例1相同的方式观察稗的生长,从而得到如表13所示的结果。
如下结果由表13显而易见。市售助剂Citowett增强了烟黄隆的除草效果。然而,烷氧基化甘油酯甚至在相同浓度下更加显著地增强了烟黄隆的除草效果。
表13
测试实施例14
将稗种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当稗长至2叶阶段时,将按照前面实施例1配制的含有烟黄隆作为活性成分的规定量(1.5ga.i./公顷)的水分散性颗粒剂用水稀释至相当于300升/公顷,以0.1重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。另外,为了进行对比,使用Frigate(与测试实施例1相同)替代烷氧基化甘油酯,以相同方式进行叶面施药。
在施用除草剂后的第22天,按照与前面测试实施例1相同的方式观察稗的生长,从而得到如表14所示的结果。
如下结果由表14显而易见。市售助剂Frigate增强了烟黄隆的除草效果。然而,烷氧基化甘油酯甚至在相同浓度下更加显著地增强了烟黄隆的除草效果。
表14
测试实施例15
将稗种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当稗长至2叶阶段时,将按照前面实施例1配制的含有烟黄隆作为活性成分的规定量(3ga.i./公顷)的水分散性颗粒剂用水稀释至相当于300升/公顷,以0.1重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。另外,为了进行对比,使用Citowett(与测试实施例3相同)替代烷氧基化甘油酯,以相同方式进行叶面施药。
在施用除草剂后的第22天,按照与前面测试实施例1相同的方式观察稗的生长,从而得到如表15所示的结果。
如下结果由表15显而易见。市售助剂Citowett增强了烟黄隆的除草效果。然而,烷氧基化甘油酯甚至在相同浓度下更加显著地增强了烟黄隆的除草效果。
表15
测试实施例16
将马唐种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当马唐长至3叶阶段时,将按照前面实施例1配制的含有烟黄隆作为活性成分的规定量(18ga.i./公顷)的水分散性颗粒剂用水稀释至相当于300升/公顷,以预定浓度向其中加入烷氧基化甘油酯和螯合剂(柠檬酸或乙二胺四乙酸(EDTA))作为助剂,然后叶面施药。
在施用除草剂后的第22天,按照与前面测试实施例1相同的方式观察马唐的生长,从而得到如表16所示的结果。
如下结果由表16显而易见。烷氧基化甘油酯增强了烟黄隆的除草效果。然而,当还加入助剂时,尽管烷氧基化甘油酯和助剂的总量与单独加入的烷氧基化甘油酯的量相同,但烟黄隆的除草效果更加显著地增强。
表16
测试实施例17
将马唐种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当马唐长至3叶阶段时,将按照前面实施例1配制的含有烟黄隆作为活性成分的规定量(20ga.i./公顷)的水分散性颗粒剂用水稀释至相当于300升/公顷,以0.025重量%的浓度向其中加入烷氧基化甘油酯,然后叶面施药。另外,为了进行对比,使用Citowett(与测试实施例3相同)替代烷氧基化甘油酯,以相同方式进行叶面施药。
在施用除草剂后的第21天,按照与前面测试实施例1相同的方式观察马唐的生长,从而得到如表17所示的结果。
如下结果由表17显而易见。市售助剂Citowett增强烟黄隆的除草效果。然而,烷氧基化甘油酯甚至在相同浓度下更加显著地增强了烟黄隆的除草效果。
表17
测试实施例18
将马唐种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当马唐长至3叶阶段时,将规定量(15ga.i./公顷)的按照前面实施例17中的配制方法得到的配制剂用水稀释至相当于300升/公顷,然后叶面施药。另外,为了进行对比,使用规定量(15ga.i./公顷)的含有烟黄隆作为活性成分的商品Onehope NYUZAI(由ISK BIOSCIENCES K.K.生产),以相同方式进行叶面施药。
在施用除草剂后的第21天,按照与前面测试实施例1相同的方式观察马唐的生长,从而得到如表18所示的结果。
如下结果由表18显而易见。即使在其剂量(15ga.i./公顷)低于Onehope NYUZAI标准剂量下,含有烷氧基化甘油酯的本发明基于油的悬浮剂仍然具有显著的除草效果。
表18
配制剂 | 生长抑制比(%) | |
本发明 | 实施例17 | 72 |
对照 | Onehope NYUZAI | 48 |
测试实施例19
将马唐种子播种于装有旱地土壤的1/1,000,000公顷的盆中,在温室中生长。当马唐长至3叶阶段时,将按照前面实施例1配制的含有烟黄隆作为活性成分的规定量(20ga.i./公顷)的水分散性颗粒剂用水稀释至相当于300升/公顷,在规定浓度下向其中加入烷氧基化甘油酯和含氮肥料(商品名:ANBLA,由Sankyo Co.,Ltd.生产,氨氮∶水溶性磷酸∶水溶性钾=4∶30∶16),然后叶面施药。
在施用除草剂后的第21天,按照与前面测试实施例1相同的方式观察马唐的生长,从而得到如表19所示的结果。
如下结果由表19显而易见。烷氧基化甘油酯增强了烟黄隆的除草效果。然而,当加入含氮肥料时,烟黄隆的除草效果进一步增强。
表19
Claims (10)
1.一种借助烷氧基化甘油酯增强除草磺酰脲化合物或其盐的除草效果的方法,其包括使用重量比为2∶1-1∶600的除草磺酰脲化合物或其盐和烷氧基化甘油酯。
