CN100580025C - 用地沟油及废弃动植物油制备环氧增塑剂的方法 - Google Patents
用地沟油及废弃动植物油制备环氧增塑剂的方法 Download PDFInfo
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- CN100580025C CN100580025C CN200710020438A CN200710020438A CN100580025C CN 100580025 C CN100580025 C CN 100580025C CN 200710020438 A CN200710020438 A CN 200710020438A CN 200710020438 A CN200710020438 A CN 200710020438A CN 100580025 C CN100580025 C CN 100580025C
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- epoxy plasticizer
- waste oils
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- 239000004593 Epoxy Substances 0.000 title claims abstract description 32
- 239000004014 plasticizer Substances 0.000 title claims abstract description 28
- 238000004519 manufacturing process Methods 0.000 title abstract description 9
- 239000010828 animal waste Substances 0.000 title 1
- 235000013311 vegetables Nutrition 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 111
- 239000003054 catalyst Substances 0.000 claims abstract description 47
- 238000005886 esterification reaction Methods 0.000 claims abstract description 29
- 230000032050 esterification Effects 0.000 claims abstract description 28
- 239000003921 oil Substances 0.000 claims abstract description 26
- 239000007787 solid Substances 0.000 claims abstract description 25
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000011973 solid acid Substances 0.000 claims abstract description 21
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000005406 washing Methods 0.000 claims abstract description 9
- 239000003513 alkali Substances 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims description 37
- 239000002699 waste material Substances 0.000 claims description 26
- 235000014593 oils and fats Nutrition 0.000 claims description 25
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 24
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 20
- 238000006735 epoxidation reaction Methods 0.000 claims description 19
- 238000003756 stirring Methods 0.000 claims description 18
- 238000005809 transesterification reaction Methods 0.000 claims description 18
- 239000002585 base Substances 0.000 claims description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 16
- 239000004519 grease Substances 0.000 claims description 13
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 10
- 235000019253 formic acid Nutrition 0.000 claims description 10
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 8
- 235000011187 glycerol Nutrition 0.000 claims description 8
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 8
- 238000004821 distillation Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 238000005119 centrifugation Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 230000018044 dehydration Effects 0.000 claims description 6
- 238000006297 dehydration reaction Methods 0.000 claims description 6
- -1 emits lower floor Chemical compound 0.000 claims description 6
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 4
- 230000035484 reaction time Effects 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 2
- 150000002910 rare earth metals Chemical class 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- 235000019198 oils Nutrition 0.000 abstract description 17
- 239000002253 acid Substances 0.000 abstract description 8
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 2
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 abstract 2
- 239000010775 animal oil Substances 0.000 abstract 1
- 239000012467 final product Substances 0.000 abstract 1
- 230000001939 inductive effect Effects 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract 1
- 239000008158 vegetable oil Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 5