3.根据权利要求1的方法,其中烷氧基化甘油酯是至少一种选自如下的烷氧基化甘油酯:聚氧乙烯氢化蓖麻油、聚氧乙烯甘油基单硬脂酸酯、聚氧乙烯蓖麻油、聚氧乙烯甘油基三异硬脂酸酯、聚氧乙烯甘油基单异硬脂酸酯、聚氧乙烯甘油基三硬脂酸酯、聚氧乙烯甘油基二硬脂酸酯、聚氧乙烯甘油基三油酸酯、聚氧乙烯氢化蓖麻油单异硬脂酸酯、聚氧乙烯氢化蓖麻油三异硬脂酸酯、聚氧乙烯氢化蓖麻油单月桂酸酯、聚氧乙烯1,1,1-三羟甲基丙烷三硬脂酸酯、聚氧乙烯1,1,1-三羟甲基丙烷三肉豆蔻酸酯、聚氧乙烯1,1,1-三羟甲基丙烷二硬脂酸酯、聚氧乙烯1,1,1-三羟甲基丙烷三异硬脂酸酯、聚氧乙烯氢化蓖麻油焦谷氨酸异硬脂酸酯和聚氧乙烯甘油基焦谷氨酸异硬脂酸酯。
4.根据权利要求3的方法,其中烷氧基化甘油酯是至少一种选自如下的烷氧基化甘油酯:聚氧乙烯氢化蓖麻油、聚氧乙烯甘油基三异硬脂酸酯、聚氧乙烯甘油基单异硬脂酸酯、聚氧乙烯1,1,1-三羟甲基丙烷三异硬脂酸酯、聚氧乙烯氢化蓖麻油焦谷氨酸异硬脂酸酯和聚氧乙烯甘油基焦谷氨酸异硬脂酸酯。
5.根据权利要求1的方法,其中除草磺酰脲化合物或其盐是至少一种选自如下的除草磺酰脲化合物或其盐:磺氨黄隆、四唑黄隆、苄嘧黄隆、氯嘧黄隆、绿黄隆、醚黄隆、环丙黄隆、胺苯黄隆、乙氧嘧黄隆、啶嘧黄隆、氟吡磺隆、氟啶黄隆、甲酰胺黄隆、吡氯黄隆、啶咪黄隆、碘黄隆、甲磺胺黄隆、甲黄隆、烟黄隆、环丙氧黄隆、氟嘧黄隆、氟丙黄隆、吡嘧黄隆、玉嘧黄隆、嘧黄隆、乙黄黄隆、噻黄隆、醚苯黄隆、苯黄隆、三氟啶黄隆、氟胺黄隆和三氟甲黄隆。
6.根据权利要求5的方法,其中除草磺酰脲化合物或其盐是至少一种选自啶嘧黄隆、甲酰胺黄隆、烟黄隆、玉嘧黄隆、三氟啶黄隆和三氟甲黄隆的除草磺酰脲化合物或其盐。
7.根据权利要求1的方法,其还含有一种或多种其它除草化合物。
8.根据权利要求1的方法,其还含有助剂。
9.根据权利要求1的方法,其还含有一种或多种其它除草化合物以及助剂。
10.根据权利要求8或9的方法,其中助剂是螯合剂和/或含氮肥料。
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109042706A (zh) * | 2018-07-23 | 2018-12-21 | 安徽华星化工有限公司 | 一种烟嘧磺隆水分散粒剂及其制备方法 |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2472806A1 (en) | 2004-05-18 | 2005-11-18 | Petro-Canada | Compositions and methods for treating turf insect pests and diseases such as fungal infestations |
CN101828569B (zh) * | 2004-09-17 | 2013-03-06 | 石原产业株式会社 | 除草剂组合物 |
KR101387815B1 (ko) * | 2005-02-21 | 2014-04-21 | 고유 아그리 가부시키가이샤 | 제초제 조성물 |
US7981839B2 (en) | 2005-03-14 | 2011-07-19 | Ishihara Sangyo Kaisha, Ltd. | Herbicidal suspension |
UA87198C2 (ru) * | 2005-03-14 | 2009-06-25 | Ишигара Сангйо Каиша, Лтд. | Гербицидная суспензия и способ борьбы с нежелательными растениями или ингибирования их роста |
CN102388902B (zh) * | 2006-03-02 | 2014-06-04 | 石原产业株式会社 | 固体除草组合物 |
EP1996547A2 (en) * | 2006-03-17 | 2008-12-03 | Croda, Inc. | Amine/amide-functionalized lipophiles |
JP5122841B2 (ja) * | 2006-03-24 | 2013-01-16 | 石原産業株式会社 | 除草組成物 |
US9357768B2 (en) | 2006-10-05 | 2016-06-07 | Suncor Energy Inc. | Herbicidal composition with increased herbicidal efficacy |
US20080108537A1 (en) * | 2006-11-03 | 2008-05-08 | Rees Wayne M | Corrosion inhibitor system for mildly acidic to ph neutral halogen bleach-containing cleaning compositions |
TW200843642A (en) * | 2007-03-08 | 2008-11-16 | Du Pont | Liquid sulfonylurea herbicide formulations |
ES2619731T3 (es) | 2008-06-26 | 2017-06-26 | Suncor Energy Inc. | Formulación fungicida para hierba de césped mejorada con pigmento |
WO2010105047A2 (en) * | 2009-03-11 | 2010-09-16 | Monsanto Technology Llc | Herbicidal formulations comprising glyphosate and alkoxylated glycerides |
RU2440731C2 (ru) * | 2010-02-24 | 2012-01-27 | Юрий Аглямович Гарипов | Суспензионный концентрат гербицидной композиции и способ его получения |
CA2810578C (en) | 2010-09-09 | 2016-08-30 | Suncor Energy Inc. | Synergistic paraffinic oil and boscalid fungicides |
TWI510190B (zh) | 2010-11-26 | 2015-12-01 | Ishihara Sangyo Kaisha | 除草組成物 |
JP5927007B2 (ja) * | 2011-04-11 | 2016-05-25 | 石原産業株式会社 | 除草組成物 |
CA2836819C (en) | 2011-06-03 | 2017-11-21 | Suncor Energy Inc. | Paraffinic oil-in-water emulsions for controlling infection of crop plants by fungal pathogens |
RU2466128C1 (ru) * | 2011-07-26 | 2012-11-10 | Владимир Веняминович Андронников | Способ получения гранулированного водорастворимого гербицидного препарата на основе диэтилэтаноламинных и щелочных солей арилсульфонилмочевин |
MX2015014010A (es) | 2013-04-03 | 2016-07-08 | Fmc Corp | Suspoemulsion de fomesafen y flutiacet-metilo. |
RU2584434C2 (ru) * | 2014-05-06 | 2016-05-20 | Общество с ограниченной ответственностью Малое инновационное предприятие "Кубанские агротехнологии" | Гербицидная композиция и способ повышения эффективности действия гербицида на основе глифосата |
CN105935056B (zh) * | 2015-03-02 | 2018-06-15 | 四川利尔作物科学有限公司 | 除草组合物及其应用 |
US11384032B2 (en) | 2016-05-12 | 2022-07-12 | Verdesian Life Sciences, U.S., Llc | Compositions for controlling enzyme-induced urea decomposition |
CR20190051A (es) * | 2016-07-06 | 2019-05-03 | Crop Enhancement Inc | Recubrimientos no tóxicos para aplicaciones agrícolas |
CN106818827A (zh) * | 2016-12-15 | 2017-06-13 | 新昌县奥而特农业科技有限公司 | 一种除草剂组合物及其应用 |
US11261136B2 (en) | 2017-03-28 | 2022-03-01 | Verdesian Life Sciences U.S., Llc | Triarylmethane compounds for controlling enzyme-induced urea decomposition |
CN109287632A (zh) * | 2018-09-26 | 2019-02-01 | 广西田园生化股份有限公司 | 一种油基农药制剂增效剂组合物及其应用 |
MX2021009954A (es) | 2019-02-19 | 2021-12-10 | Gowan Company L L C | Composiciones liquidas estables y metodos para usar las mismas. |
CA3201292A1 (en) * | 2020-11-27 | 2022-06-02 | Nouryon Chemicals International B.V. | Liquid agrochemical composition |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1032729C (zh) * | 1992-09-10 | 1996-09-11 | 山西省农业科学院蔬菜研究所 | 种子包衣剂 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2569342B2 (ja) | 1987-10-22 | 1997-01-08 | 石原産業株式会社 | 除草懸濁状組成物 |