- 239000004902 Softening Agent Substances 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 230000009466 transformation Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000004062 sedimentation Methods 0.000 description 4
- 235000012424 soybean oil Nutrition 0.000 description 4
- 239000003549 soybean oil Substances 0.000 description 4
- 208000031968 Cadaver Diseases 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 150000004702 methyl esters Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- OYHQOLUKZRVURQ-HZJYTTRNSA-M 9-cis,12-cis-Octadecadienoate Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O OYHQOLUKZRVURQ-HZJYTTRNSA-M 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 230000001458 anti-acid effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229940049918 linoleate Drugs 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
Landscapes
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
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CN200710020438A CN100580025C (zh) | 2007-02-27 | 2007-02-27 | 用地沟油及废弃动植物油制备环氧增塑剂的方法 |
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CN200710020438A CN100580025C (zh) | 2007-02-27 | 2007-02-27 | 用地沟油及废弃动植物油制备环氧增塑剂的方法 |
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CN101029177A CN101029177A (zh) | 2007-09-05 |
CN100580025C true CN100580025C (zh) | 2010-01-13 |
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CN200710020438A Expired - Fee Related CN100580025C (zh) | 2007-02-27 | 2007-02-27 | 用地沟油及废弃动植物油制备环氧增塑剂的方法 |
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Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101372539B (zh) * | 2008-07-31 | 2011-07-06 | 浙江嘉澳环保科技股份有限公司 | 一种利用废油及油脚生产环保型增塑剂的方法 |
CN101343380B (zh) * | 2008-09-02 | 2011-06-01 | 山东蓝帆塑胶股份有限公司 | 一种制备增塑剂的方法 |
CN101705155A (zh) * | 2009-11-07 | 2010-05-12 | 青岛福瑞斯生物能源科技开发有限公司 | 一种利用废弃油脂工业化制备生物柴油的方法 |
CN101914219B (zh) * | 2010-07-26 | 2012-09-05 | 江阴市向阳科技有限公司 | 一种复合环氧增塑剂的制备方法 |
CN102344856A (zh) * | 2010-07-28 | 2012-02-08 | 肖连朝 | 一种利用废植物油脂制备增塑剂环氧脂肪酸甲酯的工艺方法 |
CN102161938B (zh) * | 2011-03-25 | 2013-01-02 | 河北金谷油脂科技有限公司 | 一种用地沟油生产环氧脂肪酸甲酯的方法 |
CN102250688B (zh) * | 2011-06-21 | 2014-12-03 | 广州市新锦龙实业有限公司 | 高速动态分离环氧大豆油的方法 |
CN103103745A (zh) * | 2011-11-10 | 2013-05-15 | 天津三吉和盛科技有限公司 | 新型节能、环保毛纺专用和毛油及其制备方法 |
CN103361186B (zh) * | 2012-03-30 | 2015-03-18 | 中国石油化工股份有限公司 | 一种生物柴油生产增塑剂的方法 |
CN102876465A (zh) * | 2012-09-07 | 2013-01-16 | 宝林 | 利用餐厨废弃油脂制备生物柴油的方法 |
CN102942995B (zh) * | 2012-12-03 | 2013-12-11 | 浙江嘉澳环保科技股份有限公司 | 一种植物油分离与改性的方法 |
CN103013675A (zh) * | 2012-12-18 | 2013-04-03 | 石河子大学 | 一种环氧地沟油增塑pvc的配方 |
CN103193933B (zh) * | 2013-03-29 | 2015-07-08 | 宁波市江北成达色母粒有限公司 | 一种基于地沟油的大分子增塑剂的制备方法 |
CN103435870A (zh) * | 2013-09-04 | 2013-12-11 | 沈阳化工大学 | 餐饮废油制备橡胶增塑剂的方法 |
CN103773609A (zh) * | 2013-10-29 | 2014-05-07 | 尚诚德 | 一种利用地沟油制备塑料增塑剂的方法 |
CN103642079B (zh) * | 2013-12-04 | 2015-09-30 | 沈阳化工大学 | 利用地沟油制备橡胶增塑剂的方法 |
CN103834061B (zh) * | 2014-02-26 | 2015-12-02 | 四川大学 | 低品质动植物油改性及深度环氧化制备环保型增塑剂的方法 |
CN104592171B (zh) * | 2015-01-21 | 2017-01-04 | 吴俊荣 | 环氧脂肪酸甲酯的生产方法 |
CN104557796B (zh) * | 2015-01-21 | 2016-06-29 | 吴俊荣 | 环氧脂肪酸甲酯的制备方法 |
US10093636B2 (en) | 2016-08-05 | 2018-10-09 | Cpc Corporation, Taiwan | Method for synthesizing bio-plasticizers using acidic ionic liquids as catalysts |
CN106519081B (zh) * | 2016-09-22 | 2018-06-26 | 深圳立山环保材料有限公司 | 一种环氧类增塑剂及其制备方法 |
CN106433153A (zh) * | 2016-11-10 | 2017-02-22 | 滁州思达机电有限责任公司 | 一种配电设备塑料外壳专用增塑剂的制备方法 |
CN108440454A (zh) * | 2018-05-31 | 2018-08-24 | 江苏向阳科技有限公司 | 一种基于微流场反应技术的环保型环氧增塑剂的制备方法 |
CN109369574A (zh) * | 2018-09-14 | 2019-02-22 | 许昌鑫瑞德化工科技有限公司 | 一种改性动植物油的加工方法 |
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2007
- 2007-02-27 CN CN200710020438A patent/CN100580025C/zh not_active Expired - Fee Related
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