CA2059450A1 (en) | 1991-01-24 | 1992-07-25 | Nobuyuki Sakashita | Subsituted pyridinesulfonamide compound or its salt, process for preparing the same, and herbicide containing the same |
EP0554015B1 (en) * | 1992-01-28 | 1995-03-22 | Ishihara Sangyo Kaisha, Ltd. | Chemically stabilized herbicidal oil-based suspension |
ATE171841T1 (de) | 1992-11-18 | 1998-10-15 | Ishihara Sangyo Kaisha | Verfahren zur steigerung der heroiziden wirksamkeit und herbizeiden zusammensetzungen mit gesteigerter wirksamkeit |
DE69423242T2 (de) * | 1994-05-20 | 2000-09-07 | Kao Corp., Tokio/Tokyo | Herbizide zusammensetzung |
US5830827A (en) * | 1995-09-21 | 1998-11-03 | Ishihara Sangyo Kaisha, Ltd. | Granular herbicidal composition comprising flazasulfuron and a sulfosuccinate or benzoate stabilizer |
DE19701123B4 (de) | 1996-02-06 | 2008-12-24 | Basf Se | Verwendung einer Mischung zur Herstellung pestizider Pflanzenschutzmittel |
US5731264A (en) | 1996-10-17 | 1998-03-24 | Isp Investments Inc. | Stabilized liquid emulsifiable concentrate for a sulfonyl or sulfamoylurea herbicide |
CN1325269B (zh) * | 1998-11-04 | 2010-04-21 | 辛根塔参与股份公司 | 除草组合物 |
-
2004
- 2004-06-30 WO PCT/JP2004/009598 patent/WO2005009132A1/en active Application Filing
- 2004-06-30 PL PL04747067.9T patent/PL1651042T3/pl unknown
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- 2004-06-30 BR BRPI0412932-6A patent/BRPI0412932A/pt not_active Application Discontinuation
- 2004-06-30 US US10/562,980 patent/US8575067B2/en active Active
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Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1032729C (zh) * | 1992-09-10 | 1996-09-11 | 山西省农业科学院蔬菜研究所 | 种子包衣剂 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109042706A (zh) * | 2018-07-23 | 2018-12-21 | 安徽华星化工有限公司 | 一种烟嘧磺隆水分散粒剂及其制备方法 |
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US8575067B2 (en) | 2013-11-05 |
EP1651042B1 (en) | 2016-04-27 |
MXPA06000924A (es) | 2006-03-30 |
CN1829440A (zh) | 2006-09-06 |
RU2006105643A (ru) | 2006-08-10 |
HUE029041T2 (hu) | 2017-01-30 |
CN101390520A (zh) | 2009-03-25 |
ES2570984T3 (es) | 2016-05-23 |
BRPI0412932A (pt) | 2006-09-26 |
EP1651042A1 (en) | 2006-05-03 |
WO2005009132A1 (en) | 2005-02-03 |
PL1651042T3 (pl) | 2016-09-30 |
RU2337549C2 (ru) | 2008-11-10 |
CA2531213C (en) | 2013-02-19 |
US20060154824A1 (en) | 2006-07-13 |
CA2531213A1 (en) | 2005-02-03 |
AR045918A1 (es) | 2005-11-16 |
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